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61. 发明授权

US5216180A Microbicidal hydroxyethyl-cyclopropyl-azolyl derivatives 失效
标题翻译：杀微生物羟乙基 - 环丙基 - 唑基衍生物
公开(公告)号：US5216180A
公开(公告)日：1993-06-01
申请号：US786481
申请日：1991-11-01
申请人： Jurgen Scherkenbeck , Monika Frie , Klaus Stroech , Thomas Himmler , Georg-W. Ludwig , Wilhelm Brandes , Stefan Dutzmann
发明人： Jurgen Scherkenbeck , Monika Frie , Klaus Stroech , Thomas Himmler , Georg-W. Ludwig , Wilhelm Brandes , Stefan Dutzmann
IPC分类号： A01N43/50 , A01N43/653 , C07C33/44 , C07C33/50 , C07C45/74 , C07C49/577 , C07D303/22 , C07D307/46 , C07D333/16 , C07D407/06 , C07D407/14 , C07D409/06 , C07D409/14 , C07D521/00
CPC分类号： C07D303/22 , A01N43/50 , A01N43/653 , C07C33/44 , C07C33/50 , C07C45/74 , C07C49/577 , C07D231/12 , C07D233/56 , C07D249/08 , C07D307/46 , C07D333/16 , C07D407/06 , C07D407/14 , C07D409/06 , C07D409/14
摘要： A herbicidal hydroxyethyl-cyclopropyl-azolyl derivative of the formula ##STR1## in which R.sup.1 represents halogen, phenyl or the grouping --Z-R.sup.3, whereinZ represents oxygen, sulphur, SO or SO.sub.2 andR.sup.3 represents alkyl, phenyl or benzyl,R.sup.2 represents alkenyl, optionally substituted furyl, optionally substituted thienyl or the radical of the formula ##STR2## wherein R.sup.4 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy, 1,1,2-trifluoro-2-chloro-ethoxy, cyano, formyl, alkoximinoalkyl, carbalkoxy, dialkoxyalkyl, phenoxyalkyl which is optionally substituted in the phenyl moiety by halogen, or benzyloxy which is optionally substituted in the phenyl moiety by halogen andR.sup.5 represents hydrogen or halogen, orR.sup.4 and R.sup.5 are linked in the ortho-position and together represent --O--CH.sub.2 --O--, orR.sup.2 represents the radical of the formula ##STR3## in which R.sup.6 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy or 1,1,2-trifluoro-2-chloro-ethoxy, orR.sup.2 also represents phenyl which is optionally substituted by halogen and/or phenyl if Y represents the grouping ##STR4## X represents nitrogen or a CH group and Y represents the groupings --CH.sub.2 -CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C-- or ##STR5## or an acid or metal salt addition product thereof.
摘要翻译：式（I）的除草羟乙基 - 环丙基 - 唑基衍生物，其中R 1表示卤素，苯基或基团-Z-R 3，其中Z表示氧，硫，SO或SO 2，R 3表示烷基，苯基或苄基，R 2表示烯基，任选取代的呋喃基，任选取代的噻吩基或式的基团其中R 4表示二氟甲氧基，1,1,2,2-四氟乙氧基，1,1,2-三氟-2-氯乙氧基，氰基，甲酰基，肟基烷基，烷氧基，二烷氧基烷基，在苯基部分被卤素任意取代的苯氧基烷基，或在苯基部分被卤素任意取代的苄氧基，R5代表氢或卤素，或R4和R5连接在邻位并且一起表示-O-CH 2 -O-，或R 2表示式“IMAGE”的基团，其中R 6表示二氟甲氧基，1,1,2,2-四氟乙氧基或1,1,2-三氟-2- 氯乙氧基，或R2也表示任选取代的苯基如果Y表示分组，则由卤素和/或苯基发生。X表示氮或CH基，Y表示分组-CH 2 -CH 2 - ， - CH = CH - ， - C 3BOND C或或酸或金属盐加成产物。

