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    • 73. 发明授权
      US5403814A Sulfonylureas 失效
    • Sulfonylureas
    • 磺脲类
    • US5403814A
    • 1995-04-04
    • US224393
    • 1994-04-07
    • Werner Fory
    • Werner Fory
    • A01N47/36 , C07D521/00 , C07D401/12 , A01N43/54
    • C07D521/00 , A01N47/36
    • N-pyridinesulfonyl-N'-pyrimidinyl- and -triazinyl-ureas of formula I ##STR1## wherein R.sub.1 is hydrogen or fluorine;or R.sub.1 together with R.sub.3 is a C.sub.2 -C.sub.4 alkylene chain;R.sub.3 is hydrogen, fluorine or C.sub.1 -C.sub.3 alkyl;R.sub.2 is hydrogen, fluorine or C.sub.1 -C.sub.3 alkyl;R.sub.4 is hydrogen, fluorine, chlorine or C.sub.1 -C.sub.3 alkyl;R.sub.5 is hydrogen, fluorine, chlorine, C.sub.1 -C.sub.3 alkyl, or C.sub.1 -C.sub.3 alkyl substituted by fluorine or chlorine;R.sub.a is hydrogen or halogen, or a C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylthio radical each of which may be unsubstituted or mono- or poly-substituted by halogen;R.sub.b is hydrogen or a C.sub.1 -C.sub.4 alkyl radical;X is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkyl mono- to tri-substituted by halogen, C.sub.1 -C.sub.3 alkoxy, or C.sub.1 -C.sub.3 alkoxy mono- to tri-substituted by halogen;Y is halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkyl mono- to tri-substituted by halogen, C.sub.1 -C.sub.3 alkoxy, orC.sub.1 -C.sub.3 alkoxy mono- to tri-substituted by halogen, or is cyclopropyl, methylamino or dimethylamino; andE is nitrogen or the methine group,and the salts of those compounds, with the proviso that at least one of the radicals R.sub.1 to R.sub.5 is fluorine, or one of the radicals R.sub.4 and R.sub.5 is chlorine, have good selective-herbicidal properties. The preparation of those compounds and their use as herbicidal active ingredients is described.
    • 式I的N-吡啶磺酰基-N'-嘧啶基 - 和 - 三嗪基 - 脲其中R 1是氢或氟; 或R 1与R 3一起为C 2 -C 4亚烷基链; R3是氢，氟或C1-C3烷基; R2是氢，氟或C1-C3烷基; R4是氢，氟，氯或C1-C3烷基; R5是氢，氟，氯，C1-C3烷基或被氟或氯取代的C1-C3烷基; R a是氢或卤素，或C 1 -C 4烷基，C 1 -C 4烷氧基或C 1 -C 4烷硫基，其各自可以是未取代的或被卤素单取代或多取代; Rb是氢或C1-C4烷基; X是C1-C3烷基，被卤素单取代至三取代的C1-C3烷基，C1-C3烷氧基或被卤素单取代至三取代的C1-C3烷氧基; Y为卤素，C 1 -C 3烷基，被卤素单取代至三取代的C 1 -C 3烷基，C 1 -C 3烷氧基或被卤素单取代至三取代的C 1 -C 3烷氧基，或为环丙基，甲氨基或二甲基氨基; 并且E是氮或次甲基，以及那些化合物的盐，条件是基团R 1至R 5中的至少一个为氟，或者基团R 4和R 5之一为氯，具有良好的选择性除草性质。 描述了这些化合物的制备及其作为除草活性成分的用途。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 75. 发明授权
      US4675417A Fused phenylsulfonamides 失效
    • Fused phenylsulfonamides
    • 稠油苯磺酰胺
    • US4675417A
    • 1987-06-23
    • US825282
    • 1986-02-03
    • Josef Ehrenfreund , Werner Fory
    • Josef Ehrenfreund , Werner Fory
    • A01N47/36 , C07D217/24 , C07D279/02 , C07D311/18 , C07D311/76 , C07D327/06 , C07D335/06 , C07D339/08 , C07D401/12 , C07D411/12 , C07D521/00
    • C07D521/00 , A01N47/36 , C07D217/24 , C07D327/06
    • Fused N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the general formula ##STR1## wherein Z is oxygen or sulfur,E is nitrogen or .dbd.CH--,R.sup.