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61. 发明授权

US5846643A Thermally stable fuser member 失效
标题翻译：耐热稳定的定影器构件
公开(公告)号：US5846643A
公开(公告)日：1998-12-08
申请号：US556556
申请日：1995-11-13
申请人： Santokh S. Badesha , Arnold W. Henry , Robert J. Gruber
发明人： Santokh S. Badesha , Arnold W. Henry , Robert J. Gruber
IPC分类号： G03G15/20 , B32B5/16
CPC分类号： G03G15/2057 , Y10T428/1355 , Y10T428/139 , Y10T428/25 , Y10T428/251 , Y10T428/26 , Y10T428/3154 , Y10T428/31663 , Y10T428/31678
摘要： A fuser member for use in an electrostatographic printing machine has at least one layer of an elastomer composition comprising a silicone elastomer and a mica-type layered silicate, the silicone elastomer and mica-type layered silicate forming a delaminated nanocomposite with silicone elastomer inserted among the delaminated layers of the mica-type layered silicate.
摘要翻译：用于静电印刷机的定影器构件具有至少一层弹性体组合物，其包含硅氧烷弹性体和云母型层状硅酸盐，硅氧烷弹性体和云母型层状硅酸盐形成具有硅酮弹性体的分层纳米复合材料，其插入在云母型层状硅酸盐的分层。

62. 发明授权

US5332641A Fuser member with an amino silane adhesive layer 失效
标题翻译：具有氨基硅烷粘合剂层的定影器构件
公开(公告)号：US5332641A
公开(公告)日：1994-07-26
申请号：US874165
申请日：1992-04-27
申请人： Patrick J. Finn , George J. Heeks , Arnold W. Henry , Alan R. Kuntz
发明人： Patrick J. Finn , George J. Heeks , Arnold W. Henry , Alan R. Kuntz
IPC分类号： C09D127/12 , G03G15/20 , G03G13/20 , B32B15/04 , G03G9/00
CPC分类号： G03G15/2057 , C09D127/12 , Y10T428/31656 , Y10T428/31663
摘要： A fuser member for fusing thermoplastic resin toner images to a substrate has an aluminum base member and an elastomer fusing surface of a poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) where the vinylidenefluoride is present in an amount less than 40 mole percent, the elastomer having been cured from a solvent solution thereof with a nucleophilic curing agent soluble in the solution and in the presence of 5 or less than 4 parts by weight of inorganic base per 100 parts of polymer, the inorganic base being effective to at least partially dehydrofluorinate the vinylidenefluoride, and an adhesive layer between the surface of said aluminum base member and the elastomer fusing surface, the adhesive layer having been cured from a solvent solution of a poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) where the vinylidenefluoride is present in an amount less than 40 mole percent and from about 6 to 20 parts by weight per 100 parts by weight of said poly(vinylidenefluoride hexafluoropropylene-tetrafluoroethylene) of an amino silane represented by the formula: ##STR1## where R can be an alkyl group having 1 to 7 carbon atoms; R' can be an alkyl group having 1 to 7 carbon atoms or a polyalkoxyalkyl group of less than 7 carbon atoms; Y is an amino group or an amino substituted alkyl, or a polyamino substituted alkyl, or an alkenylalkoxy amino, or an aryl amino group of less than 15 carbon atoms, h is 1 to 3, b is 0 to 2, q is 1 or 2 and h+b=3.
摘要翻译：用于将热塑性树脂调色剂图像融合到基底的定影器构件具有铝基底构件和聚（偏二氟乙烯 - 六氟丙烯 - 四氟乙烯）的弹性体熔合表面，其中偏二氟乙烯以小于40摩尔％的量存在，弹性体已经用可溶于该溶液的亲核固化剂和每100份聚合物5或4重量份以下的无机碱存在下，从其溶剂溶液中固化，所述无机碱有效地至少部分地使所述偏二氟乙烯脱氢氟化，以及在所述铝基部件的表面和弹性体熔合表面之间的粘合剂层，所述粘合剂层已经从聚偏氟乙烯 - 六氟丙烯 - 四氟乙烯的溶剂溶液中固化，其中所述偏二氟乙烯以小于40摩尔的量存在百分比和约6至20重量份/ 100重量份的所述聚（乙烯基）氟代六氟丙烯四氟乙烯）由下式表示的氨基硅烷：其中R可以是具有1至7个碳原子的烷基; R'可以是具有1至7个碳原子的烷基或少于7个碳原子的聚烷氧基烷基; Y为小于15个碳原子的氨基或氨基取代的烷基，或聚氨基取代的烷基或链烯基烷氧基氨基或芳基氨基，h为1至3，b为0至2，q为1或 2和h + b = 3。

