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81. 发明授权

US06183558B2 Method and apparatus for producing molecular film 有权
标题翻译：生产分子膜的方法和装置
公开(公告)号：US06183558B2
公开(公告)日：2001-02-06
申请号：US09294297
申请日：1999-04-19
申请人： Tadashi Otake , Norihisa Mino , Tohru Nakagawa , Mamoru Soga , Kazufumi Ogawa , Takaiki Nomura , Yasuo Takebe
发明人： Tadashi Otake , Norihisa Mino , Tohru Nakagawa , Mamoru Soga , Kazufumi Ogawa , Takaiki Nomura , Yasuo Takebe
IPC分类号： B05C108
CPC分类号： B82Y30/00 , B05D1/283 , B05D3/0486 , B82Y40/00
摘要： A method for forming a molecular film includes the steps of: coating a surface of a substrate having active hydrogen atoms on its surface with a coating solution containing a silane-based compound having at least one reactive group selected from the group consisting of a chloro group, an alkoxy group and an isocyanate group; and effecting an elimination reaction between the active hydrogen atoms on the surface of the substrate and reactive groups of the silane-based compound, thereby covalently bonding the silane-based compounds to the surface of the substrate. The substrate is supplied to a chamber in which an atmosphere is maintained at a low water vapor density. The surface of the substrate is coated with a coating solution containing the silane-based compound and a solvent by using a transfer element. A dehydrochlorination reaction is effected between the active hydrogen atoms and the chloro groups of the silane-based compounds. Thereafter, any coating solution containing unreacted silane-based compounds after coating is removed inside or outside the chamber.
摘要翻译：形成分子膜的方法包括以下步骤：用包含具有至少一个选自氯基团的反应性基团的硅烷基化合物的涂布溶液在其表面上涂覆具有活性氢原子的基材的表面，烷氧基和异氰酸酯基; 并且进行基板表面上的活性氢原子与硅烷类化合物的反应性基团之间的消除反应，从而将硅烷类化合物共价键合到基板的表面。将基板供给到气氛保持在低水蒸汽密度的室中。通过使用转印元件，将含有硅烷系化合物和溶剂的涂布液涂布在基材的表面上。在活性氢原子和硅烷基化合物的氯基之间进行脱氯化氢反应。此后，在室内或室外除去涂布后含有未反应的硅烷类化合物的任何涂布溶液。

82. 发明授权

US5981056A Chemically adsorbed film 失效
标题翻译：化学吸附膜
公开(公告)号：US5981056A
公开(公告)日：1999-11-09
申请号：US872185
申请日：1992-04-22
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
IPC分类号： B05D1/18 , C09D4/00 , B32B7/00
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C09D4/00 , Y10T428/261 , Y10T428/31612 , Y10T428/31663 , Y10T428/31667
摘要： According to the invention, a fluorine-based or siloxane-based chemical adsorbed film containing a fluorocarbon compound can be formed on a given substrate surface in a laminated state and through chemical bonds (i.e., covalent bonds) with the substrate, it is possible to obtain a laminated film which has satisfactory adhesion to the substrate, is substantially pin-hole free and is very thin. Further, since the outermost layer may be substituted by fluorocarbon groups or hydroxyl groups, it is possible to obtain a film which has excellent water- and oil-repelling properties or hydrophilic and oil-repelling properties and can replace fluorine-based coating films, thus improving the performance of products requiring a coating having a water- and oil-repelling resistant property, weather-resistant property, wear-resistant property and so forth which are desirable in electric products, vehicles, industrial devices and so forth.
摘要翻译：根据本发明，含氟碳化合物的氟系或硅氧烷系化学吸附膜可以在层叠状态的规定的基材表面上形成，并通过与基材的化学键（即共价键）形成，获得对基材具有令人满意的粘合性的层压膜，其基本上无针孔，并且非常薄。此外，由于最外层可以被碳氟基或羟基取代，所以可以获得具有优异的防水疏斥性或亲水性和拒油性能，并且可以代替氟基涂膜的膜提高了在电气产品，车辆，工业装置等中需要具有耐斥油性，耐油污性，耐候性，耐磨性等的涂层的产品的性能。

