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71. 发明授权

US5512831A Method and apparatus for testing electrochemical energy conversion devices 失效
标题翻译：用于测试电化学能量转换装置的方法和装置
公开(公告)号：US5512831A
公开(公告)日：1996-04-30
申请号：US344285
申请日：1994-11-23
申请人： Alan J. Cisar , Oliver J. Murphy
发明人： Alan J. Cisar , Oliver J. Murphy
IPC分类号： B01F3/02 , B01J8/00 , B01J19/24 , C02F1/78 , G01R1/20 , G01R31/36 , G01N27/403 , G01R19/00
CPC分类号： B01J8/009 , B01F3/022 , B01J19/2475 , G01R1/203 , G01R31/36 , B01J2219/00058 , B01J2219/00067 , B01J2219/00069 , B01J2219/00135 , B01J2219/00162 , B01J2219/00184 , C02F1/78 , H01M2300/0082
摘要： A system for testing electrochemical energy conversion and storage devices includes means for sensing the current from the storage device and varying the load across the storage device in response to the current sensed. The system is equally adaptable to batteries and fuel cells. Means is also provided to sense system parameters from a plurality of locations within the system. Certain parameters are then stored in digital form for archive purposes and certain other parameters are used to develop control signals in a host processor.
摘要翻译：用于测试电化学能量转换和存储装置的系统包括用于感测来自存储装置的电流并响应于感测的电流改变存储装置两端的负载的装置。该系统同样适用于电池和燃料电池。还提供了用于从系统内的多个位置感测系统参数的装置。然后以数字形式存储某些参数用于存档目的，并且使用某些其他参数来在主机处理器中开发控制信号。

72. 发明申请

US20100021778A1 FUEL CELL EMERGENCY POWER SYSTEM 审中-公开
标题翻译：燃料电池紧急动力系统
公开(公告)号：US20100021778A1
公开(公告)日：2010-01-28
申请号：US12490486
申请日：2009-06-24
申请人： Jeremy D. Steinshnider , Mark J. Flushe , Oliver J. Murphy
发明人： Jeremy D. Steinshnider , Mark J. Flushe , Oliver J. Murphy
IPC分类号： H01M8/00 , H01M2/02 , H01M8/18 , H01M8/04 , B01D19/00 , B01D21/30
CPC分类号： H01M8/04753 , B01D19/0042 , B01D19/0063 , C25B1/04 , H01M8/04089 , H01M8/04164 , H01M8/045 , H01M8/04619 , H01M8/186 , Y02E60/366 , Y02E60/528
摘要： Fuel cell emergency power systems comprising a fuel cell having an anode and a cathode, a power distribution unit for selectively directing electrical current from the fuel cell to one or more consuming device, a hydrogen gas control system and an oxygen gas control system. The hydrogen gas control system includes a pressurized hydrogen tank providing hydrogen gas in selective fluid communication to the anode, a hydrogen gas-liquid water phase separator in downstream fluid communication with the anode, and a hydrogen recirculation pump for recirculating substantially liquid water-free hydrogen from the hydrogen gas-liquid water phase separator to the anode. Similarly, the oxygen gas control system includes a pressurized oxygen tank providing oxygen gas in selective fluid communication to the anode, an oxygen gas-liquid water phase separator in downstream fluid communication with the anode, and an oxygen recirculation pump for recirculating substantially liquid water-free oxygen from the oxygen gas-liquid water phase separator to the anode.
摘要翻译：包括具有阳极和阴极的燃料电池的燃料电池应急电力系统，用于选择性地将来自燃料电池的电流引导到一个或多个消耗装置的配电单元，氢气控制系统和氧气控制系统。氢气控制系统包括一个加压氢罐，提供与阳极选择性流体连通的氢气，与阳极下游流体连通的氢气 - 液态水相分离器，以及用于再循环基本上液态无水氢从氢气 - 液态水相分离器到阳极。类似地，氧气控制系统包括提供与阳极选择性流体连通的氧气的加压氧气罐，与阳极下游流体连通的氧气 - 液体水相分离器和用于再循环基本上液体的水 - 游离氧从氧气 - 液态水相分离器到阳极。