63. 发明授权

US5049444A Silane adhesive system for fusing member 失效
标题翻译：用于定影部件的硅烷粘合剂系统
公开(公告)号：US5049444A
公开(公告)日：1991-09-17
申请号：US451056
申请日：1989-12-15
申请人： George J. Bingham , Patrick J. Finn , George J. Heeks , Arnold W. Henry , Donald A. Seanor
发明人： George J. Bingham , Patrick J. Finn , George J. Heeks , Arnold W. Henry , Donald A. Seanor
IPC分类号： G03G15/20
CPC分类号： G03G15/2057 , Y10T428/269 , Y10T428/31663
摘要： A multilayered member for fusing thermoplastic resin toner images to a substrate in a fuser system of the type wherein a polymeric release agent having functional groups is applied to the surface of the fuser member. The multilayered fuser member has in sequential order a base support member, an adhesive layer comprising a copolymer of vinylidene fluoride and hexafluoropropylene and at least 20% by weight of the adhesive layer of a coupling agent comprising at least one organo functional silaneand an activator, a tie coat layer of active ingredients comprising a copolymer of vinylidene fluoride and hexafluoropropylene and an outer elastomeric fusing surface comprising a copolymer of vinylidene fluoride and hexafluoropropylene and containing a metal oxide present in an amount sufficient to interact with a polymeric release agent having functional groups to provide an interfacial barrier layer between said fusing surface and toner.
摘要翻译：一种用于将热塑性树脂调色剂图像融合到其中将具有官能团的聚合物脱模剂施加到定影器构件的表面的定影系统中的基底的多层构件。多层定影器构件依次具有基底支撑构件，包含偏二氟乙烯和六氟丙烯的共聚物的粘合剂层和至少20重量％的包含至少一个有机官能的硅烷和活化剂的偶联剂的粘合剂层，包含偏二氟乙烯和六氟丙烯的共聚物的活性成分的粘结涂层和包含偏二氟乙烯和六氟丙烯的共聚物并且含有金属氧化物的外部弹性体熔融表面，其存在的量足以与具有官能团的聚合物脱模剂相互作用以提供在所述定影表面和调色剂之间的界面阻挡层。

64. 发明授权

US5933695A Rapid wake up fuser system members with silicone layer 有权
标题翻译：快速唤醒定影系统成员与硅胶层
公开(公告)号：US5933695A
公开(公告)日：1999-08-03
申请号：US127949
申请日：1998-08-03
申请人： Arnold W. Henry , George J. Heeks , David J. Gervasi
发明人： Arnold W. Henry , George J. Heeks , David J. Gervasi
IPC分类号： G03G15/20
CPC分类号： G03G15/2057
摘要： An rapid wake up fuser system member for use in an electrophotographic apparatus for fusing toner images to a copy substrate, the fuser member having a substrate, a heat transmissive layer having a silicone material and a Q-resin provided on the substrate layer, and a polymer-containing toner release layer provided on the heat transmissive layer.
摘要翻译：一种快速唤醒定影系统构件，用于将调色剂图像定影到复印基板的电子照相设备中，具有基底的定影器构件，具有硅酮材料的透光层和设置在基底层上的Q-树脂，以及设置在透热层上的含聚合物的调色剂分离层。

