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71. 发明专利

JP2006131770A Conductive silicone material and conductive coating film 审中-公开
标题翻译：导电硅材料和导电涂膜
公开(公告)号：JP2006131770A
公开(公告)日：2006-05-25
申请号：JP2004322800
申请日：2004-11-05
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： IWASAKI TOMOYUKI , YAMATANI MASAAKI
IPC分类号： C08G77/392 , C09D5/24 , C09D183/08 , H01B1/04 , H01B1/24
摘要： PROBLEM TO BE SOLVED: To provide a conductive silicone material which comprises an ion conductive substituent-having organopolysiloxane, especially has good coating film formability as a coating and excellent heat resistance, and scarcely changes surface resistance value with the passage of time, and to provide a conductive coating film comprising the material.
SOLUTION: This conductive silicone material comprises an organopolysiloxane obtained by a method comprising a process for supplying a mercapto group-free silane compound A and a mercapto group-having silane compound B into a reaction system and then proceeding a cohydrolysis reaction and a polycondensation to obtain the organopolysiloxane sol solution, a process for drying and solidifying the sol solution to obtain the solid product, and a process for oxidizing the mercapto groups of the solid product. And the conductive coating film comprising the conductive silicone material.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种包含具有离子导电取代基的有机聚硅氧烷的导电性硅酮材料，特别是作为涂层具有良好的涂膜成形性和优异的耐热性，并且随着时间的推移几乎不改变表面电阻值，并提供包含该材料的导电涂膜。解决方案：该导电硅酮材料包括通过包括将无巯基硅烷化合物A和含巯基的硅烷化合物B供给到反应体系中然后进行共水解反应和缩聚得到有机聚硅氧烷溶胶溶液，干燥固化溶胶溶液以获得固体产物的方法，以及固化产物的巯基氧化方法。并且导电涂膜包含导电硅材料。版权所有（C）2006，JPO＆NCIPI

72. 发明专利

JP2005314616A Silicone coating composition and article to be coated 审中-公开
标题翻译：硅胶涂料组合物和待包装的物品
公开(公告)号：JP2005314616A
公开(公告)日：2005-11-10
申请号：JP2004136124
申请日：2004-04-30
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： HIGUCHI KOICHI , YAMATANI MASAAKI
IPC分类号： C08G77/04 , C08G77/16 , C08J7/04 , C08K5/19 , C08K5/50 , C09D7/12 , C09D183/02 , C09D183/04
CPC分类号： C09D183/04 , C08G77/16 , C08J7/047 , C08J2483/04 , C08K5/19 , C08K5/50 , Y10T428/31663
摘要： PROBLEM TO BE SOLVED: To provide a silicone coating composition which has excellent storage stability, and can form a coating film having high hardness, scratch resistance, adhesiveness, toughness, and crack resistance, and to provide an article to be coated which has this cured coating layer on a surface of its base material. SOLUTION: The silicone coating composition comprises (A) a silicone resin in which at least one kind of alkoxy silane of the formula: (R 1 ) m (R 2 ) n Si(OR 3 ) 4-m-n (wherein R 1 , R 2 are each H or a monovalent hydrocarbon group, R 3 is an alkyl group, m, n are each 0 or 1, and m+n is 0, 1, or 2) and its partially hydrolyzed/condensed material are (co-)hydrolyzed/condensed; (B) a compound which does not include an aromatic group of the formula: [(R 4 )(R 5 )(R 6 )(R 7 )M] + X - (wherein R 4 -R 7 are each an alkyl group, and a total of Taft-Dubois substituent stereo effect coefficient Es is ≤-0.5. M is an ammonium or phosphonium cation, X - is halogen, a hydroxide, or a carboxylate anion), and (C) a solvent. The coating on the cured coating layer is applied on the article to be coated. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种具有优异的储存稳定性的硅酮涂料组合物，并且可以形成具有高硬度，耐划伤性，粘合性，韧性和抗裂性的涂膜，并提供一种待涂布的制品在其基材的表面上具有固化的涂层。聚硅氧烷涂料组合物包含（A）有机硅树脂，其中至少一种下式的烷氧基硅烷：（R 1 SP＆lt; SP＆gt;）其中R 2 ）其中R 2 ，R 2 SP 2各自为H或一价烃基，R 3为烷基，m，n各自为0或1，m + n为0,1 ，或2），其部分水解/缩合的材料是（共）水解/缩合的; （B）不包括下式的芳族基团的化合物：[（R SP 5）（R SP 5））（R SP 5）（R 7 ）M] + X - （其中R 4 -R > - >均为烷基，Taft-Dubois取代立体效应系数Es的总和≤0.5，M为铵或鏻阳离子，X为卤素，氢氧根或羧酸根阴离子）和（C）溶剂。将固化的涂层上的涂层施加在待涂覆的制品上。版权所有（C）2006，JPO＆NCIPI

