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    • 62. 发明授权
    • Organic low K dielectric etch with NH3 chemistry
    • 有机低K电介质蚀刻与NH3化学
    • US06743732B1
    • 2004-06-01
    • US09769812
    • 2001-01-26
    • Li-Te LinLi-Chih ChaoChia-Shiung Tsai
    • Li-Te LinLi-Chih ChaoChia-Shiung Tsai
    • H01L21302
    • H01L21/76811H01L21/31116H01L21/31138H01L21/76802H01L21/76813
    • A plasma etch process for organic low-k dielectric layers using NH3 only, or NH3/H2 or NH3/H2 gases. A low k dielectric layer is formed over a substrate. A masking pattern is formed over the low k dielectric layer. The masking pattern has an opening. Using the invention's etch process, the low k dielectric layer is etched through the opening using the masking pattern as an etch mask. In a first embodiment, the etch process comprises: etching the low k dielectric layer by applying a plasma power and flowing only NH3 gas. In a second embodiment, the etch process comprises: etching the low k dielectric layer by applying a plasma power and flowing only NH3/H2 gas. In a third embodiment, the etch process comprises: etching the low k dielectric layer by applying a plasma power and flowing only NH3/N2 gas. The invention's NH3 containing plasma etch etches organic Low k materials unexpectedly fast. The invention's NH3 only etch had a 30 to 80% high etch rate than N2/H2 etches of low-k materials like Silk™.
    • 仅使用NH3或NH3 / H2或NH3 / H2气体的有机低k电介质层的等离子体蚀刻工艺。 在衬底上形成低k电介质层。 在低k电介质层上形成掩模图案。 掩模图案具有开口。 使用本发明的蚀刻工艺,使用掩模图案作为蚀刻掩模,通过开口蚀刻低k电介质层。 在第一实施例中,蚀刻工艺包括:通过施加等离子体功率并仅流过NH 3气体来蚀刻低k电介质层。 在第二实施例中,蚀刻工艺包括:通过施加等离子体功率并仅流过NH 3 / H 2气体来蚀刻低k电介质层。 在第三实施例中,蚀刻工艺包括:通过施加等离子体功率并仅流过NH 3 / N 2气体来蚀刻低k电介质层。 本发明的含NH 3的等离子体蚀刻意外地快速蚀刻有机低k材料。 本发明的仅NH3蚀刻具有比Silk TM的低k材料的N 2 / H 2蚀刻高30至80%的高蚀刻速率。
    • 63. 发明授权
    • Method of fabricating a DRAM device featuring alternate fin type capacitor structures
    • 制造具有交替鳍式电容器结构的DRAM器件的方法
    • US06624018B1
    • 2003-09-23
    • US09839965
    • 2001-04-23
    • Chih-Hsing YuChih-Yang PaiChia-Shiung Tsai
    • Chih-Hsing YuChih-Yang PaiChia-Shiung Tsai
    • H01L218242
    • H01L28/87H01L27/0207H01L27/10817H01L27/10852
    • A process for fabricating an alternate fin type capacitor structure, used to increase capacitor surface area has been developed. The process features the formation of fin shaped, storage node structures, located in fin type capacitor openings, which are in turn defined in a group of composite insulator layers. A first fin type capacitor opening is formed by selectively creating lateral recesses in first type insulator layers, exposed in a first capacitor opening in the composite insulator layers, while an adjacent, second fin type capacitor opening is formed by selectively creating lateral recesses in second type insulator components, exposed in a second capacitor opening located in the same composite insulator layers. Portions of the lateral recesses in the first and second fin type capacitor openings overlay, allowing intertwined or alternate, storage node structures to be realized, thus reducing the space needed for the capacitor structure. The horizontal features of the fin shaped storage node structure, located in the lateral recesses, result in increased capacitor surface area when compared to counterparts fabricated without the lateral recess component.