65. 发明授权

US5219612A Silane adhesive system for fuser member 失效
标题翻译：用于定影器构件的硅烷粘合剂系统
公开(公告)号：US5219612A
公开(公告)日：1993-06-15
申请号：US695069
申请日：1991-05-03
申请人： George J. Bingham , Patrick J. Finn , George J. Heeks , Arnold W. Henry , Donald A. Seanor
发明人： George J. Bingham , Patrick J. Finn , George J. Heeks , Arnold W. Henry , Donald A. Seanor
IPC分类号： G03G15/20
CPC分类号： G03G15/2057
摘要： A method of using multilayered member for fusing thermoplastic resin toner images to a substrate in a fuser system of the type wherein a polymeric release agent having functional groups is applied to the surface of the fuser member. The multilayered fuser member has in sequential order a base support member, an adhesive layer comprising a copolymer of vinylidene fluoride and hexafluoropropylene and at least 20% by weight of the adhesive layer of a coupling agent comprising at least one organo functional silane and an activator, a tie coat layer of active ingredients comprising a copolymer of vinylidene fluoride and hexafluoropropylene and an outer elastomeric fusing surface comprising a copolymer of vinylidene fluoride and hexafluoropropylene and containing a metal oxide present in an amount sufficient to interact with a polymeric release agent having functional groups to provide an interfacial barrier layer between said fusing surface and toner.
摘要翻译：使用将热塑性树脂调色剂图像熔合到其中具有官能团的聚合物脱模剂施加到定影器构件的表面的定影系统中的基材的多层构件的方法。多层定影器构件依次具有基底支撑构件，包含偏二氟乙烯和六氟丙烯的共聚物的粘合剂层和至少20重量％的包含至少一种有机官能的硅烷和活化剂的偶联剂的粘合剂层，包含偏二氟乙烯和六氟丙烯的共聚物的活性成分的粘结层，以及包含偏二氟乙烯和六氟丙烯的共聚物并且含有金属氧化物的外部弹性体熔融表面，所述共聚物的量足以与具有官能团的聚合物脱模剂相互作用在所述定影表面和调色剂之间提供界面阻挡层。

