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51. 发明授权

US4436878A Water-dispersible binders for cationic electropaints, and a process for their preparation 失效
标题翻译：用于阳离子电极的水分散性粘合剂及其制备方法
公开(公告)号：US4436878A
公开(公告)日：1984-03-13
申请号：US471739
申请日：1983-03-03
申请人： Wolfgang Batzill , Horst Diefenbach , Michael Geist , Eberhard Schupp
发明人： Wolfgang Batzill , Horst Diefenbach , Michael Geist , Eberhard Schupp
IPC分类号： C08G59/00 , C08G59/02 , C08G59/14 , C08G59/56 , C08G59/62 , C09D5/44 , C08L63/00
CPC分类号： C08G59/621 , C08G59/02 , C08G59/1477 , C08G59/56 , C09D5/4446 , Y10S524/901
摘要： The invention relates to water-dispersible binders which are intended for cationic electropaints and are based on reaction products which are formed from modified epoxy resins and primary and/or secondary amines and which can, if desired, also contain crosslinking agents, pigments, flow-control agents and other customary auxiliaries. The reaction products have been prepared by reacting(A) Low molecular weight epoxy resins which contain aromatic groups and have an epoxide equivalent weight of less than 375 with(B) aliphatic and/or alicyclic polyfunctional alcohols or carboxylic acids having a molecular weight of less than 350 by addition to the epoxy group in such a way that the reaction products contain 10-45% of aromatic groups, calculated as phenylene group, and reacting the reaction products of A and B with(C) if desired up to 60% by weight, relative to total binder, of polyfunctional alcohols, carboxylic acids and/or SH compounds having a molecular weight of 300-5,000, the molar ratios of (A), (B) and, if desired, (C) being chosen in such a way that the resulting intermediate product has terminal epoxy groups,(D) by reacting the intermediate product by the addition of a phenolic hydroxyl group of a monophenol and/or diphenol to the epoxy groups, the monophenol or diphenol having as a substituent on the aromatic ring(s) at least one grouping of the general formula ##STR1## in which R.sup.1 and R.sup.2 are identical to or different from one another and represent hydrogen or a methyl group, and by adding a primary and/or secondary amine before or after the reaction of the phenolic hydroxyl groups with the epoxy groups, to at least some of the double bonds of the grouping of the formula (I).
摘要翻译：本发明涉及用于阳离子电穿孔剂的水分散性粘合剂，并且基于由改性环氧树脂和伯胺和/或仲胺形成的反应产物，并且如果需要，其也可以含有交联剂，颜料，控制剂和其他常规助剂。反应产物通过（A）含有芳族基团并且具有小于375的环氧当量重量的低分子量环氧树脂与（B）分子量较小的（B）脂族和/或脂环族多官能醇或羧酸反应制备通过加入环氧基，使反应产物含有10-45％的芳族基团，以亚苯基计算，并且如果需要，将A和B的反应产物与（C）反应直到60％相对于总粘合剂，分子量为300-5,000的多官能醇，羧酸和/或SH化合物的重量，（A），（B）的摩尔比和如果需要，（C）选自于所得到的中间产物具有末端环氧基的方式，（D）通过将酚类羟基和/或二酚加成到环氧基上，通过使中间产物与酚类作为取代基的单酚或二酚反应芳香至少一个通式为其中R 1和R 2彼此相同或不同并且代表氢或甲基的通式（I）的至少一个基团，并且通过加入伯胺和/或仲胺在酚羟基与环氧基反应之前或之后，至少部分式（I）的组的双键。

