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1. 发明专利

JP2012224077A Organic resin laminated body 有权
标题翻译：有机树脂层压体
公开(公告)号：JP2012224077A
公开(公告)日：2012-11-15
申请号：JP2012064699
申请日：2012-03-22
申请人： Exatec Llc , Shin-Etsu Chemical Co Ltd , エグザテック・リミテッド・ライアビリティー・カンパニーExatec,LLC. , 信越化学工業株式会社
发明人： GILLIAM MARY , HIGUCHI KOICHI , YAMATANI MASAAKI
IPC分类号： B32B27/28 , C09C1/04 , C09C1/36 , C09C3/06 , C09D5/00 , C09D7/12 , C09D133/00 , C09D183/02 , C09D183/04
CPC分类号： C08J7/045 , C08J2383/04 , C08J2483/02 , Y10T428/24983 , Y10T428/256 , Y10T428/257
摘要： PROBLEM TO BE SOLVED: To provide an organic resin laminated body which develops abrasion resistance and ultraviolet screening properties while laminated films maintain transparency of visible light, has weatherability and durability that can endure long-term outdoor exposure and is suitable for outdoor use such as a vehicle, a window of a transportation facility such as an aircraft, protection against wind, a building window and a sound insulation wall along a road.SOLUTION: The organic resin laminated body includes an organic resin base material and a plurality of coating layers, and has ultraviolet screening properties and abrasion resistance. The plurality of coating layers include: an outermost surface layer (I) constituted by plasma polymerization of an organosilicon compound; a lower layer (II) of a silicone coating composition containing a composite oxide particle dispersive substance, silicone resin, a catalytic hardener and a solvent; and a lower layer (III) of acrylic resin, optionally.
摘要翻译：要解决的问题：提供一种显影耐磨性和紫外线屏蔽性的有机树脂层压体，同时层压膜保持可见光的透明度，具有耐久性和耐久性，可承受长期室外暴露并适合户外使用例如车辆，诸如飞机的运输设施的窗口，防风，建筑物窗和沿道路的隔音墙。解决方案：有机树脂层压体包括有机树脂基材和多个涂层，并且具有紫外线屏蔽性和耐磨性。多个涂层包括：由有机硅化合物的等离子体聚合构成的最外表面层（I）含有复合氧化物粒子分散物质的有机硅涂料组合物的下层（II），有机硅树脂，催化固化剂和溶剂; 和丙烯酸树脂的下层（III），任选地。版权所有（C）2013，JPO＆INPIT

2. 发明专利

JP2013189485A Method for producing weather-resistant coating composition and method for preventing coloration and coated article 有权
标题翻译：生产耐候涂料组合物的方法和防止涂料和涂料的方法
公开(公告)号：JP2013189485A
公开(公告)日：2013-09-26
申请号：JP2012054393
申请日：2012-03-12
申请人： Shin-Etsu Chemical Co Ltd , 信越化学工業株式会社
发明人： HIGUCHI KOICHI
IPC分类号： C09D157/00 , C09D7/12 , C09D133/14 , C09D143/04 , C09D145/00 , C09D157/06 , C09D183/04
摘要： PROBLEM TO BE SOLVED: To provide a method for producing non-colored weather-resistant coating composition and a method for preventing coloration, and to provide a coated article using the composition.SOLUTION: A method for producing a weather-resistant coating composition comprising a vinylic polymer (A) to whose side chains hydrolyzable silyl groups and organic UV ray-absorbing groups are bound, respectively, fine silica particles (B) dispersed in an organic solvent, a carbonyl group-containing organic solvent (C), an orthocarbonic ester (D), and a tertiary amine or its organic acid salt (E), includes: the following step [1] or [2]. [1]: (I) a step of preparing a coating precursor containing one or more components excluding the component (E), and (II) a step of adding the component (E) to the coating precursor. [2]: (III) a step of preparing a coating precursor containing the component (A), or containing (A) and one or more components excluding the components (D), (IV) a step of adding water to the coating precursor to partially hydrolyze the coating precursor, and (V) a step of adding the component (D) to the hydrolysate of the coating precursor.
摘要翻译：要解决的问题：提供一种生产无色耐候性涂料组合物的方法和防着色方法，并提供使用该组合物的涂布制品。方法：一种耐候性涂料组合物的制备方法，包括其侧链可水解甲硅烷基和有机紫外线吸收基的乙烯基聚合物（A）分别结合分散在有机溶剂中的二氧化硅微粒（B），含羰基的有机溶剂（C），正碳酸酯（D）和叔胺或其有机酸盐（E）包括：以下步骤[1]或[2]。 [1]：（I）制备包含除组分（E）之外的一种或多种组分的涂料前体的步骤，和（II）将组分（E）加入到涂料前体中的步骤。 [2]：（III）制备包含组分（A）或包含（A）和除组分（D），（IV）之外的一种或多种组分的涂料前体的步骤，部分水解涂料前体，和（V）将组分（D）加入到涂料前体的水解产物中的步骤。

