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71. 发明专利

JP2007231060A Curable composition and coated article 审中-公开
标题翻译：可固化组合物和涂层物品
公开(公告)号：JP2007231060A
公开(公告)日：2007-09-13
申请号：JP2006051759
申请日：2006-02-28
申请人： Shin Etsu Chem Co Ltd , Toyota Industries Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 信越化学工業株式会社 , 株式会社豊田自動織機
发明人： HIGUCHI KOICHI , YAMATANI MASAAKI , MURAMATSU HISASHI , SENBOKU KOICHI , WATANABE TOSHIO , NAGAI TAKAYUKI , KONDO TOSHIRO
IPC分类号： C08L101/10 , C08K5/3477 , C08K5/5415
CPC分类号： C09D183/06 , C08L83/06 , C09D143/04 , C08L2666/02
摘要： PROBLEM TO BE SOLVED: To provide a curable composition for forming protective coating film free from drawbacks including cracking, debonding and yellowing under long-term use and excellent in weatherability, and to provide a coated article using the composition. SOLUTION: The curable composition comprises (A) a vinyl polymer where hydrolyzable silyl groups and/or SiOH groups and organic ultraviolet-absorbing groups are bound to the side chains, (B) an organic ultraviolet light absorber 500 or higher in molecular weight and 95% or greater in mass residue percentage when kept at 150°C for 24 h under opened state, and (C) an organosilicon compound having in the molecule a nitrogen atom and an alkoxysilyl group. This curable composition, because being markedly improved in light resistance, prevented from the ultraviolet light absorber's being washed away and used as a weatherability-rich binder, gives ultraviolet-absorbing coating film of high water resistance, high solvent resistance and high light resistance. When a weatherability-poor article is coated/cured with this curable composition, the discoloration and/or deterioration of the article is prevented and the article can be imparted with good weatherability. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种形成保护涂膜的可固化组合物，其不含长期使用下的开裂，脱粘和变黄以及耐候性优良的缺点，并提供使用该组合物的涂布制品。解决方案：可固化组合物包含（A）其中水解性甲硅烷基和/或SiOH基团和有机紫外线吸收基团与侧链结合的乙烯基聚合物，（B）分子中的有机紫外线吸收剂500以上重量和95％以上的质量残留百分比，在150℃下保持打开状态24小时，（C）分子内具有氮原子和烷氧基甲硅烷基的有机硅化合物。该可固化组合物由于耐光性显着提高，防止紫外线吸收剂被洗去并用作耐候脆性粘合剂，得到耐水性高，耐溶剂性高，耐光性高的紫外线吸收性涂膜。当用这种可固化组合物涂覆/固化耐候性差的制品时，防止了制品的变色和/或变质，并且可赋予制品良好的耐候性。版权所有（C）2007，JPO＆INPIT

72. 发明专利

JP2007176968A Silicone rubber composition for polyelectrolyte, polyelectrolyte film and method for producing the same 有权
标题翻译：用于聚电解质的硅酮橡胶组合物，聚电解质膜及其制备方法
公开(公告)号：JP2007176968A
公开(公告)日：2007-07-12
申请号：JP2005373693
申请日：2005-12-27
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： FUKUSHIMA MOTOO , IWASAKI TOMOYUKI , YAMAMOTO AKIRA , YAMATANI MASAAKI
IPC分类号： C08L83/07 , B01D67/00 , B01D71/70 , B01D71/82 , C08J3/20 , C25B13/08 , H01B1/06 , H01B13/00 , H01M8/02 , H01M8/10
CPC分类号： Y02E60/521
摘要： PROBLEM TO BE SOLVED: To provide a silicone rubber composition for a polyelectrolyte affording a polyelectrolyte film (ion conductive film) achieving a readily producible and inexpensive fuel cell having excellent strength, high heat resistance and high proton conductivity and responsive to high-temperature operation, to provide the polyelectrolyte film and to provide a method for producing the same. SOLUTION: The silicone rubber composition for the polyelectrolyte comprises (A) 100 pts.mass of a vinyl group-containing organopolysiloxane, (B) 5-100 pts.mass of either one or both of a sulfonic acid group-containing siloxane and a salt thereof and (C) 0.1-10 pts.mass of a mercapto group-containing organopolysiloxane containing at least 2 mercapto groups in one molecule. The silicone rubber composition for the polyelectrolyte is obtained as follows. The component (A) is mixed with a solution containing the component (B) and a solvent to provide a first mixture. The solvent is then removed from the first mixture to afford a second mixture. The component (C) is mixed with the second mixture. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：解决问题的方案为了提供一种提供聚电解质膜（离子导电膜）的聚电解质的硅橡胶组合物，其实现了易于生产且廉价的燃料电池，其具有优异的强度，高耐热性和高质子传导性，提供聚电解质膜并提供其制造方法。解决方案：聚电解质用硅橡胶组合物包含（A）100质量份含乙烯基的有机聚硅氧烷，（B）5-100质量份的含磺酸基的硅氧烷及其盐，（C）在一分子中含有至少2个巯基的含巯基的有机聚硅氧烷为0.1-10质量份。聚电解质的硅橡胶组合物如下获得。将组分（A）与含有组分（B）和溶剂的溶液混合以提供第一混合物。然后从第一混合物中除去溶剂，得到第二混合物。将组分（C）与第二混合物混合。版权所有（C）2007，JPO＆INPIT