52. 发明授权

US4315840A Preparation of cathodic electrocoating binders 失效
标题翻译：阴极电泳涂料的制备
公开(公告)号：US4315840A
公开(公告)日：1982-02-16
申请号：US85965
申请日：1979-10-18
申请人： Fritz E. Kempter , Eberhard Schupp , Erich Gulbins
发明人： Fritz E. Kempter , Eberhard Schupp , Erich Gulbins
IPC分类号： C08G18/00 , C08G18/08 , C08G18/65 , C08G18/66 , C08G18/80 , C09D5/44 , C09D175/08 , C08G18/48 , C08J3/04 , C08L91/00
CPC分类号： C08G18/0814 , C08G18/8061 , C09D5/4465 , Y10S524/901
摘要： A process for the preparation of self-crosslinking, cathodic electrocoating binders by reacting polyether-polyols, which may or may not contain thio groups, with semi-blocked diisocyanates or partially blocked polyisocyanates, wherein the reaction products (A), containing blocked isocyanate groups, are reacted with a polyamine (B), some of whose amino groups may or may not be in the form of ketimine groups, in such a way that one or more amino groups of the polyamine (B) form a urea group with a blocked isocyanate group of the reaction product (A), and the self-cross-linking reaction product of (A) and (B) is converted into a water-dilutable form in the conventional manner by protonization with an acid.The coating binders prepared according to the invention may be used for cathodic electrocoating of metal articles.
摘要翻译：一种制备自交联阴极电泳涂料粘合剂的方法，该方法是将可能含有或不含有硫基的聚醚多元醇与半封端二异氰酸酯或部分封闭的多异氰酸酯反应，其中含有封端异氰酸酯基团的反应产物（A）与多胺（B）反应，其一些氨基可以是或可以不是酮亚胺基的形式，使得多胺（B）的一个或多个氨基形成具有封闭的脲基团反应产物（A）的异氰酸酯基和（A）和（B）的自交联反应产物以常规方式通过用酸质子化转化成水可稀释形式。根据本发明制备的涂料粘合剂可用于金属制品的阴极电泳涂覆。

53. 发明授权

US4310645A Polyadducts of ammonia and epoxide compounds, processes for their modification, and their use 失效
标题翻译：氨和环氧化合物的加合物，其改性方法及其用途
公开(公告)号：US4310645A
公开(公告)日：1982-01-12
申请号：US213174
申请日：1980-12-04
申请人： Fritz E. Kempter , Eberhard Schupp , Hans-Uwe Schenck , Erich Gulbins
发明人： Fritz E. Kempter , Eberhard Schupp , Hans-Uwe Schenck , Erich Gulbins
IPC分类号： C08G12/00 , C08G12/02 , C08G12/46 , C08G59/00 , C08G59/14 , C08G59/40 , C08G65/26 , C08K5/29 , C09D5/44 , C09D163/00
CPC分类号： C08G12/46 , C08G12/00 , C08G12/02 , C08G59/1405 , C08G59/4014 , C08G65/2624 , C09D5/4438 , Y10S524/901 , Y10T428/2933
摘要： Polyadducts, free from epoxide groups, are obtained from ammonia and epoxide compounds by reacting 1 mole of ammonia with from 1.2 to 2.0 equivalents of epoxide, so that if diepoxide compounds are used products of the general formula (I) ##STR1## are obtained, while if triepoxides and/or tetraepoxide compounds are used, by themselves, or together with diepoxide compounds, products of the general formula II ##STR2## are produced; in these formulae, the E.sup.1 's are identical or different hydroxyl-containing divalent radicals and the E.sup.2 's are identical or different hydroxyl-containing trivalent or tetravalent radicals, resulting from the opening of the oxirane rings of epoxide compounds containing two, three or four epoxide groups in the molecule, n.sup.1, n.sup.3 and n.sup.5 are from 0 to 3, n.sup.2 and n.sup.4 are from 1 to 3 and X is 0 or 1, and one or more of the divalent radicals E.sup.1 in the general formula (II) may or may not be replaced by polyvalent radicals E.sup.2.The novel polyadducts can be modified by reaction with aldehydes, ketones, monoepoxide compounds, carboxylic acids, carboxylic acid esters or isocyanates, or by protonation with an acid, and may be used, for example, for the cathodic electrocoating of metallic articles.
摘要翻译：通过使1摩尔氨与1.2-2.0当量的环氧化物反应，从氨和环氧化合物得到不含环氧基的多元加成物，因此如果使用二环氧化合物，则得到通式（I）的产物而如果三环氧化物和/或四环氧化合物本身或与二环氧化合物一起使用，则制备通式II的产物（II）; 在这些式中，E1是相同或不同的含羟基的二价基团，并且E2是相同或不同的含羟基的三价或四价基团，其由环氧乙烷环的环氧化物环开放，所述环氧化物包含两个，三个或四个环氧基团分子n1，n3和n5为0〜3，n2和n4为1〜3，X为0或1，通式（II）中的一个或多个二价基团E1可以是也可以不是由多价基团E2代替。可以通过与醛，酮，单环化合物，羧酸，羧酸酯或异氰酸酯的反应或通过用酸质子化来改变新的多加合物，并且可以用于例如金属制品的阴极电泳涂层。