73. 发明授权

US06881308B2 Electrochemical synthesis of ammonia 失效
标题翻译：电化学合成氨
公开(公告)号：US06881308B2
公开(公告)日：2005-04-19
申请号：US10090444
申请日：2002-03-04
申请人： Adrian J. Denvir , Oliver J. Murphy , Alan J. Cisar , Priscilla Robertson , Kyle Uselton
发明人： Adrian J. Denvir , Oliver J. Murphy , Alan J. Cisar , Priscilla Robertson , Kyle Uselton
IPC分类号： C25B1/00 , C25B9/06 , C25B3/02 , C25B9/18
CPC分类号： C25B1/00
摘要： A method for electrochemical synthesis of ammonia gas comprising providing an electrolyte between an anode and a cathode, providing hydrogen gas to the anode, oxidizing negatively charged nitrogen-containing species present in the electrolyte at the anode to form an adsorbed nitrogen species, and reacting the hydrogen with the adsorbed nitrogen species to form ammonia. Preferably, the hydrogen gas is provided to the anode by passing the hydrogen gas through a porous anode substrate. It is also preferred to produce the negatively charged nitrogen-containing species in the electrolyte by reducing nitrogen gas at the cathode. However, the negatively charged nitrogen-containing species may also be provided by supplying a nitrogen-containing salt, such as lithium nitride, into the molten salt electrolyte mixture in a sufficient amount to provide some or all of the nitrogen consumed in the production of ammonia.
摘要翻译：一种用于电化学合成氨气的方法，包括在阳极和阴极之间提供电解质，向阳极提供氢气，在阳极处氧化存在于电解质中的带负电荷的含氮物质以形成吸附的氮物质，并使氢与吸附的氮物质形成氨。优选地，通过使氢气通过多孔阳极基板而将氢气提供给阳极。还优选通过还原阴极处的氮气来在电解质中产生带负电的含氮物质。然而，带负电的含氮物质也可以通过向熔融盐电解质混合物中提供足够量的含氮盐（例如氮化钠）来提供在氨生产中消耗的一部分或全部氮。

74. 发明授权

US06827811B2 Method for vacuum pressing electrochemical cell components 失效
标题翻译：真空电化学电池组件的方法
公开(公告)号：US06827811B2
公开(公告)日：2004-12-07
申请号：US10072303
申请日：2002-02-07
申请人： Craig C. Andrews , Oliver J. Murphy
发明人： Craig C. Andrews , Oliver J. Murphy
IPC分类号： B29C6548
CPC分类号： B29C65/542 , B29C65/482 , B29C65/483 , B29C65/544 , B29C65/546 , B29C65/548 , B29C66/004 , B29C66/1122 , B29C66/133 , B29C66/433 , B29C66/54 , B29C66/71 , B29C66/81455 , B29C66/82423 , B29C66/8322 , B29C66/83413 , H01M8/0258 , H01M8/0271 , H01M8/0297 , Y10T29/4911 , Y10T29/49114 , Y10T428/13 , B29C65/00 , B29K2077/00 , B29K2023/06
摘要： Assembling electrochemical cell components using a bonding agent comprising aligning components of the electrochemical cell, applying a bonding agent between the components to bond the components together, placing the components within a container that is essentially a pliable bag, and drawing a vacuum within the bag, wherein the bag conforms to the shape of the components from the pressure outside the bag, thereby holding the components securely in place. The vacuum is passively maintained until the adhesive has cured and the components are securely bonded. The bonding agent used to bond the components of the electrochemical cell may be distributed to the bonding surface from distribution channels in the components. To prevent contamination with bonding agent, some areas may be treated to produce regions of preferred adhesive distribution and protected regions. Treatments may include polishing, etching, coating and providing protective grooves between the bonding surfaces and the protected regions.
摘要翻译：使用粘合剂组装电化学电池组件，包括对准电化学电池的组分，在组分之间施加粘合剂以将组分粘合在一起，将组分置于基本上是柔软袋的容器内，并在袋内抽真空，其中所述袋从所述袋外部的压力符合所述部件的形状，从而将所述部件牢固地保持在适当的位置。真空被动地保持，直到粘合剂固化并且组分牢固地粘合。用于结合电化学电池组件的粘合剂可以从部件中的分配通道分配到粘合表面。为了防止粘结剂的污染，可以处理一些区域以产生优选的粘合剂分布区域和保护区域。处理可以包括抛光，蚀刻，涂覆和在粘合表面和受保护区域之间提供保护槽。