62. 发明授权

US5128368A Pesticides based on substituted aminomethyl heterocyclic compounds 失效
标题翻译：基于取代氨基甲基杂环化合物的农药
公开(公告)号：US5128368A
公开(公告)日：1992-07-07
申请号：US595143
申请日：1990-10-10
申请人： Wolfgang Kramer , Joachim Weissmuller , Graham Holmwood , Dieter Berg , Stefan Dutzmann , Wilhelm Brandes , Gerd Hanssler , Paul Reinecke
发明人： Wolfgang Kramer , Joachim Weissmuller , Graham Holmwood , Dieter Berg , Stefan Dutzmann , Wilhelm Brandes , Gerd Hanssler , Paul Reinecke
IPC分类号： A01N43/08 , A01N43/28 , C07D307/14 , C07D307/22 , C07D317/28 , C07D327/04 , C07D407/12 , C07D417/12
CPC分类号： C07D407/12 , A01N43/08 , A01N43/28 , C07D307/14 , C07D317/28 , C07D327/04
摘要： Combatting fungi and bacteria with aminomethylheterocyclic compounds of the formula ##STR1## in which R.sup.1 represents hydrogen, alkyl, alkenyl, in each case optionally substituted tetrahydronaphthyl, decahydronaphthyl, cycloalkyl or cycloalkenyl, furthermore alkyl which is substituted by cycloalkyl, cycloalkenyl, cycloalkyloxy or cycloalkylthio, where the cyclic radicals may optionally be substituted, furthermore optionally substituted aryl, in addition alkyl which is substituted by aryl, aryloxy, arylthio, arylsulphinyl or arylsulphonyl, or alkenyl which is substituted by aryl, where the aryl radicals may in each case optionally be substituted;R.sup.2 represents hydrogen or methyl,R.sup.3 represents alkyl, alkenyl, alkinyl, alkoxyalkyl, hydroxyalkyl, hydroxyalkoxyalkyl, dialkoxyalkyl, or in each case optionally substituted cycloalkyl, cycloalkylalkyl, aryl, aralkyl, aralkenyl, furanylalkyl, tetrahydrofuranylalkyl, tetrahydropyranylalkyl, dioxolanylalkyl or dioxanylalkyl, andX represents oxygen, sulphur or a CH.sub.2 group,or acid addition salts thereof.Many of the compounds wherein R.sup.1 has a narrower meaning are new.
摘要翻译：用下式（Ⅰ）的氨基甲基杂环化合物与R1代表氢，烷基，烯基，各取代四氢萘基，十氢萘基，环烷基或环烯基，以及被环烷基，环烯基，环烷基或环烷硫基，其中环状基团可任选被取代，此外任选取代的芳基，另外被芳基，芳氧基，芳硫基，芳基亚磺酰基或芳基磺酰基取代的烷基或被芳基取代的烯基，其中芳基可以在每种情况下任选被取代; R 2表示氢或甲基，R 3表示烷基，烯基，炔基，烷氧基烷基，羟基烷基，羟基烷氧基烷基，二烷氧基烷基，或在每种情况下任选取代的环烷基，环烷基烷基，芳基，芳烷基，芳烯基，呋喃基烷基，四氢呋喃基烷基，四氢吡喃基烷基，二氧戊环烷基或二烷基烷基，X 代表氧，硫或CH2基，或其酸加成盐。其中R1具有较窄含义的许多化合物是新的。

