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    • 84. 发明授权
    • Carbamoylphenylsulfonylureas, processes for their preparation and their use as herbicides and plant growth regulators
    • 氨基甲酰基苯基磺酰脲,其制备方法及其作为除草剂和植物生长调节剂的用途
    • US06228808B1
    • 2001-05-08
    • US09182763
    • 1998-10-30
    • Heinz KehneLothar WillmsChristian WaldraffHansjörg DietrichHermann BieringerChristopher RosingerThomas Auler
    • Heinz KehneLothar WillmsChristian WaldraffHansjörg DietrichHermann BieringerChristopher RosingerThomas Auler
    • A01N4354
    • C07D275/06C07C311/16C07D521/00
    • Compounds of the formula (I) or salts thereof in which R1, R3=H, (subst.) hydrocarbon radical (HC) or (subst.) heterocyclyl which, including substituents, have 1-30 carbon atoms, R2=R0—Q0—, in which R0=H, (subst.) HC or (subst.) heterocyclyl radical, in each case having 1-30 carbon atoms including substituents, and Q0=a direct bond or —O—, —SO2-, —NH—, —N[(C1-C6)alkyl]-, —CO—, —CO—NH— or —O—CO—NH—; R4=H, halogen, NO2, CN, (C1-C4)alkyl, (C1-C4)alkoxy, [(C1-C4)alkyl]carbonyl or [(C1-C4)alkoxy]carbonyl, where each of the last four radicals may be halogenated; R5=H or (C1-C4)alkyl; Q=O or NR*; R*=H. (C1-C4)alkyl, (C3-C4)alkenyl or (C3-C4)alkynyl, where each of the last three radicals may be substituted by halogen, (C1-C4)alkoxy and/or (C1-C4)alkylthio, W=O or S; X,Y=H, halogen, (C1-C4)alkyl, (C1-C4)alkoxy, (C1-C4)alkylthio, where each of the last three radicals may be substituted by halogen, (C1-C4)alkoxy and/or (C1-C4)alkylthio, or mono- or di[(C1-C4)alkyl]amino, (C3-C4)cycloalkyl, (C2-C5)alkenyl, (C2-C5)alkynyl, (C2-C5)alkenyloxy or (C2-C5)alkynyloxy, Z=CH or N, are suitable as herbicides or plant growth regulators, for example for controlling harmful plants in crop plants, including transgenic crop plants. They can be prepared by processes according to claim 6, via intermediates, some of which are novel.
    • 式(I)化合物或其盐,其中R 1,R 3 = H,(取代)烃基(HC)或(取代)杂环基,其包括取代基,具有1-30个碳原子,R 2 = R 0 -Q 0-, 其中R 0 = H,(低级)HC或(取代)杂环基,在每种情况下具有包含取代基的1-30个碳原子,Q 0 =直接键或-O-,-SO 2 - , - NH-, -N [(C 1 -C 6)烷基] - , - CO - , - CO-NH-或-O-CO-NH-; R4 = H,卤素,NO2,CN,(C1-C4)烷基,(C1-C4)烷氧基,[(C1-C4)烷基]羰基或[(C1-C4)烷氧基]羰基, 自由基可以被卤化; R5 = H或(C1-C4)烷基; Q = O或NR *; R * = H。 (C 1 -C 4)烷基,(C 3 -C 4)烯基或(C 3 -C 4)炔基,其中最后三个基团中的每一个可以被卤素,(C 1 -C 4)烷氧基和/或(C 1 -C 4)烷硫基取代, W = O或S; X,Y = H,卤素,(C1-C4)烷基,(C1-C4)烷氧基,(C1-C4)烷硫基,其中最后三个基团中的每一个可以被卤素,(C 1 -C 4)烷氧基和/ 或(C 1 -C 4)烷硫基或单或二[(C 1 -C 4)烷基]氨基,(C 3 -C 4)环烷基,(C 2 -C 5)烯基,(C 2 -C 5)炔基,(C 2 -C 5) 或(C 2 -C 5)炔氧基Z = CH或N适合作为除草剂或植物生长调节剂,例如用于控制作物植物(包括转基因作物植物)中的有害植物。 它们可以通过根据权利要求6的方法通过中间体制备,其中一些是新颖的。
    • 88. 发明授权