73. 发明专利

JP2005200546A Silicone resin composition and article covered with the same 审中-公开
标题翻译：硅胶树脂组合物及其盖章
公开(公告)号：JP2005200546A
公开(公告)日：2005-07-28
申请号：JP2004008291
申请日：2004-01-15
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： HIGUCHI KOICHI , YAMATANI MASAAKI
IPC分类号： C08G77/14 , C08G77/06 , C08G77/16 , C08G77/18 , C08J7/04 , C09D183/04
CPC分类号： C08J7/047 , C08G77/06 , C08G77/16 , C08G77/18 , C08J2483/00 , C09D183/04 , Y10T428/31663
摘要： PROBLEM TO BE SOLVED: To provide a silicone resin composition providing a cured product having high hardness and excellent scratch resistance, and also having excellent crack resistance, adhesiveness, water resistance, heat resistance and weather resistance, and effective as a coating agent forming a protective coated film on the surface of an organic resin base material or the like. SOLUTION: The silicone resin composition contains the following silicone resin, a curing catalyst and a solvent as essential components: the silicone resin is obtained by co-hydrolyzing and condensing 1-50 Si-mol% tetraalkoxysilane, 50-99 Si-mol% trialkoxysilane and 0-10 Si-mol% dialkoxysilane by using 1 SiO 3/2 may be 30-80 mol% and the total content of units represented by R 1 SiO 2/2 (OX) and R 1 SiO 1/2 (OX) 2 may be 20-70 mol% in a nuclear magnetic resonance spectrometry. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：解决问题的方案：提供一种具有高硬度和优异的耐刮擦性的固化产物的硅树脂组合物，并且还具有优异的抗裂性，粘合性，耐水性，耐热性和耐候性，并且作为涂布剂有效在有机树脂基材等的表面上形成保护涂膜。解决方案：硅树脂组合物含有以下有机硅树脂，固化催化剂和溶剂作为必要组分：硅氧烷树脂通过将1-50Si-mol％四烷氧基硅烷，50-99 Si- mol％三烷氧基硅烷和0-10Si-mol％二烷氧基硅烷，使用<100重量份水基100重量份总共的烷氧基硅烷具有≥1,500个数均分子量，并且被调节为使得由R 1 SiO 3/2 表示的单元的含量可以为30- 80摩尔％，由R 1表示的单位的总含量SiO 2/2（SB）（OX）和R SP 1 SiO 2 / 在核磁共振光谱法中，2 （OX） 2 可以为20-70mol％。版权所有（C）2005，JPO＆NCIPI