63. 发明授权

US5096912A Microbicidal hydroxyethyl-cyclopropyl-azolyl derivatives 失效
标题翻译：微生物羟丙基 - 环丙基 - 氨基醇衍生物
公开(公告)号：US5096912A
公开(公告)日：1992-03-17
申请号：US535266
申请日：1990-06-08
申请人： Jurgen Scherkenbeck , Monika Frie , Klaus Stroech , Thomas Himmler , Georg-W. Ludwig , Wilhelm Brandes , Stefan Dutzmann
发明人： Jurgen Scherkenbeck , Monika Frie , Klaus Stroech , Thomas Himmler , Georg-W. Ludwig , Wilhelm Brandes , Stefan Dutzmann
IPC分类号： A01N43/50 , A01N43/653 , C07C33/44 , C07C33/50 , C07C45/74 , C07C49/577 , C07D233/60 , C07D249/08 , C07D303/22 , C07D307/46 , C07D333/16 , C07D405/06 , C07D407/06 , C07D407/14 , C07D409/06 , C07D409/14 , C07D521/00
CPC分类号： C07D303/22 , A01N43/50 , A01N43/653 , C07C33/44 , C07C33/50 , C07C45/74 , C07C49/577 , C07D231/12 , C07D233/56 , C07D249/08 , C07D307/46 , C07D333/16 , C07D407/06 , C07D407/14 , C07D409/06 , C07D409/14
摘要： A microbicidal hydroxyethyl-cyclopropyl-azolyl derivative of the formula ##STR1## in which R.sup.1 represents halogen, phenyl or the grouping --Z--R.sup.3, whereinZ represents oxygen, sulphur, SO or SO.sub.2 andR.sup.3 represents alkyl, phenyl or benzyl,R.sup.2 represents alkenyl, optionally substituted furyl, optionally substituted thienyl or the radical of the formula ##STR2## wherein R.sup.4 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy, 1,1,2-trifluoro-2-chloro-ethoxy, cyano, formyl, alkoximinoalkyl, carbalkoxy, dialkoxyalkyl, phenoxyalkyl which is optionally substituted in the phenyl moiety by halogen, or benzyloxy which is optionally substituted in the phenyl moiety by halogen andR.sup.5 represents hydrogen or halogen, orR.sup.4 and R.sup.5 are linked in the ortho-position and together represent --O--CH.sub.2 --O--, orR.sup.2 represents the radical of the formula ##STR3## in which R.sup.6 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy or 1,1,2-trifluoro-2-chloro-ethoxy, orR.sup.2 also represents phenyl which is optionally substituted by halogen and/or phenyl if Y represents the grouping ##STR4## X represents nitrogen or a CH group and Y represents the groupings --CH.sub.2 --CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C--or ##STR5## or an acid or metal salt addition product thereof.
摘要翻译：式（I）的杀微生物羟乙基 - 环丙基 - 唑基衍生物，其中R 1表示卤素，苯基或基团-Z-R 3，其中Z表示氧，硫，SO或SO 2，R 3表示烷基，苯基或苄基，R 2表示烯基，任选取代的呋喃基，任选取代的噻吩基或式的基团其中R 4表示二氟甲氧基，1,1,2,2-四氟乙氧基，1,1,2-三氟-2-氯乙氧基，氰基，甲酰基，肟基烷基，烷氧基，二烷氧基烷基，在苯基部分被卤素任意取代的苯氧基烷基，或在苯基部分被卤素任意取代的苄氧基，R5代表氢或卤素，或R4和R5连接在邻位并且一起表示-O-CH 2 -O-，或R 2表示式“IMAGE”的基团，其中R 6表示二氟甲氧基，1,1,2,2-四氟乙氧基或1,1,2-三氟-2- 氯乙氧基或R2也表示任选被取代的苯基如果Y表示分组，则由卤素和/或苯基引发。X表示氮或CH基，Y表示分组-CH 2 -CH 2 - ， - CH = CH - ， - C 3BOND C - 或或酸或金属盐加成产物。

