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71. 发明授权

US5646210A Method for the preparation of polymeric spacing particles 失效
标题翻译：聚合间隔颗粒的制备方法
公开(公告)号：US5646210A
公开(公告)日：1997-07-08
申请号：US515209
申请日：1995-08-15
申请人： Daniel Timmerman , Ronny De Clercq , Geert Defieuw , Wolfgang Podszun , Rainer Brandt
发明人： Daniel Timmerman , Ronny De Clercq , Geert Defieuw , Wolfgang Podszun , Rainer Brandt
IPC分类号： G03C1/04 , B41M5/392 , B41M5/395 , C08F2/16 , C08F257/02 , C08F290/00 , C08F291/00 , C08J3/12 , C08J5/18 , C08L51/00 , C08L51/06 , C08L67/00 , C08L67/02 , C09D7/12 , G03C1/053 , G03C1/32 , G03C1/76 , G03C1/95
CPC分类号： B41M5/395 , C08F257/02 , C08F291/00 , C08L51/00 , G03C1/32 , G03C1/95 , Y10S430/151 , Y10S430/162 , Y10T428/254 , Y10T428/31786
摘要： A method is provided for the preparation of finely divided solid spherical polymer beads having an average particle size between about 0.1 and about 10 .mu.m and having a glass transition temperature of at least 40.degree. C. The method is a one step reaction in an aqueous reaction medium and said polymer beads are formed by the simultaneous reaction of1) a silane monomer comprising an .alpha.,.beta.-ethylenically unsaturated group,2) at least one .alpha.,.beta.-ethylenically unsaturated monomer, different from said silane monomer, capable of forming a polymer that is soluble in the monomer(s) present in said aqueous solvent mixture but which is insoluble in water3) a free radical-forming polymerization initiator that is soluble in the aqueous solvent mixture, and4) a graft-polymerizable polymer containing hydrophilic groups, and capable of forming a graft polymer that remains soluble in the aqueous reaction mixture.
摘要翻译：提供了一种制备平均粒径为约0.1至约10μm并具有至少40℃的玻璃化转变温度的细分固体球形聚合物珠粒的方法。该方法是在水性反应介质和所述聚合物珠粒通过1）包含α，β-烯属不饱和基团的硅烷单体，2）至少一种不同于所述硅烷单体的α，β-烯键式不饱和单体同时反应形成，所述α，β-烯属不饱和单体能够形成可溶于所述水性溶剂混合物中存在的但不溶于水的单体的聚合物3）可溶于水性溶剂混合物的自由基形成聚合引发剂，和4）可接枝聚合的聚合物，其含有亲水基团，并且能够形成在水性反应混合物中保持可溶的接枝聚合物。

72. 发明授权

US5486548A Acrylates and methacrylates based on cyclohexyldiphenols 失效
标题翻译：基于环己基二酚的丙烯酸酯和甲基丙烯酸酯
公开(公告)号：US5486548A
公开(公告)日：1996-01-23
申请号：US275211
申请日：1994-07-14
申请人： Wolfgang Podszun , Michael Muller
发明人： Wolfgang Podszun , Michael Muller
IPC分类号： A61C13/087 , A61K6/083 , C07C69/54 , C07C69/653 , C08F20/10 , C08F20/20 , C08F20/26 , C08F20/30 , C08G65/26
CPC分类号： A61K6/083 , C07C69/54 , C08G65/2627
摘要： The invention relates to diacrylates and dimethacrylates which are derived from cyclohexyldiphenols.Di(meth)acrylates are used widely, for example, as a component of plastic filling materials in dental engineering.
摘要翻译：本发明涉及衍生自环己基二醇的二丙烯酸酯和二甲基丙烯酸酯。二（甲基）丙烯酸酯广泛用于牙科工程中作为塑料填充材料的组分。