73. 发明专利

JP2007146107A Antifouling property-imparting agent, antifouling coating composition, antifouling coating film and coated product therewith 有权
标题翻译：抗反射涂料代理，防喷涂组合物，防喷涂膜和涂层产品
公开(公告)号：JP2007146107A
公开(公告)日：2007-06-14
申请号：JP2006112110
申请日：2006-04-14
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： YAMATANI MASAAKI , SATO KAZUHARU
IPC分类号： C09D183/04 , C09D5/16 , C09D7/12 , C09D183/07
CPC分类号： C09D183/08 , C08G77/24 , C08G77/50 , C09D183/14 , G02B1/105 , G02B1/18 , Y10T428/31663
摘要： PROBLEM TO BE SOLVED: To provide an antifouling property-imparting agent which gives excellent scratch resistance and antifouling properties by one-time coating, by adding it to a coating composition; and to provide an antifouling coating composition etc., containing the same. SOLUTION: The antifouling property-imparting agent gives antifouling properties through adding it to a coating composition and is composed of a silicone resin having a fluorine atom-containing organic group, wherein the silicone resin has a number average molecular weight of ≥1,000 and a molar ratio of a fluorine atom to a silicon atom (F/Si) of 3-50, and is obtained by hydrolyzing/condensing an organosilicon compound having a fluorine atom-containing organic group expressed by the following formula (I) or a silane compound containing a hydrolyzate or a partial condensate of the organosilicon compound. The above-described formula (I) is expressed by R 1 R 2 m SiX 3-m (in the formula, R 1 is an organic substituent containing a fluorine atom; R 2 is an alkyl group or a phenyl group; X is a hydrolyzable group or an OH group; and m is 0 or 1). COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种防污性赋予剂，其通过将其添加到涂料组合物中而赋予优异的耐刮擦性和防污性，通过一次涂布; 并提供含有它的防污涂料组合物等。解决方案：防污性赋予剂通过将其添加到涂料组合物中而产生防污性，并且由具有含氟原子的有机基团的有机硅树脂组成，其中硅树脂的数均分子量≥1000 并且氟原子与硅原子的摩尔比（F / Si）为3-50，并且通过水解/缩合由下式（I）表示的含有氟原子的有机基团的有机硅化合物或含有有机硅化合物的水解产物或部分缩合物的硅烷化合物。上述式（I）由下式表示：（1）式（I）由式（I）表示为：R 2 式中，R 1是含有氟原子的有机取代基; R 2是烷基或苯基; X是可水解基团或OH基团;和 m为0或1）。版权所有（C）2007，JPO＆INPIT

74. 发明专利

JP2006188647A Electrically conductive transparent coating film-forming coating agent, substrate with electrically conductive transparent coating film, and method for forming electrically conductive transparent coating film 审中-公开
标题翻译：电导电透明涂料成膜剂，具有导电透明涂层膜的基材和形成导电透明涂层膜的方法
公开(公告)号：JP2006188647A
公开(公告)日：2006-07-20
申请号：JP2005091136
申请日：2005-03-28
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： FUKUSHIMA MOTOO , YAMAMOTO AKIRA , YAMATANI MASAAKI
IPC分类号： C09D4/02 , C09D5/00 , C09D5/24 , C09D7/12 , H01B5/14 , H01B13/00
摘要： PROBLEM TO BE SOLVED: To provide an electrically conductive transparent coating film-forming coating agent capable of forming high-hardness and electrical conductivity-improving transparent coating film through forming electrically conductive layer without causing cracks in forming the transparent coating film, and to provide a substrate bearing an electrically conductive transparent coating film using the coating agent.
SOLUTION: The electrically conductive transparent coating film-forming coating agent consists of a composition comprising a matrix precursor comprising (i) a methacryloxy or acryloxy group-containing silane compound and/or a hydrolyzate thereof, (ii) a methacryloxy or acryloxy group-containing polymerizable acid phosphate and (iii) a radical-generating compound. Particularly, in the matrix precursor, the mass ratio (i)/(ii) is (10:90) to (70:30) on a solid basis.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种能够通过形成导电层而形成高硬度和导电性改善的透明涂膜而不会在形成透明涂膜时产生裂纹的导电透明涂膜形成涂层剂，以及以提供使用该涂层剂承载导电透明涂膜的基片。导电性透明涂膜形成用涂布剂由包含（i）含甲基丙烯酰氧基或含丙烯酰氧基的硅烷化合物和/或其水解物的基质前体的组合物组成，（ii）甲基丙烯酰氧基或丙烯酰氧基含有基团的可聚合酸性磷酸酯和（iii）自由基产生化合物。特别地，在基质前体中，以固体为基准，质量比（i）/（ii）为（10:90）〜（70:30）。版权所有（C）2006，JPO＆NCIPI