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, cyano, or a --X--R.sup.5, --CO--X--R.sup.6, --CO--NR.sup.7 R.sup.8, --SO--R.sup.9 or --SO.sub.2 --R.sup.10 group,R.sup.2 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.4 alkoxy,R.sup.3 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy or C.sub.3 -C.sub.6 cycloalkyl,R.sup.4 is hydrogen, halogen, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.2 -C.sub.4 alkoxyalkoxy, C.sub.3 -C.sub.6 cycloalkyl or --NR.sup.11 R.sup.12,R.sup.5 is C.sub.3 -C.sub.5 alkynyl or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.4 alkoxy, or is C.sub.3 -C.sub.5 alkenyl, which is unsubstituted or is substituted by halogen or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 and R.sup.9 are each independently C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.4 alkylalkyl, C.sub.3 -C.sub.5 alkenyl, C.sub.3 -C.sub.5 alkynyl, phenyl or benzyl,R.sup.7 and R.sup.8 are each independently hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.4 alkoxyalkyl, C.sub.3 -C.sub.5 alkenyl, C.sub.5 -C.sub.5 alkynyl, phenyl or benzyl,R.sup.10 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy or --NR.sup.13 R.sup.14,R.sup.11 and R.sup.12 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl,R.sup.13 and R.sup.14 are each independently hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.2 -C.sub.4 alkoxyalkyl, C.sub.3 -C.sub.5 alkenyl, C.sub.3 -C.sub.5 alkynyl, phenyl or benzyl,X is oxygen or sulfur, andA is an unsubstituted or substituted unsaturated bridge of 4 atoms, of the formula --CH.dbd.CH--Y--, wherein Y is a bridge member of 2 atoms which is selected from the series consisting of --NH--CO--, --NH--SO.sub.2 --, --S--CO--, --S--SO.sub.2 --, --O--CO-- or --O--SO.sub.2 --,and the salts thereof with amines, alkali metal or alkaline earth metal bases or with quaternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties.
    • 熔融的N-苯基磺酰基-N'-嘧啶基脲和通式为（I）的N-苯基磺酰基-N'-三嗪基脲其中Z是氧或硫，E是氮或= CH-，R 1是氢，卤素，硝基 ，C1-C4烷基，C1-C4卤代烷基，氰基或-X-R5，-CO-X-R6，-CO-NR7R8，-SO-R9或-SO2-R10基团，R2是氢，C1-C4烷基或C1 -C4烷氧基，R3是C1-C4烷基，C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基或C3-C6环烷基，R4是氢，卤素，C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C2-C4烷氧基烷氧基，C3-C6环烷基 或-NR 11 R 12，R 5为未被取代或被卤素或C 1 -C 4烷氧基取代的C 3 -C 5炔基或C 1 -C 4烷基，或未被取代或被卤素或C 1 -C 4 - 烷氧基取代的C 3 -C 5烯基，R 6和R 9为 C 1 -C 4烷基，C 3 -C 5链烯基，C 3 -C 5炔基，苯基或苄基，R 7和R 8各自独立地为氢，C 1 -C 4烷基，C 1 -C 4卤代烷基，C 2 -C 4烷氧基烷基，C 3 -C 5烯基， C5-C5炔基，苯基或苄基，R10是C1-C4 烷基，C1-C4烷氧基，C1-C4卤代烷氧基或-NR13R14，R11和R12各自独立地为氢或C1-C4烷基，R13和R14各自独立地为氢，C1-C4烷基，C1-C4卤代烷基，C2-C4烷氧基烷基，C3-C5烯基，C3 C 5炔基，苯基或苄基，X是氧或硫，A是4个原子的未取代或取代的不饱和桥，其具有式-CH = CH-Y-，其中Y是2个原子的桥连， 由-NH-CO-，-NH-SO2-，-S-CO-，-S-SO2-，-O-CO-或-O-SO2-组成的系列及其与胺，碱金属或 碱土金属碱基或季铵碱，具有良好的芽前和芽后选择性除草和生长调节性质。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 76. 发明授权
      US4555262A N-Azidophenylsulfonyl-N'-pyrimidinyl ureas 失效
    • N-Azidophenylsulfonyl-N'-pyrimidinyl ureas
    • N-叠氮苯基磺酰基-N'-嘧啶基脲
    • US4555262A
    • 1985-11-26
    • US525365
    • 1983-08-22
    • Rudolph C. Thummel , Werner Fory
    • Rudolph C. Thummel , Werner Fory
    • C07D251/16 , A01N47/36 , C07D239/47 , C07D239/52 , C07D521/00 , C07D239/46
    • C07D521/00 , A01N47/36
    • The invention relates to N-azidophenylsulfonyl-N'-pyrimidinyl- and -N'-triazinylureas of the general formula ##STR1## wherein E is nitrogen or the methine bridge,R.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl or C.sub.2 -C.sub.5 alkoxyalkoxy,R.sub.2 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy,R.sub.3 is hydrogen, halogen, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy, C.sub.2 -C.sub.5 alkoxyalkoxy or --NR.sub.4 R.sub.5, whereinR.sub.4 is hydrogen or methyl andR.sub.5 is hydrogen, methyl, ethyl or methoxyand to the salts thereof with amines, alkali metal hydroxides and alkaline earth metal hydroxides or with quaternary ammonium bases. These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.