73. 发明授权

US5395730A Image formation by thermal transfer 失效
标题翻译：通过热转印形成图像
公开(公告)号：US5395730A
公开(公告)日：1995-03-07
申请号：US114082
申请日：1993-08-31
申请人： Wolfgang Podszun , Herman J. Uytterhoeven , Roland F. Beels , Luc H. Leenders
发明人： Wolfgang Podszun , Herman J. Uytterhoeven , Roland F. Beels , Luc H. Leenders
IPC分类号： G03F7/00 , G03F7/004 , G03F7/027 , G03F7/028 , G03F7/06 , G03F7/105 , G03F7/26 , G03F7/34 , G03C5/54
CPC分类号： G03F7/0285 , G03F7/34
摘要： A method is disclosed for the formation of an image comprising the steps of(1) image-wise exposing, in the presence of a photopolymerizable compound, a photosensitive element comprising a support and at least one photosensitive layer containing a silver halide sensitive to actinic radiation, an organic silver salt and a reducing agent,(2) heating said photosensitive layer while in contact with a receiving element and allowing non-photopolymerized compound in the non-exposed areas to transfer and penetrate in said receiving element, and,(3) separating said receiving element from said photosensitive element.The obtained image can be a useful visible image produced on at least one of the separated elements, or it can be a hydrophobic polymer image on a hydrophilic background formed in the finally separated-receiving element which is usable as a printing plate. In the former embodiment the receiving element comprises a support and a layer containing a pigment, e.g. carbon black. In the latter embodiment the receiving element must comprise a hydrophilic surface, e.g. a support coated with a hydrophilic layer, or a metal support having a hydrophilic surface.The photopolymerizable compound preferably bears one or more functional (meth)acrylate groups. Most preferably this compound is chosen from particular classes of reactive multifunctional monomers.
摘要翻译：公开了一种用于形成图像的方法，该方法包括以下步骤：（1）在可光聚合化合物存在下成像曝光包括载体的光敏元件和至少一个含有对光化辐射敏感的卤化银的感光层，有机银盐和还原剂，（2）在与接收元件接触的同时加热所述感光层，并且使非曝光区域中的非光聚合化合物转移并渗入所述接收元件，和（3）将所述接收元件与所述感光元件分离。获得的图像可以是在至少一个分离的元件上产生的有用的可见图像，或者它可以是形成在最终分离接收元件中的可用作印刷版的亲水性背景上的疏水性聚合物图像。在前一实施例中，接收元件包括支撑体和含有颜料的层，碳黑。在后一实施例中，接收元件必须包括亲水表面，例如。涂覆有亲水层的载体或具有亲水表面的金属载体。可光聚合的化合物优选具有一个或多个官能（甲基）丙烯酸酯基团。最优选地，该化合物选自特定类别的活性多官能单体。

74. 发明授权

US5380607A Thermal imaging method 失效
标题翻译：热成像法
公开(公告)号：US5380607A
公开(公告)日：1995-01-10
申请号：US149233
申请日：1993-11-09
申请人： Robert C. Van Haute , Luc H. Leenders , Roland F. Beels , Carlo A. Uyttendaele , Herman J. Uytterhoeven , Wolfgang Podszun
发明人： Robert C. Van Haute , Luc H. Leenders , Roland F. Beels , Carlo A. Uyttendaele , Herman J. Uytterhoeven , Wolfgang Podszun
IPC分类号： G03C1/675 , B41M5/00 , B41M5/382 , B41M5/40 , B41M5/46 , B41M5/48 , B41M5/52 , B41M7/00 , G03C5/18 , G03C8/40 , G03C5/54
CPC分类号： B41M5/48 , B41M5/38207 , B41M5/46 , B41M5/5227 , B41M5/465 , B41M7/009 , Y10S430/165
摘要： A thermal imaging process comprising the step of imagewise heating a donor element so as to transfer therefrom colored matter onto a contacting receptor element, characterized in that before said imagewise heating said receptor element contains in a layer at least one substance that by heat applied in the transfer of said colored matter undergoes a change giving rise to an increase in optical density.
摘要翻译：一种热成像方法，包括对供体元件进行成像加热以便将着色物质转移到接触接收元件上的步骤，其特征在于，在所述成像加热之前，所述受光元件在所述层中含有至少一种物质，所述着色物质的转移发生变化，导致光密度的增加。