83. 发明授权

US5716704A Hydrophylic substrate and method of manufacturing the same 失效
标题翻译：亲水底物及其制造方法
公开(公告)号：US5716704A
公开(公告)日：1998-02-10
申请号：US716723
申请日：1996-09-23
申请人： Kazufumi Ogawa , Mamoru Soga , Norihisa Mino
发明人： Kazufumi Ogawa , Mamoru Soga , Norihisa Mino
IPC分类号： B05D1/18 , C08J7/04 , C09D4/00 , D06M10/00 , D06M15/643 , D06M23/00 , B32B9/00
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C08J7/047 , C09D4/00 , D06M10/00 , D06M15/643 , D06M23/005 , C08J2483/00 , Y10T428/252 , Y10T428/2918 , Y10T428/2933 , Y10T428/2962 , Y10T428/2964 , Y10T428/31623 , Y10T428/31663 , Y10T428/31678
摘要： According to the invention, a durable hydrophilic adsorbed film is formed on the surface of a substrate including metals, glass, plastics and the like in which the substrate has a surface layer containing hydroxyl groups or imino groups. The film is formed by covalently bonding chemical absorbents of silane groups containing a pluralilty of chloro groups to the substrate surfaces. The substrate 1 such as glass or nylon is dipped and held in a non-aqueous solution containing fluorocarbon groups and hydrocarbon groups containing chemical absorbents of silane groups containing a plurality of chloro goups including SiCl.sub.4, Cl.sub.3 SiOSiCl.sub.3, HSiCl.sub.3 or Cl.sub.3 SiOSiCl.sub.2 OSiCl.sub.3. After taking out the substrate 1 from the solution, drying it in a low moisture or substantially moistureless atmosphere to remove said non-aqueous solvents, the substrate is exposed to the air. A hydrophilic adsorbed ultra-thin film is thus formed by a dehydrochlorination reaction.
摘要翻译：根据本发明，在包括金属，玻璃，塑料等的基材的表面上形成耐久的亲水性吸附膜，其中基材具有含羟基或亚氨基的表面层。该膜通过将含有多个氯基团的硅烷基团的化学吸收剂共价键合到基底表面而形成。将诸如玻璃或尼龙的基底1浸渍并保持在含有碳氟化合物基团的非水溶液中，并且含有含有多个氯化物的硅烷基团的化学吸收剂的烃基包括SiCl 4，Cl 3 SiOSiCl 3，HSiCl 3或Cl 3 SiOSiCl 2 OSiCl 3。从溶液中取出基材1后，将其在低水分或基本无水的气氛中干燥以除去所述非水溶剂，将基材暴露于空气中。因此，通过脱氯化氢反应形成亲水吸附的超薄膜。

84. 发明授权

US5635246A Chemically adsorbed film and method of manufacturing the same 失效
标题翻译：化学吸附膜及其制造方法
公开(公告)号：US5635246A
公开(公告)日：1997-06-03
申请号：US443376
申请日：1995-05-17
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga
IPC分类号： B05D1/18 , C09D4/00 , B05D3/10
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C09D4/00 , Y10T428/261 , Y10T428/31612 , Y10T428/31663 , Y10T428/31667
摘要： According to the invention, a fluorine-based or siloxane-based chemical adsorbed film containing a fluorocarbon compound can be formed on a given substrate surface in a laminated state and through chemical bonds (i.e., covalent bonds) with the substrate, it is possible to obtain a laminated film which has satisfactory adhesion to the substrate, is substantially pin-hole free and is very thin. Further, since the outermost layer may be substituted by fluorocarbon groups or hydroxyl groups, it is possible to obtain a film which has excellent water- and oil-repelling properties or hydrophilic and oil-repelling properties and can replace fluorine-based coating films, thus improving the performance of products requiring a coating having a water- and oil-repelling resistant property, weather-resistant property, wear-resistant property and so forth which are desirable in electric products, vehicles, industrial devices and so forth.
摘要翻译：根据本发明，含氟碳化合物的氟系或硅氧烷系化学吸附膜可以在层叠状态的规定的基材表面上形成，并通过与基材的化学键（即共价键）形成，获得对基材具有令人满意的粘合性的层压膜，其基本上无针孔，并且非常薄。此外，由于最外层可以被碳氟基或羟基取代，所以可以获得具有优异的防水疏斥性或亲水性和拒油性能，并且可以代替氟基涂膜的膜提高了在电气产品，车辆，工业装置等中需要具有耐斥油性，耐油污性，耐候性，耐磨性等的涂层的产品的性能。

