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    • 71. 发明申请
    • ELASTIC MOLDED FOAM BASED ON POLYOLEFIN/STYRENE POLYMER MIXTURES
    • 基于聚烯烃/苯乙烯聚合物混合物的弹性模制泡沫
    • US20110269858A1
    • 2011-11-03
    • US13143029
    • 2009-12-16
    • Carsten SchipsKlaus HahnKonrad KnollHolger RuckdäschelJens AssmannGeorg GrässelMaximilian Hofmann
    • Carsten SchipsKlaus HahnKonrad KnollHolger RuckdäschelJens AssmannGeorg GrässelMaximilian Hofmann
    • C08L53/02C08J9/18C08L23/02C08L25/04C08J9/12C08J9/224B82Y30/00
    • C08L25/06C08K5/01C08L23/06C08L23/0815C08L53/02C08L53/025C08L2205/02C08L2205/035C08L2666/06C08L2666/02
    • Expandable, thermoplastic polymer bead material, comprising A) from 45 to 97.8 percent by weight of a styrene polymer, B1) from 1 to 45 percent by weight of a polyolefin with a melting point in the range from 105 to 140° C., B2) from 0 to 25 percent by weight of a polyolefin with a melting point below 105° C., C1) from 0.1 to 25 percent by weight of a block or graft copolymer with weight-average molar mass Mw of at least 100,000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block or graft copolymer A, C2) from 0 to 20 percent by weight of a styrene-butadiene or styrene-isoprene block copolymer different from C1, C3) from 0.1 to 9.9 percent by weight of a styrene-ethylene-butylene block copolymer, D) from 1 to 15 percent by weight of a blowing agent, and E) from 0 to 5 percent by weight of a nucleating agent, where the entirety composed of A) to E) gives 100% by weight.
    • 可膨胀的热塑性聚合物珠粒材料,其包含A)45至97.8重量%的苯乙烯聚合物,B1)1至45重量%的熔点为105-140℃的聚烯烃,B2 )0至25重量%的熔点低于105℃的聚烯烃,C1)0.1至25重量%的重均摩尔质量Mw至少为100,000克/摩尔的嵌段或接枝共聚物 包括a)至少一种由95-100%重量的乙烯基芳族单体和0-5%重量二烯组成的嵌段S,和b)至少一种由63组成的共聚物嵌段(S / B)A 至80重量%的乙烯基芳族单体和20至37重量%的二烯,玻璃化转变温度TgA在5至30℃的范围内,其中全部块S的重量比为 基于嵌段或接枝共聚物A在50至70重量%的范围内,C2)0至20重量%的苯乙烯 - 丁 二烯或苯乙烯 - 异戊二烯嵌段共聚物,不同于C1,C3)0.1至9.9重量%的苯乙烯 - 乙烯 - 丁烯嵌段共聚物,D)1至15重量%的发泡剂,E)0至 5重量%的成核剂,其中由A)至E)组成的整体得到100重量%。
    • 72. 发明申请
    • TRANSPARENT, TOUGH AND RIGID MOLDING COMPOSITIONS BASED ON STYRENE-BUTADIENE BLOCK COPOLYMER MIXTURES
    • 基于苯乙烯 - 丁二烯嵌段共聚物混合物的透明,粗糙和刚性成型组合物
    • US20100304067A1
    • 2010-12-02
    • US12677960
    • 2008-09-03
    • Konrad KnollJürgen KochPiyada CharoensirisomboonDaniel Wagner
    • Konrad KnollJürgen KochPiyada CharoensirisomboonDaniel Wagner
    • C08L53/02B32B3/12B32B1/08
    • C08L25/06C08K5/0016C08L25/10C08L53/02C08L2205/02C08L2205/035C08L2666/24C08L2666/02
    • A mixture which comprises a) from 95 to 30% by weight of a copolymer or block copolymer A comprising one or more copolymer blocks (B/S)A which are respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., b) from 5 to 45% by weight of a block copolymer B comprising at least one hard block S which is composed of vinylaromatic monomers, and comprising one or more copolymer blocks (B/S)B which are respectively composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from −70° to 0° C., c) from 0 to 40% by weight of polystyrene C, and d) from 0 to 30% by weight of a block copolymer D comprising at least one copolymer block (B/S)A which is respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., and comprising at least one diene block B or one copolymer block (B/S)B which is respectively composed of from 1 to 60% by weight of vinylaromatic monomers and of from 99 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from −100° to 0° C., e) from 0 to 6% by weight of a plastifying agent, and its use for the production of packaging for electronics components.