64. 发明授权

US5081265A Microbicidal substituted dioxolanes 失效
标题翻译：微生物取代的二氧化物
公开(公告)号：US5081265A
公开(公告)日：1992-01-14
申请号：US582581
申请日：1990-09-14
申请人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
发明人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
IPC分类号： C07D317/26 , A01N43/50 , A01N43/653 , C07C45/00 , C07C45/75 , C07C49/245 , C07C49/255 , C07C49/84 , C07C67/00 , C07C323/22 , C07C323/65 , C07D405/00 , C07D407/04 , C07D409/14 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Fungicidal dioxolanes of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkinyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl, optionally substituted aryl, optionally substituted aryloxy, optionally substituted arylthio, optionally substituted arylsulphinyl, optionally substituted arylsulphonyl, optionally substituted arylalkyl, optionally substituted aryloxyalkyl, optionally substituted arylthioalkyl, optionally substituted arylsulphinylalkyl, optionally substituted arylsulphonylalkyl, optionally substituted aralkyloxyalkyl, optionally substituted aralkylthioalkyl, optionally substituted aralkylsulphinylalkyl or optionally substituted aralkylsulphonylalkyl,R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another represent hydrogen, alkyl or cycloalkyl, orR.sup.3 and R.sup.4 together represent divalent alkanediyl and/orR.sup.5 and R.sup.6 together represent divalent alkanediyl andA represents nitrogen or a CH group,and addition products thereof with acids and metal salts. Also novel intermediates of the formulas ##STR2##

65. 发明授权

US5079374A Fungicidal and plant growth-regulating hydroxyalkyl-azolyl derivatives 失效
标题翻译：杀菌剂和植物生长调节性羟基喹啉衍生物
公开(公告)号：US5079374A
公开(公告)日：1992-01-07
申请号：US464510
申请日：1990-01-12
申请人： Klaus Stroech , Monika Frie , Thomas Himmler , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
发明人： Klaus Stroech , Monika Frie , Thomas Himmler , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
IPC分类号： A01N31/04 , A01N31/14 , A01N43/32 , A01N43/50 , A01N43/653 , C07C33/50 , C07C45/62 , C07C45/74 , C07C49/163 , C07C49/225 , C07C49/237 , C07C49/293 , C07C49/327 , C07C49/457 , C07C49/467 , C07C49/533 , C07C49/563 , C07C49/567 , C07C49/657 , C07C49/687 , C07C49/693 , C07C49/753 , C07C317/24 , C07C323/22 , C07D20060101 , C07D233/60 , C07D233/61 , C07D249/08 , C07D303/08 , C07D303/22 , C07D303/34 , C07D319/16 , C07D319/18 , C07D319/20 , C07D405/06 , C07D407/06 , C07D521/00
CPC分类号： C07D303/22 , A01N43/653 , C07C321/00 , C07C33/50 , C07C45/62 , C07C45/74 , C07C49/457 , C07C49/467 , C07C49/567 , C07C49/657 , C07C49/687 , C07C49/693 , C07C49/753 , C07D231/12 , C07D233/56 , C07D249/08 , C07D303/08 , C07D303/34 , C07D407/06
摘要： Fungicidal and plant growth-regulating hydroxyalkyl-azolyl derivatives of the formula ##STR1## in which R represents hydrogen, alkyl or acyl,R.sup.1 represents halogen, optionally substituted phenyl or the grouping --z--R.sup.3, whereinz represents oxygen, sulphur, SO or SO.sub.2 andR.sup.3 represents optionally substituted alkyl, optionally substituted phenyl or optionally substituted phenylalkyl,R.sup.2 represents optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted naphthyl or the radical of the formula ##STR2## m represents the numbers 0, 1, 2 or 3, or R.sup.2 represents the radical or the formula ##STR3## X represents nitrogen or a CH group and Y represents the groupings --CH.sub.2 --CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C--, ##STR4## and their addition products with acids and metal salts. Intermediates of the formulas ##STR5## are also new.

