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81. 发明申请

US20070045155A1 Integrated scheme of processes for extracting and treating an extra-heavy or bituminous crude 有权
标题翻译：用于提取和处理超重或沥青原油的方法的综合方案
公开(公告)号：US20070045155A1
公开(公告)日：2007-03-01
申请号：US11508331
申请日：2006-08-23
申请人： Arnault Selmen , Thierry Gauthier , Mathieu Pinault , Eric Benazzi
发明人： Arnault Selmen , Thierry Gauthier , Mathieu Pinault , Eric Benazzi
IPC分类号： C10G65/02
CPC分类号： C10G45/02 , C10G1/047 , C10G9/005 , C10G9/007 , C10G47/02 , C10G65/12 , C10G69/06 , C10G2300/1033 , C10G2300/1096 , C10G2300/302 , C10G2300/308 , C10G2300/807
摘要： A process for preparation of synthetic crude from a deposit of heavy crude, comprises: (a) the extraction of heavy crude by technology using steam; (b) the separation of crude extract and water; (c) the separation of crude into at least one light fraction and one heavy fraction; (d) the conversion of the heavy fraction of separation into a lighter product, said converted product, and a residue; (e) optionally, the partial or total hydrotreatment of the converted product and/or the light fraction (or fractions) obtained during the separation c), (f) the combustion and/or gasification of the conversion residue; the converted product and the light fraction (or fractions) for separation, optionally having been subjected to a hydrotreatment e), constituting the synthetic crude; said combustion allowing the generation of steam and/or electricity and said gasification allowing the generation of hydrogen; the steam and/or electricity thus generated being used for the extraction a) and/or the electricity and/or hydrogen thus generated being used for the conversion d) and/or the hydrotreatment e).
摘要翻译：由重质原油沉积物制备合成原油的方法包括：（a）通过蒸汽技术提取重质原油; （b）粗提物与水的分离; （c）将粗分离成至少一个轻馏分和一个重馏分; （d）将重馏分转化成更轻的产物，所述转化的产物和残余物; （e）任选地，在分离期间获得的转化产物和/或轻馏分（或级分）的部分或全部加氢处理c），（f）转化残余物的燃烧和/或气化; 转化产物和用于分离的轻馏分（或级分），任选已经进行加氢处理e）构成合成粗品; 所述燃烧允许产生蒸汽和/或电，并且所述气化允许产生氢气; 由此产生的蒸汽和/或电力用于提取a）和/或由此产生的电和/或氢用于转化d）和/或加氢处理e）。

82. 发明申请

US20050000857A1 Flexible process for the production of oil bases and middle distillates with a converting pretreatment stage followed by a catalytic dewaxing stage 有权
标题翻译：用于生产油基和中间馏分的柔性方法，其具有转化预处理阶段，然后进行催化脱蜡阶段
公开(公告)号：US20050000857A1
公开(公告)日：2005-01-06
申请号：US10696548
申请日：2003-10-30
申请人： Eric Benazzi , Patrick Euzen
发明人： Eric Benazzi , Patrick Euzen
IPC分类号： B01J21/12 , B01J23/40 , B01J23/42 , B01J35/00 , B01J35/10 , C10G65/00 , C10G65/04 , C10G65/12 , C10G51/02
CPC分类号： B01J23/40 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/108 , C10G2400/10
摘要： The invention relates to an improved process for the production of very high quality base oils with simultaneous production of high quality middle distillates starting from feedstocks that are obtained from the distillation of crude or that are obtained from units for transformation and refining of the latter. The process according to the invention comprises a converting pretreatment stage of the feedstock and a catalytic dewaxing stage. The converting pretreatment stage takes place in the presence of a catalyst that contains at least one noble metal that is deposited on an acid substrate that is a particular silica-alumina. The catalytic dewaxing takes place in the presence of a catalyst with a zeolite base that is preferably selected from the group that is formed by zeolites of the TON-structural type (theta-1, ISI-1, ZSM-22, KZ-2, NU-10), and the zeolites ZSM-48, ZBM-30, EU-2, EU-11, ferrierite, EU-1 and EU-13, whereby the catalyst also contains at least one hydro-dehydrogenating element.
摘要翻译：本发明涉及一种用于生产非常高质量的基础油的改进方法，其同时从原料蒸馏中获得高质量的中间馏分，该原料可从原油蒸馏得到，或者由用于转化和精炼后者的单元得到。根据本发明的方法包括原料的转化预处理阶段和催化脱蜡阶段。转化预处理阶段在催化剂存在下进行，所述催化剂含有至少一种沉积在特定二氧化硅 - 氧化铝的酸性底物上的贵金属。催化脱蜡在具有沸石基质的催化剂存在下进行，沸石碱优选选自由TON结构型（θ-1，ISI-1，ZSM-22，KZ-2， NU-10）和沸石ZSM-48，ZBM-30，EU-2，EU-11，镁碱沸石，EU-1和EU-13，其中催化剂还含有至少一种氢脱氢元素。

