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    • 4. 发明申请
    • METHOD OF PRODUCING A LAMINATE COMPRISING A CURED ADHESIVE SHEET
    • 生产包含固化粘合片的层压板的方法
    • US20160068718A1
    • 2016-03-10
    • US14785655
    • 2014-04-22
    • 3M INNOVATIVE PROPERTIES COMPANY
    • Toshihiro SuwaHikaru Takeda
    • C09J133/08B32B37/10B32B38/00B32B37/06
    • C09J133/08B29C65/1406B29C65/1435B29C65/1483B29C65/1496B29C65/4845B29C65/526B29C66/1122B29C66/343B29C66/45B29C66/952B29L2031/3475B32B37/06B32B37/10B32B37/1207B32B38/0008B32B2037/1253B32B2305/72B32B2309/02B32B2309/04B32B2309/105B32B2310/0831C08F220/06C09J4/06C09J5/00C09J133/06C09J2203/318C09J2205/31C09J2433/00G02F2201/50G02F2202/023G02F2202/28
    • Problem: To provide a method for producing a laminate comprising a thick, highly transparent cured adhesive sheet exhibiting flow characteristics accompanied by satisfactory fluidity and satisfactory initial adhesion to an adherend before irradiation, and satisfactory hardness (in particular, a high storage modulus) after irradiation. Solution: A method for producing a laminate comprising a first substrate, a second substrate, and a cured adhesive sheet disposed therebetween, the method comprising steps of: forming into a sheet a radiation-curable adhesive sheet precursor comprising a polymer/monomer mixture comprising a partially polymerized (meth) acrylic monomer, a monomer having radiation reactive sites activated by short-wavelength radiation of a first wavelength or less, and a photoinitiator for initiating polymerization of the polymer/monomer mixture and the radiation reactive site-possessing monomer via radiation of a wavelength greater than the first wavelength; irradiating the precursor with radiation of a wavelength greater than the specific wavelength to polymerize the radiation-curable adhesive sheet precursor, forming a radiation-curable adhesive sheet; disposing the radiation-curable adhesive sheet adjacent to at least one surface of the first substrate; disposing the second substrate adjacent to a radiation-curable adhesive sheet; applying heat and/or pressure to the radiation-curable adhesive sheet; and irradiating the radiation-curable adhesive sheet with radiation comprising short-wavelength radiation of a first wavelength or less to obtain a cured adhesive sheet.
    • 问题:提供一种层叠体的制造方法,其具有厚度高透明性的固化粘合片,其具有伴随着良好的流动性的流动特性和对照射前的被粘物的良好的初始粘合性,以及照射后的令人满意的硬度(特别是高储存模量) 。 解决方案:一种用于制造层压体的方法,包括第一基板,第二基板和设置在其间的固化的粘合片,所述方法包括以下步骤:将包含聚合物/单体混合物的可辐射固化粘合片前体形成为片材,所述聚合物/单体混合物包含 部分聚合的(甲基)丙烯酸单体,具有通过第一波长或更短波长的短波长辐射活化的辐射反应位点的单体,以及用于引发聚合物/单体混合物和辐射活性位点拥有的单体通过辐射的聚合反应的光引发剂 大于第一波长的波长; 用大于特定波长的波长的辐射照射前体以聚合辐射固化粘合片前体,形成可辐射固化的粘合片; 将所述可辐射固化粘合片设置在所述第一基底的至少一个表面附近; 将第二基板设置在与辐射固化粘合片相邻的位置; 对辐射固化型粘合片施加热和/或压力; 用辐射固化型粘合片照射第一波长以下的短波长的辐射,得到固化的粘合片。
    • 7. 发明申请
    • MICRO-STRUCTURED OPTICALLY CLEAR ADHESIVES
    • 微结构光学清洁粘合剂
    • US20140262002A1
    • 2014-09-18
    • US14352189
    • 2012-10-24
    • 3M INNOVATIVE PROPERTIES COMPANY
    • Toshihiro SuwaAlbert I. EveraertsHaruyuki MikamiYasuhiro Kinoshita
    • C09J7/00C09J5/06
    • C09J5/06C09J7/00C09J7/29Y10T156/10Y10T428/24479Y10T428/24612
    • A micro-structured optically clear adhesive, including a first major surface and a second major surface, wherein at least one of the first and second major surfaces comprises a micro-structured surface of interconnected micro-structures in at least one of the planar dimensions (x-y), is disclosed. The micro-structured optically clear adhesive has a tan delta value of at least about 0.3 at a lamination temperature and is non-crosslinked or lightly crosslinked. The micro-structured surface may include indentations having a depth of between about 5 and about 80 microns. A method of laminating a first substrate and a second substrate without the use of a vacuum is provided. The method includes providing a micro-structured optically clear adhesive, removing a release liner from a first side of the micro-structured optically clear adhesive, contacting the first side of the micro-structured optically clear adhesive with a surface of the first substrate, removing a micro-structured release liner from a second side of the micro-structured optically clear adhesive to expose a micro-structured surface, and contacting the micro-structured surface with a surface of the second substrate.
    • 一种微结构光学透明粘合剂,包括第一主表面和第二主表面,其中第一和第二主表面中的至少一个包括至少一个平面尺寸的互连微结构的微结构化表面( xy)。 微结构光学透明粘合剂在层压温度下具有至少约0.3的tanδ值,并且是非交联或轻度交联的。 微结构化表面可以包括深度在约5-约80微米之间的凹陷。 提供了不使用真空层压第一基板和第二基板的方法。 该方法包括提供微结构光学透明粘合剂,从微结构光学透明粘合剂的第一侧移除释放衬垫,将微结构光学透明粘合剂的第一侧与第一衬底的表面接触,除去 微结构的释放衬垫,其从所述微结构光学透明粘合剂的第二侧暴露微结构化表面,并使所述微结构化表面与所述第二衬底的表面接触。