74. 发明专利

JP2004315712A Coating material composition for forming protective coating film, coated article, and multilayer laminate product 有权
公开(公告)号：JP2004315712A
公开(公告)日：2004-11-11
申请号：JP2003113737
申请日：2003-04-18
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： YAMATANI MASAAKI , SATO KAZUHARU , KUDO MUNEO
IPC分类号： B32B27/00 , C09D4/00 , C09D5/00 , C09D183/08 , C09D183/14
CPC分类号： C09D183/14 , C09D4/00 , Y10T428/3154 , Y10T428/31612 , Y10T428/31663 , C08G77/24
摘要： PROBLEM TO BE SOLVED: To provide a coating material composition superior in chemical resistance and scratch resistance and effective as a protective coating film for a plastic base material and the like, to provide a coated article having its hardened film, and to provide a multilayer laminate product. SOLUTION: The coating material composition for forming a protective coating film contains as the main component a disilane compound represented by the formula: X m R 1 3-m Si-Y-SiR 1 3-m X m or a (partial) hydrolysate thereof. In the formula R 1 is a 1-6C monovalent hydrocarbon group, Y is a divalent organic group containing one or more fluorine atoms, X is a hydrolyzable group, and m is 1, 2 or 3. COPYRIGHT: (C)2005,JPO&NCIPI

75. 发明专利

JP2003292893A Photocurable coating material for forming hard protective film and article having the film formed 有权
标题翻译：用于形成硬质保护膜的光刻涂料和具有电影形成的物品
公开(公告)号：JP2003292893A
公开(公告)日：2003-10-15
申请号：JP2002098734
申请日：2002-04-01
申请人： Shin Etsu Chem Co Ltd , 信越化学工業株式会社
发明人： YOSHIKAWA YUJI , YAMATANI MASAAKI
IPC分类号： C08G77/14 , C09D5/00 , C09D183/06
摘要： PROBLEM TO BE SOLVED: To provide a photocurable coating material for forming a hard protective film which gives a highly hard film having no warpage. SOLUTION: The photocurable coating material for forming a hard protective film comprises (A) 100 pts.wt. alkoxy group-free silicone compound having a unit to be represented by the formula (1): -R 1 RSiO 2/2 - (wherein R is a hydrogen atom or a monovalent hydrocarbon group; and R 1 is an organic group having an epoxycyclohexyl group), at least three R 1 s in the molecule, a molecular weight of 500-2,100, and an R 1 equivalent weight (weight per mol R 1 ) of 180-220, (B) 30-400 pts.wt. inorganic oxide fine particles having an average particle diameter of 1-500 nm, and (C) 0.1-5 pts.wt. photo acid-generator soluble in the component (A). COPYRIGHT: (C)2004,JPO
摘要翻译：要解决的问题：提供一种形成硬保护膜的光固化性涂料，其赋予不具有翘曲的高硬度的膜。解决方案：用于形成硬保护膜的光固化涂料包括（A）100重量份具有由式（1）表示的单元的不含烷氧基的硅氧烷化合物：-R 1其中R是氢原子或一价烃基; R 1是具有环氧环己基的有机基团），分子中至少三个R SP 1，分子量500-2,100，和 180-220的当量（重量/摩尔R 1 ），（B）30-400重量份平均粒径为1-500nm的无机氧化物细颗粒，（C）0.1-5重量份可溶于组分（A）的光产酸剂。版权所有（C）2004，JPO

76. 发明专利

JP2003059343A Conductive film and its manufacturing method 有权
标题翻译：导电膜及其制造方法
公开(公告)号：JP2003059343A
公开(公告)日：2003-02-28
申请号：JP2001251834
申请日：2001-08-22
申请人： Nihon University , Shin Etsu Chem Co Ltd , 信越化学工業株式会社 , 学校法人日本大学
发明人： NISHIDE RIICHI , MATSUMURA KAZUYUKI , YAMATANI MASAAKI , YAMAMOTO AKIRA
IPC分类号： H01B5/14 , H01B13/00
摘要： PROBLEM TO BE SOLVED: To provide a new conductive film usable as a hardened coat excellent in adhesion to various kinds of base materials such as glass, ceramics, metal and plastics and in abrasion resistance, having high conductivity and transparency and capable of being simply applied at a low cost by a wet method, and useful for an electromagnetic wave shield material, an antistatic material or a transparent electrode requiring transparency and/or conductivity.
SOLUTION: This conductive film is characterized by comprising a gel film containing metal ions having n-valent (n is a valence of metal) electric charge, and at least one kind of metal ions having electric charge selected from (n-2)-valent, (n-1)-valent and (n+1)-valent charge.
COPYRIGHT: (C)2003,JPO
摘要翻译：要解决的问题：提供一种新的导电膜，其可用作与各种基材如玻璃，陶瓷，金属和塑料的粘合性和耐磨性优异的硬化涂层，具有高导电性和透明度并且能够简单地应用通过湿法以低成本，并且对于电磁波屏蔽材料，抗静电材料或需要透明度和/或导电性的透明电极是有用的。解决方案：该导电膜的特征在于包含含有n价金属离子（n为金属价）电荷的凝胶膜，以及至少一种具有选自（n-2）价电荷的电荷的金属离子，（n-1）价和（n + 1）价电荷。