75. 发明授权

US06698389B2 Electrolyzer for internal combustion engine 失效
标题翻译：内燃机电解液
公开(公告)号：US06698389B2
公开(公告)日：2004-03-02
申请号：US10134029
申请日：2002-04-26
申请人： Craig C. Andrews , Oliver J. Murphy
发明人： Craig C. Andrews , Oliver J. Murphy
IPC分类号： F01P106
CPC分类号： B01D53/9454 , B60H1/00271 , B60H1/18 , B60H1/2203 , C25B1/10 , C25B9/20 , F01N3/2006 , F01N3/206 , F01N3/2889 , F01N3/32 , F01N3/34 , F01N5/02 , F01N2240/02 , F01N2610/04 , F01N2610/08 , F01P2060/00 , F01P2060/18 , F02B43/10 , F02B2043/106 , Y02A50/2324 , Y02A50/2325 , Y02E60/366 , Y02T10/16 , Y02T10/22 , Y02T10/24 , Y02T10/26 , Y02T10/32 , Y10S123/12
摘要： The present invention provides a method and apparatus for chemically heating one or more components of, or intake air flowing to, an internal combustion engine by feeding hydrogen to a catalyst. In accordance with the invention, condensation of fuels on cold engine cylinder walls during and after cold start-ups is prevented, thereby reducing wear on the engine. The invention also provides a method and apparatus for reducing pollutants commonly occurring during cold start-up of combustion engines by heating components of, or intake air flowing to, a combustion engine, in order to quickly warm the engine and its catalytic converter to operating temperatures. Preferably, the hydrogen is supplied from an electrolyzer or other on-board source of hydrogen and the hydrogen and a source of oxygen are provided to the catalyst resulting in exothermic oxidation of hydrogen to heat the air intake or other components of the engine. The invention includes preheating systems for one or more of the air intake, the fuel, the engine oil, the block, the battery and the catalytic converter.
摘要翻译：本发明提供一种用于通过将氢气输送到催化剂来化学加热流入内燃机的一个或多个组分或进气的方法和装置。根据本发明，防止在冷启动期间和之后在冷发动机气缸壁上的燃料冷凝，从而减少发动机的磨损。本发明还提供一种方法和装置，用于通过加热燃烧发动机的内燃部件或进气来减少内燃机的冷启动期间通常发生的污染物，以便将发动机及其催化转化器快速升温至工作温度。优选地，氢气由电解槽或其他板载氢源供应，氢气和氧气源被提供给催化剂，导致氢的放热氧化以加热进气口或发动机的其它部件。本发明包括用于进气，燃料，发动机油，块，电池和催化转化器中的一个或多个的预热系统。

76. 发明授权

US06602631B1 Bonding electrochemical cell components 失效
公开(公告)号：US06602631B1
公开(公告)日：2003-08-05
申请号：US09237428
申请日：1999-01-26
申请人： Alan J. Cisar , Oliver J. Murphy , Eric T. Clarke
发明人： Alan J. Cisar , Oliver J. Murphy , Eric T. Clarke
IPC分类号： H01M200
CPC分类号： H01M8/0206 , H01M8/0223 , H01M8/0228 , H01M8/023 , H01M8/0263 , H01M8/0267 , H01M8/0273 , H01M8/028 , H01M8/2404 , H01M8/242 , H01M8/2483 , Y10T29/49114 , Y10T29/49115
摘要： The invention provides a method for preparing subassemblies for an electrochemical cell or a stack of electrochemical cells, particularly a stack of fuel cells for the direct generation of electricity. The method includes bonding together two or more electrochemical cell components, such as plates, frames, flow fields, shims, gaskets, membranes and the like, to form subassemblies used to make an electrochemical cell stack. The bonding can be accomplished using either polymeric bonds (i.e., adhesives) where polymer and/or metal components are involved or metallurgical bonds (i.e., solder) where metal components are involved. The bonding provides tightly sealed cells and lower electronic contact resistances between components.

