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71. 发明授权

US06921475B2 Open circuit potential amperometry and voltammetry 失效
标题翻译：开路电位电流分析法和伏安法
公开(公告)号：US06921475B2
公开(公告)日：2005-07-26
申请号：US10098996
申请日：2002-03-14
申请人： Werner Kuhr , David Bocian , Jonathan S. Lindsey , Kristian A. Roth
发明人： Werner Kuhr , David Bocian , Jonathan S. Lindsey , Kristian A. Roth
IPC分类号： G01N27/416 , G01N27/49
CPC分类号： B82Y30/00 , B82Y10/00 , G01N27/3277
摘要： This invention provides approaches to improve the signal to noise ratio (S/N) in electrochemical measurements (e.g. amperometry, voltammetry, etc.). In particular, a method is described wherein the faradaic current is temporally dissociated from the charging current associated with reading the charge of a redox-active species (e.g. a self-assembled monolayer (SAM)). This method, designated herein as open circuit potential amperometry (OCPA), quantitatively reads the charge of the redox species bound to (electrically coupled to) an electrode surface, while discriminating against both charging current(s) and amperometric signal(s) that arise, e.g. from diffusion-based species in solution.
摘要翻译：本发明提供了改善电化学测量（例如电流分析法，伏安法等）中的信噪比（S / N）的方法。特别地，描述了一种方法，其中法拉第电流与读取氧化还原活性物质（例如自组装单层（SAM））的电荷相关的充电电流暂时解离。该方法在本文中指定为开路电位电流分析法（OCPA），定量地读取结合到（电耦合到）电极表面的氧化还原物质的电荷，同时区分出现的充电电流和电流测量信号，例如从溶液中的基于扩散的物种。

72. 发明授权

US06728129B2 Multistate triple-decker dyads in three distinct architectures for information storage applications 失效
标题翻译：用于信息存储应用的三种不同架构中的多层三层二层
公开(公告)号：US06728129B2
公开(公告)日：2004-04-27
申请号：US10079938
申请日：2002-02-19
申请人： Jonathan S. Lindsey , David F. Bocian , Karl-Heinz Schweikart , Werner G. Kuhr
发明人： Jonathan S. Lindsey , David F. Bocian , Karl-Heinz Schweikart , Werner G. Kuhr
IPC分类号： G11C1100
CPC分类号： G11C13/0014 , B82Y10/00 , G11B9/14 , G11B9/149 , G11C11/34 , G11C11/5664 , G11C13/0009 , G11C13/025 , G11C2213/77
摘要： This invention provides novel high density memory devices that are electrically addressable permitting effective reading and writing, that provide a high memory density (e.g., 1015 bits/cm3), that provide a high degree of fault tolerance, and that are amenable to efficient chemical synthesis and chip fabrication. The devices are intrinsically latchable, defect tolerant, and support destructive or non-destructive read cycles. In a preferred embodiment, the device comprises a fixed electrode electrically coupled to a storage medium having a multiplicity of different and distinguishable oxidation states wherein data is stored in said oxidation states by the addition or withdrawal of one or more electrons from said storage medium via the electrically coupled electrode. The storage medium typically comprises a storage molecule that is a triple-decker sandwich heterodimer. Such dimers can provide 8 or more oxidation states and permit the storage of at least 3 bits per molecule.
摘要翻译：本发明提供了可提供高存储密度（例如，10,15bit / cm 3）的电位置可允许有效读/写的新型高密度存储器件，其提供高度的容错能力，并且适合有效的化学合成和芯片制造。器件本质上可锁定，缺陷容忍，并支持破坏性或非破坏性的读取周期。在优选实施例中，该器件包括电耦合到存储介质的固定电极，该存储介质具有多种不同且可区分的氧化态，其中通过经由该存储介质从所述存储介质中添加或撤出一个或多个电子而将数据存储在所述氧化态中电耦合电极。存储介质通常包含作为三层三明治夹心异二聚体的储存分子。这种二聚体可以提供8个或更多个氧化态，并允许每分子存储至少3位。

73. 发明授权

US06674121B2 Method and system for molecular charge storage field effect transistor 失效
标题翻译：分子电荷存储场效应晶体管的方法和系统
公开(公告)号：US06674121B2
公开(公告)日：2004-01-06
申请号：US10017999
申请日：2001-12-14
申请人： Veena Misra , David F. Bocian , Werner G. Kuhr , Jonathan S. Lindsey
发明人： Veena Misra , David F. Bocian , Werner G. Kuhr , Jonathan S. Lindsey
IPC分类号： H01L29792
CPC分类号： H01L27/283 , B82Y10/00 , G11C11/5664 , G11C13/0009 , G11C13/0014 , G11C13/0016 , G11C2213/53 , H01L51/052 , H01L51/0529 , Y10S977/721 , Y10S977/887 , Y10S977/937
摘要： A method and/or system and/or apparatus for a molecular-based FET device (an m-FET) uses charge storing molecules between a gate and channel of an FET-type transistor. Further embodiments describe fabrication methods for using combinations of standard practices in lithography and synthetic chemistry and novel elements.
摘要翻译：用于基于分子的FET器件（m-FET）的方法和/或系统和/或设备在FET型晶体管的栅极和沟道之间使用电荷存储分子。另外的实施例描述了使用光刻和合成化学中的标准实践的组合以及新颖元件的制造方法。