75. 发明专利

JP2006152245A Flame-retardant polycarbonate resin composition and its molding 有权
标题翻译：阻燃聚碳酸酯树脂组合物及其模塑
公开(公告)号：JP2006152245A
公开(公告)日：2006-06-15
申请号：JP2005239296
申请日：2005-08-22
申请人： Mitsubishi Gas Chem Co Inc , Shin Etsu Chem Co Ltd , 三菱瓦斯化学株式会社 , 信越化学工業株式会社
发明人： ITAGAKI AKINARI , TANAKA MASAKI , YAMATANI MASAAKI , ADACHI TAKAHIRO , NORISUE YASUMASA , KANAYAMA SATOSHI
IPC分类号： C08L69/00 , C08G65/326 , C08L71/12 , C08L83/04
摘要： PROBLEM TO BE SOLVED: To obtain a flame-retardant polycarbonate resin composition that does not use a halogen-based or phosphorus-based flame retardant causing environmental pollution and performance degradation, satisfies a severe flame-retardant level equal to that obtained by using the halogen-based or phosphorus-based flame retardant and yet has excellent mechanical strength, heat stability, transparency, etc., and its molding.
SOLUTION: The flame-retardant polycarbonate resin composition is obtained by mixing 100 parts by mass of a polycarbonate resin with 0.01-3.0 parts by mass of an alkali metal or an alkaline earth metal salt of sulfonic acid of PPE (polyphenylene ether) oligomer. The molding is obtained by molding the composition.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题为了获得不使用引起环境污染和性能降解的卤素或磷系阻燃剂的阻燃性聚碳酸酯树脂组合物，满足与使用卤素或磷基阻燃剂，但具有优异的机械强度，热稳定性，透明度等，以及其成型。解决方案：阻燃聚碳酸酯树脂组合物通过将100质量份聚碳酸酯树脂与0.01-3.0质量份的PPE（聚苯醚）磺酸的碱金属或碱土金属盐混合，低聚物。通过模塑该组合物获得模制品。版权所有（C）2006，JPO＆NCIPI

76. 发明专利

JP2006131770A Conductive silicone material and conductive coating film 审中-公开
标题翻译：导电硅材料和导电涂膜
公开(公告)号：JP2006131770A
公开(公告)日：2006-05-25
申请号：JP2004322800
申请日：2004-11-05
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： IWASAKI TOMOYUKI , YAMATANI MASAAKI
IPC分类号： C08G77/392 , C09D5/24 , C09D183/08 , H01B1/04 , H01B1/24
摘要： PROBLEM TO BE SOLVED: To provide a conductive silicone material which comprises an ion conductive substituent-having organopolysiloxane, especially has good coating film formability as a coating and excellent heat resistance, and scarcely changes surface resistance value with the passage of time, and to provide a conductive coating film comprising the material.
SOLUTION: This conductive silicone material comprises an organopolysiloxane obtained by a method comprising a process for supplying a mercapto group-free silane compound A and a mercapto group-having silane compound B into a reaction system and then proceeding a cohydrolysis reaction and a polycondensation to obtain the organopolysiloxane sol solution, a process for drying and solidifying the sol solution to obtain the solid product, and a process for oxidizing the mercapto groups of the solid product. And the conductive coating film comprising the conductive silicone material.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种包含具有离子导电取代基的有机聚硅氧烷的导电性硅酮材料，特别是作为涂层具有良好的涂膜成形性和优异的耐热性，并且随着时间的推移几乎不改变表面电阻值，并提供包含该材料的导电涂膜。解决方案：该导电硅酮材料包括通过包括将无巯基硅烷化合物A和含巯基的硅烷化合物B供给到反应体系中然后进行共水解反应和缩聚得到有机聚硅氧烷溶胶溶液，干燥固化溶胶溶液以获得固体产物的方法，以及固化产物的巯基氧化方法。并且导电涂膜包含导电硅材料。版权所有（C）2006，JPO＆NCIPI

