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    • 54. 发明专利
    • FR950281A
    • 1949-09-22
    • FR950281D
    • 1946-08-28
    • KODAK PATHE
    • G03C5/32
    • 586,782. Intensifying photographic latent images. KODAK, Ltd. (Eastman Kodak Co., Weyerts, W. J., and Wiederhold, C. W.). Nov. 8, 1944, No. 21984. Addition to 570,703. [Class 98 (ii)] Intensification of a latent image in an exposed gelatino silver halide emulsion layer is produced by treatment of the layer subsequent to the exposure but prior to development with a solution containing sulphurous acid but free of developing agent, by removal uniformly of the unabsorbed solution without removal of the absorbed solution, and by storing the layer in air allowed to circulate freely over it for at least five minutes. A solution of sulphurous acid, sodium bisulphite, or potassium metabisulphite may be used, and should have a pH below 6. The colour sensitivity of the emulsion is not removed. The excess liquid may be removed by an air squeegee or wiping. The air may be allowed to circulate for 10 to 20 minutes. The sulphurous acid bath should not contain developing agents acting as antioxidants such as hydroquinone or iso-ascorbic acid. In examples, comparative figures are given for the speed, gamma and density of support plus fog, using a metol-hydroquinoneboric acid-borax developer with pre-treatments in distilled water, sodium bisulphite solution and potassium metabisulphite solution. Intensification of the latent image by exposure to ammonia vapour, by exposure to the radiation of a safelight, by subjection to the action of heat and humidity and by treatment with sulphur dioxide is referred to. Specification 510,808 is referred to.
    • 55. 发明专利
    • Improvements relating to photographic materials
    • GB586782A
    • 1947-03-31
    • GB2198444
    • 1944-11-08
    • EASTMAN KODAK COWALTER JOHN WEYERTSCHARLES WALTER WIEDERHOLD
    • G03C5/32
    • 586,782. Intensifying photographic latent images. KODAK, Ltd. (Eastman Kodak Co., Weyerts, W. J., and Wiederhold, C. W.). Nov. 8, 1944, No. 21984. Addition to 570,703. [Class 98 (ii)] Intensification of a latent image in an exposed gelatino silver halide emulsion layer is produced by treatment of the layer subsequent to the exposure but prior to development with a solution containing sulphurous acid but free of developing agent, by removal uniformly of the unabsorbed solution without removal of the absorbed solution, and by storing the layer in air allowed to circulate freely over it for at least five minutes. A solution of sulphurous acid, sodium bisulphite, or potassium metabisulphite may be used, and should have a pH below 6. The colour sensitivity of the emulsion is not removed. The excess liquid may be removed by an air squeegee or wiping. The air may be allowed to circulate for 10 to 20 minutes. The sulphurous acid bath should not contain developing agents acting as antioxidants such as hydroquinone or iso-ascorbic acid. In examples, comparative figures are given for the speed, gamma and density of support plus fog, using a metol-hydroquinoneboric acid-borax developer with pre-treatments in distilled water, sodium bisulphite solution and potassium metabisulphite solution. Intensification of the latent image by exposure to ammonia vapour, by exposure to the radiation of a safelight, by subjection to the action of heat and humidity and by treatment with sulphur dioxide is referred to. Specification 510,808 is referred to.
    • 56. 发明专利
    • Improvements relating to phenazinium salts and their use in photographic emulsions and developers
    • GB563691A
    • 1944-08-28
    • GB288743
    • 1943-02-22
    • KODAK LTD
    • G03C5/32
    • Azine dyes, which are 1 : 3-diamino-N-alkyl (or substituted alkyl) phenazinium salts, and are suitable for use as desensitizers in photographic silver salt emulsions and in photographic developers, are obtained by reducing the corresponding dinitro-N-alkyl (or substituted alkyl) 5 : 10-dihydrophenazines in presence of an acid. Such reduction may be effected with a reducing metal salt of the acid present. Specified dinitro compounds used as starting materials are the 5-methyl-, 5-ethyl-, 5-benzyl-and 5 - b - hydroxyethyl - 1 : 3 - dinitro - 5 : 10-dihydrophenazines. In examples, (1) to (4), 5-methyl-, 5-ethyl-, 5-b -hydroxyethyl- and 5-benzyl - 1 : 3 - dinitro - 5 : 10 - dihydrophenazines respectively are heated with stannous chloride and hydrochloric acid in alcohol under reflux to obtain the correspondingly 5-substituted 1 : 3-diamino-phenazinium chlorides. In examples (5) and (6), 5 - methyl - 1 : 3 - dinitro - 5 : 10 - dihydrophenazine is heated with (5) iron powder, (6) tin, and hydrochloric acid in alcohol under reflux to obtain 5-methyl-1 : 3-diamino-5 : 10-dihydrophenazinium chloride. 5 - Alkyl (or substituted alkyl) - 1 : 3 - dinitro - 5 : 10-dihydrophenazines are obtained by heating the corresponding N-alkyl (or substituted alkyl)-o-picrylaminoaniline with sodium hydroxide in methyl alcohol under reflux. N-alkyl (or substituted alkyl)-o-picrylaminoanilines are obtained by condensation of picryl chloride with the corresponding o-amino-N-alkyl-aniline, obtained by condensation of o-nitrochlorobenzene with the corresponding alkylamine and reduction of the nitro group with sodium hydrosulphite.