3. 发明专利

JP2011245684A Method of manufacturing laminate 有权
标题翻译：制造层压板的方法
公开(公告)号：JP2011245684A
公开(公告)日：2011-12-08
申请号：JP2010119403
申请日：2010-05-25
申请人： Shin-Etsu Chemical Co Ltd , 信越化学工業株式会社
发明人： FUKUSHIMA MOTOO , HIGUCHI KOICHI , KOMORI HISATOSHI
IPC分类号： B32B27/30 , B32B27/00 , B32B27/36
摘要： PROBLEM TO BE SOLVED: To provide a laminate that expresses scratch resistance and UV shielding properties maintaining the transparency of visible light, further, which has the stability of a long term.SOLUTION: A method of manufacturing the laminate includes laminating a primer layer and a top layer on a surface of a base material. In addition, the method of manufacturing the laminate includes as follows. A primer composition including: a thermoplastic (meth)acrylic polymer having an alkoxysilyl group and an ultraviolet absorption group; a silicon dioxide fine particle; and a hydrolysis prevention agent preventing hydrolysis condensation of an alkoxysilyl group is applied to a surface of the base material, subsequently, on it a hardtop composition including: a cohydrolysis condensate of an organosilicon compound having an organooxy group and a silicon dioxide fine particle; and a curing catalyst making the alkoxysilyl group of the primer composition react with the organooxy group and making the cohydrolysis condensate cure is applied to be laminated, subsequently, is heated so that the hardtop composition is bridged/cured, and thereby the primer layer having thermoplasticity and the top layer having thermosetting are formed.
摘要翻译：要解决的问题：提供表现出耐久性和耐紫外线性的层压体，其保持了长期稳定性的可见光透明度。解决方案：制造层压体的方法包括在基材的表面上层叠底漆层和顶层。此外，制造层压体的方法包括如下。一种底漆组合物，其包含：具有烷氧基甲硅烷基和紫外线吸收基的热塑性（甲基）丙烯酸类聚合物; 二氧化硅微粒; 并且在基材的表面上涂布防止烷氧基甲硅烷基的水解缩合的水解防止剂，接着在其上包含具有有机氧基的有机硅化合物与二氧化硅微粒的共水解缩合物的硬顶组合物; 使使底漆组合物的烷氧基甲硅烷基与有机氧基反应并使共水解缩合物固化的固化催化剂进行层压，随后加热，使得硬顶组合物桥接/固化，由此具有热塑性的底漆层并且形成具有热固性的顶层。版权所有（C）2012，JPO＆INPIT

