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    • 71. 发明申请
    • Granulator and method of granulation using the same
    • 造粒机及造粒方法使用
    • US20090134536A1
    • 2009-05-28
    • US12290416
    • 2008-10-30
    • Yasuhiko KojimaTakahiro Yanagawa
    • Yasuhiko KojimaTakahiro Yanagawa
    • B29B9/00
    • B01J2/16B01J2/003B01J2/02B01J2/04Y10T428/12181Y10T428/2982Y10T428/2991
    • A granulator, having: a granulation unit having a bottom floor with a perforated plate as its bottom part; an upper air-supplying pipe for supplying a fluidizing air to the bottom floor of the granulation unit; a lower air-supplying pipe; air-spouting pipes, each of which is branched from the lower air-supplying pipe, and has an opening in the bottom floor of the perforated plate, for jetting the air into the granulation unit; and spray nozzles for spraying a granulation raw material liquid, which each are provided in the center of an air outlet of the air-spouting pipe, or a granulator, having: the bottom floor; the air-supplying pipe; and spray nozzles for spraying a granulation raw material liquid, which each are provided in an opening in the bottom floor of the perforated plate, and use a high-pressure atomizing air as an auxiliary gas, wherein, in each granulator, the spray nozzles are formed in triangular arrangement.
    • 造粒机,具有:造粒单元,具有底板,多孔板作为底部; 用于向造粒单元的底层供给流化空气的上部供气管; 下供气管; 排气管,其分别从下供气管分支,并且在多孔板的底板中具有用于将空气喷射到造粒单元中的开口; 以及喷射喷嘴,用于喷射造粒原料液体,每个制粒原料液体设置在排气管的出气口的中心,或造粒机,具有:底层; 供气管; 以及喷射喷嘴,用于喷射造粒原料液体,其分别设置在多孔板的底板的开口中,并且使用高压雾化空气作为辅助气体,其中,在每个造粒机中,喷嘴为 形成三角形排列。
    • 72. 发明授权
    • Method and apparatus for synthesizing urea
    • 尿素合成方法和装置
    • US07498464B2
    • 2009-03-03
    • US11421002
    • 2006-05-30
    • Yasuhiko Kojima
    • Yasuhiko Kojima
    • C07C273/04
    • C07C273/04B01J2219/00006
    • In a process and an apparatus for synthesizing urea which synthesize urea from ammonia and carbon dioxide, the operating condition can be grasped easily and with good accuracy. A process for synthesizing urea which includes: a reaction step of obtaining a urea synthesis solution which contains urea, unreacted ammonia, unreacted carbon dioxide and water by causing ammonia and carbon dioxide to react with each other; a stripping step of separating a gas mixture containing the unreacted ammonia and the unreacted carbon dioxide by stripping the urea synthesis solution by using at least a portion of raw material carbon dioxide; a condensing step of obtaining a condensed liquid by condensing the gas mixture in an absorbing medium while cooling the gas mixture; a recycling step of recycling the condensed liquid to the reaction step; and a step of measuring the density of the condensed liquid online. An apparatus for carrying out this process is provided.
