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    • 72. 发明授权
    • Method of treating direct positive silver halide sensitive material
    • 直接卤化银感光材料的处理方法
    • US4481285A
    • 1984-11-06
    • US484811
    • 1983-04-14
    • Yoshihiro TakagiShigeo HiranoTadao Sugimoto
    • Yoshihiro TakagiShigeo HiranoTadao Sugimoto
    • G03C5/50G03C1/485G03C5/24
    • G03C1/48561Y10S430/141
    • A method of treating a direct positive silver halide sensitive material is disclosed. The material is comprised of a base having thereon a compound represented by the general formula (I), a sensitive silver halide photographic emulsion layer and a hydrophilic colloid layer. The exposed material is developed in the presence of the compound represented by the general formula (II) ##STR1## wherein R.sup.1 and R.sup.2 independently represent a hydrogen atom, an aliphatic residue, an aromatic residue or a heterocyclic residue, R.sup.3 represents a hydrogen atom or an aliphatic residue, R.sup.4 represents a hydrogen atom, an aliphatic residue or an aromatic residue, and X represents a divalent aromatic residue; ##STR2## wherein R.sup.1 and R.sup.2 represent each a hydrogen atom or an aliphatic residue, and R.sup.1 and R.sup.2 may form a ring by linking together, R.sup.3 represents a divalent aliphatic residue, X represents a single bond or a divalent heterocyclic ring containing nitrogen, oxygen or sulfur atoms, and M represents a hydrogen atom, an alkali metal, an alkaline earth metal, a quaternary ammonium salt, a quaternary phosphonium salt or an amidino group.The invention provides a process wherein the sharpness and edge effects of direct positive images are greatly improved. The results obtained with the process do not vary due to changes in the bromine ion concentration in the developing solution or the pH thereof.
    • 公开了一种处理直接正卤化银敏感材料的方法。 该材料由其上具有由通式(I)表示的化合物的底部,敏感的卤化银照相乳剂层和亲水胶体层组成。 暴露的材料在通式(II)表示的化合物的存在下显影,其中R1和R2独立地表示氢原子,脂族残基,芳族残基或杂环残基,R3表示 氢原子或脂肪族残基,R4表示氢原子,脂肪族残基或芳香族残基,X表示二价芳香族残基; (II)其中R 1和R 2各自表示氢原子或脂肪族残基,R 1和R 2可以通过连接在一起形成环,R 3表示二价脂肪族残基,X表示单键或含有 氮,氧或硫原子,M表示氢原子,碱金属,碱土金属,季铵盐,季鏻盐或脒基。 本发明提供一种方法,其中直接正像的清晰度和边缘效应大大提高。 用该方法获得的结果不会因显影液中溴离子浓度的变化或其pH而变化。
    • 74. 发明授权
    • Method of forming a photographic image
    • 形成摄影图像的方法
    • US4447522A
    • 1984-05-08
    • US486174
    • 1983-04-18
    • Shigeo HiranoYoshihiro Takagi
    • Shigeo HiranoYoshihiro Takagi
    • C07C335/32C07D277/36C07D277/72C07D285/12C07D285/125C07D295/21G03C1/06G03C1/09G03C1/43G03C5/24G03C1/02
    • C07D285/125C07C335/32C07D277/36C07D277/72C07D295/21G03C1/061G03C1/09G03C1/43Y10S430/15
    • A method of forming a photographic image which comprises development processing with an alkaline activator solution a silver halide photographic light-sensitive material comprising a support having thereon at least one surface latent image type silver halide emulsion layer, and containing in at least one layer selected from the silver halide emulsion layer and another hydrophilic colloid layer(1) a developing agents;(2) an acylhydrazine compound represented by formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an unsubstituted or substituted aryl group or alkyl group; and R.sup.2 represents a hydrogen atom, or an unsubstituted or substituted aryl group or alkyl group; and(3) at least one compound represented by formula (II): ##STR1## wherein each of W.sup.1 and W.sup.2 can represent a hydrogen atom or an aliphatic group or W.sup.1 and W.sup.2 are bonded each other to form a ring; W.sup.3 represents a divalent aliphatic group; Q.sup.1 represents a simple bond or a divalent heterocyclic group containing a nitrogen atom, an oxygen atom, or a sulfur atom; and M represents a hydrogen atom, an alkali metal atom, an alkaline earth metal atom, a quarternary ammonium salt, a quarternary phosphonium salt, or an amidino group, or an inorganic acid salt or an organic acid salt thereof.According to the activator type developing method, a dot image having good dot quality and screen range can be obtained.