4. 发明专利

JP2010065076A Method for producing primer composition and coated product 有权
标题翻译：生产原料组合物和涂层产品的方法
公开(公告)号：JP2010065076A
公开(公告)日：2010-03-25
申请号：JP2008229986
申请日：2008-09-08
申请人： Shin-Etsu Chemical Co Ltd , 信越化学工業株式会社
发明人： HIGUCHI KOICHI
IPC分类号： C09D143/04 , B32B27/00 , B32B27/30 , C08J3/205 , C08K3/36 , C08K5/00 , C08L57/06 , C09D5/00 , C09D7/12 , C09D183/00
CPC分类号： C08G77/06 , C09D183/16 , Y10T428/31663
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a primer composition forming a protective coating without cracking, peeling and yellowing for a long period of time, and excellent in weatherability, having reproducibility of these properties, having good storage stability without thickening or gelling; and to provide a coated article using the composition. SOLUTION: A method for producing a primer composition to form a polysiloxane hard film comprises the following steps [1] or [2]: [1] (I) a step to prepare a primer precursor containing a vinyl polymer (A) having a hydrolyzable silyl group and an organic UV absorbing group, bonded at side chains thereof and silica fine particles (B) dispersed in an organic solvent, respectively, (II) a step to add water to the primer precursor to hydrolyze, (III) a step to add a dehydrating agent (C) to the composition containing the hydrolyzate to remove moisture contained in the composition, [2] (IV) a step to add water to (A) to hydrolyze, (V) a step to add (B) to the hydrolyzate, and (VI) a step to add (C) to the composition to remove moisture contained in the composition. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供一种长时间形成保护涂层而不会发生龟裂，剥离和变黄的底漆组合物的制备方法，并具有优异的耐候性，具有这些性能的再现性，具有良好的储存稳定性而没有增稠或胶凝; 并提供使用该组合物的涂布制品。解决方案：制备用于形成聚硅氧烷硬膜的底漆组合物的方法包括以下步骤[1]或[2]：[1]（I）制备含有乙烯基聚合物（A）的底漆前体的步骤，具有分别结合在侧链上的可水解甲硅烷基和有机UV吸收基团和分散在有机溶剂中的二氧化硅细颗粒（B），（II）步骤以向引物前体加水以水解，（III）向含有水解产物的组合物中加入脱水剂（C）以除去组合物中所含的水分的步骤，[2]（IV）向（A）中加水以水解的步骤，（V）添加步骤 B）至水解产物，和（VI）向组合物中添加（C）以除去组合物中所含的水分的步骤。版权所有（C）2010，JPO＆INPIT

5. 发明专利

JP2011037969A Coating composition and coated article 有权
标题翻译：涂料组合物和涂层物品
公开(公告)号：JP2011037969A
公开(公告)日：2011-02-24
申请号：JP2009185591
申请日：2009-08-10
申请人： Shin-Etsu Chemical Co Ltd , 信越化学工業株式会社
发明人： FUKUSHIMA MOTOO , HIGUCHI KOICHI , KOMORI HISATOSHI
IPC分类号： C09D183/04 , B32B27/00 , C08G77/52 , C08J7/04 , C09D7/12 , C09D183/07
CPC分类号： C09D183/06 , C08G77/02 , C08G77/18 , Y10T428/31663 , C08L83/00
摘要： PROBLEM TO BE SOLVED: To provide a coating composition capable of forming a cured film excellent in film-forming property, crack resistance, flexibility and water vapor barrier property without deteriorating its curability, and a coated article on which the cured film of the composition is formed.
SOLUTION: The coating composition essentially includes (A) a hydrolytic condensate of a bisphenol A alkoxysilane, (B) silica colloid sol and (C) a curing catalyst. The coated article is produced by forming a cared film of the composition.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供能够形成成膜性，抗裂纹性，柔软性和水蒸汽阻隔性优异的固化膜而不降低其固化性的涂料组合物，以及其上固化膜形成组合物。溶液：涂料组合物基本上包括（A）双酚A烷氧基硅烷的水解缩合物，（B）二氧化硅胶体溶胶和（C）固化催化剂。通过形成组合物的保护膜来制造涂覆制品。版权所有（C）2011，JPO＆INPIT