54. 发明授权

US08143176B2 Textile two or three dimensional fabric containing materials that are capable of swelling 有权
标题翻译：纺织二维或三维织物含有能够膨胀的材料
公开(公告)号：US08143176B2
公开(公告)日：2012-03-27
申请号：US11722271
申请日：2005-12-21
申请人： Manfred Weber , Axel Weiss , Eberhard Schupp , Pulakesh Mukherjee , Ralf Mossbach , Bernd Reck , Kuno Beutler , Tibor Duris
发明人： Manfred Weber , Axel Weiss , Eberhard Schupp , Pulakesh Mukherjee , Ralf Mossbach , Bernd Reck , Kuno Beutler , Tibor Duris
IPC分类号： B32B27/04
CPC分类号： D06M15/21 , D04B21/165 , D06M15/233 , D06M15/263 , D06M15/356 , D06N3/04 , D10B2403/02421 , Y10T442/2484 , Y10T442/2492
摘要： The present invention relates to textile two- or three-dimensional structures formed from fibers and/or ribbons and swellable materials, the fibers and/or ribbons present in the structure and also the swellable materials each being present in such an amount that the fibers and/or ribbons are encased by the swellable materials and the voids in the structure are, in the swollen state, partially or completely filled by materially bound water and the swellable materials used being aqueous emulsions of (co)polymers of at least one ethylenically unsaturated monomer MON which are applied to the fibers and/or ribbons.
摘要翻译：本发明涉及由纤维和/或带和可溶胀材料形成的织物二维或三维结构，结构中存在的纤维和/或带以及可溶胀材料各自以纤维和 /或带被可膨胀材料包裹，并且结构中的空隙在膨胀状态下被部分或完全由物质结合的水填充，并且所使用的可溶胀材料是至少一种烯键式不饱和单体的（共）聚合物的水乳液 MON应用于纤维和/或带。

