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    • 86. 发明公开
    • Void-free low K dielectric composite layer between metal lines in integrated circuit structure
    • 与用于集成电路的结构的低介电常数无气泡的复合电介质层
    • EP1094508A2
    • 2001-04-25
    • EP00122684.4
    • 2000-10-18
    • LSI LOGIC CORPORATION
    • Catabay, Wilbur G.Schinella, Richard
    • H01L21/316
    • H01L21/02126H01L21/02131H01L21/02164H01L21/022H01L21/02211H01L21/02274H01L21/3146H01L21/31629H01L21/76801
    • A composite layer of low k silicon oxide dielectric material is formed on an oxide layer of an integrated circuit structure on a semiconductor substrate having closely spaced apart metal lines thereon. The composite layer of low k silicon oxide dielectric material exhibits void-free deposition properties in high aspect ratio regions between the closely spaced apart metal lines, deposition rates in other regions comparable to standard k silicon oxide, and reduced via poisoning characteristics. The composite layer of low k silicon oxide dielectric material is formed by depositing, in high aspect ratio regions between closely spaced apart metal lines, a first layer of low k silicon oxide dielectric material exhibiting void-free deposition properties until the resulting deposition of low k silicon oxide dielectric material reaches the level of the top of the metal lines on the oxide layer. A second layer of low k silicon oxide dielectric material, having a faster deposition rate than the first layer, is then deposited over the first layer up to the desired overall thickness of the low k silicon oxide dielectric layer. In a preferred embodiment, the steps to form the resulting composite layer of low k silicon oxide dielectric material are all carried out in a single vacuum processing apparatus without removal of the substrate from the vacuum apparatus.
    • 的低k氧化硅电介质材料制成的复合层是在上一集成电路结构的其上具有紧密间隔开的金属线的半导体基板上形成氧化物层。 的低k氧化硅介电材料的复合层表现出的沉积速率的紧密间隔开的金属线之间的高纵横比的区域,无空隙的沉积性质在与标准氧化k硅片,并且经由中毒特性降低等地区。 的低k氧化硅介电材料的复合层是由在高纵横比的区域上沉积FORMED之间紧密间隔开的金属线路,低介电常数的氧化硅介电材料的参展无空隙沉积性质直到低k的所得到的沉积的第一层 氧化硅的介电材料到达所述氧化物层上的金属线的顶部的水平。 的低k氧化硅的介电材料的第二层,具有更快的沉积速率比第一层,然后在所述第一层到所述的低k氧化硅电介质层的所需总厚度沉积。 在一个优选的实施方案中,步骤以形成的低k氧化硅的介电材料的所得复合层在单一的真空处理装置都被进行,而不去除所述真空装置用基板。
    • 87. 发明公开
    • Method for depositing fluorinated silica glass layers
    • Verfahren zum Auftragen fluorierter Silikaglas-Schichten
    • EP1081249A1
    • 2001-03-07
    • EP00119011.5
    • 2000-09-01
    • Applied Materials, Inc.
    • M'Saad, HichemTribula, DanaVellaikal, ManojDesai, SameerMoghadam, Farhad
    • C23C16/40C23C16/50H01L21/316
    • H01L21/02131C23C16/401H01L21/02211H01L21/02274H01L21/02304H01L21/02362H01L21/31629
    • A method of formation of a damascene FSG film with good adhesion to silicon nitride in an HDP-CVD system. Silane (SiH 4 ), silicon tetrafluoride (SiF 4 ), oxygen (O 2 ) and argon (Ar) are used as the reactant gases. SiH 4 , SiF 4 , and O 2 react to form the FSG. Ar is introduced to promote gas dissociation. All four gases are used for depositing most of the FSG film. SiH 4 is not used during deposition of the interfacial part of the FSG film. The interfacial part of the FSG film refers either to the topmost portion, if silicon nitride is to be deposited on top of the FSG or the bottom portion if the FSG is to be deposited on top of silicon nitride. Using SiH 4 with the SiF 4 tends to mitigate the destructive effects of SiF 4 throughout most of the deposition. By removing the SiH 4 from the deposition of the interfacial part of the FSG film less hydrogen is incorporated into the film in the interfacial region and adhesion to overlying or underlying silicon nitride is improved.
