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    • 61. 发明专利
    • MOISTURE-SHRINKING RESIN MOLDING
    • JPH0337233A
    • 1991-02-18
    • JP17325389
    • 1989-07-04
    • SANYO CHEMICAL IND LTD
    • SAKAKIBARA TOKUTANAKA KEIJIFUJIURA YOJI
    • C08J5/00B29C55/02B29C61/06
    • PURPOSE:To obtain the subject molding which can shrink within a short time even at a low temperature merely by absorbing moisture and is capable of package, etc., suited for the shape of an irregularly shaped article by stretching a graft copolymer of a hydrophilic resin with a thermoplastic resin. CONSTITUTION:A moisture-shrinking resin molding is obtained by stretching a graft copolymer of a hydrophilic synthetic resin (a nonionic resin, an anionic resin, a cationic resin or an amphoteric resin) with a thermosetting resin (particularly desirably one containing an acrylic ester elastomer), e.g. PVA/methyl acrylate graft copolymer. This molding can be conveniently used without requiring any special shrinking apparatus and can shrink within a short time when it absorbs moisture even at a low temperature. When an irregularly shaped article is wrapped wit the molding in the form a film and left under high humidity conditions, the film can shrink in conformity with the shape of the article and can pack it. Therefore, the molding can be used for a heat-sensitive article to which any conventional shrinking resin composition cannot be applied.
    • 69. 发明专利
    • POLYMER AND ITS PRODUCTION
    • JP2001002711A
    • 2001-01-09
    • JP2000059723
    • 2000-03-06
    • SANYO CHEMICAL IND LTD
    • TANAKA KEIJIIWASAKI YOSHIYUKI
    • C08F2/10C08F228/04
    • PROBLEM TO BE SOLVED: To obtain a polymer which has a small mol.wt. distribution and is useful as a dispersant, a coagulant, and so on, by radically polymerizing a radically polymerizable monomer in the presence of a specific chain transfer agent in an aqueous solution. SOLUTION: This method for producing a polymer comprises radically polymerizing (A) one or more kinds of radically polymerizable monomers which are soluble in water or are soluble in the water after hydrolyzed. Therein, the polymerization is carried out in the presence of water and (B) a radically copolymerizable compound having a (substituted) alkyl group and a thioether group in the same molecule. The component B is preferably a compound of the formula (R1 is H, a 1 to 4C alkyl, phenyl, carboxyl, or the like; R2 is a 1 to 12C alkyl, a 6 to 12C aromatic hydrocarbon, an aralkyl hydrocarbon, or the like). The component A is preferably (i) a water-soluble radically polymerizable monomer having a carboxylic acid (salt) group, a sulfonic acid (salt) group, or the like, and/or (ii) a radically polymerizable monomer having an acid anhydride group, a lower alkyl ester group, or the like, which is soluble in water after hydrolyzed.