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    • 61. 发明申请
    • CONTROL AND REPELLENCY OF BED BUGS
    • BED BUGS的控制和回报
    • WO2013165478A1
    • 2013-11-07
    • PCT/US2013/000122
    • 2013-04-30
    • BEDOUKIAN RESEARCH, INC.BEDOUKIAN, Robert, H.
    • BEDOUKIAN, Robert, H.
    • A01N35/06
    • C07C69/675A01N31/06A01N35/06A01N37/02A01N37/18A01N37/22A01N37/36A01N37/42A01N43/08A01N43/16A01N49/00C07C35/06C07C35/18C07C59/205C07C69/708C07C235/74C07C2601/08C07C2601/16C07D307/33C07D309/30A01N2300/00
    • Control or repellency of bed bugs is accomplished by bringing the bed bugs into contact with at least one of the compounds of the structure (I); wherein R is selected from -OH, -OC(O)R 4 , -OR 6 , -(OR 6 ) 2 , wherein each R 6 is independently selected from an alkyl group containing from 1 to 4 carbon atoms and R 4 is a branched or straight chain saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms; X is O or CH 2 , with the proviso that when X is O R can only be =0; each Z is independently selected from (CH) and (CH 2 ) y is a numeral selected from 1 and 2; R 1 is selected from H or a branched or straight chain saturated or unsaturated hydrocarbyl group with zero to two double bonds and from 1 to 15 carbon atoms. R 2 is selected from H and a branched or straight chain saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms. R 3 is selected from H, a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, -(CH 2 ) n OH, -C(O)OR 5 , -CH 2 C(O)OR 7 , - CH 2 C(O)R 8 , -C(O)NR 9 R 10 , -CH 2 C(O)NR 11 R 12 where each of R 5 , R 7 , R 8 , R 9 , R 10 , R 11 and R 12 is independently selected from H and a branched or straight chain, saturated or unsaturated hydrocarbyl group with zero to three double bonds and from 1 to 15 carbon atoms, and n is an integer of from 1 to 12; and the bond between the 2 and 3 positions in the ring structure may be a single or a double bond, and wherein the compounds of structure (1) contain from 11 to 20 total carbon atoms, except where R is =O, X = CH 2 and y is 1 the compounds of structure (I) contain from 13 to 20 total carbon atoms in the compounds, wherein the compounds of structure (1) contain from 1 1 to 20 total carbon atoms, except where R is =O, X = CH2 and y is 1 the compounds of structure (I) contain from 13 to 20 total carbon atoms in the compounds, wherein the compounds of structure (1) contain from 11 to 20 total carbon atoms, except where R is =0, X = CH 2 and y is 1 the compounds of structure (I) contain from 13 to 20 total carbon atoms in the compounds.
    • 通过使床臭虫与至少一种结构(I)的化合物接触来实现臭虫的控制或排斥; 其中R选自-OH,-OC(O)R 4,-OR 6, - (OR 6)2,其中每个R 6独立地选自含有1至4个碳原子的烷基,R 4是支链或直链饱和 或具有0至2个双键和1至15个碳原子的不饱和烃基; X是O或CH2,条件是当X是O时,R只能是= 0; 每个Z独立地选自(CH)和(CH 2)y是选自1和2的数字; R1选自H或具有0至2个双键和1至15个碳原子的支链或直链饱和或不饱和烃基。 R2选自H和具有0至3个双键和1至15个碳原子的支链或直链饱和或不饱和烃基。 R 3选自H,具有0至3个双键和1至15个碳原子的支链或直链饱和或不饱和烃基, - (CH 2)n OH,-C(O)OR 5,-CH 2 C(O)OR 7 , - CH 2 C(O)R 8,-C(O)NR 9 R 10,-CH 2 C(O)NR 11 R 12,其中R 5,R 7,R 8,R 9,R 10,R 11和R 12各自独立地选自H和支链或直链饱和 或具有0至3个双键和1至15个碳原子的不饱和烃基,n为1至12的整数; 并且环结构中2和3位之间的键可以是单键或双键,并且其中结构(1)的化合物含有11至20个总碳原子,除了R是= O,X = CH 2 并且y为1,化合物中结构(I)的化合物含有13至20个总碳原子,其中结构(1)的化合物含有11至20个总碳原子,除了R为=,X = CH2和y为1,化合物中结构(I)的化合物含有13至20个总碳原子,其中结构式(1)的化合物含有11至20个总碳原子,除了R为= 0,X = CH2和y为1,化合物中结构(I)的化合物含有13至20个总碳原子。
    • 63. 发明申请
    • METHOD FOR PRODUCING 1,6-HEXANEDIOL
    • 用于生产1,6-己二醇
    • WO99033773A1
    • 1999-07-08
    • PCT/EP1998/008072
    • 1998-12-10
    • C07B61/00C07C29/149C07C31/20
    • C07C29/149C07C2601/08C07C35/06C07C31/135C07C31/20
    • The invention relates to a method for producing 1,6-hexanediol by hydrogenating adipic acid esters and/or 6-hydroxycarboxylic acid esters in the gaseous phase at an elevated temperature and pressure in the present of chromium-free catalysts. Hydrogenation is carried out a) using catalysts containing copper, manganese and aluminium as essential constituents or in the presence of Raney copper; b) at temperatures of between 150 and 230 DEG C and pressures of between 10 and 70 bar; c) at a molar ratio of hyrogen to hydrogenating ester of between 150 to 1 and 300 to 1; and d) at a catalyst load of between 0.01 and 0.3 kg C3-ester per litre of catalyst and hour.