    • Herbicidal substituted pyridines, their preparation, and their use as herbicides and plant growth regulators
    • 除草剂取代的吡啶,它们的制备及其作为除草剂和植物生长调节剂的用途
    • US06794336B2
    • 2004-09-21
    • US10177526
    • 2002-06-21
    • Klaus HaafLothar WillmsThomas AulerHubert MenneHermann Bieringer
    • Klaus HaafLothar WillmsThomas AulerHubert MenneHermann Bieringer
    • A01N4340
    • C07D213/643A01N43/40A01N43/56A01N47/12A01N47/28A01N47/30A01N47/38A01N53/00C07D213/69C07D401/12C07D401/14C07D405/14C07D409/14
    • The present invention relates to a compound of the formula (I) or salt thereof in which R1 is identical or different at each occurrence and is H, halogen, CN, nitro, SF5, (C1-C8)alkyl, (C2-C8)alkenyl, (C2-C8)alkynyl, (C1-C8)alkoxy, [(C1-C8)alkyl]-carbonyl or (C1-C8)alkylsulfonyl, each of the radicals being unsubstituted or substituted,  or is S(O)p—R7, where p=0, 1 or 2 and R7 is (C1-C8)alkyl, (C1-C8)haloalkyl or NR8R9, where  R8 and R9 independently of one another are identical or different and are H, (C1-C8)alkyl, (C2-C8)alkenyl, (C7-C10)arylalkyl, (C7-C10)alkylaryl or (C6-C10)aryl, each of the last-mentioned five radicals being unsubstituted or substituted,  or is a group of the formula where R10 is (C1-C8)alkyl which is unsubstituted or substituted, and W=O or S, A is optionally substituted aryl or an optionally substituted heterocyclic radical, X is O or S, R2,R3,R4, and R5 are identical or different and are H, halogen, CN, (C1-C8)alkoxy or (C1-C8)alkyl, each of the two last-mentioned radicals being unsubstituted or substituted, m is 0 or 1, R6 is H, (C1-C8)alkyl, (C1-C8)alkoxy, (C2-C8)alkenyl or (C2-C8)alkynyl, each of the four last-mentioned radicals being unsubstituted or substituted, or is hydroxyl or an acyl radical, and B is an acyl radical, or B and R6 together form a 4- or 5-membered chain, with the exception of N-hydroxy-N-[(6-phenoxy-2-pyridyl)methyl]-acetamide and its salts. The compounds of the invention are suitable, for example, as herbicides and growth regulators.
    • 本发明涉及式(I)化合物或其盐,其中R 1在每次出现时均相同或不同,为H,卤素,CN,硝基,SF5,(C1-C8)烷基,(C2-C8 )链烯基,(C 2 -C 8)炔基,(C 1 -C 8)烷氧基,[(C 1 -C 8)烷基] - 羰基或(C 1 -C 8)烷基磺酰基,每个基团是未取代的或被取代的, pR 7,其中p = 0,1或2和R 7是(C 1 -C 8)烷基,(C 1 -C 8)卤代烷基或NR 8 R 9,其中R 8和R 9独立地 是(C 1 -C 8)烷基,(C 2 -C 8)烯基,(C 7 -C 10)芳基烷基,(C 7 -C 10)烷基芳基或(C 6 -C 10)芳基) 或者是R 10是未被取代或被取代的(C1-C8)烷基,W = O或S,A是任意取代的芳基或任意取代的杂环基 ,X为O或S,R 2,R 3,R 4和R 5相同或不同,为H,卤素,CN,(C 1 -C 8)烷氧基或(C 1 -C 8 )烷基,两个l 前述基团为未取代或取代的,m为0或1,R 6为H,(C 1 -C 8)烷基,(C 1 -C 8)烷氧基,(C 2 -C 8)烯基或(C 2 -C 8) 四个最后提到的四个基团中的每一个是未取代的或取代的,或者是羟基或酰基,B是酰基,或者B和R 6一起形成4-或5-元链,除了N - 羟基-N - [(6-苯氧基-2-吡啶基)甲基] - 乙酰胺及其盐。本发明的化合物适用于例如除草剂和生长调节剂。