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    • 52. 发明授权
    • Laminated multilayer structure
    • 层压多层结构
    • US4349603A
    • 1982-09-14
    • US266470
    • 1981-05-22
    • Masao KameyamaTeiichi Shiomi
    • Masao KameyamaTeiichi Shiomi
    • C08J7/04C08L43/04B32B27/32
    • C08J7/047C08L43/04C08J2323/02C08J2443/04Y10T428/263Y10T428/264Y10T428/265Y10T428/269Y10T428/31663Y10T428/31667
    • A laminated multilayer structure comprising(1) a thermoplastic olefin resin layer (A) in the form of a shaped article,(2) a primer layer (B) liquid-coated on and contacted with at least one surface of the layer (A) and composed of (b.sub.1) 20 to 100% by weight based on the weight of the layer (B) of a graft-modified synthetic olefinic rubber or graft-modified 4-methyl-1-pentene resin obtained by grafting an organic silane compound having the following formula ##STR1## wherein R represents a monovalent olefinically unsaturated hydrocarbon radical having up to 20 carbon atoms or a monovalent olefinically unsaturated hydrocarbonoxy radical having up to 11 carbon atoms, X represents a monovalent hydrocarbon radical selected from the class consisting of alkyl groups having 1 to 20 carbon atoms and aryl groups having 6 to 8 carbon atoms, and Y.sup.1, Y.sup.2 and Y.sup.3 are identical or different and each represents a functional member selected from the class consisting of alkoxy groups having 1 to 6 carbon atoms, alkylcarbonyl groups having 1 to 10 carbon atoms, oxime groups having 3 to 15 carbon atoms and substituted amino groups having a substituent selected from lower alkyl groups and a phenyl group, and (b.sub.2) 0 to 80% by weight based on the weight of the layer (B) of an ultraviolet stabilizer, and(3) a cured layer (C) liquid-coated on and contacted with the layer (B) and derived from an uncured crosslinkable Si-containing compound selected from the group consisting of organo-alkoxysilanes, organo-acyloxysilanes and organo-polysiloxanes.
    • 一种叠层多层结构,包括(1)成型制品形式的热塑性烯烃树脂层(A),(2)液体涂覆在层(A)的至少一个表面上并与其接触的底漆层(B) 由(b1)基于接枝改性的合成烯烃橡胶的层(B)的重量为20〜100重量%或通过接枝有机硅烷化合物而获得的接枝改性的4-甲基-1-戊烯树脂,所述有机硅烷化合物具有 其中R表示具有至多20个碳原子的一价烯属不饱和烃基或具有至多11个碳原子的一价烯属不饱和烃氧基,其中X表示选自以下的一价烃基: 碳原子数1〜20,碳原子数6〜8的芳基,Y1,Y2,Y3相同或不同,分别表示选自碳原子数1〜6的烷氧基的官能团 具有1至10个碳原子的烷基羰基,具有3至15个碳原子的肟基和具有选自低级烷基和苯基的取代基的取代氨基,和(b2)0至80重量%,基于重量 的紫外线稳定剂的层(B),和(3)液体涂覆在层(B)上并与层(B)接触的固化层(C),并且衍生自未固化的可交联的含Si化合物,其选自有机 - 烷氧基硅烷,有机 - 酰氧基硅烷和有机聚硅氧烷。