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    • 72. 发明授权
    • Ether carbinols, process for preparing same, products produced according
to said processes containing said ether carbinols, organoleptic uses
thereof, ether carboxaldehydes and organoleptic uses thereof
    • 醚甲醇,其制备方法,根据含有所述醚甲醇的方法生产的产品,其感官用途,醚甲醛和感官用途
    • US4619780A
    • 1986-10-28
    • US644054
    • 1984-08-24
    • Futoshi FujiokaRichard M. BodenWilliam L. Schreiber
    • Futoshi FujiokaRichard M. BodenWilliam L. Schreiber
    • A24B15/34C07C43/178C07C43/196C07C43/23C07C45/49C07C47/198C07C47/277C11B9/00
    • C11B9/0046A24B15/345C07C43/178C07C43/196C07C43/23C07C45/49C07C47/198C07C47/277
    • Described are ether carbinols defined according to the generic structure: ##STR1## wherein X.sub.1 represents a moiety selected from the group consisting of: ##STR2## and wherein Y.sub.1 represents C.sub.4 or C.sub.5 alkylene; C.sub.4 or C.sub.5 alkenylene or C.sub.4 or C.sub.5 alkynylene; processes for preparing such ether carbinols by means of first reacting allyl ethers with a mixture of carbon monoxide and hydrogen by means of an oxo reaction to produce ether carboxaldehydes and then reducing the thus formed ether carboxaldehydes to ether carbinols; or reacting camphene with appropriate diols; as well as methods for augmenting or enhancing the aroma or taste of consumable materials including perfumes, colognes and perfumed articles; foodstuffs, chewing gums, chewing tobaccos, medicinal products and toothpastes; and smoking tobaccos and smoking tobacco articles by adding thereto an aroma or taste augmenting or enhancing quantity of the thus produced ether carbinols.Also described are two ether carboxaldehydes having one of the structures: ##STR3## processes for preparing such ether carboxaldehydes by means of reacting out an appropriate allyl ether with a mixture of carbon monoxide and hydrogen by means of an oxo-reaction as well as methods for augmenting or enhancing the aroma or taste of consumable materials including perfumes, colognes and perfumed articles; foodstuffs, chewing gums, chewing tobaccos, medicinal products and toothpastes; smoking tobaccos and smoking tobacco articles by adding thereto an aroma or taste augmenting or enhancing quantity of the thus produced ether carboxaldehydes.
    • 描述了根据通用结构定义的醚甲醇:其中X 1表示选自以下的部分:其中Y 1表示C 4或C 5亚烷基; C4或C5亚链烯基或C4或C5亚炔基; 通过首先使烯丙基醚与一氧化碳和氢气的混合物通过氧代反应反应制备这种醚甲醇的方法,以产生醚甲醛,然后将由此形成的醚甲醛还原成醚甲醇; 或使camp烯与适当的二醇反应; 以及用于增强或增强消耗材料(包括香水,古龙水和香水制品)的香味或味道的方法; 食品,口香糖,咀嚼烟草,药用产品和牙膏; 并通过向其中加入香烟或味道来增加或增加如此生产的醚甲醇,从而吸烟烟草和烟草制品。 还描述了具有以下结构之一的两个醚甲醛:< IMAGE>和< IMAGE>用于通过使羰基合成的烯丙基醚与一氧化碳和氢的混合物通过氧代 - 以及用于增强或增强消耗材料(包括香水,古龙水和香水制品)的香味或味道的方法; 食品,口香糖,咀嚼烟草,药用产品和牙膏; 通过向其中加入香味或味道增加或增加如此制备的醚甲醛的量来吸烟烟草和烟草制品。
    • 73. 发明授权
    • Organoleptic uses of tertiary hydroxyl carboxaldehydes
    • 感官使用叔羟基羧醛
    • US4617144A
    • 1986-10-14
    • US768807
    • 1985-08-23
    • Futoshi FujiokaRichard M. BodenWilliam L. Schreiber
    • Futoshi FujiokaRichard M. BodenWilliam L. Schreiber
    • C07C45/49C07C47/27C07C47/36C11B9/00A61K7/46
    • C11B9/0061C07C45/49C07C47/27C07C47/36
    • Described are tertiary hydroxyl carboxaldehydes defined according to the generic structure: ##STR1## wherein the lines ##STR2## represent covalent carbon-carbon bonds when m does not=0; and wherein the lines ##STR3## do not represent any bonds when m=0; wherein R represents hydrogen or methyl; wherein p and q each represents 0 or 1 with the proviso that p=1 when q=0 and p=0 when q=1; wherein X and Z each represent one or more carbon atoms required to complete a bicyclo ring with the lines ##STR4## representing carbon-carbon bonds; wherein X and Z complete a phenyl moiety when the line ##STR5## represents no bond; wherein X and Z complete a cycloalkyl ring moiety with the lines ##STR6## represent carbon-carbon bonds and with the line ##STR7## representing no bond; and wherein when m is 0, X represents an alkylene moiety, processes for preparing same by means of reacting carbon monoxide and hydrogen with an unsaturated tertiary alcohol defined according to the structure: ##STR8## by means of an oxo reaction, and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles (e.g., cosmetic powders, perfumed polymers solid or liquid anionic, cationic, noninic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations, face creams, and the like).