66. 发明授权

US5047415A 2,2-dihalogenocyclopropyl-hydroxy-ethyltriazoles 失效
标题翻译： 2,2-二卤代环丙基 - 羟基 - 乙基三唑
公开(公告)号：US5047415A
公开(公告)日：1991-09-10
申请号：US378730
申请日：1989-07-12
申请人： Udo Kraatz , Graham Holmwood , Karl-Rudolf Gassen , Stefan Dutzmann , Wilhelm Brandes
发明人： Udo Kraatz , Graham Holmwood , Karl-Rudolf Gassen , Stefan Dutzmann , Wilhelm Brandes
IPC分类号： A01N43/653 , C07C45/45 , C07C45/62 , C07C45/63 , C07C45/71 , C07C45/74 , C07C49/327 , C07C49/567 , C07C49/577 , C07D249/08 , C07D303/08 , C07D303/22 , C07D303/34 , C07D521/00
CPC分类号： C07D303/22 , A01N43/653 , C07C45/45 , C07C45/62 , C07C45/63 , C07C45/71 , C07C45/74 , C07C49/327 , C07C49/567 , C07C49/577 , C07D231/12 , C07D233/56 , C07D249/08 , C07D303/08 , C07D303/34
摘要： Novel 2,2-dihalogenocyclopropyl-hydroxy-ethyltriazoles of the formula ##STR1## in which Ar represents optionally substituted aryl,R represents alkyl, optionally substituted aryl or optionally substituted aralkyl,X.sup.1 represents halogen,X.sup.2 represents halogen and p0 Y represents the groups --OCH.sub.2 --, --SCH.sub.2 --, --CH.sub.2 CH.sub.2 -- or --CH.dbd.CH--, where the hetero atom is linked to the aryl radical when Y represents --OCH.sub.2 -- or --SCH.sub.2 --,and acid addition salts or metal salt complexes thereof, are fungicidally active.
摘要翻译：式（I）的新型2,2-二卤代环丙基 - 羟基 - 乙基三唑，其中Ar表示任选取代的芳基，R表示烷基，任选取代的芳基或任选取代的芳烷基，X 1表示卤素，X 2表示卤素，p O Y表示基团-OCH 2 - ， - CH 2 - ， - CH 2 CH 2 - 或-CH = CH-，其中当Y表示-OCH 2 - 或-SCH 2 - 时，杂原子与芳基连接，及其酸加成盐或金属盐络合物，是杀真菌活性的。

67. 发明授权

US5010101A Pesticidal aminomethylheterocyclic compounds 失效
标题翻译：杀虫氨基甲基杂环化合物
公开(公告)号：US5010101A
公开(公告)日：1991-04-23
申请号：US395391
申请日：1989-08-17
申请人： Wolfgang Kramer , Joachim Weissmuller , Dieter Berg , Wilhelm Brandes , Stefan Dutzmann
发明人： Wolfgang Kramer , Joachim Weissmuller , Dieter Berg , Wilhelm Brandes , Stefan Dutzmann
IPC分类号： A01N43/28 , A01N43/30 , A01N43/36 , A01N43/40 , A01N43/46 , A01N43/84 , C07D317/72 , C07D327/04 , C07D411/12
CPC分类号： C07D317/72 , A01N43/28 , A01N43/30 , C07D327/04 , C07D411/12
摘要： Fungicidally active compounds of the formula ##STR1## in which X represents oxygen or sulphur,R represents cycloalkyl, or represents optionally substituted aryl, or represents the radical ##STR2## R.sup.1 and R.sup.2 each independently is hydrogen or an organic radical, or together with the nitrogen atom form a heterocyclic radical,R.sup.3 represents hydrogen, alkyl or optionally substituted aryl, andR.sup.4 represents alkyl or cycloalkyl, or represents optionally substituted aryl,but wherein R.sup.3 and R.sup.4 may not simultaneously represent methyl,and acid addition salts thereof, as well as intermediates therefor.
摘要翻译：式（I）的杀真菌活性化合物，其中X表示氧或硫，R表示环烷基，或表示任选取代的芳基，或表示基团R 1和R 2各自独立地为氢或有机基团，或与氮原子一起形成杂环基，R 3表示氢，烷基或任选取代的芳基，R 4表示烷基或环烷基，或表示任选取代的芳基，但其中R 3和R 4可不同时表示甲基，及其酸加成盐，以及其中间体。