77. 发明授权

US06458257B1 Microorganism control of point-of-use potable water sources 失效
标题翻译：使用点饮用水源的微生物控制
公开(公告)号：US06458257B1
公开(公告)日：2002-10-01
申请号：US09247767
申请日：1999-02-09
申请人： Craig C. Andrews , Oliver J. Murphy , G. Duncan Hitchens
发明人： Craig C. Andrews , Oliver J. Murphy , G. Duncan Hitchens
IPC分类号： C02F1461
CPC分类号： C02F1/78 , C02F1/283 , C02F1/44 , C02F1/4672 , C02F2001/46142 , C02F2201/46155 , C02F2201/782 , C02F2303/04 , C02F2303/18 , C25B1/13 , C25B9/08 , Y02W10/37
摘要： The present invention provides for the electrochemical generation of ozone for use in “point-of-use” applications. The electrochemical ozone generators or systems of the present invention may be used to provide disinfected water, ozone-containing water, and/or ozone gas. Disinfected water may be produced by introducing ozone gas into a potable or purified water source for the purpose of disinfecting or controlling the microorganisms in the water source. Ozonated water or ozone gas may be produced and provided for various anti-microbial and cleansing applications of the consumer, such as washing food, clothing, dishes, countertops, toys, sinks, bathroom surfaces, and the like. Furthermore, the ozone generator may be used to deliver a stream of ozone-containing water for the purpose of commercial or residential point-of-use washing, disinfecting, and sterilizing medical instruments and medical equipment. For example, the ozone-containing water may be used directly or used as a concentrated sterilant for the washing, disinfecting, and sterilizing of medical instruments or equipment. Ozone gas may also be used in many of the foregoing examples, as well as in the deodorization of air or various other applications. The invention allows the electrochemical ozone generator to operate in a nearly or entirely passive manner with simplicity of design.
摘要翻译：本发明提供了用于“使用点”的臭氧的电化学生成。本发明的电化学臭氧发生器或系统可用于提供消毒水，含臭氧的水和/或臭氧气体。可以通过将臭氧气体引入饮用水或净化水源中来消毒或控制水源中的微生物来产生消毒的水。可以生产臭氧水或臭氧气体，并提供消费者的各种抗微生物和清洁应用，例如洗涤食品，衣物，餐具，台面，玩具，水槽，浴室表面等。此外，为了商业或住宅使用点的洗涤，消毒和消毒医疗器械和医疗设备，臭氧发生器可用于输送含臭氧水流。例如，含臭氧水可以直接使用，也可以用作浓缩灭菌剂，用于医疗器械或设备的洗涤，消毒，消毒。臭氧气体也可用于许多前述实施例中，以及在除臭空气或各种其它应用中。本发明允许电化学臭氧发生器以简单的设计以几乎或完全被动的方式操作。

78. 发明授权

US06387230B1 Composite membrane suitable for use in electrochemical devices 失效
标题翻译：复合膜适用于电化学装置
公开(公告)号：US06387230B1
公开(公告)日：2002-05-14
申请号：US09504028
申请日：2000-02-29
申请人： Oliver J. Murphy , Alan J. Cisar
发明人： Oliver J. Murphy , Alan J. Cisar
IPC分类号： C25B1300
CPC分类号： C25B13/04 , C08J5/2275 , C08J2327/18 , H01M8/1023 , H01M8/1027 , H01M8/1037 , H01M8/1039 , H01M8/1044 , H01M8/1048 , H01M8/1067 , Y10T428/249954 , Y10T428/249958 , Y10T428/249964 , Y10T428/31544
摘要： The invention relates to novel inorganic-organic composite membranes especially useful as ionically conducting in electrochemical devices. The composites consist of a polymeric matrix, which may or may not be an ionic conductor in its unfilled form, filled with an inorganic material having a high affinity for water, capable of exchanging cations such as protons, and preferably with a high cation mobility, either on its surface or through its bulk.
摘要翻译：本发明涉及在电化学装置中特别用作离子导电的新型无机 - 有机复合膜。复合材料由聚合物基质组成，其可以是或不是其未填充形式的离子导体，其填充有能够交换阳离子如质子，并且优选具有高阳离子迁移率的对水具有高亲和力的无机材料，无论是在其表面还是通过其体积。