85. 发明授权

US5538762A Method of manufacturing a fluorocarbon-based coating film 失效
公开(公告)号：US5538762A
公开(公告)日：1996-07-23
申请号：US312185
申请日：1994-09-26
申请人： Kazufumi Ogawa , Mamoru Soga
发明人： Kazufumi Ogawa , Mamoru Soga
IPC分类号： B05D1/18 , B05D1/20 , B05D7/26 , C03C17/34 , C03C17/42 , C09D4/00 , C09D127/12 , C09D183/04 , B05D3/06
CPC分类号： C08J7/123 , B05D1/185 , B82Y30/00 , B82Y40/00 , C03C17/3405 , C03C17/42 , C09D183/04 , C09D4/00 , Y10T428/252 , Y10T428/31504 , Y10T428/3154 , Y10T428/31544 , Y10T428/31623 , Y10T428/31663 , Y10T428/31678
摘要： A method of contacting a substrate having a surface containing hydroxyl groups with a non-aqueous solution containing a material having a chrolosilyl group; washing if desired; coating the substrate with a non-aqueous solvent containing a compound having a fluorocarbon group and a chlorosilane group or a solvent containing a compound containing a fluorocarbon group and an alkoxysilane; and baking the substrate if necessary in order to form a fluorocarbon-based polymer coating film chemically bonded to the substrate surface. The hydroxyl groups on the substrate surface and chlorosilyl groups are reacted to form a thin film having a large number of silanol groups (--SiOH) capable of connecting the polymer coating film to the substrate to form a heat-, weather-, and wear-resistant film on various surfaces.

86. 发明授权

US5437894A Method of manufacturing a water- and oil-repelling film having surface irregularities 失效
标题翻译：制造具有表面凹凸的斥水斥油膜的方法
公开(公告)号：US5437894A
公开(公告)日：1995-08-01
申请号：US186117
申请日：1994-01-25
申请人： Kazufumi Ogawa , Mamoru Soga
发明人： Kazufumi Ogawa , Mamoru Soga
IPC分类号： B05D1/18 , C03C17/42 , C08J7/04 , C09D4/00 , C09D183/02 , C09D183/08 , B05D3/06
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C03C17/42 , C08J7/047 , C09D183/02 , C09D183/08 , C09D4/00 , C03C2217/42 , C03C2217/445 , C03C2217/47 , C03C2217/478 , C08J2483/00 , Y10T428/24355 , Y10T428/24372 , Y10T428/2438 , Y10T428/24388 , Y10T428/24421 , Y10T428/24521 , Y10T428/25 , Y10T428/252 , Y10T428/259 , Y10T428/265 , Y10T428/3154 , Y10T428/31544 , Y10T428/31663 , Y10T428/31667
摘要： A water- and oil-repelling adsorbing film formed on a material having active hydrogen such as hydroxyl group, imino group and amino group at the surface. This film is a chemically adsorbed film having surface irregularities exceeding 10 nanometers. It is directly or indirectly covalently bonded to the material surface and includes a monomolecular film or a polymer film with the molecules thereof containing a fluorocarbon group and a --Si-- bond. The surface irregularities which exceed the molecular level are at least either those formed on the material surface itself, those due to particles formed on the substrate surface or those due to particles present in the chemically adsorbed film.
摘要翻译：在表面具有羟基，亚氨基和氨基等具有活性氢的材料上形成的斥水斥油吸附膜。该膜是具有超过10纳米的表面凹凸的化学吸附膜。它直接或间接地共价结合到材料表面，并且包括单分子膜或聚合物膜，其分子含有氟碳基团和-Si-键。超过分子水平的表面不规则至少是在材料表面本身上形成的表面不规则，至少是由于在基材表面上形成的颗粒或由于存在于化学吸附膜中的颗粒引起的颗粒。