83. 发明授权

US06733657B2 Hydrocracking catalyst having a unique silica-alumina substrate 有权
标题翻译：具有独特二氧化硅 - 氧化铝底物的加氢裂化催化剂
公开(公告)号：US06733657B2
公开(公告)日：2004-05-11
申请号：US10045678
申请日：2002-01-15
申请人： Eric Benazzi , Tivadar Cseri , Magalie Roy-Auberger , Patrick Euzen
发明人： Eric Benazzi , Tivadar Cseri , Magalie Roy-Auberger , Patrick Euzen
IPC分类号： C10G4704
CPC分类号： C10G47/12 , B01J21/12 , B01J35/1019 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/108 , B01J37/0009 , B01J37/20
摘要： A hydrocarbon conversion catalyst contains at least one silica-alumina having the following characteristics: A content by weight of silica SiO2 of between 10 and 60% by weight; an Na content less than 300 ppm by weight; a total pore volume of between 0.5 and 1.2 m/g measured by mercury porosimetry; a porosity of said silica-alumina wherein: the volume of mesopores whose diameter is between 40 Å and 150 Å, and whose mean diameter varies between 80 and 120 Å represents between 30 and 80% of the total pore volume, and (ii) the volume of macropores, whose diameter is greater than 500 Å and preferably between 1000 Å and 10,000 Å represents between 20 and 80% of the total pore volume; a specific surface area greater than 200 m2/g, and at least one hydro-dehydrogenating element selected metals of group VIB and group VIII, and optionally phosphorus, boron, silicon, or elements of group VIIA, VIIB or VB.
摘要翻译：烃转化催化剂含有至少一种具有以下特征的二氧化硅 - 氧化铝：二氧化硅SiO 2的重量含量为10至60重量％; Na含量小于300重量ppm; 通过水银孔率法测量的总孔体积为0.5-1.2m 2 / g; 所述二氧化硅 - 氧化铝的孔隙率，其中直径为介于40和150之间，其平均直径在80和120之间变化的介孔的体积占总孔体积的30至80％，和（ii）其直径大于500埃，优选在1000埃至10,000埃之间的大孔体积占总孔体积的20至80％; 比表面积大于200m 2 / g，以及至少一种加氢脱氢元素选择VIB族和VIII族的金属，以及任选的磷，硼，硅或VIIA，VIIB或VB族的元素。

84. 发明授权

US06660897B1 Catalyst based on a noble metal with low dispersion, and its use in converting hydrocarbon feeds 有权
标题翻译：基于低分散度的贵金属的催化剂，以及其用于转化烃原料的用途
公开(公告)号：US06660897B1
公开(公告)日：2003-12-09
申请号：US09562478
申请日：2000-05-01
申请人： Nathalie Marchal-George , Eric Benazzi , Tivadar Cseri , Slavik Kasztelan
发明人： Nathalie Marchal-George , Eric Benazzi , Tivadar Cseri , Slavik Kasztelan
IPC分类号： C07C522
CPC分类号： C10G45/62 , B01J21/12 , B01J23/40 , B01J35/10 , B01J35/1019 , B01J35/1042 , B01J35/1061 , B01J37/10
摘要： A catalyst comprising at least one noble metal deposited on an acidic support, wherein the dispersion of the noble metal is less than 20%.
摘要翻译：包含沉积在酸性载体上的至少一种贵金属的催化剂，其中贵金属的分散体小于20％。

