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61. 发明专利

JPH06154070A PRODUCTION OF CARPET 失效
公开(公告)号：JPH06154070A
公开(公告)日：1994-06-03
申请号：JP33787592
申请日：1992-11-26
申请人： MITSUBISHI YUKA BADISCHE , SENSHIYUU STREAM KK
发明人： KATO NAOYUKI , ICHIHASHI KENZO
IPC分类号： A47G27/02 , B32B37/00 , C08L23/08 , D06M17/00 , E04F15/16
摘要： PURPOSE:To provide the light carpet having excellent flexible and shrinkage resistance by laminating a front base material for the carpet coated with a water emulsion coating material of a resin on the layer of a packing material compsn. contg. inorg. cement power in the water emulsion of a resin and curing and drying this laminate by heating the laminate. CONSTITUTION:The layer of the packing material compsn. is obtd. by incorporating 160 to 360 pts.wt. hydraulic inorg. cement powder and 160 to 460 pts.wt. non-hydraulic inorg. powder per 100 pts.wt. resin solid content into the water emulsion of the resin having 5 to 50 deg.C glass transition temperature. The front base material for the carpet coated with the water emulsion coating material of the resin having -10 to 30 deg.C glass transition temperature is then superposed thereon via the surface coated with the coating material prior to curing and drying of the packing material compsn. This laminate is cured and dried by heating at 85 to 135 deg.C. Calcium carbonate, silica sand, etc., are used for the non-hydraulic inorg. powder. The cured layer of the packing material compsn. is formed of the foam by steam and is, therefore, light in density and is excellent in cushion property.

62. 发明专利

JPH05339043A 失效
公开(公告)号：JPH05339043A
公开(公告)日：1993-12-21
申请号：JP17372792
申请日：1992-06-09
申请人： MITSUBISHI YUKA BADISCHE , DOREIN KOGYO KK
发明人： KATO NAOYUKI , KOBAYASHI NOBUYUKI
IPC分类号： B28B1/14 , B44F9/02 , C04B14/16 , C04B24/26 , C04B28/02 , C04B38/08
摘要： PURPOSE:To obtain the forming composition excellent in mold releasability in forming, having moderate elasticity and with the surface appearance and touch resembling bark or wooden board by incorporating a specified aq. resin emulsion, hydraulic inorg. cement powder, foamed body grains and non-hydraulic inorg. powder into the composition in a specified ratio. CONSTITUTION:100 pts.wt. (based on solid resin) of an aq. emulsion of a resin (e.g. 2-ethylhexyl acrylate) having

63. 发明专利

JPH05214660A CARPET FOR SPREAD LAYING 失效
公开(公告)号：JPH05214660A
公开(公告)日：1993-08-24
申请号：JP1762992
申请日：1992-02-03
申请人： MITSUBISHI YUKA BADISCHE , DIATEX KK , SENSHIYUU SUTORIIMU KK
发明人： KATO NAOYUKI , FUKUSHIMA TAKASHI , ICHIHASHI KENZO
IPC分类号： A47G27/02 , B32B5/00 , D05C17/02
摘要： PURPOSE:To provide a carpet for spread laying, resistant to slip even by using in stacked state, effective in preventing the falling-off of tufted yarn and the permeation of water to the carpet and usable also by turning upside down. CONSTITUTION:The objective carpet is a laminate of (I) a backing carpet layer A composed of a laminated mat (a) produced by laminating a primary base cloth (a ) and a nonwoven cloth (a ) made of a thermoplastic resin fiber binder and integrating the layers by needling, pile yarns (b) planted on one surface of the mat (a) at planting density, pitch, height, total denier and thickness satisfying a prescribed condition and a resin layer (c) produced by applying a liquid resin adhesive to the nonwoven cloth layer (a ) of the mat (a), (II) a surface carpet layer B having a structure same as the carpet layer A and (III) resin layers (c) and (c') integrally bonding the layers A and B.

64. 发明专利

JPH04114943A POLYMER CEMENT COMPOSITION 失效
公开(公告)号：JPH04114943A
公开(公告)日：1992-04-15
申请号：JP22802890
申请日：1990-08-31
申请人： MITSUBISHI YUKA BADISCHE
发明人： ENDO KATSUAKI , KATO NAOYUKI
IPC分类号： C04B14/02 , C04B24/26 , C04B28/02
摘要： PURPOSE:To improve elongation, cracking resistance and adhesive strength of a polymer cement composition by blending a copolymer of an unsaturated carboxylic acid ester having cyano group and a vinyl monomer with hydraulic cement and an aggregate. CONSTITUTION:A polymer cement composition is obtained by adding 2 pts.wt. anionic surfactant and nonionic surfactant, 1 pt.wt. polymerization initiator and 100 pts.wt. ion exchange water to 100 pts.wt. mixture of 0.1-20wt.% unsaturated carboxylic acid ester (e.g. 3-cyanopropyl acrylate) having cyano group and 99.9-80wt.% other vinyl monomers (e.g. a mixture of n-butyl acrylate with styrene and acrylamide), carrying out emulsion polymerization at 60-95 deg.C, providing an aqueous resin emulsion having

