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    • 66. 发明专利
    • MATERIAL FOR RUBBER-COATED GASKET
    • JPH0229484A
    • 1990-01-31
    • JP17984488
    • 1988-07-19
    • NICHIAS CORP
    • ASHIZAWA MASAAKINISHIMOTO KAZUOOMURA MUTSUMIITO SHUJI
    • C09K3/10C09D113/00F16J15/12
    • PURPOSE:To obtain the title material improved in strength, abrasion resistance and adhesiveness of the rubber layer to the primer layer by coating at least one surface of a metal sheet coated with a primer based on a phenolic resin with a specified rubber composition and vulcanizing and baking it. CONSTITUTION:A rubber composition is obtained by mixing a carboxylated nitrile rubber (a) containing COOH groups in such an amount that the carboxylated monomer is 2-15wt.% based on the monomer composition of the rubber component and kneaded with either of sulfur as the first vulcanizer and a vulcanization accelerator with a masterbatch (b) containing zinc peroxide as the second vulcanizer and kneaded with sulfur or vulcanization accelerator not added to component (a) and, optionally, materials (c) such as a filler, a rubber chemical and a solvent. A primer layer 3 is formed on at least either of the surfaces of a metal sheet 1 optionally provided with a formation layer 2 by applying a primer based on a phenolic resin and the above rubber composition is applied thereto and vulcanized and backed to form a rubber layer 4 of a thickness of 10-300mum and a nonadhesive layer 5 is optionally formed on the rubber layer 4.
    • 68. 发明专利
    • MANUFACTURE OF JOINT SHEET
    • JPS62103132A
    • 1987-05-13
    • JP11513986
    • 1986-05-20
    • NICHIAS CORP
    • YAMAMOTO TSUTOMUASHIZAWA MASAAKISEKIGUCHI YUJINISHIMOTO KAZUO
    • B29D7/00B29K7/00B29K9/00B29K105/12C08J5/04C09K3/10
    • PURPOSE:To obtain a joint sheet having equivalent physical properties to an asbestos joint sheet, by a method wherein at least two kinds of chopped state fibers selected out of the fibers other than the asbestos are mixed up with each other, which is premolded by a roll after the same has been mixed up with rubber chemical and a filling material by making use of rubber, which is obtained by dissolving the same into an organic solvent, as a binding agent and then molded through hot pressing. CONSTITUTION:A first fiber group is composed of a glass fiber, a ceramic fiber, rock wool, slag wool, wollastonite and potassium titanic acid which are comparatively rigid fiber. A second fiber groups is composed of a polyamide series fiber, polyester series fiber, a polyacrylonitrile series fiber, phenolic fiber and carbon fiber which are comparatively soft fiber. A mixture obtained by mixing up with each other the first and second fiber groups, at least two kinds of chopped state fibers obtained by combining through respective selection only out of the second fiber group, natural or synthetic rubber, chemical and filling agent is made into a premolded sheet by loading the same between a normal temperature or hot roll. The premolded sheet is made into a product by applying not pressing to the same. It is desirable to use a unit fiber whose mean diameter of an extent of 0.1-50mu and the length of an extent of 0.1-10mm.