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    • 2. 发明授权
    • Resist composition and method of forming resist pattern
    • 抗蚀剂图案的抗蚀剂组成和方法
    • US09405200B2
    • 2016-08-02
    • US13624639
    • 2012-09-21
    • Tokyo Ohka Kogyo Co., Ltd.
    • Tsuyoshi NakamuraJiro YokoyaHiroaki ShimizuHideto Nito
    • G03F7/004G03F7/38G03F7/20G03F7/038G03F7/039G03F7/075
    • G03F7/38G03F7/004G03F7/0045G03F7/0046G03F7/0382G03F7/0397G03F7/0755G03F7/0758G03F7/20
    • A method of forming a resist pattern, including: a step (1) in which a resist film is formed by coating a resist composition including a base component (A) that exhibits increased solubility in an alkali developing solution, a photo-base generator component (C) that generates a base upon exposure, an acid supply component (Z) and a compound (F) containing at least one selected from the group consisting of a fluorine atom and a silicon atom and containing no acid decomposable group which exhibits increased polarity by the action of acid on a substrate; a step (2) in which the resist film is subjected to exposure; a step (3) in which baking is conducted after the step (2); and a step (4) in which the resist film is subjected to an alkali development, thereby forming a negative-tone resist pattern, and a resist composition used in the step (1).
    • 一种形成抗蚀剂图案的方法,包括:步骤(1),其中通过涂覆抗蚀剂组合物形成抗蚀剂膜,所述抗蚀剂组合物包括在碱性显影液中表现出增加的溶解度的碱性组分(A),光产生剂组分 (C),酸性供给成分(Z)和含有选自氟原子和硅原子中的至少一种的化合物(F),并且不含显示出极性增加的酸分解基团 通过酸在基底上的作用; 其中抗蚀剂膜被曝光的步骤(2); 步骤(3),其中在步骤(2)之后进行烘烤; 以及步骤(4),其中抗蚀剂膜经受碱显影,从而形成负色调抗蚀剂图案,以及在步骤(1)中使用的抗蚀剂组合物。
    • 4. 发明申请
    • Chemical amplification type positive resist composition, resist laminated material, resist pattern forming method and method of manufacturing semiconductor device
    • 化学放大型正型抗蚀剂组合物,抗蚀剂层压材料,抗蚀剂图案形成方法和制造半导体器件的方法
    • US20050112498A1
    • 2005-05-26
    • US11028456
    • 2005-01-03
    • Kazuyuki NittaTakeyoshi MimuraSatoshi ShimataniWaki OkuboTatsuya Matsumi
    • Kazuyuki NittaTakeyoshi MimuraSatoshi ShimataniWaki OkuboTatsuya Matsumi
    • G03F7/039G03F7/11G03C1/76
    • G03F7/0392G03F7/11Y10S430/106
    • The present invention provides a resist composition comprising (A) polyhydroxystyrene in which at least a portion of hydrogen atoms of hydroxyl groups are substituted with an acid-dissociable dissolution inhibiting group, and the solubility in an alkali solution of the polyhydroxystyrene increasing when the acid-dissociable dissolution inhibiting group is eliminated by an action of an acid, and (B) a component capable of generating an acid by irradiation with radiation, wherein a retention rate of the acid-dissociable dissolution inhibiting group of the component (A) after a dissociation test using hydrochloric acid is 40% or less, and also provides a chemical amplification type positive resist composition which contains polyhydroxystyrene in which at least a portion of hydrogen atoms of hydroxyl groups are substituted with a lower alkoxy-alkyl group having a straight-chain or branched alkoxy group, and the solubility in an alkali solution of the polyhydroxystyrene increasing when the lower alkoxy-alkyl group is eliminated by an action of an acid, in place of the component (A).
    • 本发明提供了一种抗蚀剂组合物,其包含(A)聚羟基苯乙烯,其中羟基的至少一部分氢原子被酸解离的溶解抑制基团取代,并且当所述多羟基苯乙烯的碱溶液中的溶解度增加时, 通过酸的作用除去可离解的溶解抑制基团,和(B)通过辐射照射产生酸的成分,其中解离后的成分(A)的酸解离溶解抑制基团的保留率 使用盐酸的试验为40%以下,并且还提供了含有聚羟基苯乙烯的化学扩增型正性抗蚀剂组合物,其中羟基的至少一部分氢原子被具有直链的低级烷氧基 - 烷基取代, 支链烷氧基,并且当聚羟基苯乙烯的碱溶液中的溶解度增加时 低级烷氧基 - 烷基通过酸的作用代替组分(A)而被除去。