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    • 1. 发明授权
    • Fuser member with an amino silane adhesive layer
    • 具有氨基硅烷粘合剂层的定影器构件
    • US5332641A
    • 1994-07-26
    • US874165
    • 1992-04-27
    • Patrick J. FinnGeorge J. HeeksArnold W. HenryAlan R. Kuntz
    • Patrick J. FinnGeorge J. HeeksArnold W. HenryAlan R. Kuntz
    • C09D127/12G03G15/20G03G13/20B32B15/04G03G9/00
    • G03G15/2057C09D127/12Y10T428/31656Y10T428/31663
    • A fuser member for fusing thermoplastic resin toner images to a substrate has an aluminum base member and an elastomer fusing surface of a poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) where the vinylidenefluoride is present in an amount less than 40 mole percent, the elastomer having been cured from a solvent solution thereof with a nucleophilic curing agent soluble in the solution and in the presence of 5 or less than 4 parts by weight of inorganic base per 100 parts of polymer, the inorganic base being effective to at least partially dehydrofluorinate the vinylidenefluoride, and an adhesive layer between the surface of said aluminum base member and the elastomer fusing surface, the adhesive layer having been cured from a solvent solution of a poly(vinylidenefluoride-hexafluoropropylene-tetrafluoroethylene) where the vinylidenefluoride is present in an amount less than 40 mole percent and from about 6 to 20 parts by weight per 100 parts by weight of said poly(vinylidenefluoride hexafluoropropylene-tetrafluoroethylene) of an amino silane represented by the formula: ##STR1## where R can be an alkyl group having 1 to 7 carbon atoms; R' can be an alkyl group having 1 to 7 carbon atoms or a polyalkoxyalkyl group of less than 7 carbon atoms; Y is an amino group or an amino substituted alkyl, or a polyamino substituted alkyl, or an alkenylalkoxy amino, or an aryl amino group of less than 15 carbon atoms, h is 1 to 3, b is 0 to 2, q is 1 or 2 and h+b=3.
    • 用于将热塑性树脂调色剂图像融合到基底的定影器构件具有铝基底构件和聚(偏二氟乙烯 - 六氟丙烯 - 四氟乙烯)的弹性体熔合表面,其中偏二氟乙烯以小于40摩尔%的量存在,弹性体已经 用可溶于该溶液的亲核固化剂和每100份聚合物5或4重量份以下的无机碱存在下,从其溶剂溶液中固化,所述无机碱有效地至少部分地使所述偏二氟乙烯脱氢氟化, 以及在所述铝基部件的表面和弹性体熔合表面之间的粘合剂层,所述粘合剂层已经从聚偏氟乙烯 - 六氟丙烯 - 四氟乙烯的溶剂溶液中固化,其中所述偏二氟乙烯以小于40摩尔的量存在 百分比和约6至20重量份/ 100重量份的所述聚(乙烯基) 氟代六氟丙烯四氟乙烯)由下式表示的氨基硅烷:其中R可以是具有1至7个碳原子的烷基; R'可以是具有1至7个碳原子的烷基或少于7个碳原子的聚烷氧基烷基; Y为小于15个碳原子的氨基或氨基取代的烷基,或聚氨基取代的烷基或链烯基烷氧基氨基或芳基氨基,h为1至3,b为0至2,q为1或 2和h + b = 3。