77. 发明专利

JP2005314616A Silicone coating composition and article to be coated 审中-公开
标题翻译：硅胶涂料组合物和待包装的物品
公开(公告)号：JP2005314616A
公开(公告)日：2005-11-10
申请号：JP2004136124
申请日：2004-04-30
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： HIGUCHI KOICHI , YAMATANI MASAAKI
IPC分类号： C08G77/04 , C08G77/16 , C08J7/04 , C08K5/19 , C08K5/50 , C09D7/12 , C09D183/02 , C09D183/04
CPC分类号： C09D183/04 , C08G77/16 , C08J7/047 , C08J2483/04 , C08K5/19 , C08K5/50 , Y10T428/31663
摘要： PROBLEM TO BE SOLVED: To provide a silicone coating composition which has excellent storage stability, and can form a coating film having high hardness, scratch resistance, adhesiveness, toughness, and crack resistance, and to provide an article to be coated which has this cured coating layer on a surface of its base material. SOLUTION: The silicone coating composition comprises (A) a silicone resin in which at least one kind of alkoxy silane of the formula: (R 1 ) m (R 2 ) n Si(OR 3 ) 4-m-n (wherein R 1 , R 2 are each H or a monovalent hydrocarbon group, R 3 is an alkyl group, m, n are each 0 or 1, and m+n is 0, 1, or 2) and its partially hydrolyzed/condensed material are (co-)hydrolyzed/condensed; (B) a compound which does not include an aromatic group of the formula: [(R 4 )(R 5 )(R 6 )(R 7 )M] + X - (wherein R 4 -R 7 are each an alkyl group, and a total of Taft-Dubois substituent stereo effect coefficient Es is ≤-0.5. M is an ammonium or phosphonium cation, X - is halogen, a hydroxide, or a carboxylate anion), and (C) a solvent. The coating on the cured coating layer is applied on the article to be coated. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种具有优异的储存稳定性的硅酮涂料组合物，并且可以形成具有高硬度，耐划伤性，粘合性，韧性和抗裂性的涂膜，并提供一种待涂布的制品在其基材的表面上具有固化的涂层。聚硅氧烷涂料组合物包含（A）有机硅树脂，其中至少一种下式的烷氧基硅烷：（R 1 SP＆lt; SP＆gt;）其中R 2 ）其中R 2 ，R 2 SP 2各自为H或一价烃基，R 3为烷基，m，n各自为0或1，m + n为0,1 ，或2），其部分水解/缩合的材料是（共）水解/缩合的; （B）不包括下式的芳族基团的化合物：[（R SP 5）（R SP 5））（R SP 5）（R 7 ）M] + X - （其中R 4 -R > - >均为烷基，Taft-Dubois取代立体效应系数Es的总和≤0.5，M为铵或鏻阳离子，X为卤素，氢氧根或羧酸根阴离子）和（C）溶剂。将固化的涂层上的涂层施加在待涂覆的制品上。版权所有（C）2006，JPO＆NCIPI