    • 在从氨和二氧化碳合成尿素的合成尿素的方法和装置中,可以容易且准确地掌握操作条件。 一种合成尿素的方法,包括:通过使氨和二氧化碳相互反应获得含有尿素,未反应氨,未反应的二氧化碳和水的尿素合成溶液的反应步骤; 通过使用至少一部分原料二氧化碳汽提尿素合成溶液来分离含有未反应氨和未反应二氧化碳的气体混合物的汽提步骤; 冷凝步骤,通过在吸收介质中冷凝气体混合物同时冷却气体混合物来获得冷凝液体; 回收步骤,将冷凝的液体再循环到反应步骤; 以及在线测量浓缩液体的密度的步骤。 提供了一种用于执行该过程的装置。
    • 73. 发明申请
    • APPARATUS FOR SYNTHESIZING UREA
    • 用于合成尿素的装置
    • US20090036712A1
    • 2009-02-05
    • US11909744
    • 2006-04-24
    • Yasuhiko Kojima
    • Yasuhiko Kojima
    • C07C273/00B01J19/00
    • B01D3/343B01D5/003C07C273/04
    • It is intended to enable more smooth operation in an apparatus for synthesizing urea by circumventing the downward flow of a urea synthesis solution which is a gas-liquid two-phase flow and stabilizing the flow of the urea synthesis solution still remaining the gas-liquid two-phase flow and to reduce energy loss by giving smaller flow resistance. The present invention provides an apparatus for synthesizing urea including: a synthesis reactor for reacting NH3 with CO2 to obtain a urea synthesis solution containing urea, unreacted NH3, unreacted CO2, and water; a stripper for stripping the urea synthesis solution with use of at least a part of raw material CO2 to separate a gas mixture containing the unreacted NH3 and the unreacted CO2; a vertical submerged condenser having a shell and tube structure for condensing the gas mixture in an absorbing medium on the shell side while cooling the gas mixture with a cooling medium passing through the tube side; and recycling means for recycling a liquid obtained from this condenser to the synthesis reactor, wherein the synthesis reactor is a horizontal type, and wherein piping for sending the urea synthesis solution from the synthesis reactor to the stripper runs substantially horizontally and/or upward.
    • 旨在通过绕过作为气液两相流的尿素合成溶液的向下流动并使仍然保留气液二的尿素合成溶液的流动稳定化,在用于合成尿素的装置中更加平稳地操作 通过提供较小的流动阻力来减少能量损失。 本发明提供了一种用于合成尿素的装置,包括:用于使NH 3与CO 2反应的合成反应器,以获得含有尿素,未反应的NH 3,未反应的CO 2和水的尿素合成溶液; 汽提器,用于使用至少一部分原料CO 2来分离含有未反应的NH 3和未反应的CO 2的气体混合物的尿素合成溶液; 具有壳体和管结构的垂直浸没式冷凝器,用于在壳体侧的吸收介质中冷凝气体混合物,同时用通过管侧的冷却介质冷却气体混合物; 以及用于将从该冷凝器获得的液体再循环到合成反应器的再循环装置,其中合成反应器是水平型,并且其中用于将尿素合成溶液从合成反应器输送到汽提器的管道基本上水平和/或向上运行。
    • 79. 发明授权
    • Process for the synthesis of urea
    • 尿素合成方法
    • US06426434B1
    • 2002-07-30
    • US09984486
    • 2001-10-30
    • Kinichi YoshidaKenji YoshimotoYasuhiko Kojima
    • Kinichi YoshidaKenji YoshimotoYasuhiko Kojima
    • C07C27304
    • C07C273/04
    • A urea synthesis process with improved heat economy, wherein a urea synthesis solution obtained by removing most of the unreacted ammonium carbamate by stripping with carbon dioxide at a pressure approximately equal to a urea synthesis pressure is subjected to a high and low pressure decomposition. The gas mixture obtained from the high-pressure decomposition is condensed in at least two steps. Gases obtained from the stripping of the urea synthesis solution, after an initial condensation may be alternatively routed into the high-pressure decomposition column thus facilitating the decomposition of unreacted ammonium carbamate; may be mixed with off-gases from the high-pressure decomposition column and routed to an indirect heat-exchanger for concentrating the aqueous urea solution and facilitating the condensation of the off-gases from the high pressure decomposition column; or may be routed to a condenser for the gas mixture obtained from the high-pressure decomposition after it has underwent indirect heat-exchange with the aqueous urea solution, thus facilitate the further condensation of these gases.
    • 具有改善的热效率的尿素合成方法,其中通过用大约等于尿素合成压力的压力用二氧化碳汽提除去大部分未反应的氨基甲酸铵而获得的尿素合成溶液经受高低压分解。 从高压分解得到的气体混合物至少两个步骤冷凝。 在初始冷凝后从尿素合成溶液的汽提中获得的气体可以选择性地送入高压分解塔,从而促进未反应的氨基甲酸铵的分解; 可以与来自高压分解塔的废气混合,并且被引导到用于浓缩尿素水溶液的间接热交换器,并促进来自高压分解塔的废气的冷凝; 或者可以在与尿素水溶液进行间接热交换之后,将其从高压分解获得的气体混合物送至冷凝器,由此促进这些气体的进一步冷凝。