77. 发明专利

JP2012224077A Organic resin laminated body 有权
标题翻译：有机树脂层压体
公开(公告)号：JP2012224077A
公开(公告)日：2012-11-15
申请号：JP2012064699
申请日：2012-03-22
申请人： Exatec Llc , Shin-Etsu Chemical Co Ltd , エグザテック・リミテッド・ライアビリティー・カンパニーExatec,LLC. , 信越化学工業株式会社
发明人： GILLIAM MARY , HIGUCHI KOICHI , YAMATANI MASAAKI
IPC分类号： B32B27/28 , C09C1/04 , C09C1/36 , C09C3/06 , C09D5/00 , C09D7/12 , C09D133/00 , C09D183/02 , C09D183/04
CPC分类号： C08J7/045 , C08J2383/04 , C08J2483/02 , Y10T428/24983 , Y10T428/256 , Y10T428/257
摘要： PROBLEM TO BE SOLVED: To provide an organic resin laminated body which develops abrasion resistance and ultraviolet screening properties while laminated films maintain transparency of visible light, has weatherability and durability that can endure long-term outdoor exposure and is suitable for outdoor use such as a vehicle, a window of a transportation facility such as an aircraft, protection against wind, a building window and a sound insulation wall along a road.SOLUTION: The organic resin laminated body includes an organic resin base material and a plurality of coating layers, and has ultraviolet screening properties and abrasion resistance. The plurality of coating layers include: an outermost surface layer (I) constituted by plasma polymerization of an organosilicon compound; a lower layer (II) of a silicone coating composition containing a composite oxide particle dispersive substance, silicone resin, a catalytic hardener and a solvent; and a lower layer (III) of acrylic resin, optionally.
摘要翻译：要解决的问题：提供一种显影耐磨性和紫外线屏蔽性的有机树脂层压体，同时层压膜保持可见光的透明度，具有耐久性和耐久性，可承受长期室外暴露并适合户外使用例如车辆，诸如飞机的运输设施的窗口，防风，建筑物窗和沿道路的隔音墙。解决方案：有机树脂层压体包括有机树脂基材和多个涂层，并且具有紫外线屏蔽性和耐磨性。多个涂层包括：由有机硅化合物的等离子体聚合构成的最外表面层（I）含有复合氧化物粒子分散物质的有机硅涂料组合物的下层（II），有机硅树脂，催化固化剂和溶剂; 和丙烯酸树脂的下层（III），任选地。版权所有（C）2013，JPO＆INPIT

