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71. 发明授权

US3965186A 5- OR 6-Acetyl-substituted 1-methyl-4-isopropyl-1,4-ethano-cyclohex-2-enes 失效
标题翻译： 5-或6-乙酰基取代的1-甲基-4-异丙基-1,4-乙酸 - 环己-2-烯
公开(公告)号：US3965186A
公开(公告)日：1976-06-22
申请号：US590470
申请日：1975-06-26
申请人： John B. Hall
发明人： John B. Hall
IPC分类号： C11B9/00 , C11D3/50 , C07C49/61
CPC分类号： C11B9/0046 , C11D3/50
摘要： A mixture of compounds having the structure: ##SPC1##Useful as fragrance ingredients.
摘要翻译：具有以下结构的化合物的混合物：

72. 发明授权

US4609754A Process for the production of isosolanone and solanone, intermediates useful in said process and organoleptic uses of said intermediates 失效
标题翻译：用于生产异溶胶酮和溶胶酮的方法，可用于所述方法的中间体和所述中间体的感官用途
公开(公告)号：US4609754A
公开(公告)日：1986-09-02
申请号：US609348
申请日：1984-06-22
申请人： John B. Hall , James M. Sanders , James N. Siano
发明人： John B. Hall , James M. Sanders , James N. Siano
IPC分类号： A24B15/32 , C07C29/40 , C07C33/02 , C07C45/54 , C07C45/67 , C07C45/75 , C07C49/203 , C11D3/50 , C07C69/72
CPC分类号： C11D3/50 , A24B15/32 , C07C29/40 , C07C33/02 , C07C45/54 , C07C45/67 , C07C45/676 , C07C45/75 , C07C49/203 , C07C67/03 , C07C69/72
摘要： Described is a novel genus of compounds defined according to the structure: ##STR1## wherein Z represents hydrogen, MgX and the moiety having the structure: ##STR2## and X represents chlor, bromo, or iodo; as well as 5-isopropyl-8-methyl-5,8-nonadien-2-one; uses of same as intermediates in a process for producing isosolanone and solanone; and organoleptic uses of 5-isopropyl-8-methyl-5,8-nonadien-2-one and 2,6-dimethyl-5-methylene-1-hepten-4-ol.The novel process of our invention involved the steps of:(i) formation of the compound having the structure: ##STR3## by means of reacting 3-methyl-2-methylenebutanal with the compound having the structure: ##STR4## (ii) acid hydrolysis of the resulting compound in order to form 2,6-dimethyl-5-methylene-1-heptene-4-ol;(iii) reaction of 2,6-dimethyl-5-methylene-1-hepten-4-ol with methyl aceto acetate in order to form 2,6-dimethyl-5-methylene-1-hepten-4-yl aceto acetate or, directly, 5-isopropyl-8-methyl-5,8-nonadiene-2-one;(iv) reacting 2,6-dimethyl-5-methylene-1-hepten-4-yl aceto acetate in the presence of an appropriate catalyst to form the 5-isopropyl-8-methyl-5,8-nonadiene-2-one; and(v) isomerizing the 5-isopropyl-8-methyl-5,8-nonadien-2-one in order to form a mixture of solanone and the isosolanone or 5-isopropyl-8-methyl-5,8-nonadiene-2-one.
摘要翻译：描述了根据以下结构定义的化合物的新颖属性：其中Z表示氢，MgX和具有以下结构的部分：＆lt; IMAGE＆gt; X表示氯，溴或碘; 以及5-异丙基-8-甲基-5,8-壬二烯-2-酮; 在制备异山芋酮和solanone的方法中使用与中间体相同的物质; 和5-异丙基-8-甲基-5,8-壬二烯-2-酮和2,6-二甲基-5-亚甲基-1-庚烯-4-醇的感官用途。本发明的新方法涉及以下步骤：（i）通过使3-甲基-2-亚甲基丁醛与具有以下结构的化合物反应形成具有以下结构的化合物：（ⅱ）酸水解所得化合物以形成2,6-二甲基-5-亚甲基-1-庚烯-4-醇; （iii）2,6-二甲基-5-亚甲基-1-庚烯-4-醇与乙酰乙酸甲酯的反应，以形成2,6-二甲基-5-亚甲基-1-庚烯-4-基乙酸乙酯或直接得到5-异丙基-8-甲基-5,8-壬二烯-2-酮; （iv）使2,6-二甲基-5-亚甲基-1-庚烯-4-基乙酸乙酯在合适的催化剂存在下反应，形成5-异丙基-8-甲基-5,8-壬二烯-2-酮 ; 和（v）异构化5-异丙基-8-甲基-5,8-壬二烯-2-酮，以形成Solone和二异丙基酮或5-异丙基-8-甲基-5,8-壬二烯-2-酮的混合物 -一。