6. 发明专利

JP2013147018A Composite and method of manufacturing the same 有权
标题翻译：复合材料及其制造方法
公开(公告)号：JP2013147018A
公开(公告)日：2013-08-01
申请号：JP2012254367
申请日：2012-11-20
申请人： Shin-Etsu Chemical Co Ltd , 信越化学工業株式会社 , Teijin Ltd , 帝人株式会社
发明人： MINEMURA MASAHIKO , HIGUCHI KOICHI , TANAKA MASAKI , KOTANI TAKUJI , TSUNEMORI HIDEYUKI , KIMURA TAICHI
IPC分类号： B32B27/16 , B29C65/00
CPC分类号： B32B7/04 , B32B15/08 , B32B15/082 , B32B15/09 , B32B15/092 , B32B17/064 , B32B27/16 , B32B27/281 , B32B27/302 , B32B27/308 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/365 , B32B27/38 , B32B27/40 , B32B38/0008 , Y10T428/31507 , Y10T428/31511 , Y10T428/31525 , Y10T428/31529 , Y10T428/31551 , Y10T428/31562 , Y10T428/31565 , Y10T428/31587 , Y10T428/31598 , Y10T428/31612 , Y10T428/31663
摘要： PROBLEM TO BE SOLVED: To provide a composite formed by joining a base material composed of a resin molded body containing silicone-modified resin with another base material strongly with high durability, and to provide a method of simply manufacturing the composite.SOLUTION: A composite is formed by joining a first base material composed of a resin molded body containing silicone-modified resin with a second base material. Any one or more of ultraviolet radiation treatment, corona treatment and plasma treatment are applied to the surface of the first base material to be joined or the surfaces of the first base material and the second base material to be joined.
摘要翻译：要解决的问题：提供一种通过将具有硅氧烷改性树脂的树脂成型体与另一种基材的基材以强度高的耐久性接合形成的复合体，并提供简单制造复合材料的方法。解决方案：复合材料通过将由含有硅氧烷改性树脂的树脂成型体构成的第一基材与第二基材接合而形成。将紫外线处理，电晕处理和等离子体处理中的任何一种或多种施加到要接合的第一基底材料的表面或将要接合的第一基底材料和第二基底材料的表面。

7. 发明专利

JP2012056098A Plastic substrate for automotive glazing 有权
标题翻译：汽车玻璃塑料基板
公开(公告)号：JP2012056098A
公开(公告)日：2012-03-22
申请号：JP2010198654
申请日：2010-09-06
申请人： Shin-Etsu Chemical Co Ltd , Toyota Industries Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 信越化学工業株式会社 , 株式会社豊田自動織機
发明人： FUKUSHIMA MOTOO , HIGUCHI KOICHI , KOMORI HISATOSHI , YAMATANI MASAAKI , OKUMURA KAZUMASA , SENBOKU KOICHI , MARUYAMA YUYA , TAKAI TOMOKAZU , ISOBE YASUMITSU , KAWAMURA SHINYA , NAGAI TAKAYUKI
IPC分类号： B32B27/00 , B60J1/00 , C08F230/08 , C08G77/04 , C08K3/36 , C08L101/10 , C09D183/04
CPC分类号： C08J7/047 , C08J7/042 , C08J7/045 , C08J2369/00 , C08J2400/108 , C08J2433/04 , C08J2483/04 , C08L2201/08 , C09D5/32 , Y10T428/31507 , Y10T428/31909
摘要： PROBLEM TO BE SOLVED: To provide a plastic substrate for automotive glazing having abrasion resistance and UV barrier properties and excellent in hardness, transparency, adhesiveness and weather resistance and reduced deterioration after outdoor exposure for a long period.SOLUTION: The plastic substrate for automotive glazing is coated with a compound which is obtained by combining a hard coating agent containing a reactive product of alkoxysilyl-containing benzophenone and/or (partial) hydrolysate thereof and having excellent weather resistance with a primer layer formed of a polymer having a copolymerized UV-absorptive functional group is applied on the plastic substrate and is subjected to heat-curing so as to form a coating having excellent weather resistance, wear resistance and adhesiveness.
摘要翻译：解决方案：提供一种具有耐磨性和紫外线屏蔽性的车辆玻璃用塑料基材，并且在长时间室外暴露后，提供硬度，透明性，粘合性和耐候性优异且降低的劣化。解决方案：用于汽车玻璃的塑料基材涂覆有一种化合物，其通过将含有含烷氧基甲硅烷基的二苯甲酮和/或（部分）水解产物和具有优异耐候性的反应产物的硬涂层剂与底漆将由具有共聚的UV吸收官能团的聚合物形成的层施加在塑料基板上并进行热固化，以形成具有优异的耐候性，耐磨性和粘合性的涂层。版权所有（C）2012，JPO＆INPIT