55. 发明申请

US20060229369A1 Use of 2-hydroxy-2-sulfinato acetic acid or the salts thereof as an initiator in w/o emulsions 审中-公开
标题翻译：在w / o乳液中使用2-羟基-2-亚磺酰基乙酸或其盐作为引发剂
公开(公告)号：US20060229369A1
公开(公告)日：2006-10-12
申请号：US10568777
申请日：2004-08-20
申请人： Jurgen Frank , Gunter Renz , Eberhard Schupp , Bernhard Steinmetz , Karl Bayer
发明人： Jurgen Frank , Gunter Renz , Eberhard Schupp , Bernhard Steinmetz , Karl Bayer
IPC分类号： B01D17/05
CPC分类号： C08F4/40 , C08F2/32
摘要： Process for the preparation of homopolymers or copolymers by homopolymerization or copolymerization of free-radically polymerizable water-soluble and/or water-dispersible monomers, optionally with further comonomers and optionally with at least one crosslinker, in an inverse emulsion polymerization in the presence of at least one redox initiator pair comprising an oxidizing agent and a reducing agent, where the reducing agent is 2-hydroxy-2-sulfinatoacetic acid and/or salt thereof; homopolymers or copolymers preparable by the process according to the invention, water-in-oil emulsions which comprise at least one homopolymer or copolymer according to the invention, solid compositions which comprise at least one homopolymer or copolymer according to the invention, the use of 2-hydroxy-2-sulfinatoacetic acid and/or salt thereof as reducing agent in a process for the preparation of homopolymers or copolymers; the use of the water-in-oil emulsion comprising at least one homopolymer or copolymer according to the invention for the thickening of aqueous solutions, and the use of 2-hydroxy-2-sulfinatoacetic acid and/or salt thereof as reducing component of a redox initiator pair comprising an oxidizing agent and a reducing agent for avoiding induction times during inverse emulsion polymerization.
摘要翻译：通过在可溶自由基聚合的水溶性和/或水分散性单体，任选与其它共聚单体和任选与至少一种交联剂共聚合或共聚制备均聚物或共聚物的方法中，在反相乳液聚合中，在包含氧化剂和还原剂的至少一种氧化还原引发剂对，其中所述还原剂是2-羟基-2-亚磺酰基乙酸和/或其盐; 可通过本发明方法制备的均聚物或共聚物，包含至少一种根据本发明的均聚物或共聚物的油包水乳液，包含至少一种根据本发明的均聚物或共聚物的固体组合物，使用2 - 羟基-2-亚磺酰乙酸和/或其盐作为制备均聚物或共聚物的方法中的还原剂; 使用包含至少一种本发明的均聚物或共聚物的油包水乳液用于水溶液的增稠，以及使用2-羟基-2-亚磺酰基乙酸和/或其盐作为包含氧化剂和还原剂的氧化还原引发剂对，用于避免反相乳液聚合期间的诱导时间。

56. 发明授权

US4956402A Synthetic resin with basic nitrogen groups from resins reacted with the ketimine-urethane product of an alkanolamine, a ketone and anisocyanate 失效
标题翻译：来自树脂的具有碱性氮基团的合成树脂与烷醇胺，酮和异氰酸酯的酮亚胺 - 氨基甲酸酯产物反应
公开(公告)号：US4956402A
公开(公告)日：1990-09-11
申请号：US210499
申请日：1988-06-23
申请人： Thomas Perner , Rolf Osterloh , Eberhard Schupp , Thomas Schwerzel , Klaas Ahlers
发明人： Thomas Perner , Rolf Osterloh , Eberhard Schupp , Thomas Schwerzel , Klaas Ahlers
IPC分类号： C08G59/30 , C08G18/64 , C08G59/14 , C08G59/28 , C08G59/40 , C09D5/44 , C09D163/00
CPC分类号： C09D5/4438 , C08G18/643 , C08G59/4014 , C08G59/4042 , Y10T428/31511 , Y10T428/31522 , Y10T428/31529
摘要： A synthetic resin which carries basic nitrogen groups and is water-dilutable by protonation with acid is obtainable by reacting(A) an epoxy resin having an average molecular weight M.sub.n of from 200 to 6,000 and on average from 1.5 to 3.0 epoxy groups per molecule with(B) a ketimine of a primary amine additionally containing one or more urethane groups and optionally also with(C) a diketimine of a diprimary amine containing no urethane groups and optionally also with(D) a secondary amine which may contain a tertiary amimo group also, a ketimine of a primary monoamine and/or a ketimine of a primary/tertiary diamine.
摘要翻译：通过使（A）平均分子量Mn为200〜6,000的环氧树脂和每分子平均1.5〜3.0个环氧基的环氧树脂与（B）另外含有一个或多个氨基甲酸酯基团的伯胺的酮亚胺，以及任选地还含有（C）不含氨基甲酸酯基团的二原子胺的二酮亚胺，并且任选地还可以含有（D）可含有叔胺摩尔组的仲胺也可以是伯/叔二胺的伯胺和/或酮亚胺的酮亚胺。