65. 发明专利

JPH0481406A PRODUCTION OF AQUEOUS EMULSION OF CROSSLINKABLE POLYURETHANE-ACRYLIC RESIN 失效
公开(公告)号：JPH0481406A
公开(公告)日：1992-03-16
申请号：JP19708790
申请日：1990-07-25
申请人： MITSUBISHI YUKA BADISCHE
发明人： HAYASHI RYUTARO , KATO NAOYUKI , KATO YOSHINORI
IPC分类号： C08L33/04 , C08F2/44 , C08F8/30 , C08F283/00 , C08K5/24 , C09D5/02
摘要： PURPOSE:To obtain the title emulsion capable of providing a coating film having high transparency, water resistance and hardness by subjecting a carbonyl group-containing monomer, etc., to emulsion polymerization with a (meth)acrylic acid ester and comonomers and then blending a specific crosslinking agent therewith. CONSTITUTION:A water-dispersible liquid of a mixture obtained by mixing a vinyl monomer mixture consisting of (A) 1-20wt.% carbonyl group or aldehyde group-containing ethylenic unsaturated monomer, (B) 10-75wt.% methacrylic acid alkyl ester (alkyl group is 1-4C alkyl), (C) 10-55wt.% acrylic acid alkyl ester (alkyl group is 1-8C alkyl) and (D) 0-40wt.% other ethylenic unsaturated monomer at a ratio of 100-1000 pts.wt. is subjected to emulsion polymerization in the presence of 100 pts.wt. solid content of polyurethane resin and then the resultant polymer is blended with a crosslinking agent having >=2 hydrazide groups (-NH.NH2) to provide the aimed aqueous emulsion.

66. 发明专利

JPH0459645A THICKENING AGENT AND POLYMER CEMENT COMPOSITION CONTAINING THE SAME AGENT 失效
公开(公告)号：JPH0459645A
公开(公告)日：1992-02-26
申请号：JP16571790
申请日：1990-06-26
申请人： MITSUBISHI YUKA BADISCHE
发明人： ENDO KATSUAKI , KATO NAOYUKI
IPC分类号： C04B28/02 , C04B24/26
摘要： PURPOSE:To provide a thickening agent for polymer cement composition preventing coating material from running during coating and providing a coating film having excellent flexibility by constituting a specific acrylic acid alkyl ester-based copolymer as a main component. CONSTITUTION:(A) 40-90wt.% acrylic acid alkyl ester (e.g. butyl acrylate) obtained by reacting 3-8C aliphatic alcohol with acrylic acid, (B) 60-10wt.% (meth)acrylic acid and (C) 0-35wt.% other vinyl monomer (e.g. styrene) are subjected to emulsion polymerization. Then acid group of the prepared copolymer is partially or wholly neutralized to produce a water-soluble copolymer salt having

67. 发明专利

JPH045201A MITE-REPELLENT AQUEOUS RESIN EMULSION COMPOSITION 失效
公开(公告)号：JPH045201A
公开(公告)日：1992-01-09
申请号：JP10285390
申请日：1990-04-20
申请人： MITSUBISHI PETROCHEMICAL CO , MITSUBISHI YUKA BADISCHE
发明人： KATO NAOYUKI , TSUKAMOTO TAKEO , OSEGAKI KIMIHO , ONISHI AKIYOSHI
IPC分类号： A01N25/10 , A01N31/08 , A01N33/06 , A01N37/10
摘要： PURPOSE:To provide the subject composition capable of being readily and safely applied, exhibiting an excellent mite-repellent activity and having a long duration time of the activity after the application by emulsion-polymerizing in an aqueous solution a radically polymerizable unsaturated monomer containing a specific amount of a soluble mite-repellent. CONSTITUTION:100 pts. wt. of a radically polymerizable unsaturated monomer such as (meth)acrylate or styrene containing 2-30 pts. wt. of a mite-repellent selected from soluble compounds of the formula [X is H, OH; R is OH, 1-9C hydrocarbon (containing one or more hetero-atoms); R is H, 1-30C hydrocarbon radical 1-9C hydrocarbon group (containing one or more hetero-atoms)] such as phenyl salicylate, 2,5-dichloro-4-bromophenol and 2-phenylphenol in the presence of a suitable emulsifier and a polymerization initiator in an aqueous medium to prepare the objective composition. The composition is applied to various articles by a coating method, a spraying method, etc.

