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    • 81. 发明申请
    • ELECTROTRANSPORT DEVICES, METHODS AND DRUG ELECTRODE ASSEMBLIES
    • 电子输送装置,方法和药物电极组件
    • US20090005824A1
    • 2009-01-01
    • US12163821
    • 2008-06-27
    • Steven J. ViscoYevgeniy S. NimonBruce Katz
    • Steven J. ViscoYevgeniy S. NimonBruce Katz
    • A61N1/18
    • A61N1/0448A61N1/0436A61N1/0444
    • A drug electrode assembly usefully employed in an electrotransport device for the delivery of drugs across a tissue surface includes an electrode, a drug reservoir which stores the drug (including an ionized (e.g., anionic) or neutrally charged drug species), and a liquid impermeable solid-state assist ion conducting barrier layer interposed between the electrode and the drug reservoir. The barrier layer can be a single-ion conductor of a specific (unique) species of ion called the assist ion. During drug delivery, the assist ion moves across the barrier layer into or out of the drug reservoir, and as the assist ion crosses the barrier layer/drug reservoir interphase, the drug species moves to the tissue surface. The assist ion can be, for example, sodium ions (Na+), and the electrode can be an electrode of the assist ion (i.e., a sodium electrode).
    • 有效地用于电传输装置中用于在组织表面递送药物的药物电极组件包括电极,储存药物的药物储存器(包括电离(例如阴离子)或中性带电药物))和不透液体 固态辅助离子传导阻挡层介于电极和药物储存器之间。 阻挡层可以是称为辅助离子的特定(独特)离子种类的单离子导体。 在药物递送期间,辅助离子穿过阻隔层进入或流出药物储存器,并且当辅助离子穿过阻挡层/药物储存器相间时,药物物质移动到组织表面。 辅助离子可以是例如钠离子(Na +),电极可以是辅助离子的电极(即钠电极)。
    • 89. 发明授权
    • Secondary cell using organosulfur/metal charge transfer materials as
positive electrode
    • 二次电池采用有机硫/金属电荷转移材料作为正电极
    • US5516598A
    • 1996-05-14
    • US281919
    • 1994-07-28
    • Steven J. ViscoJiro K. TakemotoMay-Ying Chu
    • Steven J. ViscoJiro K. TakemotoMay-Ying Chu
    • H01M10/36H01M4/60H01M4/86
    • H01M10/36H01M4/60
    • A novel battery cell is disclosed which is characterized by a metal-organosulfur positive electrode which has one or more metal-sulfur bonds wherein when the positive electrode is charged and discharged, the formal oxidation state of the metal is changed. The positive electrode has the general formula(M'.sup.z.spsp.+.sub.(c/z) [M.sub.q (RS.sub.y).sub.x.sup.c- ]).sub.nwhereinz=1 or 2; y=1 to 20; x=1 to 10; c=0 to 10; n.gtoreq.1; and q=1 to 10;wherein M' is a metal or other cation;wherein M is any multivalent metal, and when n is >1, can be a different multivalent metal in different repeat units of the polymeric metal-organosulfur materials;wherein R is an organic group having 1 to 20 carbon atoms comprising one or more organic moieties selected from the group consisting of aliphatic chains, aromatic rings, alicyclic rings and combinations of aliphatic chains, aromatic rings, and alicylic rings, with the proviso that R does not comprise fused aromatic rings; wherein said aliphatic chains, aromatic and alicyclic rings may include one or more oxygen, sulfur, silicon, phosphorous or nitrogen heteroatoms, and which may be substituted with one or more electron withdrawing groups; and wherein each aliphatic chain may be linear or branched, saturated or unsaturated; and wherein when n>1, R can be different in different repeat units of the polymeric materials. Gel, solid-state and liquid batteries using said novel positive electrode are also disclosed.
    • 公开了一种新型的电池单元,其特征在于具有一个或多个金属 - 硫键的金属 - 有机硫正极,其中当正极被充电和放电时,金属的形式氧化态改变。 正极具有通式(M'z +(c / z)[Mq(RSy)xc - ])n,其中z = 1或2; y = 1〜20; x = 1〜10; c = 0〜10; n> / = 1; q = 1〜10; 其中M'是金属或其它阳离子; 其中M是任何多价金属,并且当n大于1时,可以是聚合物金属 - 有机硫材料的不同重复单元中的不同多价金属; 其中R是含有1至20个碳原子的有机基团,其包含一个或多个选自脂族链,芳族环,脂环族和脂族链,芳族环和芳基环的组合的有机基团,条件是R 不包含稠合芳环; 其中所述脂族链,芳族和脂环族可以包括一个或多个氧,硫,硅,磷或氮杂原子,并且其可以被一个或多个吸电子基团取代; 并且其中每个脂族链可以是直链或支链,饱和或不饱和的; 并且其中当n> 1时,R可以在聚合物材料的不同重复单元中不同。 还公开了使用所述新型正电极的凝胶,固态和液体电池。