8. 发明专利

JP2011183758A Polycarbonate resin laminate 有权
标题翻译：聚碳酸酯树脂层压板
公开(公告)号：JP2011183758A
公开(公告)日：2011-09-22
申请号：JP2010054044
申请日：2010-03-11
申请人： Shin-Etsu Chemical Co Ltd , 信越化学工業株式会社
发明人： HIGUCHI KOICHI , YOSHIKAWA YUJI
IPC分类号： B32B27/30 , B32B27/36 , C08F220/10 , C08J7/04 , C09D4/02 , C09D7/12 , C09D183/00
CPC分类号： B32B27/08 , B32B27/18 , B32B27/20 , B32B27/28 , B32B27/30 , B32B27/308 , B32B27/365 , B32B2255/10 , B32B2255/20 , B32B2255/26 , B32B2307/308 , B32B2307/412 , B32B2307/536 , B32B2307/584 , B32B2307/71 , B32B2307/712 , B32B2307/732 , B32B2307/734 , Y10T428/263 , Y10T428/31507
摘要： PROBLEM TO BE SOLVED: To provide a polycarbonate resin laminate, which expresses a scratch resistance and UV shielding property while keeping a transparency, and further, combines a weatherability and a durability which can endure a long term open air exposure. SOLUTION: In the polycarbonate resin laminate in which a cured film (2) of a scratch resistant coating composition containing a UV absorbing inorganic oxide fine particle and/or an organic UV absorber on the surface of the thermoplastic (meta)acrylic resin (1-ii) layer having the UV absorbing group immobilized is laminated in a base material (1) in which a thermoplastic (meta)acrylic resin (1-ii) layer having a UV absorbing group immobilized is laminated on at least one surface of a polycarbonate resin (1-i) substrate, the laminate has a haze of 2% or below. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种在保持透明性的同时表现出耐擦伤性和防紫外线性的聚碳酸酯树脂层压体，并且还结合耐候性和耐久性，其耐受长期露天暴露。解决方案：在热塑性（甲基）丙烯酸树脂的表面上含有UV吸收性无机氧化物细颗粒和/或有机UV吸收剂的耐刮擦涂料组合物的固化膜（2）的聚碳酸酯树脂层压体中，具有固定有UV吸收基团的（1-ii）层被层压在基材（1）中，其中固定有UV吸收基团的热塑性（甲基）丙烯酸树脂（1-ii）层被层压在至少一个表面上聚碳酸酯树脂（1-i）基材，该层压体的雾度为2％以下。版权所有（C）2011，JPO＆INPIT