85. 发明授权

US06627781B1 Process for producing, jointly or otherwise, monoalkyl aromatic compounds, dialkyl aromatic compounds and trialkyl aromatic compounds 有权
标题翻译：单烷基芳族化合物，二烷基芳族化合物和三烷基芳族化合物共同或以其他方式生产的方法
公开(公告)号：US06627781B1
公开(公告)日：2003-09-30
申请号：US09671295
申请日：2000-09-27
申请人： Patrick Briot , Pierre Yout , Jean-Claude Hipeaux , Eric Benazzi , Leon Lew
发明人： Patrick Briot , Pierre Yout , Jean-Claude Hipeaux , Eric Benazzi , Leon Lew
IPC分类号： C07C264
CPC分类号： C07C6/126 , C07C2/66 , C07C2529/08 , C07C2529/18 , C07C2529/70
摘要： Process for the production of at least one compound that is selected from among monoalkyl aromatic compounds, dialkyl aromatic compounds and trialkyl aromatic compounds by alkylation or transalkylation of an aromatic compound by at least one alkylating agent that is selected from among the olefins, whereby the process is characterized in that it is carried out in one or two stages, involving two reaction zones in series, whereby one of these two zones can be switched off so as to be able, depending on whether or not one of the zones is switched off, to meet the demand either of the three types of mono, di- and trialkyl aromatic compounds, or two of these types or a single one of the types of mono- or di- or trialkyl aromatic compounds.
摘要翻译：通过至少一种选自烯烃的烷基化剂烷基化或烷基化芳族化合物来生产至少一种选自单烷基芳族化合物，二烷基芳族化合物和三烷基芳族化合物的化合物的方法，其中该方法其特征在于它在一个或两个阶段中进行，包括串联的两个反应区域，由此可以关闭这两个区域中的一个，以便能够根据其中一个区域是否关闭，以满足三种类型的单，二和三烷基芳族化合物或这些类型中的两种或单 - 或二 - 或三烷基芳族化合物的单一类型的需求。

86. 发明授权

US06602402B1 Flexible process for producing base stock and distillates by conversion-hydroisomerisation using a catalyst with low dispersion followed by catalytic dewaxing 失效
标题翻译：通过使用低分散体催化脱蜡的催化剂通过转化 - 加氢异构化生产基础油料和馏出物的柔性方法
公开(公告)号：US06602402B1
公开(公告)日：2003-08-05
申请号：US09562286
申请日：2000-05-01
申请人： Eric Benazzi , Nathalie Marchal-George , Tivadar Cseri , Pierre Marion , Christophe Gueret , Slavik Kasztelan
发明人： Eric Benazzi , Nathalie Marchal-George , Tivadar Cseri , Pierre Marion , Christophe Gueret , Slavik Kasztelan
IPC分类号： C10G6512
CPC分类号： C10G65/12 , B01J21/12 , B01J23/40 , B01J23/42 , B01J23/44 , B01J29/064 , B01J29/076 , B01J29/67 , B01J29/7446 , B01J29/7484 , B01J35/006 , B01J35/0066 , B01J35/023 , C10G45/62 , C10G65/043
摘要： An improved process for producing very high quality base stock and for simultaneous production of high quality middle distallates, comprising successive hydroisomerisation and catalystic dewaxing steps wherein hydroisomerisation is carried out in the presence of a catalyst containing at least one noble metal deposited on an amorphous acidic support, the dispersion of the metal being less than 20%. The support is preferably an amorphous silica-alumina. Catalytic dewaxing is carried out in the presence of a catalyst containing at least one hydrodehydrogenating element (group VIII) and at least one molecular sieve (preferably zeolite). The sieve is preferable selected from NU-10, EU-1, EU-13, zeolite and ferrierite.
摘要翻译：一种用于生产非常高质量的基础油料和用于同时生产高质量中间蒸馏物的改进方法，其包括连续加氢异构化和催化脱蜡步骤，其中加氢异构化在含有至少一种沉积在无定形酸性载体上的贵金属的催化剂存在下进行，金属的分散度小于20％。载体优选为无定形二氧化硅 - 氧化铝。催化脱蜡在含有至少一种氢化脱氢元素（VIII族）和至少一种分子筛（优选沸石）的催化剂存在下进行。筛子优选选自NU-10，EU-1，EU-13，沸石和镁碱沸石。