66. 发明授权

US4777087A Heat stabilized silicone elastomers 失效
标题翻译：热稳定硅酮弹性体
公开(公告)号：US4777087A
公开(公告)日：1988-10-11
申请号：US18372
申请日：1987-02-24
申请人： George J. Heeks , Arnold W. Henry , Edward L. Schlueter, Jr.
发明人： George J. Heeks , Arnold W. Henry , Edward L. Schlueter, Jr.
IPC分类号： C08K3/24 , C08K3/00 , C08K3/30 , C08K3/32 , C08K5/00 , C08K5/36 , C08K5/59 , C08L83/00 , C08L83/04 , C08L83/05 , C08L83/07 , G03G15/20 , B32B3/26
CPC分类号： G03G15/2057 , C08K5/0091 , Y10T428/249995 , Y10T428/31663
摘要： A silicone composition curable to a heat stabilized silicone elastomer comprising at least one polyorganosiloxane having the formula: ##STR1## where R is hydrogen or substituted or unsubstituted alkyl, alkenyl or aryl having less than 19 carbon atoms, each of A and D may be any of methyl, hydroxy or vinyl groups,0 350,a complex comprising a transition metal salt of at least one polydentate chelating ligand having the formula: ##STR2## where each R.sub.1 may be an alkyl biradical having 1 to 6 carbon atoms or an aryl biradical having less than 19 carbon, atoms R'.sub.1, is an X' substituted R.sub.1, each of Z and E may be any of carboxy thiocarboxy, dithiocarboxy, or --N(R.sub.2).sub.2, --A.sub.s (R.sub.2).sub.2, --S(R.sub.2) where each R.sub.2 may be any of hydrogen or an alkyl radical having 1 to 6 carbon atoms or any aryl radical having less than 19 carbon atoms, X' may be any of hydrogen, carboxy, thiocarboxy, dithiocarboxy, --N(R.sub.2).sub.2, --A.sub.s (R.sub.2).sub.2, or --S(R.sub.2), X is --N(R.sub.2)--, --A.sub.s (R.sub.2)--, or --S-- and p is 0 to 4 present in the composition in an amount sufficient to inhibit oxidative degradation of the polyorganosiloxane and a finely divided filler and effective amounts of crosslinking agent and catalyst. The complex may be predispersed in a polyorganosiloxane oil having a viscosity within a range of to 50 to 100,000 centistokes. In a preferred embodiment for use in an electrostatographic reproducing machine a fuser member is made with an addition curable polyorganosiloxane and the complex is bis (ethylene diamine) copper (II) sulfate initially predispersed in a low viscosity silicone oil and subsequently dispersed in a higher viscosity silicone oil.
摘要翻译：包含至少一种具有下式的聚有机硅氧烷的硅氧烷组合物：其中R是氢或具有少于19个碳原子的取代或未取代的烷基，烯基或芳基，A和D中的每一个可以是任何的甲基，羟基或乙烯基，0 <（m / n）≤1和m + n> 350，包含至少一种具有下式的多齿螯合配位体的过渡金属盐的络合物：其中每个R 1 可以是具有1至6个碳原子的烷基双原子或具有少于19个碳原子的芳基双原子，R 1'是X'取代的R 1，Z和E各自可以是羧基硫代羧基，二硫代羧基或-N （R2）2，-As（R2）2，-S（R2）其中R2可以是氢或具有1-6个碳原子的烷基或任何具有少于19个碳原子的芳基，X'可以是氢，羧基，硫代羧基，二硫代羧基，-N（R2）2，-As（R2）2或-S（R2）中的任一个，X是-N（R2） - ，--As（R2） - 或-S - 和p是0到4存在于公司其量足以抑制聚有机硅氧烷和细碎填料的氧化降解和有效量的交联剂和催化剂。络合物可以预先分散在粘度在50至100,000厘沲范围内的聚有机硅氧烷油中。在用于静电复制机的优选实施方案中，定影构件由可加成固化的聚有机硅氧烷制成，并且络合物是最初预先分散在低粘度硅油中的双（乙二胺）硫酸铜（II），随后以更高的粘度分散硅油。