    • 描述的是根据通用结构定义的叔羟基甲醛:其中当m不为0时,线* * * * *和 - - - - - 和/或+ + + + +代表共价碳 - 碳键 ; 并且当m = 0时,线+ + + + + * * * * *和 - - - - - 不表示任何键; 其中R表示氢或甲基; 其中p和q各自表示0或1,条件是当q = 0时p = 1,q = 1时p = 0; 其中X和Z各自表示一个或多个完成具有代表碳 - 碳键的线+ + + + + * * * * *和 - - - - 的双环的所需的碳原子。 当线 - - - - 表示无键时,X和Z完全为苯基部分; 其中X和Z完全是环烷基环部分,其中线* * * *和+ + + +代表碳 - 碳键,并且线 - - - - - 不表示键; 并且其中当m为0时,X表示亚烷基部分,通过使一氧化碳和氢与根据以下结构定义的不饱和叔醇反应制备其方法:通过氧代反应,其用途在 增加或增强香水组合物,古龙水和香水制品(例如,化妆品粉末,加香聚合物固体或液体阴离子,阳离子,无定形或两性离子洗涤剂,织物柔软剂组合物,织物柔软剂制品,头发制剂,面霜等)的香气 )。
    • 74. 发明授权
    • Preparing tertiary hydroxyl carboxaldehyde containing perfume
compositions
    • 制备含羟基甲醛的香料组合物
    • US4608196A
    • 1986-08-26
    • US768840
    • 1985-08-23
    • Futoshi FujiokaRichard M. BodenWilliam L. Schreiber
    • Futoshi FujiokaRichard M. BodenWilliam L. Schreiber
    • C07C45/49C07C47/27C07C47/36C11B9/00A61K7/46
    • C11B9/0061C07C45/49C07C47/27C07C47/36
    • Described are tertiary hydroxyl carboxaldehydes defined according to the generic structure: ##STR1## wherein the lines ##STR2## represent covalent carbon-carbon bonds when m does not=0; and wherein the lines ##STR3## do not represent any bonds when m=0; wherein R represents hydrogen or methyl; wherein p and q each represents 0 or 1 with the proviso that p=1 when q=0 and p=0 when q=1; wherein X and Z each represent one or more carbon atoms required to complete a bicyclo ring with the lines ##STR4## representing carbon-carbon bonds; wherein X and Z complete a phenyl moiety when the line ##STR5## represents no bond; wherein X and Z complete a cycloalkyl ring moiety with the lines ##STR6## represent carbon-carbon bonds and with the line ##STR7## representing no bond; and wherein when m is 0, X represents an alkylene moiety, processes for preparing same by means of reacting carbon monoxide and hydrogen with an unsaturated tertiary alcohol defined according to the structure: ##STR8## by means of an oxo reaction, and uses thereof in augmenting or enhancing the aroma of perfume compositions, colognes and perfumed articles (e.g., cosmetic powders, perfumed polymers solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, hair preparations, face creams, and the like).
    • 描述的是根据通用结构定义的叔羟基甲醛:其中当m不为0时,线* * * * *和 - - - - - 和/或+ + + + +代表共价碳 - 碳键 ; 并且当m = 0时,线+ + + + + * * * * *和 - - - - - 不表示任何键; 其中R表示氢或甲基; 其中p和q各自表示0或1,条件是当q = 0时p = 1,q = 1时p = 0; 其中X和Z各自表示一个或多个完成具有代表碳 - 碳键的线+ + + + + * * * * *和 - - - - 的双环的所需的碳原子。 当线 - - - - 表示无键时,X和Z完全为苯基部分; 其中X和Z完全是环烷基环部分,其中线* * * *和+ + + +代表碳 - 碳键,并且线 - - - - - 不表示键; 并且其中当m为0时,X表示亚烷基部分,通过使一氧化碳和氢与根据以下结构定义的不饱和叔醇反应制备其方法:通过氧代反应,其用途在 增加或增强香水组合物,古龙水和香水制品(例如,化妆品粉末,加香聚合物固体或液体阴离子,阳离子,无定形或两性离子洗涤剂,织物柔软剂组合物,织物柔软剂制品,头发制剂,面霜等)的香气 )。
    • 76. 发明授权
    • 4(p-Cumenyloxy)-3-methyl-1-butanol
    • 4(对 - 间甲氧基)-3-甲基-1-丁醇
    • US4556746A
    • 1985-12-03
    • US709915
    • 1985-03-08
    • Futoshi FujiokaRichard M. BodenWilliam L. Schreiber
    • Futoshi FujiokaRichard M. BodenWilliam L. Schreiber
    • A24B15/34C07C43/178C07C43/196C07C43/23C07C45/49C07C47/198C07C47/277C11B9/00C07C43/205
    • C11B9/0046A24B15/345C07C43/178C07C43/196C07C43/23C07C45/49C07C47/198C07C47/277
    • Described are ether carbinols defined according to the generic structure: ##STR1## wherein X.sub.1 represents a moiety selected from the group consisting of: ##STR2## and wherein Y.sub.1 represents C.sub.4 or C.sub.5 alkylene; C.sub.4 or C.sub.5 alkenylene or C.sub.4 or C.sub.5 alkynylene; processes for preparing such ether carbinols by means of first reacting allyl ethers with a mixture of carbon monoxide and hydrogen by means of an oxo reaction to produce ether carboxaldehydes and then reducing the thus formed ether carboxaldehydes to ether carbinols; or reacting camphene with