68. 发明专利

JPH0333147A AQUEOUS EMULSION COMPOSITION OF VINYLIDENE CHLORIDE RESIN 失效
公开(公告)号：JPH0333147A
公开(公告)日：1991-02-13
申请号：JP16797689
申请日：1989-06-29
申请人： MITSUBISHI YUKA BADISCHE
发明人： TSUKAMOTO TAKEO , KATO NAOYUKI
IPC分类号： C08L27/08 , C09D5/00 , C09D5/02 , C09D127/08 , D21H19/00
摘要： PURPOSE:To prepare an aq. emulsion compsn. of a vinylidene chloride resin giving a film excellent in the transparency and antiblocking, slip and gas-barrier properties by compounding an aq. emulsion of a vinylidene chloride resin with a specific aq. emulsion of a resin having a very small particle diameter in a specified compounding ratio. CONSTITUTION:An aq. emulsion (A) of a vinylidene chloride resin having a mean particle diameter of 0.05-0.3mum is compounded with an aq. emulsion (B) of a resin having a glass transition paint of 50-150 deg.C and a mean particle diameter of 0.01-0.06mum in such an amt. that the solid content of B is 0.02-2wt.% based on that of B. The mean particle diameter of B is always less than that of A. The resulting compsn. is useful for packaging Vienna sausages, tobaccos, snacks, etc., and for forming a gas-barrier film on a surface of paper.

69. 发明专利

JPH02283749A AQUEOUS RESIN DISPERSION COMPOSITION FOR FORMING ALKALI-SOLUBLE FILM 失效
公开(公告)号：JPH02283749A
公开(公告)日：1990-11-21
申请号：JP10422789
申请日：1989-04-24
申请人： MITSUBISHI YUKA BADISCHE
发明人： KATO NAOYUKI , AWATA TAKESHI
IPC分类号： C08L33/04 , C08L33/18 , C08L33/24 , C08L33/26 , C08L41/00 , C08L43/00 , C08L43/02 , C09D133/02 , C09D133/06 , C09D141/00 , C09D143/02 , C09D157/10
摘要： PURPOSE:To form a film with improved antiblocking properties, a good tranparency, and an excellent adhesion to an adherend by compounding in a specified rartio two aq. dispersions contg. different copolymers of an unsatd. acid with vinyl monomers, said copolymers having different glass transition temps. and particle diameters. CONSTITUTION:An aq. dispersion of a copolymer (A) having a Tg of -10 to +30 deg.C and particle diameters of 0.06-3mum, obtd. by the emulsion polymn. of 7-50wt.% unsatd. acid, pref, alpha,beta-unsatd. acid such as acrylic acid, with 93-50wt.% other vinyl monomers (e.g. a mixture of a hard segment component such as 2-ethylhexyl acrylate with a soft segment component such as vinyl acetate), is compounded with an aq. dispersion of a copolymer (B) having a Tg at least 30 deg.C higher than that of A and particle diameters of 0.01-0.5mum, obtd. by the emulsion polymn. of 0-50wt.% said unsatd. acid with 100-50wt.% said other vinyl monomers, in a solid content ratio of A to B satisfying the relationship of B/(A+B)=0.3-0.65 and A/(A+B)=0.7-0.35. Thus, an aq. alkali- soluble film-forming resin dispersion composition useful for a printing ink binder, etc., is prepd.

70. 发明专利

JPH02138400A PRODUCTION OF RECLAIMED LEATHER 失效
公开(公告)号：JPH02138400A
公开(公告)日：1990-05-28
申请号：JP29191688
申请日：1988-11-18
申请人： MITSUBISHI YUKA BADISCHE
发明人： KATO NAOYUKI , AWATA TAKESHI
IPC分类号： C14B7/04
摘要： PURPOSE:To obtain a reclaimed leather of excellent bending strength by making a sheet from a a slurry containing a waste split leather based on shavings of a chromium-tanned leather and a specified aqueous anionic resin emulsion. CONSTITUTION:100 pts.wt. mixture of 0.5-10wt.% unsaturated chloro or bromo monomer (a) (e.g., vinyl monochloroacetate) reactive with the protein of leather with 99.5-90wt.% other unsaturated monomers (b) (e.g., methyl methacrylate) is emulsion-polymerized in water in the presence of 0.5-5 pts.wt. anionic emulsifier (c) to obtain an anionic resin emulsion (B) of a copolymer of components (a) and (b) having a film-forming temperature of -10 to 80 deg.C. A slurry obtained by adding water to a waste split leather (A) based on shavings of chromium- tanned leather and adding 8-50 pts.wt. (in terms of the resin content) component B per 100 pts.wt. component to to the mixture is made into a reclaimed leather.

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