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81. 发明专利

JPS6097649A RESIN SEALED SEMICONDUCTOR DEVICE 失效
公开(公告)号：JPS6097649A
公开(公告)日：1985-05-31
申请号：JP20468383
申请日：1983-11-02
申请人： HITACHI LTD
发明人： NISHIKAWA AKIO , OGATA MASAJI , KITAMURA MASAHIRO , SEGAWA MASANORI , KANESHIRO TOKUYUKI
IPC分类号： C08G59/00 , C08G59/62 , H01L23/29 , H01L23/31
摘要： PURPOSE:To improve the heat resistance and reliability at high temperature and himidity of solder by a method wherein a resin product containing a compound with at least a cyclic furan and a multi-functional epoxy compound is utilized for sealing process. CONSTITUTION:A compound A with cyclic furan such as furan denatured phenol resin includes all synthetic resins with cyclic furan, e.g. furfuryl alcohol, furfural cocondensate resin, furfural alalkyl phenol cocondensate resin etc. As for a multiple functional epoxy compound B, e.g. diglycylglyl ether of bisphenol A, triglycylglyl ether of paraminophenol are utilized. The allowable blending ratio between the compounds A and B may be within the range of 0.5-9.0wt% of B to 1wt% of A. As for the accelerating catalyst for hardening reaction of a product, amine group such as triethanol amine etc. are applicable. A resin product may be prepared by means of heating and kneading each component.

82. 发明专利

JPS6094750A LEAD FRAME 失效
公开(公告)号：JPS6094750A
公开(公告)日：1985-05-27
申请号：JP20081483
申请日：1983-10-28
申请人： HITACHI LTD
发明人： YOKOYAMA TAKASHI , KANESHIRO TOKUYUKI
IPC分类号： H01L23/50 , H01L23/495
摘要： PURPOSE:To enable the measurement of stress in the periphery of a semiconductor element by a method wherein the central point of the section for die-bonding the element is positioned so as not to be on the point of symmetry with regard to a lead frame. CONSTITUTION:The central point of the section 1 for die-bonding the semiconductor element to the lead frame is kept out of the center of the lead frame. After die-bonding of the element to such a frame, the element is sealed with resin in such a manner that the center of the frame superposes on the center of the sealing resin (center of the region drawn by a broken line 3). The more distant from the center of the resin, the larger amount of stress is applied to the element thus sealed; therefore the use of such a lead frame enables detailed investigation of the stress distribution of the element in the sealing resin.

83. 发明专利

JPS6084337A FLAME-RETARDANT RESIN COMPOSITION AND ITS USE 失效
公开(公告)号：JPS6084337A
公开(公告)日：1985-05-13
申请号：JP19099083
申请日：1983-10-14
申请人： HITACHI LTD
发明人： OGATA MASAJI , NISHIKAWA AKIO , SEGAWA MASANORI , IKEDA TAKAE , KANESHIRO TOKUYUKI
IPC分类号： C08K9/00 , C08K9/04 , C08L67/00
摘要： PURPOSE:A flame-retardant resin composition for use in obtaining electronic parts having excellent reliability under high temperature and humidity conditions, comprising antimony oxide particles with their surfaces precoated with a coating material. CONSTITUTION:A flame-retardant resin composition comprising particles of antimony oxide selected from amony Sb2O3, Sb2O4, and Sb2O5, with their surfaces precoated with a coating material composed of an agent for forming a moisture- resistant protective layer (e.g. an epoxy resin) and/or an agent for forming a layer to give an affinity for resin components (e.g. a silane coupling agent). With no difference in flame retardancy from conventional flame retardant compositions, the composition is substantially free of corrosion of a metal sealed in a resin particularly under high temperature and humidity conditions, making it possible to improve reliability; thus serves as a suitable packaging material for electronic parts, etc.