73. 发明授权

US4548821A Flavoring with tertiary pentamethylindanol derivatives 失效
标题翻译：用叔五甲基茚醇衍生物调味
公开(公告)号：US4548821A
公开(公告)日：1985-10-22
申请号：US702361
申请日：1985-02-15
申请人： John B. Hall , Takao Yoshida
发明人： John B. Hall , Takao Yoshida
IPC分类号： A24B15/34 , C07C35/23 , C07C35/32 , C11B9/00 , C11D3/50 , A23L1/226 , A23L1/235
CPC分类号： C11D3/50 , A24B15/345 , C07C35/23 , C07C35/32 , C11B9/0049
摘要： Described are tertiary pentamethylindanol derivatives defined according to the structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and uses thereof in augmenting or enhancing the aroma or taste of consumable materials selected from the group consisting of perfume compositions, colognes, perfumed articles, foodstuffs, smoking tobaccos and smoking tobacco compositions.
摘要翻译：描述了根据以下结构定义的叔五甲基茚醇衍生物：其中虚线表示碳 - 碳单键或碳 - 碳双键，并且其用于增强或增强选自组中的可消耗材料的香气或味道由香水组合物，古龙水，香料制品，食品，烟草烟草和烟草组合物组成。

74. 发明授权

US4520032A Use in augmenting or enhancing the aroma or taste of foodstuffs or chewing gums of tetrahydro-1,1,2,3,3-pentamethyl-3A[4H]-indanol 失效
标题翻译：用于增强或增强四氢-1,1,2,3,3-五甲基-3A [4H] - 茚满的食品或口香糖的香气或味道
公开(公告)号：US4520032A
公开(公告)日：1985-05-28
申请号：US589662
申请日：1984-03-14
申请人： John B. Hall , Takao Yoshida
发明人： John B. Hall , Takao Yoshida
IPC分类号： A23L27/20 , A24B3/12 , A24B15/34 , A61K8/34 , A61Q13/00 , B01J31/00 , C07C27/00 , C07C29/56 , C07C35/23 , C07C35/32 , C07C67/00 , C11B9/00 , C11D3/50 , C11D9/44 , A23L1/226
CPC分类号： C11B9/0049 , A24B15/345 , C07C35/23 , C07C35/32 , C11D3/50
摘要： Described are tertiary pentamethylindanol derivatives defined according to the structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and uses thereof in augmenting or enhancing the aroma or taste of consumable materials selected from the group consisting of perfume compositions, colognes, perfumed articles, foodstuffs, smoking tobaccos and smoking tobacco compositions.
摘要翻译：描述了根据以下结构定义的叔五甲基茚醇衍生物：其中虚线表示碳 - 碳单键或碳 - 碳双键，并且其用于增强或增强选自组中的可消耗材料的香气或味道由香水组合物，古龙水，香料制品，食品，烟草烟草和烟草组合物组成。

75. 发明授权

US4503258A Process for preparing 1(4-pentenoyl)-3,3-dimethylcyclohexane and intermediates used in said process 失效
标题翻译：制备1（4-戊烯酰）-3,3-二甲基环己烷和所述方法中使用的中间体的方法
公开(公告)号：US4503258A
公开(公告)日：1985-03-05
申请号：US551481
申请日：1983-11-14
申请人： John B. Hall , Mark A. Sprecker
发明人： John B. Hall , Mark A. Sprecker
IPC分类号： C07C49/15 , C07C51/02 , C07C59/80 , C07C403/00 , C11B9/00 , C07C49/21
CPC分类号： C11B9/0034 , C07C403/16 , C07C51/02 , C07C59/80 , C07C2101/14
摘要： Compounds of the following structure ##STR1## wherein R.sub.1 is selected from the group consisting of hydrogen and 2-propenyl are disclosed useful as intermediates in organic synthesis.
摘要翻译：公开了以下结构的化合物，其中R 1选自氢和2-丙烯基，可用作有机合成中的中间体。