    • 一种形成摄影图像的方法,其包括用碱性活化剂溶液显影处理的卤化银照相感光材料,其包含其上具有至少一个表面潜影型卤化银乳剂层的载体,并且含有至少一层选自 卤化银乳剂层和另一亲水胶体层(1)显影剂; (2)由式(I)表示的酰肼化合物:R1NHNHCOR2(I)其中R1表示未取代或取代的芳基或烷基; R2表示氢原子,或未取代或取代的芳基或烷基; 和(3)由式(II)表示的至少一种化合物:其中W1和W2各自可以表示氢原子或脂族基团,或者W1和W2彼此键合形成环; W3表示二价脂族基团; Q1表示简单键或含有氮原子,氧原子或硫原子的二价杂环基; M表示氢原子,碱金属原子,碱土金属原子,季铵盐,季铵盐或脒基,或无机酸盐或其有机酸盐。 根据活化剂型显影方法,可以获得具有良好的点质量和屏幕范围的点图像。
    • 75. 发明授权
    • Method of forming a photographic image
    • 形成摄影图像的方法
    • US4429036A
    • 1984-01-31
    • US480650
    • 1983-03-31
    • Shigeo HiranoYoshihiro Takagi
    • Shigeo HiranoYoshihiro Takagi
    • C07C335/32C07D277/36C07D277/72C07D285/12C07D285/125C07D295/21G03C1/06G03C1/09G03C1/43G03C5/24G03F7/06
    • C07D285/125C07C335/32C07D277/36C07D277/72C07D295/21G03C1/061G03C1/09G03C1/43Y10S430/15
    • A method of forming a photographic image which comprises development processing with an alkaline aqueous activator solution a silver halide photographic light-sensitive material comprising a support having thereon at least one surface latent image type silver halide emulsion layer, and containing in at least one layer selected from a silver halide emulsion layer and another hydrophilic colloid-layer (1) a hydroquinone series developing agent and (2) an acylhydrazine compound represented by formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an unsubstituted or substituted aryl group or alkyl group; and R.sup.2 represents a hydrogen atom, or an unsubstituted or substituted aryl group or alkyl group,wherein the aqueous activator solution or a prebath thereof contains at least one compound represented by formula (II): ##STR1## wherein each of W.sup.1, W.sup.2, W.sup.3, and W.sup.11 can represent a hydrogen atom, an unsubstituted or substituted alkyl group, alkenyl group, or alkynyl group, an acyl group, or a sulfonyl group, and W.sup.1 and W.sup.2, or W.sup.3 and W.sup.11, can be bonded to each other to form a ring; Q.sup.1 represents --CH.sub.2 CH.sub.2 -- or --CH.sub.2 CH.sub.2 CH.sub.2 --; and n represents an integer of 1 to 4.According to this activator type developing method, an image having good quality can be constantly obtained irrespective of the stirring conditions of the processing solution.
    • 一种形成摄影图像的方法,其包括用碱性水活化剂溶液进行显影处理,卤化银照相感光材料,其包含其上具有至少一个表面潜像型卤化银乳剂层的载体,并且在至少一层中选择 由卤化银乳剂层和另一亲水胶体层(1),氢醌系列显影剂和(2)由式(I)表示的酰肼化合物:R1NHNHCOR2(I)其中R1表示未取代或取代的芳基或烷基 ; 并且R 2表示氢原子或未取代或取代的芳基或烷基,其中活化剂水溶液或其前体含有至少一种由式(II)表示的化合物:其中W1, W2,W3和W11可以表示氢原子,未取代或取代的烷基,烯基或炔基,酰基或磺酰基,W1和W2或W3和W11可以相互键合 另外形成戒指; Q1表示-CH2CH2-或-CH2CH2CH2-; 并且n表示1〜4的整数。根据该活化剂型显影方法,无论处理溶液的搅拌条件如何,都可以恒定地获得质量好的图像。
    • 77. 发明授权
    • Direct positive silver halide light-sensitive material
    • 直接正卤化银感光材料
    • US4294919A
    • 1981-10-13
    • US156949
    • 1980-06-06
    • Nobuyuki TsujinoShigeo Hirano
    • Nobuyuki TsujinoShigeo Hirano
    • C07C67/00C07C325/00C07C335/10C07C335/40C07C335/42C07C335/44C07C337/06C07C337/08C07C381/10G03C1/485G03C1/36
    • G03C1/48561
    • A direct positive silver halide photographic light-sensitive material is described, comprising a support having coated thereon a light-sensitive silver halide photographic emulsion layer and a hydrophilic colloid layer, at least one of said layers containing a compound represented by the formula (I): ##STR1## wherein R.sup.1 represents R.sup.6 or R.sup.6 CO--; and R.sup.6 represents an aliphatic group, an aromatic group, a heterocyclic aromatic group or hydrogen; R.sup.2 and R.sup.4, which may be the same or different, each represents an aliphatic group, an aromatic group, a heterocyclic aromatic group or a hydrogen atom; or R.sup.1 and R.sup.2 together can form a ring; R.sup.3 represents hydrogen or an aliphatic group; R.sup.5 represents Y or X--A--Y wherein X and Y, which may be the same or different, each represents a divalent aromatic group; and A represents a divalent group selected from --CONH--, --NHCONH--, --SO.sub.2 NH--, --B--CONH-- and --B--SO.sub.2 NH-- wherein B represents --E--, --O--E-- or --S--E-- wherein O and S is bonded to X; and E represents a divalent aliphatic group; the compound represented by formula (I) is a fogging agent which imparts a desired fogging activity without detracting from spectral sensitization.