75. 发明授权

US5348656A Optically active bead polymers containing fillers 失效
标题翻译：含有填料的光学活性珠粒聚合物
公开(公告)号：US5348656A
公开(公告)日：1994-09-20
申请号：US156517
申请日：1992-11-23
申请人： Wolfgang Podszun , Bruno Bomer , Rolf Grosser , Walter Lange , Michael Grosse-Bley
发明人： Wolfgang Podszun , Bruno Bomer , Rolf Grosser , Walter Lange , Michael Grosse-Bley
IPC分类号： B01D15/08 , C07B57/00 , C07B63/00 , C07D209/82 , C08F2/18 , C08F2/20 , C08F2/44
CPC分类号： C08F2/44 , C07B57/00 , Y10T428/2982
摘要： The invention relates to optically active, pressurestable bead polymers containing fillers, and their use as adsorbents for the chromatographic resolution of enantiomeric mixtures (or racemates) into their enantiomers.
摘要翻译：本发明涉及含有填料的光学活性的，耐压稳定的珠粒聚合物，以及它们作为对映异构体混合物（或外消旋物）到它们的对映异构体中的色谱拆分的吸附剂的用途。

76. 发明授权

US5270350A Crosslinked shaped dental articles 失效
标题翻译：交联形状牙科用品
公开(公告)号：US5270350A
公开(公告)日：1993-12-14
申请号：US824846
申请日：1992-01-23
申请人： Michael Muller , Wolfgang Podszun , Gunther Bebermeier , Roland Richter
发明人： Michael Muller , Wolfgang Podszun , Gunther Bebermeier , Roland Richter
IPC分类号： A61C13/087 , A61K6/08 , A61K6/083
CPC分类号： A61K6/083
摘要： The invention relates to a process for the production of crosslinked dental mouldings, in particular for teeth made of plastic, the compositions used therefore and the articles obtained.
摘要翻译：本发明涉及一种用于生产交联牙科模制品的方法，特别是用于由塑料制成的牙齿，因此使用的组合物和所获得的制品。

77. 发明授权

US4617327A Inorganic-organic fillers for polymerizable compositions 失效
标题翻译：用于可聚合组合物的无机 - 有机填料
公开(公告)号：US4617327A
公开(公告)日：1986-10-14
申请号：US786256
申请日：1985-10-10
申请人： Wolfgang Podszun
发明人： Wolfgang Podszun
IPC分类号： C08K9/06 , A61K6/08 , A61K6/083 , C08F2/00 , C08F2/06 , C08F2/38 , C08F2/44 , C08F20/00 , C08F20/10 , C08F20/18 , C08F30/00 , C08F30/08 , C08F220/10 , C08F269/00 , C08F275/00 , C08F285/00 , C08F292/00 , C08K9/10 , C08L33/00 , C08L33/02 , C08L33/04 , C08L33/08 , C08L33/14 , C08L43/00 , C08L43/04 , C08L67/00 , C09C1/28 , C09C1/30 , C09C1/40 , C09C1/42 , C09C3/00 , C09C3/10 , C09C3/12
CPC分类号： A61K6/083 , C08F285/00 , C08F292/00 , C08K9/10 , C09C1/309 , C09C3/006 , C01P2004/64 , C01P2004/84
摘要： A filler for a polymerizable composition comprising an inorganic core of particles with a particle size of 10 to 500 nm, a first shell of vinylsilane and a second shell of a (meth)acrylate polymer. The filler is then used to prepare dental moldings of acrylates in conventional manner. The moldings are very hard and abrasion resistant.
摘要翻译：一种可聚合组合物的填料，其包含粒径为10-500nm的颗粒的无机核，乙烯基硅烷的第一壳和（甲基）丙烯酸酯聚合物的第二壳。然后将填料用于以常规方式制备丙烯酸酯的牙科模制品。模制品非常坚硬耐磨。