84. 发明专利

JPS6032827A RESIN COMPOSITION HAVING LOW THERMAL EXPANSION COEFFICIENT 失效
公开(公告)号：JPS6032827A
公开(公告)日：1985-02-20
申请号：JP13943883
申请日：1983-08-01
申请人： HITACHI LTD , HITACHI CHEMICAL CO LTD
发明人： NUMATA SHIYUNICHI , FUJISAKI KOUJI , KANESHIRO TOKUYUKI , IMAIZUMI JIYUNICHI , MIKAMI YOSHIKATSU
IPC分类号： C08G73/00 , C08G73/10 , H01B3/30
摘要： PURPOSE:To provide the titled material composed of a polyimide containing specific two kinds of structural units, having low linear expansion coefficient and thermal stress and excellent tensile strength, and suitable as a carrier tape for the manufacture of IC, insulation film for insulated coil, etc. CONSTITUTION:The objective material composed of a polyimide containing the chemical structural unit of formula I and formula II [Ar1 is group of formula III(R is lower alkyl or F-containing lower alkyl; n is 0-4), formula IV or formula V; Ar2 is bivalent aromatic group; Ar3 is tetravalent aromatic group], is produced by reacting an aromatic diamine or its isocyanate (e.g. p-phenylenediamine) with biphenyltetracarboxylic acid or its derivative (e.g. tetracarboxylic acid dianhydride) in a solvent such as N-methyl-2-pyrrolidone at 0-200 deg.C.

85. 发明专利

JPS59206753A Humidity sensor 失效
标题翻译：湿度传感器
公开(公告)号：JPS59206753A
公开(公告)日：1984-11-22
申请号：JP8074183
申请日：1983-05-11
申请人： Hitachi Ltd
发明人： OOHARA SHIYUUICHI , KANESHIRO TOKUYUKI , SUGAWARA TOORU , TSUCHIYA SHIGEKI
IPC分类号： H01C7/00 , G01N27/12
CPC分类号： G01N27/126 , G01N27/121
摘要： PURPOSE:To obtain a humidity sensor having low electric resistance with excellent durability and responsiveness which shows stable responsiveness especially under high temps. and humidity for a long time by using a copolymer of a monomer having a hydroxyalkyl group and a monomer having an ionic group as a humidity-sensitive material. CONSTITUTION:A copolymer of a monomer having an OH group shown in the formula (R1 is H, CH3, C2H5, R2 is -COOCH2-, -COOCH2CH2-, or -CONHCH2 CH2-) and a monomer such as styrene sulfonic acid, (metha) acrylic acid or the salt thereof for reducing the electric resistance of a humidity-sensitive material, or a cationic monomer, or, in certain circumstances, a cross-linked copolymer obtained by adding a cross-linking agent to said monomers, is used as the humidity sensitive material. An SiO2 layer 12 and an Si3N4 layer 13 are provided successively on a silicon substrate 11 as an insulating layer. After forming a comb line electrode 14 on the layer 13, a humidity-sensitive layer 4 for covering the electrode 14 is provided to obtain the humidity sensor. In this way, the sensor having a stable sensitivity under high temps. and humidity or at a place wherein the change in temp. and humidity is violent or further in the presence of various gases is obtained.
摘要翻译：目的：获得具有低电阻，耐久性和响应性优异的湿度传感器，特别是在高温下显示出稳定的响应性。通过使用具有羟烷基的单体和具有离子性基团的单体的共聚物作为湿度敏感性材料的共聚物长时间的湿度。构成：具有式（R 1为H，CH 3，C 2 H 5，R 2为-COOCH 2 - ， - COCH 2 CH 2 - 或-CONHCH 2 CH 2 - ）的具有OH基团的单体和单体如苯乙烯磺酸，（甲基）丙烯酸或其盐，用于降低湿敏材料或阳离子单体的电阻，或者在某些情况下，通过向所述单体加入交联剂获得的交联共聚物被使用作为湿敏材料。在作为绝缘层的硅基板11上依次设置SiO 2层12和Si 3 N 4层13。在层13上形成梳线电极14之后，设置用于覆盖电极14的湿度敏感层4，以获得湿度传感器。以这种方式，传感器在高温下具有稳定的灵敏度。湿度或温度变化的地方。并且在存在各种气体的情况下，湿度是剧烈的或进一步的。

86. 发明专利

JPS5941453B2 JPS5941453B2 - 失效
公开(公告)号：JPS5941453B2
公开(公告)日：1984-10-06
申请号：JP7773276
申请日：1976-07-02
申请人： Hitachi Ltd
发明人： KANESHIRO TOKUYUKI , MYADERA YASUO , ISHII TAKEO , YOKONO ATARU
IPC分类号： C08G69/00 , C08G69/32 , C08G69/42

