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    • 58. 发明授权
    • Low viscosity unsaturated polyester resins
    • 低粘度不饱和聚酯树脂
    • US4292218A
    • 1981-09-29
    • US107710
    • 1979-12-27
    • Giovanni CorradoElvio BertottiBruno Sopino
    • Giovanni CorradoElvio BertottiBruno Sopino
    • C08G63/00B29D19/04C08G63/52C08G63/676C08L91/00
    • C08G63/676B29D19/04
    • A low viscosity unsaturated polyester resin for making buttons is described, which comprises an alkyd prepared by esterification of maleic anhydride and/or acid and/or fumaric acid, optionally together with phthalic anhydride and/or acid and/or adipic, sebacic, azelaic or dodecanedioic acid, with one or more glycols, essentially comprising dipropylene glycol, and further comprises 20-30% by weight of the total resins of an ethylenically unsaturated monomer copolymerizable with the alkyd, essentially chosen among styrene and vinyl toluene, the alkyd having a molecular weight/double bond factor between 300 and 390 and an amount of free functional groups between 80 and 100 mg of KOH per g of alkyd inclusive. The buttons obtainable from said resin are also described. The disc blanks made from said resin have better workability and cause less wear of the tools than those of the prior art and the finished buttons have greater impact strength, and better lustre, greater color stability when exposed to sun light.
    • 描述了用于制造纽扣的低粘度不饱和聚酯树脂,其包括通过马来酸酐和/或酸和/或富马酸的酯化制备的醇酸树脂,任选与邻苯二甲酸酐和/或酸和/或己二酸,癸二酸,壬二酸或/ 十二烷二酸与一种或多种二醇,基本上包含二丙二醇,并且还包含20-30重量%的可与醇酸树脂共聚的烯属不饱和单体的总树脂,基本上选自苯乙烯和乙烯基甲苯,醇酸树脂具有分子 重量/双键因子在300和390之间,游离官能团的量在80至100mg的KOH / g醇酸树脂之间。 还描述了可从所述树脂获得的按钮。 由所述树脂制成的圆盘坯料具有更好的可加工性,并且比现有技术的工具具有更少的磨损,并且完成的按钮具有更大的冲击强度,并且在暴露于阳光下时具有更好的光泽,更大的颜色稳定性。
    • 59. 发明授权
    • Process for the manufacture of patterned urea thermoplastic molding
compound preforms to be used for the production of consistently
patterned buttons with molded holes
    • 用于制造用于生产具有模制孔的一致图案化按钮的图案化尿素热塑性模塑复合预成型件的方法
    • US4239721A
    • 1980-12-16
    • US3000
    • 1979-01-12
    • Leonard R. Nitzberg
    • Leonard R. Nitzberg
    • B29B11/06B29C43/00B29D19/00B29D19/04B29C17/00B29C25/00B29G2/00
    • B29D19/04B29B11/06B29D19/00B29C43/00Y10S264/34
    • A process for the manufacture of patterned urea thermoplastic molding compound preforms is disclosed where such preforms are suitable for the compressive thermocasting of buttons containing cast holes and displaying an undistorted and consistent pattern. The process utilizes commercially produced molding compound, pigment, adhesives, crystalligerous material plus water which are united to form pliable, self-adhesive aggregates of various colors or hues. These masses are volumetrically measured and/or formed and then assembled in various specific arrangements. This mass is then contained and compressed to expel excess air and cause adhesion of the constituents. The mass is then extruded to a consistently patterned soft rod of a specific diameter. The rod is subsequently sliced to a specific thickness and weight and then dried prior to shipment. In the preferred embodiment of the process, excessive drying is performed by thermal dehydration and necessary minimum water content levels are re-established by specifically prolonged exposure to supersaturated air.
    • 公开了一种用于制造图案化的尿素热塑性模塑复合预成型件的方法,其中这种预成型件适用于含有铸造孔的按钮的压缩热压,并显示无失真和一致的图案。 该方法利用商业上生产的成型化合物,颜料,粘合剂,结晶材料加上水,这些水合在一起形成各种颜色或色调的柔韧的自粘聚集体。 这些质量体积测量和/或形成,然后以各种具体布置组装。 然后将该质量包含并压缩以排出多余的空气并引起组分的粘附。 然后将该质量挤出到具有特定直径的一致图案的软棒。 随后将棒切片至特定的厚度和重量,然后在装运前干燥。 在该方法的优选实施方案中,通过热脱水进行过度干燥,并且通过特别延长暴露于过饱和空气来重新建立必需的最低含水量。