    • 一种用于通过在升高的温度和压力下己二酸酯和/或6-羟基羧酸酯在气相中的氢化在无铬催化剂的存在下,该方法包括使用作为基本组分,铜,锰和氢化a)制备1,6-己二醇过程 含铝的催化剂或在阮内铜的存在下,b)在150至230℃和10至70巴的压力,c)在氢气存在下在150至被氢化酯为1〜300的摩尔比为1,和d) 每升催化剂·小时为0.01〜0.3公斤C3-酯的催化剂下进行。
    • 69. 发明专利
    • Preparation of furfuryl alcohols
    • 富勒烯醇的制备
    • JPS59118780A
    • 1984-07-09
    • JP23058582
    • 1982-12-24
    • Sumitomo Chem Co Ltd
    • TAKIZAWA YUKIHISAKOUNO NOBUHARUSAITOU KENJIYAMACHIKA HIROSHI
    • B01J27/00B01J27/138C07B49/00C07B61/00C07C29/40C07C33/042C07C33/048C07C33/30C07C35/06C07D307/42C07D333/16
    • C07D307/42C07C29/40C07C33/042C07C33/048C07C33/30C07C35/06C07C2601/08C07D333/16
    • PURPOSE: To obtain the titled substance useful as an intermediate for agricultural chemicals, drugs, etc. in high yield without problems of pollution, by reacting a furfural with Mg and a porpargyl halide in THF in the presence of a zinc halide as a catalyst, followed by hydrolysis.
      CONSTITUTION: A furfural shown by the formula I (R
      1 is H, CH
      3 , or C
      2 H
      5 ) and a propargyl halide (e.g., propargyl chloride, 3-bromo-1-butene) are simultaneously treated with Mg in THF in the presence of a catalyst (of a zinc halide (e.g., zinc chloride) to give a compound shown by the formula II (R
      2 is propargyl, or α-methylpropargyl). An amount of the propargyl halide used is 1.1W1.3 times the molar amount of the furfural, and an amount of Mg used is preferably ≥1.05 times the molar amount of it. The reaction temperature is 10W60°C.
      EFFECT: Free from problems of recovery of mercury, as it replaces the existing method using a mercury catalyst.
      COPYRIGHT: (C)1984,JPO&Japio
    • 目的:通过在卤化锌作为催化剂的存在下,通过糠醛与镁和卤代卟啉在THF中反应,获得高产率,无污染的农药,药物等作为中间体的标题物质, 然后水解。 构成:在催化剂存在下,用Mg在THF中同时处理由式I表示的糠醛(R 1是H,CH 3或C 2 H 5)和炔丙基卤(例如炔丙基氯,3-溴-1-丁烯) (卤化锌(如氯化锌)),得到式Ⅱ所示化合物(R2为炔丙基或α-甲基炔丙基),所用炔丙基卤用量为糠醛摩尔量的1.1〜1.3倍, 使用的Mg的量优选为其摩尔量的1.05倍,反应温度为10-60℃。效果:不用汞回收的问题,因为它取代了使用汞催化剂的现有方法。