87. 发明专利

JPS5994442A RESIN-SEALED TYPE SEMICONDUCTOR DEVICE 失效
公开(公告)号：JPS5994442A
公开(公告)日：1984-05-31
申请号：JP20377782
申请日：1982-11-22
申请人： HITACHI LTD , HITACHI CHEMICAL CO LTD
发明人： KITAMURA MASAHIRO , SEGAWA MASANORI , NISHIKAWA AKIO , NUMATA SHIYUNICHI , KANESHIRO TOKUYUKI , MUKAI JIYUNJI , SUZUKI HIROSHI , NISHI KUNIHIKO
IPC分类号： C08G59/00 , C08L7/00 , C08L21/00 , C08L63/00 , H01L23/29
摘要： PURPOSE:To improve moisture resistance and crack resistance of a resin-sealed type semiconductor device by sealing a semiconductor element with ultrafine particles of synthetic rubber of high molecular weight and epoxy resin which contains organopolysiloxane. CONSTITUTION:Rubber ultrafine particles of derivative having polybutadiene, polyisoprene or their hydroxyl group, carboxylic group, amino group, chiol group, isocyanate group or epoxy group (with 150mum or less in diameter) and silicone oil particularly having as substituted group methyl group, epoxy group, or hydroxyl group (dimethylpolysiloxane) are mixed in the amount of 0.1- 20pts.wt. to 100pts.wt. of epoxy resin. The epoxy resin, curing agent and cure accelerator of known materials may be widely used. Maleic anhydride, tetra- substituted phosphonium.tetra-substituted borate are, for example, added to bisphenol A. A solid material is pulverized to be sufficiently mixed. This resin is reduced in elastic modulus, has good adhesive with an element, prevents crack at the molding time, and a semiconductor device which has good moisture resistance can be formed.

88. 发明专利

JPS5920844A Relative humidity detecting device 失效
标题翻译：相对湿度检测装置
公开(公告)号：JPS5920844A
公开(公告)日：1984-02-02
申请号：JP13035382
申请日：1982-07-28
申请人： Hitachi Ltd
发明人： SUGAWARA TOORU , TSUCHIYA SHIGEKI , KANESHIRO TOKUYUKI , OOHARA SHIYUUICHI
IPC分类号： G01N27/12 , G01N25/64 , G01N33/00
CPC分类号： G01N33/0062
摘要： PURPOSE:To obtain the highly accurate measured value of relative humidity without temporal errors, by sampling the outputs of a humidity sensor at a specified time interval, ocmparing the deviation between the relative humidity values at the previous time and the last time, and performing the correction. CONSTITUTION:Gate signals are generated from a pulse train generator 14 based on pulses having a constant interval from a timer 13. A gate G1 and then a gate G2 are opened by said signals, and the output signal from a humidity sensor 7 is held in holding circuits 15 and 16. The difference between the held values is obtained by subtracting circuit 18 and compared with a preset value by a comparing circuit 19. When the deviation exceeds the preset value, a signal is issued, a value corresponding to the time constant is set in a counter 20, and a gate circuit G3 is opened. Then the value, which is obtained by amplifying the output of the subtracting circuit 18 by an amplifier circuit 21, and the held value of the holding circuit 16 are added in an adding circuit 22. Then the corrected relative humidity value is displayed on a display circuit 24. Thus, the highly accurate measured value of the relative humidity without temporal errors can be obtained.
摘要翻译：目的：为了获得高度准确的相对湿度测量值，没有时间误差，通过以指定的时间间隔对湿度传感器的输出进行采样，显示上一次和最后一次的相对湿度值之间的偏差，并执行更正。构成：基于来自定时器13的具有恒定间隔的脉冲，从脉冲串发生器14产生门信号。门G1和门G2由所述信号打开，并且来自湿度传感器7的输出信号保持在保持电路15和16.通过减法电路18获得保持值之间的差异，并通过比较电路19与预设值进行比较。当偏差超过预设值时，发出信号，对应于时间常数设置在计数器20中，并且打开门电路G3。然后，通过放大电路21将减法电路18的输出放大而获得的值和保持电路16的保持值相加在加法电路22中。然后将校正的相对湿度值显示在显示器上因此，可以获得没有时间误差的相对湿度的高精度测量值。