    • 本发明涉及通式为“IMAGE”的N-叠氮苯基磺酰基-N'-嘧啶基和-N'-三嗪基脲，其中E为氮或次甲基桥，R1为氢，卤素，硝基，C1-C4烷基，C1-C4卤代烷基 ，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷氧基羰基，C1-C4烷硫基，C1-C4烷基亚磺酰基，C1-C4烷基磺酰基或C2-C5烷氧基烷氧基，R2是C1-C3烷基，C1-C3烷氧基或C1-C3卤代烷氧基，R3是氢， C 3烷基，C 1 -C 3卤代烷基，C 1 -C 3烷氧基，C 1 -C 3卤代烷氧基，C 2 -C 5烷氧基烷氧基或-NR 4 R 5，其中R 4是氢或甲基，R 5是氢，甲基，乙基或甲氧基，其盐与胺，碱金属氢氧化物和 碱土金属氢氧化物或季铵碱。 这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 77. 发明授权
      US4493726A Phenylpyrimidines as antidotes for protecting cultivated plants against phytotoxic damage caused by herbicides 失效
    • Phenylpyrimidines as antidotes for protecting cultivated plants against phytotoxic damage caused by herbicides
    • US4493726A
    • 1985-01-15
    • US486651
    • 1983-04-20
    • Kurt Burdeska , Guglielmo Kabas, deceased , Hans-Georg Brunner , Werner Fory
    • Kurt Burdeska , Guglielmo Kabas, deceased , Hans-Georg Brunner , Werner Fory
    • A01N57/10 , A01N25/02 , A01N25/32 , A01N37/22 , A01N43/54 , A01P13/00 , C07D239/30 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/52 , C07D405/10 , C07F9/6512 , A01N43/48 , C07D239/02
    • C07D239/30 , A01N25/32 , C07D239/42 , C07D239/47 , C07D239/52 , C07F9/65122
    • Phenylpyrimidines of the formula I as defined below are suitable as antidotes for protecting cultivated plants from phytotoxic effects caused by herbicides. These antidotes, either together with the herbicides or also by themselves, are applied to the plants or incorporated in the soil in which the plants grow, or they are used to treat the seeds of the plants. Suitable herbicides are those belonging to the class of the haloacetanilides, haloacetamides, thiocarbamates, carbamates, nitroanilides, triazines, phenylureas, haloacetic acids, phenoxy- and pyridyloxyphenoxyalkanecarboxylic acid derivatives, benzoic acid derivatives etc. The phenylpyrimidines have the formula I ##STR1## wherein n is an integer from 1 to 5,R is hydrogen, halogen, cyano, nitro or hydroxyl, a C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 alkylthio group, which is unsubstituted or mono- or polysubstituted by halogen, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.12 alkoxyalkyl, C.sub.1 -C.sub.6 alkylcarbonyl, C.sub.1 -C.sub.6 alkylcarbonyloxy, C.sub.1 -C.sub.6 alkoxycarbonyl, C.sub.2 -C.sub.6 alkenylcarbonyl or C.sub.2 -C.sub.6 alkynylcarbonyl, di(C.sub.1 -C.sub.6)alkylamino, C.sub.1 -C.sub.6 alkylenedioxy, phosphonyl or C.sub.1 -C.sub.6 alkylphosphonyl; or R is a C.sub.2 -C.sub.6 alkenyl or C.sub.2 -C.sub.6 alkenyloxy group or the formyl or carboxyl group; or is a carbonyl or carbonyloxy group which is substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl, C.sub.1 -C.sub.6 alkoxy, C.sub.2 -C.sub.6 alkenyl, C.sub.2 -C.sub.6 alkynyl, amino, di(C.sub.1 -C.sub.6)alkylamino, or by a 5- to 6-membered saturated heterocyclic ring which is bound through the nitrogen atom; or is an amino group which is unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 alkylcarbonyl; or it is an ureido radical which is unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl or C.sub.1 -C.sub.6 alkoxy or it is the sulfonyl, a C.sub.1 -C.sub.6 alkylsulfonyl, the sulfamoyl, a C.sub.1 -C.sub.6 alkylsulfamoyl or a C.sub.1 -C.sub.6 alkylcarbonylsulfamoylrest,R.sub.1 and R.sub.3 each independently of the other is halogen, cyano, hydroxyl, sulfhydryl, a C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy or C.sub.1 -C.sub.6 ethylthio radical, which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.6 alkoxy; a C.sub.2 C.sub.6 alkenyl or C.sub.2 -C.sub.6 alkynyl radical, a C.sub.3 -C.sub.6 cycloalkyl radical, an amino, C.sub.1 -C.sub.6 alkylamino or di(C.sub.1 -C.sub.6 alkyl) amino, group, a 5- to 6-membered saturated heterocyclic ring, which is bound through the nitrogen atom, a phenyl or phenoxyrest andR.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 haloalkyl or phenyl.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