78. 发明专利

JP2010261012A Uv-shielding coating composition and coated article 审中-公开
标题翻译：紫外线防护涂料组合物和涂层物品
公开(公告)号：JP2010261012A
公开(公告)日：2010-11-18
申请号：JP2010051511
申请日：2010-03-09
申请人： Shin-Etsu Chemical Co Ltd , 信越化学工業株式会社
发明人： HIGUCHI KOICHI , YAMATANI MASAAKI
IPC分类号： C09D5/32 , C08F230/08 , C09D5/00 , C09D7/12 , C09D125/04 , C09D133/08 , C09D133/10 , C09D133/20 , C09D133/24 , C09D135/08 , C09D183/07
CPC分类号： C09D143/04 , C08K3/22 , C08K9/02 , C09D5/32 , C09D7/62 , C09D7/67 , C09D7/68 , Y10T428/249991 , Y10T428/31663
摘要： PROBLEM TO BE SOLVED: To provide a coating composition of which the cured coating film develops scratch resistance and UV-shielding properties while maintaining transparency to visible light and also has weatherability and durability sustainable during long-term outdoor exposure, and a coated article coated with the composition. SOLUTION: A UV-shielding coating composition contains (A) a dispersion of composite zinc oxide fine particles that is obtained by dispersing composite zinc oxide fine particles, which is obtained by coating surfaces of zinc oxide fine particles with at least one selected from an oxide or a hydroxide of Al, Si, Zr and Sn, in a dispersing medium, and that has photocatalytic degradability 12 hours after black light irradiation of 25% or less in evaluation of photocatalytic degradability which is calculated from the following formula: photocatalytic degradability (%)=[(A0-A)/A0]×100 (wherein A0 is an initial absorbance and A is an absorbance after light irradiation) by using change of the absorbance at 653 nm when the dispersion of composite zinc oxide fine particles is added into methylene blue solution and absorbance at 653 nm is measured before and after black light irradiation, (B) a vinyl copolymer obtained from copolymerization of 1-50 mass% of an alkoxysilyl group-containing vinyl monomer, 5-40 mass% of a UV-absorbing vinyl monomer, and 10-94 mass% of another monomer copolymerizable with these vinyl monomers, and (C) a solvent. Also, the solid content of the composite zinc oxide in (A) the dispersion of composite zinc oxide fine particles is 1-50 mass% based on the solid content of (B) the vinyl copolymer. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供固化涂膜显影耐刮擦性和紫外线屏蔽性同时保持对可见光的透明度并且还具有耐久性和耐久性在长期室外暴露期间可持续的涂料组合物，以及涂布制品涂有组合物。 UV屏蔽涂料组合物含有（A）通过分散复合氧化锌微粒得到的复合氧化锌微粒的分散体，该复合氧化锌微粒是通过将至少一种所选择的氧化锌微粒的表面从分散介质中的Al，Si，Zr和Sn的氧化物或氢氧化物中分离，并且在由下式计算的光催化降解性评价为25％以下，黑光照射后12小时具有光催化降解性：光催化降解性（％）= [（A0-A）/ A0]×100（其中A0是初始吸光度，A是光照射后的吸光度），当复合氧化锌微粒分散时，通过使653nm处的吸光度的变化加入到亚甲基蓝溶液中，并且在黑光照射之前和之后测量在653nm处的吸光度，（B）由1-50质量％的含烷氧基甲硅烷基的葡萄 5-40质量％的紫外线吸收性乙烯基单体和10-94质量％的可与这些乙烯基单体共聚的单体，和（C）溶剂。此外，（A）复合氧化锌微粒的分散液中的复合氧化锌的固体成分，相对于（B）乙烯基共聚物的固体成分为1-50质量％。版权所有（C）2011，JPO＆INPIT

