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    • 71. 发明授权
    • Process for producting optical resin materials with distributed
refractive index
    • 具有折射率分布的光学树脂材料的制造方法
    • US5763514A
    • 1998-06-09
    • US475101
    • 1995-06-07
    • Yasuhiro Koike
    • Yasuhiro Koike
    • C08F2/00C08F2/44C08K5/00C08L67/07G02B1/04G02B6/028C08F263/00
    • G02B6/02038C08F2/44C08K5/0008C08L67/07G02B1/04G02B1/045Y10S525/932
    • An optical resin, of which the refractive index continuously changes in a specific direction, is produced by filling a polymerization container with a mixed solution containing at least one type of polymerizable monomer or polymerizable monomer sol and at least one type of substance whose solubility parameter differs by 7 (cal/cm.sup.3).sup.1/2 or less and refractive index by 0.001 or more from those of a polymer produced by polymerization of the monomer, and by subjecting the mixture to polymerization reaction by applying heat or energy rays to the container from outside so that the polymerization reaction starts and progresses preferentially from a particular region of the mixture, thus forming a concentration gradient of the substance having different refractive index.The polymerization container may be made of a polymer which swells and dissolves into the mixed solution from an inner wall thereof. After completing the polymerization reaction, the optical resin is subjected to hot drawing to obtain an optical conductor. Further, post-treatment based on crosslinking reaction is applied to improve heat resistance.
    • 通过用含有至少一种可聚合单体或可聚合单体溶胶的混合溶液和至少一种溶解度参数不同的物质填充聚合容器来产生折射率在特定方向上连续变化的光学树脂 通过单体聚合制备的聚合物的折射率乘以7(cal / cm 3)+ E,fra 1/2 + EE或更低,折射率为0.001以上,并且通过施加热或能量使混合物进行聚合反应 从聚合反应开始并优先从混合物的特定区域进行聚合反应,从而形成具有不同折射率的物质的浓度梯度。 聚合容器可以由从其内壁溶胀并溶解到混合溶液中的聚合物制成。 聚合反应完成后,对光学树脂进行热拉伸,得到光导体。 此外,应用基于交联反应的后处理以改善耐热性。
    • 73. 发明授权
    • Process for producing light-transmitting element of synthetic resin
    • 合成树脂透光元件的制造方法
    • US4521351A
    • 1985-06-04
    • US533532
    • 1983-09-16
    • Yasuji OhtsukaYasuhiro KoikeMotoaki Yoshida
    • Yasuji OhtsukaYasuhiro KoikeMotoaki Yoshida
    • B29D11/00G02B5/14
    • B29D11/00721
    • A process for producing a light-transmitting element of a synthetic resin, which comprises(1) preparing a mixture composed of at least three monomers, said monomers having a difference in the ease of polymerization under given polymerization conditions, and that monomer in the monomeric mixture which is easiest to polymerize being capable of giving a polymer having a lower refractive index than a polymer from any of the other monomers in the monomeric mixture,(2) maintaining the monomeric mixture in a predetermined shape, and(3) thereafter applying to the monomeric mixture maintained in the predetermined shape such polymerization conditions that polymerization begins at the outside portion of the predetermined shape of the monomeric mixture and proceeds gradually toward its inside portion, thereby to form a polymeric article in which the proportion of polymer units derived from the monomer which is easiest to polymerize is largest at said outside portion and gradually decreases toward its inside portion and the refractive index of the article is lowest at said outside portion and gradually increases toward its inside portion.
    • 一种制造合成树脂的透光元件的方法,其包括(1)制备由至少三种单体组成的混合物,所述单体在给定的聚合条件下具有差异的聚合性,单体的单体 最容易聚合的混合物能够从单体混合物中的任何其它单体得到折射率低于聚合物的聚合物,(2)将单体混合物保持在预定形状,以及(3)然后施加到 单体混合物保持预定形状,这样的聚合条件使聚合从单体混合物的预定形状的外部开始聚合,并逐渐向其内部逐渐进入,从而形成聚合物,其中衍生自 最容易聚合的单体在所述外部部分最大,并逐渐降低towa 其内部部分和物品的折射率在所述外部部分处最低,并且朝向其内部部分逐渐增加。