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    • 51. 发明授权
    • Method for the preparation of methyl chloride from carbon tetrachloride
and methyl alcohol
    • 碳化四氯化硼和甲醇制备甲基氯化物的方法
    • US5196618A
    • 1993-03-23
    • US843848
    • 1992-02-28
    • Toshihiro OkonTakaaki Shimizu
    • Toshihiro OkonTakaaki Shimizu
    • C07C17/16C07C19/03
    • C07C19/03C07C17/16
    • An improvement is proposed in the method for the preparation of methyl chloride from carbon tetrachloride and methyl alcohol by the reaction including the partial reactions of, first, the hydrolysis reaction of carbon tetrachloride with water to form hydrogen chloride and carbon dioxide and, second, the reaction of methyl alcohol with hydrogen chloride, each in the presence of a solid catalyst of zinc chloride supported on active carbon. The uncontrollable temperature increase when these reactions are performed on a single catalyst bed can be avoided by conducting the first partial reaction in a first reaction zone with a feed of carbon tetrachloride and water alone and the second partial reaction is conducted in a separate second reaction zone into which the gaseous mixture from the first zone and methyl alcohol are introduced. When carbon dioxide in the gaseous mixture from the first zone is removed therefrom prior to introduction of the mixture into the second reaction zone, the problems accompanying the separation of carbon dioxide from a gaseous mixture containing methyl chloride can be solved.
    • 在四氯化碳和甲醇中通过包括部分反应的四氯化碳与甲醇的制备方法提出了一个改进,首先是四氯化碳与水的水解反应形成氯化氢和二氧化碳,其次, 甲基醇与氯化氢的反应,各自在负载在活性炭上的氯化锌的固体催化剂存在下进行。 在单一催化剂床上进行这些反应时,不可控制的温度升高可以通过在第一反应区域中与四氯化碳和水单独进料进行第一部分反应来避免,第二部分反应在单独的第二反应区 其中引入来自第一区和甲醇的气体混合物。 在将混合物引入第二反应区之前,来自第一区的气态混合物中的二氧化碳被除去时,可以解决伴随着含有甲基氯的气态混合物分离二氧化碳的问题。
    • 55. 发明申请
    • METHOD FOR PRODUCING POLYCRYSTALLINE SILICON
    • 生产多晶硅的方法
    • US20090060822A1
    • 2009-03-05
    • US12190229
    • 2008-08-12
    • Takaaki ShimizuKyoji OguroTakeshi Aoyama
    • Takaaki ShimizuKyoji OguroTakeshi Aoyama
    • H01L21/205
    • C23C16/24C01B33/03C01B33/1071C01B33/10721C23C16/4412C23C16/45593
    • A by-product mixture produced when polycrystalline silicon is deposited on a base material in a CVD reactor is made to react with chlorine to form a tetrachlorosilane (STC) effluent in a chlorination reaction vessel, and the tetrachlorosilane (STC) distillate is made to react with hydrogen in a hydrogenation reaction vessel to be converted into trichlorosilane (TCS). In the chlorination step, poly-silane contained in the above described by-product mixture can be efficiently recycled as a raw material for producing the polycrystalline silicon, which can enhance a yield of the production process. In addition, in the chlorination step, methyl chlorosilanes having boiling points close to TCS are hyper-chlorinated to be converted into hyper-chlorinated methyl chlorosilanes having higher boiling points, which facilitates the hyper-chlorinated methyl chlorosilanes to be separated into high concentration, and reduces carbon contamination of the polycrystalline silicon.
    • 将多晶硅沉积在CVD反应器中的基材上产生的副产物混合物与氯反应,在氯化反应容器中形成四氯硅烷(STC)流出物,并使四氯硅烷(STC)馏出物反应 在氢化反应容器中用氢气转化为三氯硅烷(TCS)。 在氯化工序中,上述副产物混合物中含有的聚硅烷可以作为制造多晶硅的原料被有效地再循环,从而可提高生产工艺的产率。 此外,在氯化工序中,沸点接近TCS的甲基氯硅烷被高氯化转化为沸点较高的高氯甲基氯硅烷,有利于高氯化甲基氯硅烷分离成高浓度, 减少多晶硅的碳污染。
    • 56. 发明申请
    • METHOD FOR PRODUCING TRICHLOROSILANE AND METHOD FOR PRODUCING POLYCRYSTALLINE SILICON
    • 生产三氯硅烷的方法和生产多晶硅的方法
    • US20090060820A1
    • 2009-03-05
    • US12203395
    • 2008-09-03
    • Takaaki ShimizuKyoji Oguro
    • Takaaki ShimizuKyoji Oguro
    • C01B33/107C23C16/22
    • C01B33/03C01B33/035C01B33/1071
    • The present invention includes a step of separating an effluent produced in a hydrogenation step of making tetrachlorosilane (STC) react with hydrogen into trichlorosilane (TCS), into a chlorosilane fraction containing a hydrocarbon and a TCS fraction, and a chlorination step of making the chlorosilane fraction containing the hydrocarbon react with chlorine to form STC and a substance containing a chlorinated hydrocarbon, wherein the effluent containing STC produced in the chlorination step is circulated to the hydrogenation step. In the chlorination step, the chlorosilane fraction containing a hydrocarbon (capable of containing hyper-hydrogenated chlorosilanes) having a boiling point close to TCS is hyper-chlorinated to be converted and acquire a higher boiling point, which facilitates the hyper-chlorinated chlorosilanes and the hyper-chlorinated hydrocarbons to be separated into high concentration, and increases the purity of TCS to be finally obtained.
    • 本发明包括将制备四氯硅烷(STC)的氢化步骤中产生的流出物与氢气反应成三氯硅烷(TCS)的步骤,分离成含有烃和TCS馏分的氯硅烷部分,以及制备氯硅烷 含有烃的馏分与氯反应形成STC和含有氯化烃的物质,其中在氯化步骤中产生的含有STC的流出物循环到氢化步骤。 在氯化步骤中,含有沸点接近TCS的烃(能够含有高氢氯硅烷)的氯代硅烷馏分被高氯化转化并获得较高的沸点,这有助于高氯代氯代硅烷和 将高氯化烃分离成高浓度,并提高最终获得的TCS的纯度。