67. 发明授权

US4925895A Heat stabilized silicone elastomers 失效
标题翻译：热稳定硅酮弹性体
公开(公告)号：US4925895A
公开(公告)日：1990-05-15
申请号：US194068
申请日：1988-05-12
申请人： George J. Heeks , Arnold W. Henry , Edward L. Schlueter, Jr.
发明人： George J. Heeks , Arnold W. Henry , Edward L. Schlueter, Jr.
IPC分类号： C08K3/24 , C08K3/00 , C08K3/30 , C08K3/32 , C08K5/00 , C08K5/36 , C08K5/59 , C08L83/00 , C08L83/04 , C08L83/05 , C08L83/07 , G03G15/20
CPC分类号： G03G15/2057 , C08K5/0091 , Y10T428/249995 , Y10T428/31663
摘要： A silicone composition curable to a heat stabilized silicone elastomer comprising at least one polyorganosiloxane having the formula: ##STR1## where R is hydrogen or substituted or unsubstituted alkyl, alkenyl or aryl having less than 19 carbon atoms, each of A and D may be any of methyl, hydroxy or vinyl groups,0 350,a complex comprising a transition metal salt of at least one polydentate chelating ligand having the formula: ##STR2## where each R.sub.1 may be an alkyl biradical having 1 to 6 carbon atoms or an aryl biradical having less than 19 carbon atoms R.sub.1, is an X' substituted R.sub.1, each of Z and E may be any of carboxy thiocarboxy, dithiocarboxy, or --N(R.sub.2).sub.2, --As(R.sub.2).sub.2, --S(R.sub.2) where each R.sub.2 may be any of hydrogen or an alkyl radical having 1 to 6 carbon atoms or any aryl radical having less than 19 carbon atoms, X' may be any of hydrogen, carboxy, thiocarboxy, dithiocarboxy, --N(R.sub.2).sub.2, --A.sub.s (R.sub.2).sub.2, or --S(R.sub.2), X is --N(R.sub.2)--, --A.sub.s (R.sub.2)--, or --S-- and p is 0 to 4 present in the composition in an amount sufficient to inhibit oxidative degradation of the polyorganosiloxane and a finely divided filler and effective amounts of crosslinking agent and catalyst. The complex may be predispersed in a polyorganosiloxane oil having a viscosity within a range of to 50 to 100,000 centistokes. In a preferred embodiment for use in an electrostatographic reproducing machine a fuser member is made with an addition curable polyorganosiloxane and the complex is bis(ethylene diamine) copper (II) sulfate initially redispersed in a low viscosity silicone oil and subsequently dispersed in a higher viscosity silicone oil.
摘要翻译：包含至少一种具有下式的聚有机硅氧烷的硅氧烷组合物：其中R是氢或具有少于19个碳原子的取代或未取代的烷基，烯基或芳基，A和D中的每一个可以是任何的甲基，羟基或乙烯基，0 350，包含至少一个具有下式的多齿螯合配位体的过渡金属盐的络合物：其中每个R 1可以是具有1至6个碳原子的烷基双基或具有少于19个碳原子的芳基双基R 1是X'取代的R 1，Z和E各自可以是羧基硫代羧基，二硫代羧基或-N（R 2）2， -As（R 2）2，-S（R 2），其中每个R 2可以是氢或具有1至6个碳原子的烷基或任何具有少于19个碳原子的芳基，X'可以是氢，羧基，硫代羧基，二硫代羧基，-N（R2）2，-As（R2）2或-S（R2），X是-N（R2） - ，--As（R2） - 或-S-，p是0 到4个在compos 其量足以抑制聚有机硅氧烷和细分散填料的氧化降解和有效量的交联剂和催化剂。络合物可以预先分散在粘度在50至100,000厘沲范围内的聚有机硅氧烷油中。在用于静电复制机的优选实施例中，定影器构件由可加成固化的聚有机硅氧烷制成，并且配合物是双（乙二胺）硫酸铜（II）硫酸盐，最初再分散在低粘度硅油中，随后以更高的粘度分散硅油。

68. 发明授权

US5217837A Multilayered fuser member 失效
标题翻译：多层熔炉会员
公开(公告)号：US5217837A
公开(公告)日：1993-06-08
申请号：US755274
申请日：1991-09-05
申请人： Arnold W. Henry , Patrick J. Finn , George J. Heeks , Robert N. Finsterwalder , George A. Riehle , William J. Cheslock
发明人： Arnold W. Henry , Patrick J. Finn , George J. Heeks , Robert N. Finsterwalder , George A. Riehle , William J. Cheslock
IPC分类号： B32B25/04 , C08L27/12 , G03G15/20
CPC分类号： G03G15/2057 , Y10T428/269 , Y10T428/31663
摘要： A multilayered fuser member for fusing thermoplastic resin toner images to a substrate in a fuser system of the type wherein a polymeric release agent having functional groups is applied to the surface of the fuser member, the fuser member has a base support member, a thermally conductive silicone elastomer layer, an amino silane primer layer, an adhesive layer and an elastomer fusing surface comprising poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) a metal oxide present in the fusing surface to interact with the polymeric release agent to provide an interfacial barrier layer between the fusing surface and the toner and substantially unreactive with the elastomer, the elastomer having been cured from a solvent solution with a nucleophilic curing agent soluble in the solution and in the presence of 4 parts by weight of inorganic base per 100 parts of polymer, the adhesive layer having been cured from a solvent solution of the above composition from which the fusing surface is cured and from about 5 to about 10% by weight of a coupling agent represented by the formula: ##STR1## where R can be an alkyl having 1 to 4 carbon atoms; R' can be an alkyl group having 1 to 7 carbon atoms; R" can be H, R or the acyl radical, ##STR2## X is a vinyl group or an alkenyl group or an alkyl, having 1 to 4 carbon atoms, substituted alkenylcarboxy group of less than 8 carbon atoms; and q is 1 or 2, k is 0 to 3, b is 0 to 2, a is 0 or 1, p is 0 to 20 and k+b+a=3.