79. 发明授权

US06365026B1 Limited use components for an electrochemical device and method 有权
标题翻译：有限的使用组件用于电化学装置和方法
公开(公告)号：US06365026B1
公开(公告)日：2002-04-02
申请号：US09598067
申请日：2000-06-20
申请人： Craig C. Andrews , Oliver J. Murphy
发明人： Craig C. Andrews , Oliver J. Murphy
IPC分类号： C25D554
CPC分类号： C25B15/00 , C25B1/13 , C25B9/00
摘要： The present invention provides an ozone generating system that combines single-use elements or segments with an extended use fixture that is used to activate the single-use elements. One embodiment of the invention consists of a strip of proton exchange membrane (PEM) having the ozone producing catalyst applied directly onto one side of membrane. Optionally, the application of this catalyst may be divided into segments or patches, wherein each segment represents the limited-use portion of the ozone generator. Each segment may be advanced into a fixture that provides the balance of the electrochemical system required for operation of the ozone generator. This balance of system may include additional subsystems, with a power supply, water source, electrical contacts, electronic controllers, sensors and feedback components, being typical examples. After an individual segment is advanced into the operating fixture, the membrane may be hydrated by a water source and electrical contact made to the positive (anode) face of the membrane having the ozone generating catalyst and to the negative (cathode) side of the membrane which may also include a catalyst layer.
摘要翻译：本发明提供了一种臭氧发生系统，其将一次性元件或部分与用于激活一次性元件的扩展使用固定装置相结合。本发明的一个实施方案由质子交换膜（PEM）组成，其具有直接施加在膜一侧上的产生臭氧的催化剂。任选地，该催化剂的应用可以分成段或片，其中每个段表示臭氧发生器的有限使用部分。每个段可以前进到提供臭氧发生器操作所需的电化学系统的平衡的固定装置。作为典型的例子，系统的这种平衡可以包括具有电源，水源，电触头，电子控制器，传感器和反馈部件的附加子系统。在单独的段进入操作夹具之后，膜可以被水源水合，并且与具有臭氧产生催化剂的膜的正（阳极）面形成并且与膜的负极（阴极）侧形成电接触其还可以包括催化剂层。

80. 发明授权

US06334965B1 Electronically conductive polymers 有权
标题翻译：电子导电聚合物
公开(公告)号：US06334965B1
公开(公告)日：2002-01-01
申请号：US09390194
申请日：1999-09-07
申请人： Waheguru Pal Singh , Dalibor Hodko , Suchitra Chepin , Oliver J. Murphy
发明人： Waheguru Pal Singh , Dalibor Hodko , Suchitra Chepin , Oliver J. Murphy
IPC分类号： H01B100
CPC分类号： H01B1/127 , H01B1/128 , H05K3/424
摘要： The present invention provides a formulation for forming an electronically conducting polymer. The formulation contains an electron acceptor comprising a dopant anion and a metal cation selected from Ag+, Fe3+, Cu2+ or combinations thereof. The preferred electron acceptor is a silver salt, preferably selected from AgNO3, AgClO4 and AgNO2. The formulation also contains between 2 and 100 moles of a polymerizable component per mole of the electron acceptor, the polymerizable component being selected from pyrrole, aniline, their oligomers, or combinations thereof. In addition, the formulation includes an aqueous solvent selected from acetonitrile, acetone, and combinations thereof, the aqueous solvent having up to 30 volume percent water.
摘要翻译：本发明提供了一种用于形成电子导电聚合物的配方。该制剂含有包含掺杂剂阴离子和选自Ag +，Fe 3+，Cu 2+或其组合的金属阳离子的电子受体。优选的电子受体是银盐，优选选自AgNO 3，AgClO 4和AgNO 2。该配方还含有每摩尔电子受体2至100摩尔可聚合组分，可聚合组分选自吡咯，苯胺，其低聚物或其组合。此外，该制剂包括选自乙腈，丙酮及其组合的水性溶剂，所述水性溶剂具有至多30体积％的水。

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