    • 描述了直接正性卤化银照相感光材料,其包括其上涂覆有感光卤化银照相乳剂层和亲水胶体层的载体,所述层中的至少一层含有由式(I)表示的化合物, (I) 其中R1表示R6或R6CO-; R 6表示脂肪族基团,芳香族基团,杂环芳香族基团或氢原子; R 2和R 4可以相同或不同,表示脂族基团,芳族基团,杂环芳族基团或氢原子; 或者R 1和R 2一起形成环; R3表示氢或脂族基; R5表示Y或X-A-Y,其中X和Y可以相同或不同,表示二价芳族基团; 并且A表示选自-CONH - , - NHCONH-, - SO 2 NH - , - CON-CONH和-B-SO 2 NH-的二价基团,其中B表示-E-,-OE-或-SE-,其中O和S为 与X键合; E表示二价脂族基; 由式(I)表示的化合物是赋予所需起雾活性而不降低光谱增感作用的起雾剂。
    • 78. 发明授权
    • Silver halide photographic light-sensitive material
    • 卤化银照相感光材料
    • US4272614A
    • 1981-06-09
    • US105689
    • 1979-12-20
    • Hiroyuki MifuneShigeo Hirano
    • Hiroyuki MifuneShigeo Hirano
    • C07D233/88C07D277/12C07D277/18C07D277/54C07D277/82G03C1/043G03C1/06G03C1/09
    • G03C1/043C07D277/54C07D277/82G03C1/061G03C1/09Y10S430/15
    • A silver halide photographic light-sensitive material having at least one silver halide photographic emulsion layer comprising substantially surface latent image type silver halide grains, and containing in said photographic emulsion layer or at least one of other hydrophilic colloid layers a compound represented by the following general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, an aliphatic group which may be substituted or an aromatic group which may be substituted; Ar represents a divalent aromatic group which may be substituted; Y represents a divalent linking group; n represents 0 or 1; R.sup.2 represents a hydrogen atom, an aliphatic group which may be substituted or an aromatic group which may be substituted; and Z represents a nonmetallic atomic group necessary to form a 5-membered or 6-membered heterocyclic ring together with the ##STR2## linkage.
    • 一种卤化银摄影感光材料,其具有至少一个卤化银照相乳剂层,其包含基本上表面的潜像型卤化银颗粒,并且在所述照相乳剂层或至少一种其它亲水胶体层中含有下列通式 式(I):其中R 1表示氢原子,可被取代的脂肪族基团或可被取代的芳香族基团的化合物(I) Ar表示可以被取代的二价芳基; Y表示二价连接基团; n表示0或1; R2表示氢原子,可以被取代的脂肪族基团或可以被取代的芳香族基团; Z表示与键形成5元或6元杂环所必需的非金属原子团。
    • 79. 发明授权
    • Radiation image conversion panel and manufacturing method therefor
    • 辐射图像转换面板及其制造方法
    • US07169481B2
    • 2007-01-30
    • US09810230
    • 2001-03-19
    • Hiroshi OgawaShinichiro FukuiYasuo IwabuchiNoriyuki InoueShigeo Hirano
    • Hiroshi OgawaShinichiro FukuiYasuo IwabuchiNoriyuki InoueShigeo Hirano
    • G01J1/00B32B9/00
    • G21K4/00C09K11/7733
    • A radiation image conversion panel that has a phosphor layer. The phosphor layer contains a binding agent, a phosphor particle, and at least aryl carboxylic acid or alicyclic carboxylic acid, expressed by the following general Formula: R—R1—COOX, or R—COOX in which R represents (1) an aryl group; (2) an aryl group, replaced with an alkyl group whose number of carbons is 1 to 5, a hydroxyl group, a carboxylic acid group, or a halogen group; (3) a hydroaryl group; or (4) a hydroaryl group (alicyclic group), replaced with an alkyl group whose number of carbons is 1 to 5, a hydroxyl group, or a halogen group; R1 is a hydrocarbon radical whose number of carbons is 1 to 12; and X represents a hydrogen atom, alkaline metal, or —N+ (R2)4 (where R2 represents an alkyl group whose number of carbons is 2 or less).
    • 一种具有荧光体层的放射线图像转换面板。 磷光体层含有粘合剂,荧光体颗粒,和至少芳基羧酸或脂环族羧酸,由以下通式表示:<?in-line-formula description =“In-line Formulas”end =“lead” ??RR <1> -COOX或<?in-line-formula description =“In-line formula”end =“tail”?> <?in-line-formula description =“In-line 公式“end =”lead“?> R-COOX <?in-line-formula description =”In-line formula“end =”tail“?>其中R表示(1)芳基; (2)芳基,被碳数为1〜5的烷基取代,羟基,羧酸基或卤素基; (3)加氢芳基; 或(4)加氢芳基(脂环基),被碳原子数为1〜5的烷基取代,羟基或卤素基; R 1是碳原子数为1〜12的烃基, 并且X表示氢原子,碱金属或-N + +(R 2)4(其中R 2 O / >表示碳原子数为2以下的烷基。