87. 发明授权

US06548040B1 Process for preparing a zeolite with structure type MTT using specific template precursors 有权
标题翻译：使用特定模板前体制备具有MTT结构类型的沸石的方法
公开(公告)号：US06548040B1
公开(公告)日：2003-04-15
申请号：US09672053
申请日：2000-09-29
申请人： Loïc Rouleau , Frédéric Kolenda , Eric Benazzi
发明人： Loïc Rouleau , Frédéric Kolenda , Eric Benazzi
IPC分类号： C01B3948
CPC分类号： B01J20/18 , B01J29/04 , C01B39/48 , C10G45/64 , Y10S423/36
摘要： The present invention concerns a process for synthesising a zeolite with structure type MTT comprising at least one element X selected from silicon and germanium and at least one element T selected from aluminium, iron gallium, boron, titanium, vanadium, zirconium, molybdenum, arsenic, antimony, chromium and manganese, comprising reacting an aqueous mixture comprising at least one source of at least one element X, at least one source of at least one element T, and at least one precursor of an organic compound comprising at least one alkylated polymethylene &agr;-&ohgr; diammonium derivative, characterized in that at least one precursor is selected from monoamines. The present invention also concerns the use of the zeolite obtained as a catalyst in a process for converting hydrocarbon-containing feeds, as an adsorbent to control pollution and as a molecular sieve for separation.
摘要翻译：本发明涉及合成具有结构类型MTT的沸石的方法，该方法包括至少一种选自硅和锗的元素X和至少一种选自铝，铁镓，硼，钛，钒，锆，钼，砷，锑，铬和锰，包括使包含至少一种元素X的至少一种源，至少一种元素T的至少一种源的至少一种含有至少一种烷基化聚亚甲基α - 大豆二铵衍生物，其特征在于至少一种前体选自单胺。本发明还涉及在用于转化含烃原料作为吸附剂以控制污染和分离分子筛的方法中作为催化剂获得的沸石的用途。

88. 发明授权

US06333289B1 Process for activating catalysts for isomerizing aromatic compounds containing eight carbon atoms 有权
标题翻译：用于活化用于异构化含有8个碳原子的芳族化合物的催化剂的方法
公开(公告)号：US06333289B1
公开(公告)日：2001-12-25
申请号：US09288676
申请日：1999-04-09
申请人： Jean-François Joly , Julia Magne-Drisch , Fabio Alario , Elisabeth Merlen , Eric Benazzi , Sylvie Lacombe
发明人： Jean-François Joly , Julia Magne-Drisch , Fabio Alario , Elisabeth Merlen , Eric Benazzi , Sylvie Lacombe
IPC分类号： B01J2100
CPC分类号： B01J29/7446 , B01J29/18 , B01J29/22 , B01J29/7246 , B01J33/00 , B01J37/20 , B01J2229/26 , B01J2229/42 , C07C5/2724 , C07C2529/72 , C07C15/067
摘要： The present invention relates to a process for activating catalysts for isomerizing aromatic compounds containing 8 carbon atoms, the catalysts containing at least one group VIII metal, comprising at least one sulfurization and at least one passivation using ammonia.
摘要翻译：本发明涉及一种用于使含有8个碳原子的芳族化合物异构化的催化剂的活化方法，含有至少一种第Ⅷ族金属的催化剂，包括至少一种硫化和至少一种使用氨的钝化。