68. 发明授权

US4988715A Microbicidal substituted dioxolanes 失效
标题翻译：杀菌剂取代二氧戊环
公开(公告)号：US4988715A
公开(公告)日：1991-01-29
申请号：US389032
申请日：1989-08-03
申请人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
发明人： Hans-Ludwig Elbe , Eckart Kranz , Wilhelm Brandes , Stefan Dutzmann , Gerd Hanssler
IPC分类号： C07D317/26 , A01N43/50 , A01N43/653 , C07C45/00 , C07C45/75 , C07C49/245 , C07C49/255 , C07C49/84 , C07C67/00 , C07C323/22 , C07C323/65 , C07D405/00 , C07D407/04 , C07D409/14 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , C07D233/56 , C07D249/08
摘要： Fungicidal dioxolanes of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, or other radicalsR.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another represent hydrogen, alkyl or cycloalkyl, orR.sup.3 and R.sup.4 together represent divalent alkanediyl and/orR.sup.5 and R.sup.6 together represent divalent alkanediyl andA represents nitrogen or a CH group,and addition products thereof with acids and metal salts. Also novel intermediates of the formulas ##STR2##
摘要翻译：其中R 1表示任选取代的烷基或其它基团R 2，R 3，R 4，R 5和R 6彼此独立地表示的式（I）的杀真菌二氧戊环代表氢，烷基或环烷基，或者R 3和R 4一起代表二价烷二基和/或R 5和R 6一起表示二价烷二基，A表示氮或CH基，并且其与酸和金属盐的加成产物。（VIa）（VIIa）（VIIa）（VIIa）（VIIa）（VIIa）中的新颖的中间体

69. 发明授权

US4988383A Fungicidal and plant growth-regulating cyclopropyl-hydroxyethyl-azolyl-derivatives 失效
标题翻译：杀真菌和植物生长调节环丙基 - 羟乙基 - 唑基衍生物
公开(公告)号：US4988383A
公开(公告)日：1991-01-29
申请号：US475640
申请日：1990-02-06
申请人： Gerhard Jager , Udo Kraatz , Stefan Dutzmann , Wilhelm Brandes , Gerd Hanssler
发明人： Gerhard Jager , Udo Kraatz , Stefan Dutzmann , Wilhelm Brandes , Gerd Hanssler
IPC分类号： A01N43/653 , C07D249/08 , C07D303/20 , C07D303/22 , C07D303/24 , C07D303/34 , C07D303/40 , C07D521/00
CPC分类号： C07D303/22 , A01N43/653 , C07D231/12 , C07D233/56 , C07D249/08 , C07D303/24 , C07D303/40
摘要： Fungicidal and plant growth-regulating cyclopropyl-hydroxyethyl-azolyl-derivatives of the formula ##STR1## in which R.sup.1 represents halogen, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, alkylthio having 1 to 4 carbon atoms, halogenoalkyl having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenalkoxy having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkylthio having 1 or 2 carbon atoms and 1 to 5 halogen atoms, alkoximinomethyl having 1 to 4 carbon atoms in the alkoxy group, phenyl optionally substituted by alkyl having 1 to 2 carbon atoms and/or halogen or phenoxy optionally substituted by alkyl having 1 or 2 carbon atoms and/or halogen,m represents the numbers 0, 1, 2 or 3,R.sup.2 represents optionally substituted benzyl or the radical --COOR.sup.3, in whichR.sup.3 represents alkyl, optionally substituted phenyl or optionally substituted benzyl,andY represents oxygen or sulphur,and their acid addition salts and metal salt complexes.
摘要翻译： R 1表示卤素，具有1至4个碳原子的烷基，具有1至4个碳原子的烷氧基的杀真菌剂和植物生长调节的环丙基 - 羟乙基 - 唑基衍生物，其中R 1表示卤素，具有1至4个碳原子的烷硫基原子，具有1或2个碳原子和1至5个卤素原子的卤代烷基，具有1或2个碳原子和1至5个卤素原子的卤代烷氧基，具有1或2个碳原子的卤代烷硫基和1至5个卤素原子，具有1至4个碳原子的烷氧基甲基烷氧基中的原子，任选被具有1至2个碳原子的烷基取代的苯基和/或任选被具有1或2个碳原子的烷基和/或卤素取代的卤素或苯氧基，m表示数字0,1,2或3， R 2表示任选取代的苄基或基团-COOR 3，其中R 3表示烷基，任选取代的苯基或任选取代的苄基，Y表示氧或硫，以及它们的酸加成盐和金属盐络合物。

