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    • 56. 发明授权
    • Methods and systems for low interfacial oxide contact between barrier and copper metallization
    • 屏障和铜金属化之间的低界面氧化物接触的方法和系统
    • US08053355B2
    • 2011-11-08
    • US12828082
    • 2010-06-30
    • Fritz RedekerJohn BoydYezdi DordiHyungsuk Alexander YoonShijian Li
    • Fritz RedekerJohn BoydYezdi DordiHyungsuk Alexander YoonShijian Li
    • H01L21/4763
    • C25D7/123C23C18/1653C23C28/023C23C28/322C23C28/34C23C28/341H01L21/28562H01L21/76843H01L21/76849H01L21/76856H01L21/76862H01L21/76873H01L21/76874H01L23/53238H01L2221/1089H01L2924/0002H01L2924/00
    • The present invention relates to methods and systems for the metallization of semiconductor devices. One aspect of the present invention is a method of depositing a copper layer onto a barrier layer so as to produce a substantially oxygen free interface therebetween. In one embodiment, the method includes providing a substantially oxide free surface of the barrier layer. The method also includes depositing an amount of atomic layer deposition (ALD) copper on the oxide free surface of the barrier layer effective to prevent oxidation of the barrier layer. The method further includes depositing a gapfill copper layer over the ALD copper. Another aspect of the present invention is a system for depositing a copper layer onto barrier layer so as to produce a substantially oxygen-free interface therebetween. In one embodiment, the integrated system includes at least one barrier deposition module. The system also includes an ALD copper deposition module configured to deposit copper by atomic layer deposition. The system further includes a copper gapfill module and at least one transfer module coupled to the at least one barrier deposition module and to the ALD copper deposition module. The transfer module is configured so that the substrate can be transferred between the modules substantially without exposure to an oxide-forming environment.
    • 本发明涉及用于半导体器件金属化的方法和系统。 本发明的一个方面是将铜层沉积在阻挡层上以在其间产生基本上无氧的界面的方法。 在一个实施例中,该方法包括提供阻挡层的基本上无氧化物的表面。 该方法还包括在阻挡层的无氧化物表面上沉积一定量的原子层沉积(ALD)铜,以有效地防止阻挡层的氧化。 该方法还包括在ALD铜上沉积间隙填充铜层。 本发明的另一方面是一种用于在阻挡层上沉积铜层以在其间产生基本上无氧的界面的系统。 在一个实施例中,集成系统包括至少一个阻挡层沉积模块。 该系统还包括配置为通过原子层沉积沉积铜的ALD铜沉积模块。 该系统还包括铜间隙填充模块和耦合到至少一个阻挡层沉积模块和ALD铜沉积模块的至少一个传输模块。 转移模块被配置为使得基板可以在基本上不暴露于氧化物形成环境的基础之间传递。
    • 58. 发明授权
    • Plasma immersion ion implantation with highly uniform chamber seasoning process for a toroidal source reactor
    • 用于环形源反应器的等离子体浸没离子注入与高度均匀的室调节过程
    • US07691755B2
    • 2010-04-06
    • US11748783
    • 2007-05-15
    • Shijian LiLily L. PangMajeed A. FoadSeon-Mee Cho
    • Shijian LiLily L. PangMajeed A. FoadSeon-Mee Cho
    • H01L21/00H01L21/26
    • H01L21/2236H01J37/32412H01J37/3244H01J37/32449
    • A method is provided for performing plasma immersion ion implantation with a highly uniform seasoning film on the interior of a reactor chamber having a ceiling and a cylindrical side wall and a wafer support pedestal facing the ceiling. The method includes providing a gas distribution ring with plural gas injection orifices on a periphery of a wafer support pedestal, the orifices facing radially outwardly from the wafer support pedestal. Silicon-containing gas is introduced through the gas distribution orifices of the ring to establish a radially outward flow pattern of the silicon-containing gas. The reactor includes pairs of conduit ports in the ceiling adjacent the side wall at opposing sides thereof and respective external conduits generally spanning the diameter of the chamber and coupled to respective pairs of the ports. The method further includes injecting oxygen gas through the conduit ports into the chamber to establish an axially downward flow pattern of oxygen gas in the chamber. RF power is coupled into the interior of each of the conduits to generate a toroidal plasma current of SixOy species passing through the chamber to deposit a seasoning layer of a SixOy material on surfaces within the chamber, while leaving the pedestal without a wafer so as to expose a wafer support surface of the pedestal.
    • 提供了一种用于在具有天花板和圆柱形侧壁的反应室的内部以及面向天花板的晶片支撑台架上执行具有高度均匀的调味膜的等离子体浸没离子注入的方法。 该方法包括在晶片支撑基座的外围提供具有多个气体注入孔的气体分配环,所述孔从晶片支撑基座径向向外。 含硅气体通过环的气体分配孔引入,以建立含硅气体的径向向外流动图案。 反应器包括在天花板中的相邻侧壁处的相对侧的导管端口对,以及相应的外部导管,其通常跨越室的直径并且耦合到相应的端口对。 该方法还包括将氧气通过导管端口注入到腔室中,以在腔室中建立轴向向下的氧气气流模式。 RF功率耦合到每个导管的内部,以产生通过该室的六十种物质的环形等离子体电流,以在室内的表面上沉积SixOy材料的调味层,同时离开基座而没有晶片,以便 露出基座的晶片支撑表面。