76. 发明授权

US4428966A Use of substituted cyclohexyl carboalkoxy ketone in augmenting or enhancing the aroma or taste of foodstuffs 失效
标题翻译：使用取代的环己基碳烷氧基酮来增强或增强食品的香气或味道
公开(公告)号：US4428966A
公开(公告)日：1984-01-31
申请号：US474161
申请日：1983-03-10
申请人： John B. Hall , Mark A. Sprecker
发明人： John B. Hall , Mark A. Sprecker
IPC分类号： A23L27/29 , C07C51/02 , C07C59/80 , C11B9/00 , A23L1/235
CPC分类号： C07C403/16 , C07C51/02 , C07C59/80 , C11B9/0034 , C07C2101/14
摘要： Described is a process for augmenting or enhancing the aroma or taste of raspberry flavored foodstuffs or chewing gums by adding to a foodstuff or chewing gum an aroma or taste augmenting or enhancing quantity of at least one compound having the structure: ##STR1## wherein R represents C.sub.1 -C.sub.3 alkyl.
摘要翻译：描述了通过向食品或口香糖中添加或增加至少一种具有以下结构的化合物的香味或味道增加或增加量来增强或增强覆盆子风味食品或口香糖的香味或味道的方法：其中R表示 C 1 -C 3烷基。

77. 发明授权

US4264456A Benzodioxanones and organoleptic uses thereof 失效
公开(公告)号：US4264456A
公开(公告)日：1981-04-28
申请号：US145984
申请日：1980-05-02
申请人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
发明人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
IPC分类号： A23L27/20 , A24B15/40 , C07D319/20 , C11B9/00 , A23L1/226
CPC分类号： C11B9/008 , A23L27/2052 , A24B15/403 , C07D319/20
摘要： Described are the bicyclic compounds having the generic structure: ##STR1## wherein Z is benzo or cyclohexano and processes for preparing same and compositions containing same for use in augmenting or enhancing the aroma and/or taste of foodstuffs, chewing gums, toothpastes and medicinal products; tobacco; perfumes, colognes and perfumed articles, produced by a process described by the reaction: ##STR2## wherein X is chloro or bromo; Y is chloro, bromo or OR; R is C.sub.1 -C.sub.3 lower alkyl, that is: methyl, ethyl, n-propyl or i-propyl; B is MOH, MH, MOR', trialkylamine, or M.sub.2 -CO.sub.3 (wherein M is alkali metal such as sodium or potassium); and R' is C.sub.1 -C.sub.5 lower alkyl, such as methyl, ethyl, n-propyl, i-propyl and t-butyl with the proviso that B is trialkylamine or an alkali metal carbonate when Y is chloro or bromo and B is MOH, MH or MOR' when Y is OR.The above mentioned compounds produce:A. In foodstuffs, chewing gums and medicinal products, a sweet, green, fruity, coumarinic, marzipan-like aroma and taste.B. In tobacco, a sweet, spicy, vanilla-like, woody, hay, tobacco-like aroma prior to smoking and a sweet, spicy, hay, tobacco-like aroma on smoking.C. In perfumes, colognes and perfumed articles, sweet, fruity, and green aroma nuances.

78. 发明授权

US4248787A Process for preparing substituted cyclic acetals of oxyacetaldehydes and said cyclic acetals 失效
标题翻译：制备取代的环氧缩醛缩醛和所述环状缩醛的方法
公开(公告)号：US4248787A
公开(公告)日：1981-02-03
申请号：US968009
申请日：1978-12-08
申请人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
发明人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
IPC分类号： C07C41/48 , C07C43/303 , C11B9/00 , C07D317/10 , C07D319/06 , C07D321/06
CPC分类号： C11B9/0015 , C07C41/48 , C07C43/303 , C07C45/59
摘要： A process is described for the preparation of substituted oxyacetaldehydes and cyclic acetals thereof according to the reaction sequence: ##STR1## wherein R.sub.1 and R.sub.2, taken together form a lower alkylene group; wherein R.sub.3 is alkyl, alkenyl or alkadienyl and X is halogen selected from the group consisting of chlorine and bromine, the reaction (i) being carried out (1) using a "phase transfer agent" and (2) in a two phase system.
摘要翻译：描述了根据反应顺序制备取代的氧乙醛及其缩醛的方法：其中R 1和R 2一起形成低级亚烷基（ⅰ）其中R 1和R 2一起形成低级亚烷基 ; 其中R 3是烷基，烯基或链二烯基，X是选自氯和溴的卤素，反应（i）使用“相转移剂”和（2）在两相体系中进行（1）。