    • 在HDP-CVD系统中形成对氮化硅具有良好粘附性的镶嵌FSG膜的方法。 硅烷(SiH4),四氟化硅(SiF4),氧(O2)和氩(Ar)用作反应气体。 SiH4,SiF4和O2反应形成FSG。 引入Ar来促进气体分解。 所有四种气体都用于沉积大部分FSG膜。 在沉积FSG膜的界面部分期间不使用SiH4。 如果将FSG沉积在氮化硅的顶部,则FSG膜的界面部分指的是最高部分,如果氮化硅沉积在FSG或底部的顶部。 SiF4与SiF4一起使用可以减轻SiF4在大部分沉积过程中的破坏作用。 通过从FSG膜的界面部分的沉积中除去SiH 4,在界面区域中更少的氢被引入到膜中,并且改善了覆盖或下层氮化硅的粘附性。
    • 89. 发明公开
    • Silicon oxynitride cap for fluorinated silicate glass film in intermetal dielectric semiconductor fabrication
    • 硅氧烷基硝基氟化物氟化物玻璃纤维
    • EP0975017A2
    • 2000-01-26
    • EP99113533.6
    • 1999-07-06
    • SIEMENS AKTIENGESELLSCHAFT
    • Lee, Gill Yong
    • H01L21/314
    • H01L21/02131H01L21/0214H01L21/02211H01L21/02274H01L21/02304H01L21/02362H01L21/3145H01L21/31629H01L21/76801H01L21/76802H01L21/76829H01L23/3192H01L23/5329H01L2924/0002H01L2924/12044H01L2924/00
    • A semiconductor device and method of forming a patterned conductive layer on a semiconductor substrate are provided so as to prevent fluorine substance outflow from a fluorinated silicate glass (FSG) layer thereon and simultaneously so as to suppress back reflection of light waves into a photoresist layer during photolithographic processing. The substrate is coated in turn with a conductive layer, a dielectric (e.g., silicon dioxide) liner, a FSG layer, a silicon oxynitride layer preventing fluorine substance outflow therethrough from the FSG layer and also forming an antireflective coating (ARC), and a photoresist layer. The photoresist layer is exposed and developed to uncover pattern portions of the underlying silicon oxynitride layer. The uncovered pattern portions of the silicon oxynitride ARC layer and corresponding underlying portions of the FSG layer and dielectric liner are then removed, e.g., by,a single dry etching step, to expose pattern portions of the conductive layer for metallization. Upon metallization, the substrate is provided with a combination of the FSG layer and silicon oxynitride layer, in which the silicon oxynitride layer prevents fluorine substance outflow therethrough from the underlying FSG layer to an overlying conductive layer.
    • 提供半导体器件和在半导体衬底上形成图案化导电层的方法,以防止氟物质从其上的氟化硅酸盐玻璃(FSG)层流出,并同时抑制光波反射到光致抗蚀剂层中 光刻处理。 依次用导电层,电介质(例如,二氧化硅)衬垫,FSG层,氮氧化硅层涂覆衬底,防止氟物质从FSG层流出并形成抗反射涂层(ARC),以及 光致抗蚀剂层。 光致抗蚀剂层被曝光和显影以露出下面的氮氧化硅层的图案部分。 氧氮化硅ARC层的未覆盖图案部分和FSG层和电介质衬垫的相应的下面部分然后例如通过单次干蚀刻步骤被去除,以暴露用于金属化的导电层的图案部分。 在金属化时,基板设置有FSG层和氮氧化硅层的组合,其中氧氮化硅层防止氟物质从下面的FSG层流出到覆盖的导电层。