89. 发明授权

US06235960B1 Process for improving the pour point, and a catalyst based on at least one MTT, Ton or Fer zeolite 有权
标题翻译：改善倾点的方法，以及基于至少一种MTT，Ton或Fer沸石的催化剂
公开(公告)号：US06235960B1
公开(公告)日：2001-05-22
申请号：US09310181
申请日：1999-05-12
申请人： Eric Benazzi , Slavik Kasztelan , Nathalie George-Marchal
发明人： Eric Benazzi , Slavik Kasztelan , Nathalie George-Marchal
IPC分类号： C07C513
CPC分类号： C10G45/64 , B01J29/67 , B01J29/7284 , B01J29/7292 , B01J29/7484 , B01J29/7492 , B01J29/7884 , B01J29/7892 , B01J35/1061 , B01J35/1085 , B01J2229/26 , B01J2229/42
摘要： A process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which the feed to be treated is brought into contact with a catalyst comprising at least one zeolite with structure type MTT, TON or FER or any possible combination of these three, at least one hydro-dehydrogenating element selected from elements from group VIB and group VIII of the periodic table, at least one deposited promoter element (boron, silicon, phosphorous), optionally at least one group VIIA element, optionally at least one group VIIB element, at a temperature in the range 170° C. to 500° C., a pressure in the range 1 to 250 bars and at an hourly space velocity in the range 0.05 to 100 h−1, in the presence of hydrogen in an amount of 50 to 2000 l/l of feed. The oils obtained have good pour points and high viscosity indices (VI). The process is also applicable to gas oils, and other feeds requiring a reduction in pour point. The invention also relates to a catalyst containing silicon and to its use for converting hydrocarbon-containing feeds.
摘要翻译：一种用于改进含有多于10个碳原子的链烷烃的进料的倾点的方法，其中待处理的进料与包含至少一种结构类型为MTT，TON或FER的沸石或任何可能的组合的催化剂接触这些三种中的至少一种选自元素周期表第VIB族和第VIII族元素的至少一种加氢脱氢元素，至少一种沉积的促进元素（硼，硅，磷），任选至少一种VIIA族元素，任选至少一组VIIB元素，在170℃至500℃的温度范围内，压力范围为1至250巴，时间空间速度为0.05至100小时-1，在存在量为50至2000升/升的进料的氢。所得油具有良好的倾点和高粘度指数（VI）。该方法也适用于需要降低倾点的瓦斯油和其它进料。本发明还涉及含硅的催化剂及其用于转化含烃物料的用途。

90. 发明授权

US06197276B1 Hydrated aluminum compounds, their preparation and use thereof 失效
标题翻译：水合铝化合物，其制备和用途
公开(公告)号：US06197276B1
公开(公告)日：2001-03-06
申请号：US09249077
申请日：1999-02-12
申请人： Frédéric Kolenda , Jean-Louis Guth , Sabine Valange , Zelimir Gabelica , Eric Benazzi
发明人： Frédéric Kolenda , Jean-Louis Guth , Sabine Valange , Zelimir Gabelica , Eric Benazzi
IPC分类号： C01F702
CPC分类号： C01F7/34 , C01B37/00 , C01P2002/72 , C01P2002/78 , C01P2002/86
摘要： Hydrated aluminium compounds of the present invention are represented by the general formula nS, mM, Al2O3, xH2O where S is a surfactant or a group of surfactants, n is the number of moles of S, M is an alkaline cation, preferably selected from the group formed by Na+, K+, NH4+, m is the number of moles of M and x is the number of moles of water. The hydrated compounds are obtained from inorganic aluminium sources which are in the form of cation-monomers and/or cation-oligomers. The surfactants are anionic and/or non-ionic surfactants. When the group of surfactants comprises at least one anionic surfactant, at least one cationic surfactant can optionally be added.
摘要翻译：本发明的水合铝化合物由通式nS，mM，Al 2 O 3，xH 2 O表示，其中S是表面活性剂或一组表面活性剂，n是S的摩尔数，M是碱性阳离子，优选选自由Na +，K +，NH 4 +，m形成的基团是M的摩尔数，x是水的摩尔数。水合化合物由阳离子单体和/或阳离子低聚物形式的无机铝源获得。表面活性剂是阴离子和/或非离子表面活性剂。当该组表面活性剂包含至少一种阴离子表面活性剂时，可以任选地加入至少一种阳离子表面活性剂。

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