    • 78. 发明授权
      US4437879A Oxime derivatives for protecting plant crops 失效
    • Oxime derivatives for protecting plant crops
    • US4437879A
    • 1984-03-20
    • US398164
    • 1982-07-14
    • Werner Fory , Henry Martin , Georg Pissiotas
    • Werner Fory , Henry Martin , Georg Pissiotas
    • A01N25/32 , A01N37/32 , A01N37/34 , C07C67/00 , C07C251/32 , C07C251/54 , C07C313/00 , C07C315/04 , C07C317/28 , C07C317/44 , C07C323/47 , C07C325/00 , C07C327/28 , C07D207/26 , C07D207/273 , C07D207/325 , C07D207/404 , C07D207/408 , C07D207/44 , C07D207/452 , C07D207/456 , C07D209/48 , A01N43/38
    • C07D207/273 , A01N25/32 , C07D207/452 , C07D207/456 , C07D209/48
    • Oxime derivatives of the formula (I) ##STR1## wherein n is 0, 1 or 2 and m is 0 or 1, andAr is a phenyl radical ##STR2## a naphthyl radical substituted by R.sub.2 and R.sub.3, a 5- to 10-membered heterocyclic radical which contains not more than 3 identical or different heteroatoms N, O and/or S and which is substituted by R.sub.2, R.sub.3 and R.sub.4 and can be substituted by oxo or thiono, or if m is O, Ar is a radical R--CO, wherein R is a radical --OR.sub.5, in which R.sub.5 is an aliphatic group containing not more than 8 carbon atoms or is an araliphatic group containing not more than 15 carbon atoms or is a cycloaliphatic or aromatic group, each containing not more than 10 carbon atoms, while the possible substituents of the aromatic radicals or of the cycloaliphatic radical are halogen, --CN, --NO.sub.2, lower alkyl, lower alkoxy, haloalkyl; or R is a radical --NH--CO--NH--R.sub.7 or a radical --N(R.sub.6)(R.sub.7), wherein R.sub.6 is hydrogen or lower alkyl and R.sub.7 is hydrogen or an aliphatic group containing not more than 8 carbon atoms or an araliphatic group containing not more than 15 carbon atoms, or a cycloaliphatic ##STR3## wherein R.sub.9 is hydrogen, a cycloaliphatic, araliphatic or aromatic group which is unsubstituted or mono- or polysubstituted at the ring by CN, NO.sub.2, halogen, lower alkyl, lower alkoxy or haloalkyl, or is lower alkenyl, lower haloalkenyl or lower alkynyl, R.sub.10 is an aliphatic group or a cycloaliphatic, araliphatic or aromatic group which is unsubstituted or mono- or polysubstituted at the ring by CN, NO.sub.2, halogen, lower alkyl, lower alkoxy or haloalkyl, R.sub.11 is hydrogen, lower alkyl or cycloalkyl, R.sub.12 is lower alkyl or an aromatic group, while Y is O, S SO, SO.sub.2 or ##STR4## and A is C.sub.2 -C.sub.3 alkylene or C.sub.2 -C.sub.3 alkenylene which is unsubstituted or substituted by halogen, CN or lower alkyl and which together with a carbon chain which is unsubstituted or substituted by halogen, CN or lower alkyl can form a fused ring, and Hal is halogen. These compounds are used for protecting plant crops from the action of aggressive agricultural chemicals.
    • 基本信息 添加关注 加入工作空间 PDF全文 PDF下载 全文下载 相似专利 双屏查看 权利要求书 说明书全文 Global Dossier Espacenet 法律信息 同族专利 专利引用
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