89. 发明专利

JPS58213245A Humidity sensitive material used for sensor 失效
标题翻译：用于传感器的湿度敏感材料
公开(公告)号：JPS58213245A
公开(公告)日：1983-12-12
申请号：JP9635082
申请日：1982-06-07
申请人： Hitachi Ltd
发明人： OOHARA SHIYUUICHI , KANESHIRO TOKUYUKI , SUGAWARA TOORU , TSUCHIYA SHIGEKI
IPC分类号： C08F20/00 , C08F12/00 , C08F20/34 , C08F246/00 , C08F291/00 , G01N27/12
CPC分类号： G01N27/121
摘要： PURPOSE:To enhance resistance to water, organic solvent, stain, etc., and to enable long-term stable action, by using an org. polymer, used for a sensor as a humidity-sensitive material, cross-linked with a monomer having at least two CH2=C= groups. CONSTITUTION:The humidity-sensitive material to be used is a copolymer of a cationic monomer, a nonionic monomer, and a monomer having at least two CH2=C= groups in one molecule (designated shortly to DV cross-linking molecule). The humidity-sensitive material to be especially preferred uses the DV cross-linking molecule having one quaternary ammonium group and two CH2=C= groups represented by the shown formula in which R, R''' are each H, CH3; R , R are each alkyl, and X is an anion. A latex-like fluid contg. said material is applied onto all the surface of an insulating base 1 including a pair of comb-shaped electrodes 3 formed on the base 1 and dried to form the film 4 on the humidity sensitive material. The obtained sensor has good humidity sensitivity, and superior stain resistance, and it can operate stably for a long term.
摘要翻译：目的：提高对水，有机溶剂，污渍等的耐受性，并通过使用组织来实现长期稳定的作用。聚合物，用作传感器作为湿度敏感材料，与具有至少两个CH 2 = C =基团的单体交联。构成：使用的湿敏材料是阳离子单体，非离子单体和在一个分子中具有至少两个CH 2 = C =基团的单体的共聚物（短于DV交联分子）。特别优选的湿度敏感材料使用具有一个季铵基的DV交联分子和由下式表示的两个CH 2 = C =基团，其中R，R“'各自为H，CH 3; R 1，R 2各自为烷基，X为阴离子。乳胶状液体将所述材料施加到包括形成在基体1上的一对梳状电极3的绝缘基底1的所有表面上，并干燥以在湿敏材料上形成薄膜4。获得的传感器具有良好的湿度敏感性和优异的耐污染性，可长期稳定运行。

90. 发明专利

JPS58180531A Fluorine-containing polyimide, polyamic acid and production thereof 失效
标题翻译：含氟聚酰亚胺，聚氨酯及其生产
公开(公告)号：JPS58180531A
公开(公告)日：1983-10-22
申请号：JP6385682
申请日：1982-04-19
申请人： Hitachi Chem Co Ltd , Hitachi Ltd
发明人： NUMATA SHIYUNICHI , FUJISAKI KOUJI , KANESHIRO TOKUYUKI
IPC分类号： C08G73/00 , C08G73/10
摘要： PURPOSE: To obtain a fluorine-contg. polyimide or polyamic acid useful as various insulating films in electronics such as insulating film for the multi-layered wiring of semiconductor and having low hygroscopicity and excellent heat resistance, by reacting a specified diamine with a tetracarboxylic acid derivative.
CONSTITUTION: A diamine of formula I
1 (wherein R
1 is -Cn F
2n+1 ; n is 0W4) is reacted with a tetracarboxylic acid to obtain a polyimide having a repeating unit of formula I or a polyamic acid having a repeating unit of formula I
2 (wherein R
1 is Cn F
2n+1 ; n is 0W4; R
2 is H, lower alkyl). Usually, a polyimide film can be obtd. by coating its precursor polyamic acid, drying and curing it. When solvent resistance is required, the polymer is modified with a compd. of formula V (wherein R
2 is a (2+m)-valent arom. org. group; X is -NH
2 , -CONH
2 , -SO
2 NH
2 and situated at ortho position with respect to amino group; m is 1W2).
COPYRIGHT: (C)1983,JPO&Japio
摘要翻译：目的：获得氟聚酰亚胺或聚酰胺酸用作电子器件中的各种绝缘膜，例如用于半导体多层布线的绝缘膜，具有低吸湿性和优异的耐热性，通过使特定的二胺与四羧酸衍生物反应。构成：将式I 1（其中R 1为-C n F 2n + 1; n为0-4）的二胺与四羧酸反应，得到具有式I重复单元的聚酰亚胺或具有重复式I <2的单元（其中R 1为Cn F 2n + 1; n为0-4; R 2为H，低级烷基）。通常可以得到聚酰亚胺膜。通过涂覆其前体聚酰胺酸，干燥和固化。当需要耐溶剂性时，用聚合物改性聚合物。（其中R 2为（2 + m）价芳烃基团; X为-NH 2，-CONH 2，-SO 2 NH 2，位于相对于氨基的邻位; m为1-2 ）。

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