74. 发明授权

US06603070B2 Convergent synthesis of multiporphyrin light-harvesting rods 失效
标题翻译：多卟啉光收获杆的收敛合成
公开(公告)号：US06603070B2
公开(公告)日：2003-08-05
申请号：US09939010
申请日：2001-08-24
申请人： Jonathan S. Lindsey , Robert S. Loewe
发明人： Jonathan S. Lindsey , Robert S. Loewe
IPC分类号： H01L310248
CPC分类号： C09K11/06 , B82Y10/00 , C07D487/22 , C09B47/00 , C09B69/109 , C09K2211/1029 , C09K2211/1074 , C09K2211/186 , C09K2211/188 , H01G9/2059 , H01G9/209 , H01L51/0034 , H01L51/0035 , H01L51/0077 , H01L51/0078 , H01L51/009 , H01L51/0093 , H01L51/0595 , H01L51/4206 , Y02E10/542 , Y02E10/549 , Y02P70/521 , Y02T10/7022
摘要： The present invention provides a convergent method for the synthesis of light harvesting rods. The rods are oligomers of the formula A1(Ab+1)b, wherein b is at least 1, A1 through Ab+1 are covalently coupled rod segments, and each rod segment A1 through A1+b comprises a compound of the formula X1(Xm+1)m wherein m is at least 1 and X1 through Xm+1 are covalently coupled porphyrinic macrocycles. Light harvesting arrays and solar cells containing such light harvesting rods are also described, along with intermediates useful in such methods and rods produced by such methods.
摘要翻译：本发明提供了一种用于合成光收集杆的收敛方法。棒是式A1（Ab + 1）b的低聚物，其中b至少为1，Al至Ab + 1为共价键，每个棒段A1至A1 + b包含式X1化合物 Xm + 1）m，其中m为至少1，X1至Xm + 1为共价偶联的卟啉大环。还描述了含有这种光收获杆的光收集阵列和太阳能电池，以及可用于通过这种方法制备的这种方法和棒中的中间体。

75. 发明申请

US20140154186A1 BACTERIOCHLORIN IMIDES 有权
公开(公告)号：US20140154186A1
公开(公告)日：2014-06-05
申请号：US14117212
申请日：2012-05-30
申请人： Jonathan S. Lindsey , Michael Krayer
发明人： Jonathan S. Lindsey , Michael Krayer
IPC分类号： C09B47/00 , A61K41/00 , G01N33/58 , A61K49/00
CPC分类号： C07D487/22 , A61K41/0071 , A61K49/0036 , A61N5/062 , C09B47/00 , G01N15/1404 , G01N33/582
摘要： Compound of Formula I: are described, along with compositions containing the same and methods of use thereof.
摘要翻译：描述了式I化合物，以及含有其的组合物及其使用方法。

76. 发明授权

US08529996B2 High-temperature attachment of organic molecules to substrates 失效
标题翻译：将有机分子高温附着于底物
公开(公告)号：US08529996B2
公开(公告)日：2013-09-10
申请号：US11688194
申请日：2007-03-19
申请人： David F. Bocian , Jonathan S. Lindsey , Zhiming Liu , Amir A. Yasseri , Veena Misra , Qian Zhao , Qiliang Li , Shyam Surthi , Robert S. Loewe
发明人： David F. Bocian , Jonathan S. Lindsey , Zhiming Liu , Amir A. Yasseri , Veena Misra , Qian Zhao , Qiliang Li , Shyam Surthi , Robert S. Loewe
IPC分类号： C23C16/00
CPC分类号： H01L51/0002 , B82Y10/00 , G11B9/14 , G11B9/149 , G11C13/0014 , G11C13/0016 , H01L51/0008 , H01L51/001 , H01L51/0026 , H01L51/0075 , H01L51/0077 , H01L51/0595 , H01L51/4213 , H01M4/60 , H01M14/005 , Y02E10/549
摘要： This invention provides a new procedure for attaching molecules to semiconductor surfaces, in particular silicon. The molecules, which include, but are not limited to porphyrins and ferrocenes, have been previously shown to be attractive candidates for molecular-based information storage. The new attachment procedure is simple, can be completed in short times, requires minimal amounts of material, is compatible with diverse molecular functional groups, and in some instances affords unprecedented attachment motifs. These features greatly enhance the integration of the molecular materials into the processing steps that are needed to create hybrid molecular/semiconductor information storage devices.
摘要翻译：本发明提供了一种将分子连接到半导体表面，特别是硅的新方法。以前已经显示出包括但不限于卟啉和二茂铁的分子是用于基于分子的信息存储的有吸引力的候选物。新的附件程序简单，可以在短时间内完成，需要最少量的材料，与不同的分子官能团相容，并在某些情况下提供前所未有的附着图案。这些特征大大增强了分子材料与创建混合分子/半导体信息存储设备所需的处理步骤的集成。