79. 发明授权

US4241228A 2,2,3-Trimethyl-3-cyclopenten-1-ylalkenyl and alkylidene secondary alkanols, alkanones, cycloalkanols and cycloalkanones, organoleptic uses thereof in perfume compositions, colognes and perfumed articles and process for producing same 失效
标题翻译： 2,2,3-三甲基-3-环戊烯-1-基烯基和亚烷基仲链烷醇，链烷酮，环烷醇和环烷酮，在香料组合物，古龙水和香料制品中的感官用途及其制备方法
公开(公告)号：US4241228A
公开(公告)日：1980-12-23
申请号：US23322
申请日：1979-03-22
申请人： Takao Yoshida , Braja D. Mookherjee , Venkatesh Kamath , John B. Hall , William I. Taylor , Frederick L. Schmitt
发明人： Takao Yoshida , Braja D. Mookherjee , Venkatesh Kamath , John B. Hall , William I. Taylor , Frederick L. Schmitt
IPC分类号： C07C33/12 , C07C45/74 , C11B9/00 , C07C35/21
CPC分类号： C11B9/0034 , C07C33/12 , C07C45/74 , C11B9/003
摘要： Described are perfume and fragrance compositions and perfumed articles including soaps, detergents, powders as well as colognes containing 2,2,3-trimethyl-3-cyclopenten-1-ylalkenyl and alkylidene secondary alkanols, alkanones, cycloalkanols and cycloalkanones having the generic structure: ##STR1## wherein one of the lines +++++ is a carbon-carbon double bond and the other of the lines +++++ is a carbon-carbon single bond; wherein X is carbinol having the structure: ##STR2## or carbonyl having the structure ##STR3## wherein A' is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; wherein B' is hydrogen, CH.sub.3, C.sub.2 H.sub.5 or --CH.sub.2 --; where n is 0, 1 or 2; wherein each of the dashed lines are the same and each represents a carbon-carbon single bond or no bond; wherein A' and B' are both --CH.sub.2 -- when n is 1 or 2 and the dashed line is a carbon-carbon single bond or A' is hydrogen and B' is C.sub.2 H.sub.5 or CH.sub.3 or both A' and B' are each CH.sub.3 or A' is C.sub.2 H.sub.5 and B' is CH.sub.3 when n is 0 and the dashed line represents no bond, which imparts thereto rich, musky, cedar woody, sandalwood, sweet, floral, ionone-like, soft-fruity (apricot), green and earthy aromas with resinous topnotes and nutty oily nuances. Also described is a process for preparing such compounds according to the reaction schemes: ##STR4## wherein the lines +++++ A', B', the dashed lines and n are as defined above wherein M is alkaline metal.
摘要翻译：描述了香料和香料组合物和包含肥皂，洗涤剂，粉末以及含有具有以下通用结构的2,2,3-三甲基-3-环戊烯-1-基烯基和亚烷基仲链烷醇，链烷酮，环烷醇和环烷酮的香水制品，其中线+++++之一是碳 - 碳双键，另一条线+++++是碳 - 碳单键; 其中X是具有以下结构的甲醇：具有结构的羰基，其中A'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中B'是氢，CH 3，C 2 H 5或-CH 2 - ; 其中n为0,1或2; 其中每个虚线相同并且各自表示碳 - 碳单键或无键; 其中当n为1或2并且虚线为碳 - 碳单键或A'为氢且B'为C 2 H 5或CH 3时，A'和B'均为-CH 2 - ，或者A'和B'均为CH 3 或A'为C 2 H 5，B'为CH 3，n为0，虚线表示无键，赋予其丰富，麝香，雪松木香，檀香，甜，花，紫罗兰酮，软果（杏），绿和土质的香气与树脂的顶部和坚果油的细微差别。还描述了根据反应方案制备这些化合物的方法：其中线+++++ A'，B'，虚线和n 如上所定义，其中M是碱金属。

80. 发明授权

US4205186A Process for preparing substituted oxyacetaldehydes and acetals thereof 失效
标题翻译：制备取代的氧乙醛及其缩醛的方法
公开(公告)号：US4205186A
公开(公告)日：1980-05-27
申请号：US3883
申请日：1979-01-16
申请人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
发明人： Mark A. Sprecker , John J. Kryschuk , John B. Hall
IPC分类号： C07C41/48 , C07C43/315 , C07C45/51 , C07C47/277 , C11B9/00 , C07C43/30
CPC分类号： C11B9/0015 , C07C41/48 , C07C43/315 , C07C45/515 , C07C47/277
摘要： A process is described for the preparation of substituted oxyacetaldehydes and acetals thereof according to the reaction sequence: ##STR1## wherein R.sub.1 and R.sub.2 are each lower alkyl or R.sub.1 and R.sub.2, taken together form a lower alkylene group; wherein R.sub.3 is alkyl, alkenyl or alkadienyl and X is halogen selected from the group consisting of chlorine and bromine, the reaction (i) being carried out (1) using a "phase transfer agent" and (2) in a two phase system.
摘要翻译：描述根据反应顺序制备取代的氧乙醛及其缩醛的方法：其中R 1和R 2各自为低级烷基或R 1和R 2，取代一起形成低级亚烷基; 其中R 3是烷基，烯基或链二烯基，X是选自氯和溴的卤素，反应（i）使用“相转移剂”和（2）在两相体系中进行（1）。

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