79. 发明专利

JP2012229449A Ion-conductive polymer material, method for producing the same, and ion-conductive polymer derivative 有权
标题翻译：导电聚合物材料，其制造方法和导电聚合物衍生物
公开(公告)号：JP2012229449A
公开(公告)日：2012-11-22
申请号：JP2012188297
申请日：2012-08-29
申请人： Shin-Etsu Chemical Co Ltd , 信越化学工業株式会社
发明人： FUKUSHIMA MOTOO , YAMATANI MASAAKI
IPC分类号： C08F220/56
摘要： PROBLEM TO BE SOLVED: To provide a method for producing an ion-conductive polymer material capable of imparting the film strength practically necessary for use in a fuel cell etc., imparting high electroconductivity in a hydrous state, and forming an ion-conductive film imparting the high electroconductivity even in a low-humidity state and inexpensively producible by using an environmentally safe solvent.SOLUTION: The method for producing an ion-conductive polymer material is provided, in which an unsaturated monomer is copolymerized in the presence of a hydrophilic polymerization catalyst and a lipophilic polymerization catalyst, wherein the unsaturated monomer includes (A) an unsaturated monomer represented by formula (1), (B) a sulfonic acid group-containing unsaturated monomer having at least one sulfonic acid group and at least one ethylenically unsaturated bond in the molecule, and (C) a phosphonic acid group-containing unsaturated monomer having at least one phosphonic acid group and at least one ethylenically unsaturated bond in the molecule. In formula, Ris a hydrogen atom or a methyl group; R, R, and Rare each a hydrogen atom or a substituted or unsubstituted alkyl group; m is an integer of 1-6; and n is an integer of 1-3.
摘要翻译：解决的问题：提供一种能够赋予燃料电池等实际上必需的膜强度的离子导电性高分子材料的制造方法，赋予含水状态高的导电性，导电膜即使在低湿度状态也赋予高导电性，并且通过使用环境安全的溶剂可以廉价地生产。解决方案：提供了一种离子导电聚合物材料的制备方法，其中不饱和单体在亲水聚合催化剂和亲油聚合催化剂存在下共聚合，其中不饱和单体包括（A）不饱和单体由式（1）表示，（B）分子中具有至少一个磺酸基和至少一个烯属不饱和键的含磺酸基的不饱和单体，（C）含有膦酸基的不饱和单体，至少一个膦酸基团和至少一个烯键式不饱和键。在式中，R 1 是氢原子或甲基; R 2 ，R 3 ，而R 4 或取代或未取代的烷基; m为1-6的整数; n为1-3的整数。版权所有（C）2013，JPO＆INPIT

80. 发明专利

JP2012144808A Metal surface treatment agent, metal surface treated steel product and method for treating the same, and coated steel product and method for producing the same 有权
标题翻译：金属表面处理剂，金属表面处理钢产品及其处理方法，以及涂层钢产品及其生产方法
公开(公告)号：JP2012144808A
公开(公告)日：2012-08-02
申请号：JP2012017551
申请日：2012-01-31
申请人： Shin-Etsu Chemical Co Ltd , 信越化学工業株式会社
发明人： TSUCHIDA KAZUHIRO , YAMATANI MASAAKI
IPC分类号： C23C22/07 , B05D3/10 , B05D7/14 , B32B15/08 , C09D5/00 , C09D5/08 , C09D7/12 , C09D133/00 , C09D179/02 , C09D183/14 , C23C22/23
摘要： PROBLEM TO BE SOLVED: To provide: a non-chromate metal surface treatment agent optimal for metal, especially for metal coated steel products, containing no chrome, capable of imparting excellent workability, adhesion, and corrosion resistance in pretreatment of coating of paint or the like; surface treated steel products surface-treated with the treatment agent and a surface treatment method therefor; and coated steel products having an upper layer coating film thereon and a method for producing the coated steel products.SOLUTION: The metal surface treatment agent includes: one or more silicon-containing water-soluble compound dissolved in water and/or an organic solvent, the silicon-containing water-soluble compound having a plurality of primary amino groups and a hydrolyzable silyl group and/or a silanol group; and a water dispersible silica.
摘要翻译：要解决的问题：提供：对于金属，特别是不含铬的金属涂层钢产品而言，非铬酸盐金属表面处理剂，能够赋予涂层预处理中优异的可加工性，附着力和耐腐蚀性油漆等; 用处理剂表面处理的表面处理钢产品及其表面处理方法; 以及其上具有上层涂膜的涂覆钢产品及其制造方法。解决方案：金属表面处理剂包括：溶解在水和/或有机溶剂中的一种或多种含硅水溶性化合物，具有多个伯氨基的含硅水溶性化合物和可水解的甲硅烷基和/或硅烷醇基; 和水分散二氧化硅。版权所有（C）2012，JPO＆INPIT

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