69. 发明授权

US4372246A Externally heated fusing member for electrostatographic copiers 失效
标题翻译：用于静电复印机的外部加热定影构件
公开(公告)号：US4372246A
公开(公告)日：1983-02-08
申请号：US260649
申请日：1981-05-04
申请人： Jack C. Azar , Arnold W. Henry , Robert M. Ferguson
发明人： Jack C. Azar , Arnold W. Henry , Robert M. Ferguson
IPC分类号： G03G15/20 , B05C11/00
CPC分类号： G03G15/2057
摘要： In an externally heated fusing system, the improvement which comprises providing an externally heated fuser member which is made of a base, a relatively thick layer of a foam of a fluoroelastomer on the base, and a relatively thin layer of a silicone elastomer on the foam layer. The silicone elastomer layer containing an iron oxide filler therein.
摘要翻译：在外部加热的定影系统中，改进包括提供外部加热的定影器构件，其由基底制成，基底上的相对厚的含氟弹性体的泡沫层以及泡沫上的相对薄的硅氧烷弹性体层层。含有氧化铁填料的硅氧烷弹性体层。

70. 发明授权

US5017432A Fuser member 失效
标题翻译：定影器成员
公开(公告)号：US5017432A
公开(公告)日：1991-05-21
申请号：US405392
申请日：1989-09-11
申请人： Clifford O. Eddy , Arnold W. Henry , Lynn Lorenzo , Che C. Chow , Robert M. Ferguson , Robert N. Finsterwalder
发明人： Clifford O. Eddy , Arnold W. Henry , Lynn Lorenzo , Che C. Chow , Robert M. Ferguson , Robert N. Finsterwalder
IPC分类号： C08K3/22 , G03G15/20
CPC分类号： G03G15/2057 , C08K3/22 , Y10S428/906 , Y10T428/31544 , Y10T428/31699
摘要： A fuser member and fuser system of a type wherein a polymeric release agent having functional groups supplied to the surface of the fuser member has an elastomer fusing surface comprising poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) wherein the vinylidenefluoride is present in the amount less than 40 mole percent, a metal oxide is present in amounts sufficient to interact with the polymer release agent having functional groups to provide an interfacial barrier layer between the fusing surface and the toner and being substantially unreactive with the elastomer and wherein the elastomer is cured from a solvent solution thereof with a nucleophilic curing agent soluble in the solution and in the presence of less than 4 parts by weight of inorganic base per 100 parts by weight of polymer with the inorganic base being effective to at least partially dehydrofluorinate the vinylidenefluoride.
摘要翻译：一种定影器构件和定影器系统，其中具有提供给定影器构件表面的官能团的聚合物脱模剂具有包含聚（偏二氟乙烯 - 六氟丙烯 - 四氟乙烯）的弹性体熔融表面，其中所述偏二氟乙烯以小于40的量存在摩尔百分数，金属氧化物的存在量足以与具有官能团的聚合物脱模剂相互作用，以在熔融表面和调色剂之间提供界面阻隔层，并且与弹性体基本上不反应，并且其中弹性体由溶剂固化其溶液与可溶于溶液的亲核固化剂和每100重量份聚合物存在下的少于4重量份的无机碱的存在下，无机碱有效地至少部分地使偏氟乙烯基氟化氢化。

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