    • 包含a)95至30重量%的共聚物或嵌段共聚物A,其包含一种或多种共聚物嵌段(B / S)A,其分别由65至95重量%的乙烯基芳族单体和 35〜5重量%的二烯,玻璃化转变温度TgA在40℃〜90℃的范围内,b)5〜45重量%的嵌段共聚物B,其包含至少一个硬嵌段S, 由乙烯基芳族单体组成,并且包含一种或多种共聚物嵌段(B / S)B,其分别由20至60重量%的乙烯基芳族单体和80至40重量%的二烯组成,并且其玻璃化转变 温度TgB在-70℃至0℃的范围内,c)0至40重量%的聚苯乙烯C,以及d)0至30重量%的嵌段共聚物D,其包含至少一个共聚物嵌段 (B / S)A,其分别由65至95重量%的乙烯基芳族单体和35至5重量%的重量 并且其玻璃化转变温度TgA在40℃至90℃的范围内,并且包含至少一个二烯嵌段B或一个共聚物嵌段(B / S)B,其分别由1至60个 乙烯基芳族单体的重量百分比和99至40重量%的二烯,其玻璃化转变温度TgB在-100℃至0℃的范围内,e)0至6重量%的塑化 代理商及其用于生产电子元件包装的用途。
    • 73. 发明申请
    • HIGHLY TRANSPARENT AND TOUGH-STIFF STYRENE-BUTADIENE BLOCK COPOLYMER MIXTURES
    • 高透明度和韧性苯乙烯 - 丁二烯嵌段共聚物混合物
    • US20090286918A1
    • 2009-11-19
    • US12306258
    • 2007-06-13
    • Jennifer R. StewartPeter MerkelDaniel WagnerKonrad KnollJürgen Koch
    • Jennifer R. StewartPeter MerkelDaniel WagnerKonrad KnollJürgen Koch
    • C08L53/02
    • C08F297/044C08F297/04C08L53/02C08L2205/025C08L2205/03C08L2666/02C08L2666/24C08L25/06
    • A mixture which comprises a) from 25 to 75% by weight of a block copolymer A which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more soft blocks BA in each case composed of from 0 to 5% by weight of vinylaromatic monomers and from 95 to 100% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer A is from 65 to 90% by weight; b) from 5 to 25% by weight of a block copolymer B which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B in each case composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer B is from 25 to 70% by weight; c) from 0 to 70% by weight of polystyrene or of a block copolymer C other than A and B, and d) from 0 to 6% by weight of a plasticizer D, where the entirety of components A) to D) gives 100% by weight, and use for transparent thermoforming foils or transparent injection-molded items.
    • 一种混合物,其包含a)25至75重量%的嵌段共聚物A,其包含至少一种由乙烯基芳族单体组成的硬质块S,并且包含一种或多种软块BA,每种情况由0至5重量% 的乙烯基芳族单体和95〜100重量%的二烯,其中嵌段共聚物A中的硬质块S的重量比为65〜90重量% b)5至25重量%的嵌段共聚物B,其包含至少一种由乙烯基芳族单体组成的硬质块S,并且包含一种或多种共聚物嵌段(B / S)B,每种情况下由20至60%由 乙烯基芳族单体的重量和80〜40重量%的二烯,其中嵌段共聚物B中的硬质块S的重量比为25〜70重量% c)0至70重量%的聚苯乙烯或除A和B之外的嵌段共聚物C,以及d)0至6重量%的增塑剂D,其中组分A)至D)的总量为100 重量%,用于透明热成型箔或透明注塑件。
    • 74. 发明申请
    • COUPLING OF LIVING CARBOCATIONIC POLYMERS
    • 生活CARCOCICIC聚合物的联合
    • US20080125549A1
    • 2008-05-29
    • US11564650
    • 2006-11-29
    • Judit E. PUSKASSzilard CsihonyKonrad KnollHeike PfistnerHans-Michael Walter
    • Judit E. PUSKASSzilard CsihonyKonrad KnollHeike PfistnerHans-Michael Walter
    • C08F297/00
    • C08F299/00
    • A process for coupling a living carbocationic polymer by reacting two molecules of a living carbocationic polymer with a coupling agent, the coupling agent having the formula I: CR1R2═CR3-Zn—CR4═CR5R6   (I) wherein R1, R2, R3, R4, R5 and R6 are, independently from one another, hydrogen, alkyl, or alkenyl, or two of R1, R2, R3, R4, R5 and R6, together are alkylene or alkenylene, Z is CR7R8, R7 and R8 are, independently from one another, hydrogen or alkyl, and n is 0 or an integer from 1 to 5, with the proviso that, when R3 is hydrogen, both R1 and R2 are different from hydrogen, and, when R4 is hydrogen, both R5 and R6 are different from hydrogen. The process allows for the convenient preparation of ABA-type block copolymers and of telechelic polymers.