78. 发明申请

US20080229882A1 Process for Purifying Sulphuric Acids 审中-公开
标题翻译：纯化硫酸的方法
公开(公告)号：US20080229882A1
公开(公告)日：2008-09-25
申请号：US10570455
申请日：2004-08-23
申请人： Olaf Halle , Wolfgang Podszun , Bruno Hees , Rheinhold Klipper , Jean-Marc Vesselle
发明人： Olaf Halle , Wolfgang Podszun , Bruno Hees , Rheinhold Klipper , Jean-Marc Vesselle
IPC分类号： C25C1/12 , C22B9/00
CPC分类号： C01B17/904 , B01J45/00 , C01B17/907 , C01B17/908 , C25C1/12
摘要： The present invention relates to a process for purifying sulphuric acids, in particular metal-containing sulphuric acids, characterized in that monodisperse ion exchangers having chelating functional groups are used.
摘要翻译：本发明涉及一种纯化硫酸，特别是含金属硫酸的方法，其特征在于使用具有螯合官能团的单分散离子交换剂。

79. 发明申请

US20080087604A1 Heat-stable anion exchangers 有权
标题翻译：热稳定阴离子交换剂
公开(公告)号：US20080087604A1
公开(公告)日：2008-04-17
申请号：US11899125
申请日：2007-09-04
申请人： Pierre Vanhoorne , Wolfgang Podszun , Reinhold Klipper , Michael Schelhaas
发明人： Pierre Vanhoorne , Wolfgang Podszun , Reinhold Klipper , Michael Schelhaas
IPC分类号： C08J9/00 , B01D15/04
CPC分类号： B01J41/14 , B01J31/08 , C02F1/42 , C02F2001/422 , C02F2103/023
摘要： The present invention relates to heat-stable anion exchangers based on at least one aromatic monomer and at least one crosslinker having structural elements of the general formula (I) where Ak, Ak′, Ak″ are in each case independently of one another identically or differently a C1-C18-alkyl radical, n is an even number between 5 and 18, x+y=2 and X is Cl, Br, OH, HCO3, HSO4, ½ (SO4), ½ CO3, NO3, F, H2PO4, ½ HPO4, ⅓ PO4 with the result that these anion exchangers, preferably in the OH form, withstand a working temperature of at least 60° C., preferably of at least 80° C., over a relatively long time, a process for production thereof and also use thereof.
摘要翻译：本发明涉及基于至少一种芳族单体和至少一种具有通式（I）的结构元件的交联剂的热稳定阴离子交换剂，其中Ak，Ak'，Ak“在每种情况下彼此独立地彼此独立地或者不同的是C 1 -C 18 - 烷基，n是5至18之间的偶数，x + y = 2，X是Cl，Br，OH， HCO 3，HSO 4，½（SO 4 S），1/3 CO 3，NO 3， / SUB，F，H 2 PO 4，1/2 HPO 4，1/3 PO 4，和结果是这些阴离子交换剂优选为OH形式，在相当长的时间内经受至少60℃，优选至少80℃的工作温度，其制备方法及其用途。

80. 发明授权

US07238762B2 Weakly acidic cation exchangers 失效
公开(公告)号：US07238762B2
公开(公告)日：2007-07-03
申请号：US11509984
申请日：2006-08-25
申请人： Wolfgang Podszun , Olaf Halle , Reinhold Klipper , Rudolf Wagner , Pierre Vanhoorne , Wolfgang Zarges
发明人： Wolfgang Podszun , Olaf Halle , Reinhold Klipper , Rudolf Wagner , Pierre Vanhoorne , Wolfgang Zarges
IPC分类号： C08F20/10 , C08F20/06
CPC分类号： C08J5/20 , B01J39/07 , B01J39/20 , C08F8/44 , C08F212/36 , C08F220/06 , C08F220/14 , C08F2810/20 , C08F8/12
摘要： The present invention relates to a process for producing weakly acidic cation exchangers of the polymethacrylic acid type by alkaline saponification of a crosslinked copolymer of alkyl methacrylate and methacrylic acid.

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