70. 发明授权

US4968712A Fungicidal 1,4-disubstituted 1-azolyl-3,3-dimethylbutane derivatives 失效
标题翻译：杀真菌剂1,4-二取代的1-噻唑基-3,3-二甲基丁烷衍生物
公开(公告)号：US4968712A
公开(公告)日：1990-11-06
申请号：US225971
申请日：1988-07-29
申请人： Hans-Ludwig Elbe , Albrecht Marhold , Karl H. Buchel , Stefan Dutzmann , Paul Reinecke , Wilhelm Brandes , Gerhard Hanssler
发明人： Hans-Ludwig Elbe , Albrecht Marhold , Karl H. Buchel , Stefan Dutzmann , Paul Reinecke , Wilhelm Brandes , Gerhard Hanssler
IPC分类号： A01N43/653 , A01N47/02 , C07D233/60 , C07D249/08 , C07D405/10 , C07D521/00
CPC分类号： C07D231/12 , A01N43/653 , A01N47/02 , C07D233/56 , C07D249/08
摘要： Fungicidal 1,4-disubstituted 1-azolyl-3,3-dimethylbutane derivatives of the formula ##STR1## in which R.sup.1 represents hydrogen or halogen,R.sup.2 represents hydrogen or halogen,R.sup.3 represents hydrogen, halogen or trifluoromethoxy,R.sup.4 represents halogen, trifluoromethoxy, trifluoromethylthio, trifluoromethylsulphinyl, trifluoromethylsulphonyl, difluoromethoxy, difluorochloromethoxy, trifluorochloroethoxy, tetrafluoroethoxy, trifluoroethoxy, difluoromethylthio, trifluorochloroethylthio, tetrafuoroethylthio, difluoromethylsulphinyl, difluorochloromethylsulphinyl, trifluorochloroethylsulphinyl, tetrafluoroethylsulphinyl, difluoromethylsulphonyl, difluorochloromethylsulphonyl, trifluorochloroethylsulphonyl, tetrafluoroethylsulphonyl, difluorobromomethylthio, difluorobromomethylsulphinyl, difluorobromomethylsulphonyl or difluorochloromethylthio orR.sup.3 and R.sup.4 together represent alkylenedioxy substituted by halogen,R.sup.5 represents hydrogen or halogen,A represents a keto group or a CH(OH) grouping,Z represents a nitrogen atom or the CH group andR.sup.6 and R.sup.7 identical or different and independently of one another represent hydrogen, alkyl, alkenyl, alkynyl, optionally substituted cycloalkyl, optionally substituted cycloalkylalkyl or optionally substituted phenylalkyl, whereR.sup.3 represents trifluoromethoxy whenR.sup.4 represents halogen,and addition products thereof with acids and metal salts.
摘要翻译：式（I）的杀真菌的1,4-二取代的1-吡唑基-3,3-二甲基丁烷衍生物，其中R 1表示氢或卤素，R 2表示氢或卤素，R 3表示氢，卤素或三氟甲氧基，R 4表示卤素三氟甲氧基，三氟甲硫基，三氟甲磺酰基，三氟甲磺酰基，二氟甲氧基，二氟氯甲氧基，三氟氯乙氧基，四氟乙氧基，三氟乙氧基，二氟甲硫基，三氟氯乙硫基，四氟乙基硫代，和R4一起代表被卤素取代的亚烷基二氧基，R 5代表氢或卤素，A代表酮基或CH（OH） Z表示氮原子或CH基团，R 6和R 7相同或不同且彼此独立地表示氢，烷基，烯基，炔基，任选取代的环烷基，任选取代的环烷基烷基或任选取代的苯基烷基，其中当R 4表示卤素时，R 3表示三氟甲氧基，及其与酸和金属盐的加成产物。

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