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81. 发明授权

US4205008A Optically active sulfonates of allethrolone 失效
标题翻译：光学活性磺酸盐
公开(公告)号：US4205008A
公开(公告)日：1980-05-27
申请号：US945328
申请日：1978-09-25
申请人： Jacques Martel , Jean Tessier
发明人： Jacques Martel , Jean Tessier
IPC分类号： C07C45/67 , C07C143/68
CPC分类号： C07C309/00 , C07C45/673
摘要： Optically active sulfonates of allethrolone of the formula ##STR1## wherein X is selected from the group consisting of alkyl of 1 to 3 carbon atoms and phenyl optionally substituted in the para position with a member selected from the group consisting of methyl, fluorine, chlorine and bromine with an (R) or (S) configuration which are useful for obtaining optically active allethrolone of antipodal configuration and process for their preparation.
摘要翻译：其中X选自1至3个碳原子的烷基和在对位任选被取代的苯基的光学活性磺酸盐，其中X选自甲基，氟，氯和具有（R）或（S）构型的溴，其可用于获得对映体形式的光学活性羟基噻吩酮及其制备方法。

82. 发明授权

US4166063A Lactones of 2,2-dimethyl-cyclopropane-1-carboxylic acids 失效
标题翻译： 2,2-二甲基 - 环丙烷-1-羧酸
公开(公告)号：US4166063A
公开(公告)日：1979-08-28
申请号：US914399
申请日：1978-06-12
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Jean Jolly
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute , Jean Jolly
IPC分类号： C07C61/40 , C07C51/00 , C07C51/09 , C07C61/35 , C07C62/02 , C07C67/00 , C07D307/93
CPC分类号： C07D307/93 , C07C62/02
摘要： Novel lactones of 2,2-dimethyl-cyclopropane-1-carboxylic acids of the formula ##STR1## wherein X.sub.1, X.sub.2 and X.sub.3 when identical are selected from the group consisting of chlorine and bromine and when at least two are different, are selected from the group consisting of fluorine, chlorine and bromine and a novel process for their preparation and a process for the preparation of cis 2,2-dimethyl-cyclopropane-1-carboxylic acids of the formula ##STR2##
摘要翻译：式XI的顺式2,2-二甲基 - 环丙烷-1-羧酸的新型内酯，其中X1，X2和X3当相同时选自氯和溴，当至少两个不同时，它们是选自氟，氯和溴的组合及其制备方法和制备式IV的顺式2,2-二甲基 - 环丙烷-1-羧酸的方法式IV的酸可用于制备提高杀虫活性的酯。

83. 发明授权

US4101574A Cyclopropanecarboxylic acid chlorides 失效
公开(公告)号：US4101574A
公开(公告)日：1978-07-18
申请号：US749402
申请日：1976-12-10
申请人： Jacques Martel , Chanh Huynh , Jean Buendia
发明人： Jacques Martel , Chanh Huynh , Jean Buendia
IPC分类号： B23D61/02 , B29C37/00 , C07C21/14 , C07C22/04 , C07C35/04 , C07C61/35 , C07D307/45 , C07D307/54 , C07D309/04 , C07D309/20 , C07C61/18
CPC分类号： C07D309/20 , B29C37/00 , C07C21/14 , C07C22/04 , C07C35/045 , C07C61/35 , C07D307/42 , C07D307/54 , C07D309/04
摘要： Novel cyclopropanecarboxylic acids and esters of the formula ##STR1## wherein Z.sub.1 and Z.sub.2 are selected from the group consisting of hydrogen, alkyl, aralkyl, aryl, alkenyl non-conjugated with the cyclopropane ring, alkynyl non-conjugated with the cyclopropane ring, cycloalkyl, cycloalkenyl and heterocyclic; R is selected from the group consisting of OH and OR' in which R' is selected from the group consisting of lower alkyl which may be substituted, benzyl which may be substituted on the phenyl or methylene portion, N-methylene-dicarboximide, (5-benzyl-furyl-3) methyl, and a cyclopentene of the formula ##STR2## WHEREIN R" is selected from the group consisting of alkyl, alkynyl, alkenyl, aryl, aralkyl, cycloalkyl, cycloalkenyl and heterocyclic; A is a bivalent alkyl radical selected from the group consisting of ##STR3## WHEREIN R.sub.1 is selected from the group consisting of hydrogen and lower alkyl, R.sub.2 and R.sub.3 are selected from the group consisting of alkyl, alkynyl, alkenyl, aryl, aralkyl, cycloalkyl, cycloalkenyl and heterocyclic and taken together with the carbon atom to which they are attached form a ring selected from the group consisting of carbon homo rings and unsaturated carbon homo rings of 3 to 7 carbon atoms and heterocyclic rings which may be substituted with lower alkyl or lower alkoxy and R.sub.2 and R.sub.3 may together form a polycyclic aromatic radical, R.sub.4 is lower alkyl, R.sub.5 is selected from the group consisting of hydrogen and lower alkyl and R.sub.4 and R.sub.5 together with the carbon atoms to which they are attached may form a saturated or unsaturated carbon homo ring or a heterocyclic ring, Y is selected from the group consisting of methylene and a saturated or unsaturated carbon chain and Y' is selected from the group consisting of methine and a saturated or unsaturated carbon chain with the proviso that when Z.sub.1 and Z.sub.2 are methyl and R.sub.1 is hydrogen, R.sub.2 is other than methyl and their preparation.

84. 发明授权

US4024172A Preparation of prostanoic acid derivatives 失效
标题翻译：前列腺酸衍生物的制备
公开(公告)号：US4024172A
公开(公告)日：1977-05-17
申请号：US176234
申请日：1971-08-30
申请人： Jacques Martel , Jean Buendia , Edmond Toromanoff
发明人： Jacques Martel , Jean Buendia , Edmond Toromanoff
IPC分类号： C07C61/06 , C07C69/74 , C07C405/00 , C07D303/42 , C07D309/12 , C07D521/00 , C07C177/00
CPC分类号： C07D231/12 , C07C405/00 , C07D233/56 , C07D249/08 , C07D303/42 , C07D309/12
摘要： A novel process for the preparation of derivatives of prostanoic acids of the prostaglandin A.sub.2 (PGA.sub.2) group of the formula ##STR1## wherein R is selected from the group consisting of hydrogen and lower alkyl, n is a whole number of 2, 3 or 4 and m is a whole number of 3, 4 or 5 and to novel intermediates produced in the said process.
摘要翻译：用于制备式IMA的前列腺素A2（PGA2）组的前列腺酸衍生物的新方法，其中R选自氢和低级烷基，n是整数2,3或 4和m是3,4或5的整数，以及在所述方法中生产的新型中间体。

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