78. 发明专利

JP2005200546A Silicone resin composition and article covered with the same 审中-公开
标题翻译：硅胶树脂组合物及其盖章
公开(公告)号：JP2005200546A
公开(公告)日：2005-07-28
申请号：JP2004008291
申请日：2004-01-15
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： HIGUCHI KOICHI , YAMATANI MASAAKI
IPC分类号： C08G77/14 , C08G77/06 , C08G77/16 , C08G77/18 , C08J7/04 , C09D183/04
CPC分类号： C08J7/047 , C08G77/06 , C08G77/16 , C08G77/18 , C08J2483/00 , C09D183/04 , Y10T428/31663
摘要： PROBLEM TO BE SOLVED: To provide a silicone resin composition providing a cured product having high hardness and excellent scratch resistance, and also having excellent crack resistance, adhesiveness, water resistance, heat resistance and weather resistance, and effective as a coating agent forming a protective coated film on the surface of an organic resin base material or the like. SOLUTION: The silicone resin composition contains the following silicone resin, a curing catalyst and a solvent as essential components: the silicone resin is obtained by co-hydrolyzing and condensing 1-50 Si-mol% tetraalkoxysilane, 50-99 Si-mol% trialkoxysilane and 0-10 Si-mol% dialkoxysilane by using 1 SiO 3/2 may be 30-80 mol% and the total content of units represented by R 1 SiO 2/2 (OX) and R 1 SiO 1/2 (OX) 2 may be 20-70 mol% in a nuclear magnetic resonance spectrometry. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：解决问题的方案：提供一种具有高硬度和优异的耐刮擦性的固化产物的硅树脂组合物，并且还具有优异的抗裂性，粘合性，耐水性，耐热性和耐候性，并且作为涂布剂有效在有机树脂基材等的表面上形成保护涂膜。解决方案：硅树脂组合物含有以下有机硅树脂，固化催化剂和溶剂作为必要组分：硅氧烷树脂通过将1-50Si-mol％四烷氧基硅烷，50-99 Si- mol％三烷氧基硅烷和0-10Si-mol％二烷氧基硅烷，使用<100重量份水基100重量份总共的烷氧基硅烷具有≥1,500个数均分子量，并且被调节为使得由R 1 SiO 3/2 表示的单元的含量可以为30- 80摩尔％，由R 1表示的单位的总含量SiO 2/2（SB）（OX）和R SP 1 SiO 2 / 在核磁共振光谱法中，2 （OX） 2 可以为20-70mol％。版权所有（C）2005，JPO＆NCIPI

79. 发明专利

JP2004315712A Coating material composition for forming protective coating film, coated article, and multilayer laminate product 有权
公开(公告)号：JP2004315712A
公开(公告)日：2004-11-11
申请号：JP2003113737
申请日：2003-04-18
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： YAMATANI MASAAKI , SATO KAZUHARU , KUDO MUNEO
IPC分类号： B32B27/00 , C09D4/00 , C09D5/00 , C09D183/08 , C09D183/14
CPC分类号： C09D183/14 , C09D4/00 , Y10T428/3154 , Y10T428/31612 , Y10T428/31663 , C08G77/24
摘要： PROBLEM TO BE SOLVED: To provide a coating material composition superior in chemical resistance and scratch resistance and effective as a protective coating film for a plastic base material and the like, to provide a coated article having its hardened film, and to provide a multilayer laminate product. SOLUTION: The coating material composition for forming a protective coating film contains as the main component a disilane compound represented by the formula: X m R 1 3-m Si-Y-SiR 1 3-m X m or a (partial) hydrolysate thereof. In the formula R 1 is a 1-6C monovalent hydrocarbon group, Y is a divalent organic group containing one or more fluorine atoms, X is a hydrolyzable group, and m is 1, 2 or 3. COPYRIGHT: (C)2005,JPO&NCIPI

80. 发明专利

JP2003292893A Photocurable coating material for forming hard protective film and article having the film formed 有权
标题翻译：用于形成硬质保护膜的光刻涂料和具有电影形成的物品
公开(公告)号：JP2003292893A
公开(公告)日：2003-10-15
申请号：JP2002098734
申请日：2002-04-01
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： YOSHIKAWA YUJI , YAMATANI MASAAKI
IPC分类号： C08G77/14 , C09D5/00 , C09D183/06
摘要： PROBLEM TO BE SOLVED: To provide a photocurable coating material for forming a hard protective film which gives a highly hard film having no warpage. SOLUTION: The photocurable coating material for forming a hard protective film comprises (A) 100 pts.wt. alkoxy group-free silicone compound having a unit to be represented by the formula (1): -R 1 RSiO 2/2 - (wherein R is a hydrogen atom or a monovalent hydrocarbon group; and R 1 is an organic group having an epoxycyclohexyl group), at least three R 1 s in the molecule, a molecular weight of 500-2,100, and an R 1 equivalent weight (weight per mol R 1 ) of 180-220, (B) 30-400 pts.wt. inorganic oxide fine particles having an average particle diameter of 1-500 nm, and (C) 0.1-5 pts.wt. photo acid-generator soluble in the component (A). COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供一种形成硬保护膜的光固化性涂料，其赋予不具有翘曲的高硬度的膜。解决方案：用于形成硬保护膜的光固化涂料包括（A）100重量份具有由式（1）表示的单元的不含烷氧基的硅氧烷化合物：-R 1其中R是氢原子或一价烃基; R 1是具有环氧环己基的有机基团），分子中至少三个R SP 1，分子量500-2,100，和 180-220的当量（重量/摩尔R 1 ），（B）30-400重量份平均粒径为1-500nm的无机氧化物细颗粒，（C）0.1-5重量份可溶于组分（A）的光产酸剂。版权所有（C）2004，JPO

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