87. 发明授权

US5372851A Method of manufacturing a chemically adsorbed film 失效
标题翻译：化学吸附膜的制造方法
公开(公告)号：US5372851A
公开(公告)日：1994-12-13
申请号：US984478
申请日：1992-12-02
申请人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga , Hidetaka Higashino
发明人： Kazufumi Ogawa , Norihisa Mino , Mamoru Soga , Hidetaka Higashino
IPC分类号： B05D1/18 , B05D3/14 , B05D7/24 , C09D4/00 , C23C14/24
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , B82Y5/00 , C09D4/00 , B05D1/60 , B05D3/144
摘要： This invention aims to form uniformly and effectively an ultra thin chemical adsorbing film having an excellent water repellent property, oil repellent property, and contamination-proof property on the surface of a substrate by chemically adsorbing in a gas phase atmosphere. A chemically adsorbed film can be formed on any type of substrate and in a short time by chemically adsorbing a chlorosilane based surface-active agent on the surface of a substrate having active hydrogen groups. Further, a chemically adsorbed monomolecular film, or a polymer film, can be formed on any type of substrate and in a short time by forming a siloxane based monomolecular film or a polysiloxane adsorbed film in a gas atmosphere having a chlorosilane based surface-active agent having plurality of chlorosilyl groups.
摘要翻译：本发明旨在通过在气相气氛中化学吸附在基材表面上均匀有效地形成具有优异的防水性，防油性和耐污染性的超薄化学吸附膜。可以在任何类型的基材上形成化学吸附的膜，并且在短时间内通过在具有活性氢基团的基材的表面上化学吸附氯硅烷基表面活性剂。此外，可以在任何类型的基材上形成化学吸附的单分子膜或聚合物膜，并且在短时间内通过在具有氯硅烷基表面活性剂的气体气氛中形成硅氧烷基单分子膜或聚硅氧烷吸附膜具有多个氯甲硅烷基。

88. 发明授权

US5338579A Method of manufacturing a chemically adsorbed film 失效
标题翻译：化学吸附膜的制造方法
公开(公告)号：US5338579A
公开(公告)日：1994-08-16
申请号：US068533
申请日：1993-05-27
申请人： Kazufumi Ogawa , Mamoru Soga , Shinji Ozaki , Shigeo Ikuta
发明人： Kazufumi Ogawa , Mamoru Soga , Shinji Ozaki , Shigeo Ikuta
IPC分类号： B05D1/18 , C09D4/00 , B05D1/02
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C09D4/00
摘要： A method of manufacturing a chemically adsorbed film, which can efficiently provide a water and oil repelling and anti-contaminating ultra thin film with uniform thickness by spraying a solution comprising a chemical adsorbent on a substrate surface having active hydrogen groups in a dry atmosphere. A chemically adsorbed film can be formed by spraying a chlorosilane-based surface active agent on a substrate surface having active hydrogen groups such as hydroxyl, imino groups or the like. After forming a siloxane-based monomolecular layer or polysiloxane layer beforehand by spraying a chlorosilane compound or a solution comprising a chlorosilane compound on a substrate surface, a chemically adsorbed monomolecular or polymer layer can be formed by spraying a solution comprising a chlorosilane-based surface active agent. The film can be formed in a short time without being inhibited by the shapes and sizes of substrates.
摘要翻译：一种制造化学吸附膜的方法，其可以通过在干燥气氛中将含有化学吸附剂的溶液喷涂在具有活性氢基团的基材表面上，从而有效地提供具有均匀厚度的防水排斥和抗污染的超薄膜。可以通过在具有活性氢基团的基底表面如羟基，亚氨基等上喷射氯硅烷基表面活性剂来形成化学吸附的膜。通过将氯硅烷化合物或包含氯硅烷化合物的溶液喷涂在基材表面上而预先形成硅氧烷基单分子层或聚硅氧烷层之后，可以通过喷雾包含氯硅烷基表面活性剂的溶液来形成化学吸附的单分子或聚合物层代理商该膜可以在短时间内形成，而不受基板的形状和尺寸的抑制。