    • 通过使活性碳阳离子聚合物的两分子与偶联剂反应来偶联活性碳阳离子聚合物的方法,具有式I的偶联剂:<?in-line-formula description =“In-line Formulas”end =“lead” ?>>>>> 2 2>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>>> 其中R 1是一个或多个,其中R 1,R 2,R 3,R 6, R 2,R 3,R 4,R 5,R 5和R 6, 氢,烷基或链烯基,或R 1,R 2,R 3,R 3,R 3, R 4,R 5和R 6一起是亚烷基或亚烯基,Z是CR 7 R 7, R 8,R 7和R 8彼此独立地为氢或烷基,n为0或1至5的整数, 条件是当R 3是氢时,R 1和R 2都不同于氢,并且wh R 4是氢,R 5和R 6都不同于氢。 该方法可以方便地制备ABA型嵌段共聚物和遥爪聚合物。
    • 79. 发明授权
    • Thermoplastic moulding compounds
    • 热塑性模塑料
    • US06235839B1
    • 2001-05-22
    • US09254917
    • 1999-03-17
    • Norbert GüntherbergMartin WeberKonrad KnollGerhard Lindenschmidt
    • Norbert GüntherbergMartin WeberKonrad KnollGerhard Lindenschmidt
    • C08L5100
    • C08L51/003C08F265/04C08L25/12C08L53/02C08L2666/24
    • Thermoplastic molding compositions comprising A) a graft polymer comprising 1) an elastomeric graft core, obtainable by copolymerization of one or more C1-C10-alkyl acrylates, and a monomer with crosslinking effect, and 2) a graft shell comprising a styrene compound or a C1-C8-alkyl acrylate or methacrylate, or a mixture of the styrene compound and the C1-C8-alkyl acrylate or methacrylate, and B) a thermoplastic polymer comprising C) an elastomeric block copolymer in which all or virtually all of the olefinic double bonds have been hydrogenated, comprising at least one block A, which forms a hard phase and contains, in its polymer chain, units of a vinylaromatic monomer, and/or a block B, which forms a first elastomeric (soft) phase and contains diene monomers, and at least one elastomeric block B/A, which forms a soft phase, and contains, randomly in its polymer chain, units of both a vinylaromatic monomer and a diene, where the glass transition temperature Tg of the block A is above 25° C. and that of the block B/A is below 25° C. and the phase-volume ratio of block A to block B/A is chosen so that the proportion of the hard phase in the entire block copolymer is from 1 to 40% by volume and the proportion by weight of the diene is less than 50% by weight.
    • 包含A)接枝聚合物的热塑性成型组合物,其包含1)通过一种或多种丙烯酸C 1 -C 10烷基酯的共聚获得的弹性体接枝核心和具有交联效应的单体,和2)包含苯乙烯化合物或C 1 -C 8 烷基丙烯酸酯或甲基丙烯酸酯,或苯乙烯化合物和丙烯酸或甲基丙烯酸C 1 -C 8烷基酯的混合物,和B)包含C)弹性体嵌段共聚物的热塑性聚合物,其中所有或几乎所有的烯属双键已被氢化, 包含至少一个嵌段A,其形成硬质相并且在其聚合物链中包含乙烯基芳族单体和/或嵌段B的单元,所述单元形成第一弹性体(软)相并含有二烯单体,并且至少 一个弹性体嵌段B / A,其形成软相,并且在其聚合物链中随机含有乙烯基芳族单体和二烯的单元,其中嵌段A的玻璃化转变温度Tg高于25° 并且块B / A的相体积比低于25℃,并且选择块A与嵌段B / A的相体积比,使得整个嵌段共聚物中硬相的比例为1至40 体积比,二烯重量比小于50重量%。