57. 发明授权

US4752631A Binders for cathodic electrocoating 失效
标题翻译：阴极电泳用粘合剂
公开(公告)号：US4752631A
公开(公告)日：1988-06-21
申请号：US934625
申请日：1986-11-25
申请人： Eberhard Schupp , Rolf Osterloh , Werner Loch , Klaas Ahlers
发明人： Eberhard Schupp , Rolf Osterloh , Werner Loch , Klaas Ahlers
IPC分类号： C09D5/44 , C09D163/00 , C08L63/02
CPC分类号： C09D5/4419 , Y10S524/901 , Y10T428/31529
摘要： Binders for cathodic electrocoating which are based on polyadducts/polycondensates which carry basic nitrogen groups and are rendered water-dilutable by protonation with an acid, and one or more crosslinkng agents for these polyadducts/polycondensates, and their use.These binders essentially consist of a mixture of(A) from 50 to 90% by weight of a polyadduct/polycondensate which carries basic nitrogen groups and is obtainable by reacting(a) an adduct of a secondary amine and a polyepoxide compound, the adduct still containing free epoxide groups, with(b) a condensate which contains primary amino groups and is obtained from a primary diamine of not less than 4 carbon atoms and one or more mono- and/or dicarboxylic acids, one or more primary amino groups of the condensate (b) being used per free epoxide group of the adduct (a), and(B) from 10 to 50% by weight of a crosslinking agent which does not react with component (A) at room temperature but reacts with the latter at elevated temperatures with crosslinking.The binders are useful for the cathodic electrocoating of electrically conductive substrates and as coating materials.
摘要翻译：用于阴极电泳的粘合剂，其基于携带碱性氮基并通过用酸质子化而被水稀释的多加成物/缩聚物，以及用于这些聚加合物/缩聚物的一种或多种交联剂及其用途。这些粘合剂基本上由（A）50-90％重量的承载碱性氮基团的聚加合物/缩聚物组成，可通过使（a）仲胺和聚环氧化合物的加合物，含有游离环氧基团，其中（b）含有伯氨基的缩合物，其由不少于4个碳原子的伯胺和一个或多个单 - 和/或二羧酸，一个或多个伯氨基缩合物（b）每加成物（a）的每个游离环氧基使用，和（B）10至50重量％的在室温下不与组分（A）反应的交联剂，但与交联温度升高。粘合剂可用于导电基材和涂料的阴极电泳涂层。

58. 发明授权

US4721758A Binders for cathodic electrocoating which contain non-tertiary basic amino groups in addition to phenolic mannich bases 失效
标题翻译：用于阴极电泳的粘合剂，除酚酚基底物之外还含有非叔氨基
公开(公告)号：US4721758A
公开(公告)日：1988-01-26
申请号：US744200
申请日：1985-06-13
申请人： Eberhard Schupp , Rolf Osterloh , Werner Loch , Klaas Ahlers
发明人： Eberhard Schupp , Rolf Osterloh , Werner Loch , Klaas Ahlers
IPC分类号： C09D5/44 , C09D161/04 , C08L61/14 , C08L33/08 , C08L61/00 , C08L61/34
CPC分类号： C09D5/4496
摘要： The present invention relates to binders for cathodic electrocoating. These binders contain non-tertiary basic amino groups in addition to phenolic Mannich bases and consist of a mixture or precondensate of a polymer, polycondensate or polyadduct which has a mean molecular weight of 800 to 8,000 and a content of basic, primary and/or secondary amino groups of 0.8 to 8 equivalents per 1,000 molecular weight units and one or more phenolic Mannich bases prepared from one or more polynuclear polyphenols, formaldehyde or a formaldehyde donor and one or more secondary aliphatic amines, not more than one equivalent of a secondary amine and not more than 2 equivalents of formaldehyde being employed per equivalent of phenol for the preparation of component (B). These binders can be rendered water-dilutable by the addition of an acid and are suitable for the cathodic electrocoating of electrically conductive articles.
摘要翻译：本发明涉及阴极电泳涂料用粘合剂。这些粘合剂除酚胺尼希基之外还含有非叔碱性氨基，并由聚合物，缩聚物或聚加成物的混合物或预缩合物组成，其平均分子量为800至8,000，碱性，初级和/或次级的含量每1000个分子量单位为0.8至8当量的氨基和由一种或多种多核多酚，甲醛或甲醛供体和一种或多种仲脂族胺制备的一种或多种酚类曼尼希碱，不超过1当量的仲胺，对于组分（B）的制备，每当量苯酚使用不超过2当量的甲醛。这些粘合剂可以通过添加酸使其水可稀释，并且适用于导电制品的阴极电涂覆。