    • 已经开发了用于制造用于增加电容器表面积的替代鳍式电容器结构的工艺。 该方法的特征在于形成翅片形状的存储节点结构,其位于翅片式电容器开口中,其又限定在一组复合绝缘体层中。 第一鳍型电容器开口通过选择性地产生在第一类型绝缘体层中形成的横向凹槽而形成,暴露在复合绝缘体层中的第一电容器开口中,而相邻的第二鳍状电容器开口通过选择性地产生第二类型的横向凹槽而形成 绝缘体部件,暴露在位于同一复合绝缘体层中的第二电容器开口中。 第一和第二鳍式电容器开口中的横向凹部的部分覆盖,允许实现相互缠绕或交替的存储节点结构,从而减少电容器结构所需的空间。 与没有横向凹槽部件的制造商相比,位于横向凹槽中的翅片形储存结构的水平特征导致增加的电容器表面积。
    • 64. 发明授权
    • Method to form dual damascene structure
    • 形成双镶嵌结构的方法
    • US06579791B1
    • 2003-06-17
    • US10074909
    • 2002-02-12
    • Yeur Luen TuChia-Shiung TsaiMin-Hwa Chi
    • Yeur Luen TuChia-Shiung TsaiMin-Hwa Chi
    • H01L214763
    • H01L21/76808
    • A method of fabricating a dual damascene opening, comprising the following sequential steps. A structure having a stop layer formed over a second low-k material layer formed over a stop layer formed over a first low-k material layer is provided. These layers are etched to form a via opening exposing a portion of the structure. A photoresist layer is formed over the second low-k material layer stop layer and filling the via opening. The photoresist layer having a treated upper portion including a central trench pattern area that is wider than, and substantially centered over, the via opening. The treated upper portion of the photoresist layer preventing any effects to the underlying photoresist layer so that the underlying photoresist layer does not deleteriously interact with the first or second low-k material layer. Removing: (1) the central trench pattern area of the upper treated portion of the photoresist and the photoresist under the central trench pattern area a to form a trench pattern opening exposing a portion of the second low-k material layer stop layer under the removed central trench pattern area; and (2) the photoresist layer within the via opening while leaving a portion of the photoresist layer within the via opening overlying the portion of the structure that was exposed by the via opening. Transferring the trench pattern opening to the second low-k material layer stop layer and the second low-k material layer to form a trench substantially centered over the remaining via opening and completing the dual damascene opening.
    • 一种制造双镶嵌开口的方法,包括以下顺序步骤。 提供一种具有形成在形成在第一低k材料层上形成的停止层上的第二低k材料层上的停止层的结构。 蚀刻这些层以形成露出结构的一部分的通孔。 在第二低k材料层停止层上形成光致抗蚀剂层并填充通孔。 光致抗蚀剂层具有经处理的上部,其包括中心沟槽图案区域,该中心沟槽图案区域比通孔开口宽,并且基本上居中。 光致抗蚀剂层的经处理的上部防止对下面的光致抗蚀剂层的任何影响,使得下面的光致抗蚀剂层不会与第一或第二低k材料层有害地相互作用。 去除:(1)光致抗蚀剂的上部处理部分的中心沟槽图案区域和在中心沟槽图案区域a下方的光致抗蚀剂,以形成沟槽图形开口,暴露出被去除的第二低k材料层停止层的一部分 中央沟槽图案区; 和(2)通孔开口内的光致抗蚀剂层,同时留下通孔开口内的一部分光致抗蚀剂层,覆盖由通孔开口暴露的结构部分。 将沟槽图案开口转移到第二低k材料层停止层和第二低k材料层,以形成基本上位于剩余通孔开口上方的沟槽,并完成双镶嵌开口。
    • 67. 发明授权
    • Process for improving copper fill integrity
    • 改善铜填充完整性的工艺
    • US06383943B1
    • 2002-05-07
    • US09687160
    • 2000-10-16
    • Chao-Cheng ChenJen-Cheng LiuJyu-Horng ShiehChia-Shiung TsaiBor-Shyang Lin
    • Chao-Cheng ChenJen-Cheng LiuJyu-Horng ShiehChia-Shiung TsaiBor-Shyang Lin
    • H01L21302
    • H01L21/76843H01L21/3105H01L21/76802H01L21/76814H01L21/76826H01L21/76829
    • A method for eliminating the problems associated with the discontinuous deposition of the glue layer at the bottom of the via resulting from the notch in the silicon nitride etch stop layer. First conductive layer traces are patterned and a silicon nitride (SiN) etch stop layer is provided overlying the first conductive layer. An inter-metal dielectric (IMD) layer then overlies the entire surface. An anisotropic etch is performed leaving via holes in the IMD layer. This is followed by a second anisotropic etch step to remove the etch stop layer not protected by the IMD layer resulting in the formation a notch at the bottom of the via hole. An important step of the present invention is the elimination of this notch accomplished by nitridizing the surface of the IMD layer. A wet polymer cleaning is performed to remove the nitridized IMD surface and eliminating the notch. A glue layer is conformally applied lining the via hole. A second conductive layer is then deposited and the surface is planarized.