77. 发明授权

US08445695B2 Synthesis of phosphono-substituted porphyrin compounds for attachment to metal oxide surfaces 失效
公开(公告)号：US08445695B2
公开(公告)日：2013-05-21
申请号：US13597815
申请日：2012-08-29
申请人： Jonathan S. Lindsey , Robert S. Loewe , Kannan Muthukumaran , Arounaguiry Ambroise
发明人： Jonathan S. Lindsey , Robert S. Loewe , Kannan Muthukumaran , Arounaguiry Ambroise
IPC分类号： C07D207/00 , C07F9/02
CPC分类号： H01L51/0077 , C07F9/6524 , H01G9/2031 , H01L51/4226 , Y02E10/542 , Y02P70/521
摘要： A method of making a phosphono-substituted dipyrromethane comprises reacting an aldehyde or acetal having at least one phosphono group substituted thereon with pyrrole to produce a phosphono-substituted dipyrromethane; and wherein the phosphono is selected from the group consisting of dialkyl phosphono, diaryl phosphono, and dialkylaryl phosphono. Additional methods, intermediates and products are also described.

78. 发明授权

US08304561B2 Synthetic route to ABCD-porphyrins 失效
公开(公告)号：US08304561B2
公开(公告)日：2012-11-06
申请号：US13456482
申请日：2012-04-26
申请人： Jonathan S. Lindsey , Dilek Dogutan Kiper
发明人： Jonathan S. Lindsey , Dilek Dogutan Kiper
IPC分类号： C07D207/333 , C07D207/36
CPC分类号： C07D487/22 , C07D207/34 , C07D207/36 , Y02P20/55
摘要： A method of making a metalloporphyrin is carried out by reacting (i) a linear tetrapyrrole, said linear tetrapyrrole having a 19-acyl group and a 1-protecting group, with (ii) a metal salt under basic conditions to produce the metalloporphyrin. Products produced by such methods and intermediates useful for carrying out such methods are also described.

79. 发明申请

US20120245508A1 SYNTHESIS OF CHLORINS AND PHORBINES WITH ENHANCED RED SPECTRAL FEATURES 审中-公开
标题翻译：具有增强的红色光谱特征的氯离子和磷酸盐的合成
公开(公告)号：US20120245508A1
公开(公告)日：2012-09-27
申请号：US13480796
申请日：2012-05-25
申请人： Jonathan S. Lindsey , Joydev K. Laha , Muthiah Chinnasamy , K. Eszter Borbas
发明人： Jonathan S. Lindsey , Joydev K. Laha , Muthiah Chinnasamy , K. Eszter Borbas
IPC分类号： C07D487/22 , A61M37/00 , A61K31/409
CPC分类号： C07D487/22
摘要： The present invention provides compounds of the general Formula DI: along with methods of making such compounds, formulations containing the same, and methods of using the same (e.g., in photodynamic therapy, for the production of solar cells, etc.).
摘要翻译：本发明提供了通式DI的化合物，以及制备此类化合物的方法，含有该化合物的制剂及其使用方法（例如，在光动力疗法中，用于生产太阳能电池等）。

80. 发明授权

US08212023B2 Methods and intermediates for the synthesis of porphyrins 失效
标题翻译：合成卟啉的方法和中间体
公开(公告)号：US08212023B2
公开(公告)日：2012-07-03
申请号：US13014914
申请日：2011-01-27
申请人： Jonathan S. Lindsey , Masahiko Taniguchi , Dazhong Fan
发明人： Jonathan S. Lindsey , Masahiko Taniguchi , Dazhong Fan
IPC分类号： C07D487/22 , C07B47/00
CPC分类号： C07D403/04 , C07D487/22
摘要： A method of making a porphyrin is carried out by: (a) condensing (i) a 1,9-bis(N,N-)dialkylaminomethyl)dipyrromethane of Formula II: with (ii) a dipyrromethane to produce a reaction product; then (b) oxidizing the reaction product; and then (c) optionally demetallating said reaction product to produce the porphyrin. The reaction is particularly useful for making substituted porphyrins with a wide range of substituents at the A and/or B (the 5 and/or 15) positions.
摘要翻译：通过以下方法进行卟啉的制备方法：（a）将（ⅰ）式Ⅱ的1,9-双（N，N-）二烷基氨基甲基）二吡咯烷与（ⅱ）二吡咯甲烷缩合生成反应产物; 然后（b）氧化反应产物; 然后（c）任选地使所述反应产物脱金属以产生卟啉。该反应对于在A和/或B（5和/或15）位置制备具有宽范围取代基的取代卟啉是特别有用的。

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