appropriate diols; as well as methods for augmenting or enhancing the aroma or taste of consumable materials including perfumes, colognes and perfumed articles; foodstuffs, chewing gums, chewing tobaccos, medicinal products and toothpastes; and smoking tobaccos and smoking tobacco articles by adding thereto an aroma or taste augmenting or enhancing quantity of the thus produced ether carbinols.Also described are two ether carboxaldehydes having one of the structures: ##STR3## processes for preparing such ether carboxaldehydes by means of reacting out an appropriate allyl ether with a mixture of carbon monoxide and hydrogen by means of an oxo-reaction as well as methods for augmenting or enhancing the aroma or taste of consumable materials including perfumes, colognes and perfumed articles; foodstuffs, chewing gums, chewing tobaccos, medicinal products and toothpastes; smoking tobaccos and smoking tobacco articles by adding thereto an aroma or taste augmenting or enhancing quantity of the thus produced ether carboxaldehydes.
    • 描述了根据通用结构定义的醚甲醇:其中X 1表示选自以下的部分:其中Y 1表示C 4或C 5亚烷基; C4或C5亚链烯基或C4或C5亚炔基; 通过首先使烯丙基醚与一氧化碳和氢气的混合物通过氧代反应反应制备这种醚甲醇的方法,以产生醚甲醛,然后将由此形成的醚甲醛还原成醚甲醇; 或使camp烯与适当的二醇反应; 以及用于增强或增强消耗材料(包括香水,古龙水和香水制品)的香味或味道的方法; 食品,口香糖,咀嚼烟草,药用产品和牙膏; 并通过向其中加入香烟或味道来增加或增加如此生产的醚甲醇,从而吸烟烟草和烟草制品。 还描述了具有以下结构之一的两个醚甲醛:< IMAGE>和< IMAGE>用于通过使羰基合成的烯丙基醚与一氧化碳和氢的混合物通过氧代 - 以及用于增强或增强消耗材料(包括香水,古龙水和香水制品)的香味或味道的方法; 食品,口香糖,咀嚼烟草,药用产品和牙膏; 通过向其中加入香味或味道增加或增加如此制备的醚甲醛的量来吸烟烟草和烟草制品。
    • 78. 发明授权
    • Ether carboxaldehydes
    • US4532364A
    • 1985-07-30
    • US533915
    • 1983-09-19
    • Futoshi FujiokaRichard M. BodenWilliam L. Schreiber
    • Futoshi FujiokaRichard M. BodenWilliam L. Schreiber
    • A24B15/34C07C43/178C07C43/196C07C43/23C07C45/49C07C47/198C07C47/277C11B9/00C07C45/50C07C47/225
    • C11B9/0046A24B15/345C07C43/178C07C43/196C07C43/23C07C45/49C07C47/198C07C47/277Y10S514/974
    • Described are ether carboxaldehydes defined according to the generic structure: ##STR1## wherein X represents aryl, alkaryl, hydroxyalkyl, alkenyl, cycloalkenyl, lower alkyl or bicycloalkyl; wherein Y represents C.sub.1 -C.sub.3 lower alkylene; wherein Z completes an alkyl substituted C.sub.6 cycloalkyl ring or represents no moiety; wherein R represents hydrogen or methyl; wherein m represents 0 or 1; wherein n represents 0 or 1; wherein p represents 0 or 1 and wherein q represents 0 or 1 with the provisos that when m is 1, Z completes the alkyl substituted or unsubstituted C.sub.6 cycloalkyl ring; that p is 1 when q is 0; and that when p is 0, q is 1, processes for producing same by reacting allyl ethers defined according to the structure: ##STR2## wherein x, y, z, m, n and r are as defined above with a mixture of carbon monoxide and hydrogen by means of an oxo reaction products produced according to said oxo reaction which are mixtures which contain the above-mentioned ether carboxaldehydes as well as methods for augmenting or enhancing the aroma or taste of consumable materials, including perfumes, colognes and perfumed articles; foodstuffs, chewing gums, chewing tobaccos, medicinal products and toothpastes; and smoking tobaccos and smoking tobacco articles by adding thereto aroma or taste augmenting or enhancing quantities of the thus produced ether carboxaldehydes or ether carboxaldehyde-containing mixtures.Also described are perfume compositions, colognes, perfumed articles (including solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, drier-added fabric softener articles, hair preparations, deodorant compositions, bleaching compositions and perfumed polymers), foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos and smoking tobacco articles containing the products thus produced.