9. 发明专利

JP2011037948A Abrasion resistant silicone coating composition, coated article, and making method 有权
标题翻译：耐磨硅胶涂料组合物，涂层制品和制造方法
公开(公告)号：JP2011037948A
公开(公告)日：2011-02-24
申请号：JP2009184597
申请日：2009-08-07
申请人： Shin-Etsu Chemical Co Ltd , 信越化学工業株式会社
发明人： HIGUCHI KOICHI
IPC分类号： C09D183/00 , B05D5/00 , B05D7/24 , B32B27/00 , C08J7/04 , C09D5/00 , C09D5/32 , C09D7/12 , C09D151/00 , C09D167/00 , C09D169/00 , C09D175/04
CPC分类号： C09D183/04 , C08K3/36 , C08L51/06 , C08L2666/24
摘要： PROBLEM TO BE SOLVED: To provide a silicone coating composition directly coatable on an organic resin base material, and providing a cured coated film having excellent transparency, exhibiting scratch resistance and having good long-term adhesiveness, and to provide a coated article obtained by coating the composition. SOLUTION: The abrasion resistant silicone coating composition comprises (A) a hydrolytic condensate obtained by (co)hydrolytic condensation of an alkoxysilane represented by formula (1): R 1 m R 2 n Si(OR 3 ) 4-m-n (1) (wherein, R 1 and R 2 are each H or monovalent hydrocarbon with the proviso that the substituents may be bonded to each other; R 3 is alkyl; and m and n are each 0 or 1 with the proviso that m+n are 0, 1 or 2) or a partial hydrolytic condensation product thereof, (B) colloidal silica, (C) a polycarbonate-based and/or polyester-based urethane-modified vinyl polymer, (D) a curing catalyst, and (E) a solvent, the solid content of component (C) being 1 to 30 mass% of urethane-modified vinyl polymer based on the total solid content of components (A) the hydrolytic condensate and (B) the colloidal silica. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供可直接涂布在有机树脂基材上的硅氧烷涂料组合物，并提供具有优异透明性，显示耐刮擦性和长期粘合性好的固化涂膜，并提供涂布物通过涂覆组合物获得。耐磨性有机硅涂料组合物包含（A）通过式（1）表示的烷氧基硅烷（共）水解缩合获得的水解缩合物：R 1 3 > 1 和R 2 各自为H或一价烃，条件是取代基可以彼此键合; R 3是烷基; m和 n分别为0或1，条件是m + n为0,1或2）或其部分水解缩合产物，（B）胶态二氧化硅，（C）聚碳酸酯基和/或聚酯基氨基甲酸酯改性乙烯基聚合物，（D）固化催化剂和（E）溶剂，基于组分（A）的总固体含量，组分（C）的固含量为氨基甲酸酯改性乙烯基聚合物的1〜30质量％冷凝物和（B）胶体二氧化硅。版权所有（C）2011，JPO＆INPIT

10. 发明专利

JP2010202731A Uv-shielding silicone coating composition and coated article 审中-公开
标题翻译：紫外线屏蔽硅胶涂料组合物和涂层制品
公开(公告)号：JP2010202731A
公开(公告)日：2010-09-16
申请号：JP2009047965
申请日：2009-03-02
申请人： Shin-Etsu Chemical Co Ltd , 信越化学工業株式会社
发明人： HIGUCHI KOICHI , KOMORI HISATOSHI
IPC分类号： C09D183/06 , C09D5/00 , C09D7/12 , C09D183/05 , C09D201/10
CPC分类号： C08J7/047 , C08J7/04 , C08J2369/00 , C08J2483/00 , C09D183/04 , Y10T428/31663
摘要： PROBLEM TO BE SOLVED: To provide a silicone coating composition whose coated cured film expresses mar resistance, and UV-shielding property while maintaining visible light transparency, and further simultaneously has weatherability durable against long term out-door exposure and durability, and a coated article using the same. SOLUTION: The UV-shielding silicone coating composition comprises (A) a dispersion in a dispersing medium of composite zinc oxide fine particles which are obtained by coating the surface of the zinc oxide fine particles with at least one kind selected from an oxide or hydroxide of Al, Si, Zr and Sn, the dispersion having a photocatalytic degradability of up to 25%, (B) a silicone resin, (C) a curing catalyst, and (D) a solvent, the solids content of composite zinc oxide nanoparticle dispersion (A) being 1 to 50 mass% based on silicone resin (B). COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种涂覆固化膜表现耐磨性的硅树脂涂料组合物，同时保持可见光透明性的紫外线屏蔽性，并且还具有耐长期暴露和耐久性耐久性的耐候性，以及使用其的涂布制品。 UV屏蔽硅酮涂料组合物包含（A）复合氧化锌微粒的分散介质中的分散体，其通过用至少一种选自氧化物的氧化锌微粒表面涂覆而获得或Al，Si，Zr和Sn的氢氧化物，光催化降解性高达25％的分散体，（B）有机硅树脂，（C）固化催化剂和（D）溶剂，复合锌的固体含量氧化物纳米粒子分散体（A）为1〜50质量％。版权所有（C）2010，JPO＆INPIT

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