    • 一种用于消除与在氮化硅蚀刻停止层中由凹口产生的通孔底部的胶层不连续沉积相关的问题的方法。 图案化第一导电层迹线,并且覆盖第一导电层提供氮化硅(SiN)蚀刻停止层。 金属间电介质(IMD)层然后覆盖整个表面。 进行各向异性蚀刻,留下IMD层中的通孔。 然后进行第二个各向异性蚀刻步骤以去除不被IMD层保护的蚀刻停止层,从而在通孔的底部形成切口。 本发明的重要步骤是消除通过使IMD层的表面氮化而实现的这个缺口。 执行湿式聚合物清洁以除去氮化的IMD表面并消除凹口。 粘合层适用于衬套通孔。 然后沉积第二导电层并且将表面平坦化。
    • 68. 发明授权
    • Method of fabricating a metal-insulator-metal (MIM), capacitor structure using a damascene process
    • 金属绝缘体金属(MIM)的制造方法,使用镶嵌工艺的电容器结构
    • US06271084B1
    • 2001-08-07
    • US09759912
    • 2001-01-16
    • Yeur-Luen TuChia-Shiung TsaiMin-Hwa Chi
    • Yeur-Luen TuChia-Shiung TsaiMin-Hwa Chi
    • H01L218242
    • H01L28/82H01L21/76838H01L21/76895H01L27/10855H01L27/10894H01L28/55H01L28/60
    • A process for forming a vertical, metal-insulator-metal (MIM), capacitor structure, for embedded DRAM devices, using a damascene procedure, has been developed. The process features forming a capacitor opening in a composite insulator layer comprised of a overlying insulator stop layer, a low k insulator layer, and an underlying insulator stop layer, with a lateral recess isotropically formed in the low k insulator layer. After formation of a bottom electrode structure in the capacitor opening, a high k insulator layer is deposited followed by the deposition of a conductive layer, completely filling the capacitor opening. A chemical mechanical polishing procedure is then used to remove portions of the conductive layer, and portions of the high k insulator layer, from the top surface of the overlying insulator stop layer, resulting in the formation of the vertical MIM capacitor structure, in the capacitor opening, comprised of: a top electrode structure, defined from the conductive layer; a capacitor dielectric layer, formed from the high k insulator layer; and a bottom electrode structure.
    • 已经开发了使用镶嵌程序形成用于嵌入式DRAM器件的垂直金属 - 绝缘体金属(MIM),电容器结构的工艺。 该工艺的特征是在复合绝缘层中形成电容器开口,该复合绝缘层由上覆的绝缘体停止层,低k绝缘体层和下面的绝缘体阻挡层组成,在低k绝缘体层中各向同性地形成有横向凹槽。 在电容器开口中形成底部电极结构之后,沉积高k绝缘体层,随后沉积导电层,完全填充电容器开口。 然后使用化学机械抛光方法从上覆绝缘体停止层的顶表面去除导电层的部分和高k绝缘体层的部分,从而在电容器中形成垂直MIM电容器结构 开口,包括:由导电层限定的顶部电极结构; 由高k绝缘体层形成的电容器电介质层; 和底部电极结构。
    • 70. 发明授权
    • PE-SiN spacer profile for C2 SAC isolation window
    • 用于C2 SAC隔离窗的PE-SiN间隔件
    • US06225203B1
    • 2001-05-01
    • US09304334
    • 1999-05-03
    • Jen-Cheng LiuJen-Shiang LeuChia-Shiung Tsai
    • Jen-Cheng LiuJen-Shiang LeuChia-Shiung Tsai
    • H01L21302
    • H01L27/10855H01L21/31116H01L21/3185H01L21/76897H01L27/10814H01L27/10885
    • A method of forming a PE-CVD silicon nitride spacer having a good profile in the fabrication of a self-aligned contact wherein a two-step etching process forms the spacer is described. Semiconductor device structures are formed on a semiconductor substrate. A layer of silicon nitride is deposited by plasma-enhanced chemical vapor deposition over the surface of the substrate and overlying the semiconductor device structures. The silicon nitride layer is etched away using a two-step etching process to leave silicon nitride spacers on the side surfaces of the semiconductor device structures. The two-step process comprises a first etching away of 70% of the silicon nitride layer using Cl2/He chemistry and a second etching away of the remaining silicon nitride on top surface of the semiconductor device strucutures using SF6/CHF3/He chemistry.
    • 描述了在制造自对准接触中具有良好外形的PE-CVD氮化硅间隔物的方法,其中两步蚀刻工艺形成间隔物。 半导体器件结构形成在半导体衬底上。 通过等离子体增强化学气相沉积在衬底的表面上并覆盖半导体器件结构来沉积氮化硅层。 使用两步蚀刻工艺蚀刻掉氮化硅层,以在半导体器件结构的侧表面上留下氮化硅间隔物。 两步法包括使用Cl2 / He化学法首先蚀刻掉70%的氮化硅层,并且使用SF6 / CHF3 / He化学法在半导体器件结构的顶表面上第二次蚀刻剩余的氮化硅。