89. 发明授权

US5293209A Electrophotographic apparatus containing a chemical adsorption film coating 失效
标题翻译：含有化学吸附膜涂层的电子照相设备
公开(公告)号：US5293209A
公开(公告)日：1994-03-08
申请号：US914534
申请日：1992-07-17
申请人： Mamoru Soga , Norihisa Mino , Kazufumi Ogawa
发明人： Mamoru Soga , Norihisa Mino , Kazufumi Ogawa
IPC分类号： G03G5/147 , G03G15/02 , G03G15/20 , G03G21/00 , G03G15/00
CPC分类号： B82Y30/00 , G03G15/0291 , G03G15/2028 , G03G15/2057 , G03G21/0017 , G03G5/14773
摘要： A chemical adsorption film possessing a fluorocarbon group through siloxane coupling is applied on the surface of a photoimaging component such as a photoconductor, the surface of a cleaning blade, the surface of a fixing roller, the surface of a separation pawl used in offset of paper, the surface of a corona wire, or the surface of a corona grid. Further according to the invention, the chemical adsorption film is laminated via a siloxanebased inner layer, the inner layer being bonded by covalent bonds to the surface of the device, the inner layer and the chemical adsorption film being bonded together by covalent bonds. Furthermore according to the invention, since the chemical adsorption film of the invention is an ultrathin film, on the order of nanometers or Angstroms, it does not spoil the properties of the separation pawl such as mechanical strength.
摘要翻译：通过硅氧烷偶联具有碳氟化合物基团的化学吸附膜被施加在光成像组件如光电导体的表面上，清洁刮板的表面，定影辊的表面，用于纸张偏移的分离爪的表面，电晕丝的表面或电晕网的表面。此外，根据本发明，通过硅氧烷基内层层叠化学吸附膜，通过共价键将内层与构件的表面接合，内层和化学吸附膜通过共价键结合在一起。此外，根据本发明，由于本发明的化学吸附膜是纳米或埃等级的超薄膜，因此不会破坏分离爪的性能，例如机械强度。

90. 发明授权

US5216102A Process for producing polyacetylene 失效
标题翻译：生产聚乙炔的方法
公开(公告)号：US5216102A
公开(公告)日：1993-06-01
申请号：US767580
申请日：1991-09-30
申请人： Mamoru Soga , Shu Hotta , Nobuo Sonoda , Hideki Shirakawa , Kazuo Akagi
发明人： Mamoru Soga , Shu Hotta , Nobuo Sonoda , Hideki Shirakawa , Kazuo Akagi
IPC分类号： C08F38/02 , C08F138/02 , C08J5/18
CPC分类号： C08J5/18 , C08F138/02 , C08F38/02 , C08J2349/00 , Y10S526/901
摘要： The present invention provides a process for producing a polyacetylene.In the present process for producing a polyacetylene, acetylene is polymerized with a Ziegler-Natta catalyst consisting of a trialkylaluminum and an alkyl titanate, wherein there is used, as the trialkylaluminum, a trialkylaluminum having an alkyl group of 6 or more carbon atoms, or, as the alkyl titanate, an alkyl titanate having an alkyl group of 6 or more carbon atoms.The polyacetylene obtained according to the present invention is superior in mechanical properties, particularly stretchability.
摘要翻译：本发明提供聚乙炔的制造方法。在本发明的聚乙炔的制备方法中，乙炔与由三烷基铝和钛酸烷基酯组成的齐格勒 - 纳塔催化剂聚合，其中作为三烷基铝使用具有6个或更多个碳原子的烷基的三烷基铝，或作为钛酸烷基酯，具有6个以上碳原子的烷基的钛酸烷基酯。根据本发明获得的聚乙炔的机械性能，特别是拉伸性优异。

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