59. 发明授权

US4647604A Heat-curable coating agent and its use 失效
标题翻译：热固性涂料及其用途
公开(公告)号：US4647604A
公开(公告)日：1987-03-03
申请号：US744205
申请日：1985-06-13
申请人： Fritz E. Kempter , Harro Petersen , Eberhard Schupp , Gunther Sabelus , Horst Schmidt
发明人： Fritz E. Kempter , Harro Petersen , Eberhard Schupp , Gunther Sabelus , Horst Schmidt
IPC分类号： C08G59/00 , C08G59/10 , C08G59/28 , C08G59/32 , C08L63/00 , C09D5/44 , C09D163/00
CPC分类号： C09D5/4419
摘要： The heat-curable coating agent according to the invention contains a combination of a binder, which possesses basic nitrogen groups and is rendered water-dilutable by protonation with an acid, and a crosslinking agent and, if required, pigments, fillers, corrosion inhibitors, surface coating assistants and catalysts, and the binder used is a reaction product of a dicarboxylic acid or of a dicarboxylate or of a (meth)acrylate oligomer or polymer with an adduct of a di- or triglycidyl ether and a polyamine, the polyamine containing 2 or more amine nitrogen atoms per molecule and one or more alkylene chains of 3 or more carbon atoms between the amino groups, and has an NH amine number of from 50 to 150 mg of KOH/g and is combined with aminoplasts and/or phenoplasts as crosslinking agents.The novel coating agent is useful as a binder for the cathodic electrocoating of metal articles.
摘要翻译：根据本发明的热固化涂层剂含有具有碱性氮基并通过用酸质子化而进行水稀释的粘合剂和交联剂以及如果需要的颜料，填料，腐蚀抑制剂，所使用的粘合剂是二羧酸或二羧酸酯或（甲基）丙烯酸酯低聚物或聚合物与二缩水甘油醚和多胺的加合物的反应产物，所述多胺含有2 或更多的胺氮原子和氨基之间具有3个或更多个碳原子的一个或多个亚烷基链，并且具有50至150mg KOH / g的NH胺数，并与氨基塑料和/或酚质体合并为交联剂。该新型涂料可用作金属制品的阴极电泳涂料的粘合剂。

60. 发明授权

US4599371A Preparation of self-crosslinking synthetic resins 失效
标题翻译：自交联合成树脂的制备
公开(公告)号：US4599371A
公开(公告)日：1986-07-08
申请号：US641859
申请日：1984-08-17
申请人： Werner Loch , Eberhard Schupp , Rolf Osterloh , Arnold Dobbelstein , Klaas Ahlers
发明人： Werner Loch , Eberhard Schupp , Rolf Osterloh , Arnold Dobbelstein , Klaas Ahlers
IPC分类号： C08G14/14 , C09D5/44 , C08K3/20
CPC分类号： C08G14/14 , C09D5/4419
摘要： Synthetic resins which are self-crosslinking under the action of heat have on average two phenolic hydroxyl groups per molecule and are prepared by reacting a reaction product of an epoxy resin and a bifunctional phenol with formaldehyde and a mixture of secondary amines.After they have been protonated with an acid, the resins are suitable as cathodic electrocoating binders.
摘要翻译：在热作用下自交联的合成树脂每分子具有平均两个酚羟基，并且通过使环氧树脂和双官能酚的反应产物与甲醛和仲胺的混合物反应来制备。在用酸质子化之后，该树脂适合作为阴极电涂层粘合剂。

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