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51. 发明授权

US5596052A Atactic polypropylene 失效
标题翻译：无规聚丙烯
公开(公告)号：US5596052A
公开(公告)日：1997-01-21
申请号：US622566
申请日：1996-03-25
申请人： Luigi Resconi , Enrico Albizzati
发明人： Luigi Resconi , Enrico Albizzati
IPC分类号： C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F8/00 , C08F10/06 , C08F110/06 , C08F4/64
CPC分类号： C08F110/06 , C08F4/65927 , C08F4/65912 , Y10S526/943
摘要： Amorphous propylene polymers are disclosed having the following characteristics:(a) intrinsic viscosity [.eta.]>1 d1/g;(b) %(r)-%(m)>0, wherein % (r) is the % of syndiotactic diads and %(m) is the % of isotactic diads;(c) less than 2% of the CH.sub.2 groups contained in sequences (CH.sub.2).sub.n, with n.gtoreq.2;(d) Bernoullianity index (B)=1.+-.0.2.These propylene polymers, which are in addition endowed with a narrow molecular weight distribution, can be obtained directly from the polymerization reaction of propylene as sole product and, therefore, do not require to be separated.
摘要翻译：公开了无定形丙烯聚合物，其具有以下特性：（a）特性粘度η1d1/ g; （b）％（r） - ％（m）> 0，其中％（r）是间同立构二价的％，％（m）是全同立构二价的％（c）小于2％的序列（CH2）n中所含的CH2基团，其中n≥2; （d）伯努利亚指数（B）= 1 +/- 0.2。另外具有窄分子量分布的丙烯聚合物可以直接从丙烯作为单一产物的聚合反应获得，因此不需要分离。

52. 发明授权

US5049535A Catalysts for the polymerization of olefins 失效
标题翻译：用于烯烃聚合的催化剂
公开(公告)号：US5049535A
公开(公告)日：1991-09-17
申请号：US471901
申请日：1990-01-30
申请人： Luigi Resconi , Umberto Giannini , Enrico Albizzati
发明人： Luigi Resconi , Umberto Giannini , Enrico Albizzati
IPC分类号： C08F4/60 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F10/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65922 , Y10S526/943
摘要： Catalysts for the polymerization of olefins, obtained from special zirconocenic compounds and from alkyl-Al compounds.

53. 发明授权

US09243137B2 Sealing propylene copolymer 有权
标题翻译：密封丙烯共聚物
公开(公告)号：US09243137B2
公开(公告)日：2016-01-26
申请号：US13984245
申请日：2012-02-07
申请人： Kristin Reichelt , Luigi Resconi , Juha Paavilainen
发明人： Kristin Reichelt , Luigi Resconi , Juha Paavilainen
IPC分类号： C08L23/04 , C08L23/10 , C08L23/14 , C08J5/18 , C09D123/14 , C08F2/00 , C08F4/659
CPC分类号： C08L23/14 , C08F2/001 , C08F4/65912 , C08J5/18 , C08L23/142 , C08L2203/162 , C08L2205/025 , C08L2308/00 , C08L2314/02 , C09D123/14 , C09D123/142 , C08L2666/06 , C08F210/16
摘要： Propylene copolymer composition comprising a propylene copolymer (A) having a comonomer content in the range of equal or more than 0.5 to equal or below 2.0 wt.-%, the comonomers are C5 to C12 α-olefins, and a propylene copolymer (B) having a comonomer content in the range of equal or more than 4.0 to equal or below 10.0 wt.-%, the comonomers are C5 to C12 α-olefins, wherein further the propylene copolymer composition has a comonomer content in the range of equal or more than 3.5 to equal or below 7.0 wt.-%, the comonomers are C5 to C12 α-olefins, and the weight ratio of the propylene copolymer (A) to the propylene copolymer (B) is in the range of 20/80 to below 55/45.
摘要翻译：包含丙烯共聚物（A）的丙烯共聚物组合物，其共聚单体含量在等于或大于等于或小于2.0重量％的范围内，共聚单体是C 5 -C 12α-烯烃，丙烯共聚物（B）共聚单体含量在等于或大于4.0至等于或低于10.0重量％的范围内，共聚单体是C 5 -C 12α-烯烃，其中丙烯共聚物组合物的共聚单体含量在等于或等于 3.5以上7.0重量％以下，共聚单体为C 5〜C 12α-烯烃，丙烯共聚物（A）与丙烯共聚物（B）的重量比为20/80〜 55/45。

54. 发明授权

US09079985B2 Bridged metallocene catalysts 有权
标题翻译：桥接金属茂催化剂
公开(公告)号：US09079985B2
公开(公告)日：2015-07-14
申请号：US13996831
申请日：2011-12-20
申请人： Luigi Resconi , Pascal Castro , Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich
发明人： Luigi Resconi , Pascal Castro , Alexander Z. Voskoboynikov , Vyatcheslav V. Izmer , Dmitry S. Kononovich
IPC分类号： C08F4/6592 , C08F4/642 , C08F4/643 , C08F10/00 , C08F4/76 , C08F4/659 , B01J31/22 , C07F17/00 , C08F4/52 , C08F110/06 , C08F210/06
CPC分类号： C08F4/76 , B01J31/2295 , B01J2231/122 , B01J2531/48 , B01J2531/49 , C07F17/00 , C08F4/52 , C08F4/65908 , C08F4/65927 , C08F10/00 , C08F110/06 , C08F210/06 , C08F4/65912 , C08F2500/03 , C08F2500/12 , C08F210/16
摘要： A solid, particulate catalyst comprising: (i) a complex of formula (I) wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; each R18 is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with at least one R5 group; each R5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5; and each R7 is a C1-C20 hydrocarbyl radical; and (ii) a cocatalyst, preferably comprising an organometallic compound of a Group 13 metal.
摘要翻译：一种固体颗粒催化剂，其包含：（i）式（I）的络合物，其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在原子团上分支到环戊二烯基的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在原子团分支的C 3 -C 20烃基其中原子是硅原子的环戊二烯基环; 每个R18是任选地含有一个或多个属于第14-16族的杂原子的C1-C20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被至少一个R 5基团取代; 每个R 5相同或不同，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环，其被稠合至可任选地被一个或两个基团R 5取代的W; 并且每个R 7是C 1 -C 20烃基; 和（ii）助催化剂，优选包含第13族金属的有机金属化合物。

55. 发明授权

US08933256B2 Catalysts 有权
标题翻译：催化剂
公开(公告)号：US08933256B2
公开(公告)日：2015-01-13
申请号：US13806421
申请日：2011-06-29
申请人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
发明人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
IPC分类号： C08F4/642 , C08F4/6592 , C08F10/00 , C07F17/00 , C08F4/659 , C08F110/06
CPC分类号： C08F4/65912 , C07F17/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F2500/03 , C08F2500/12
摘要： A complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; n is 0-3; each R18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group each R5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5.
摘要翻译：式（I）的络合物：其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20烷基芳基; 每个R 1是在原子团上分支到环戊二烯基的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在原子团分支的C 3 -C 20烃基其中原子是硅原子的环戊二烯基环; n为0-3; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R5基团取代，每个R 5相同或不同，并且是任选地含有一个或多个属于基团14的杂原子的C 1 -C 20烃基 -16; 并且任选地两个相邻的R5基团可以形成另外的单环或多环稠合至可任选被一个或两个基团R 5取代的W。

56. 发明授权

US08742042B2 Process for the preparation of ethylene copolymers 有权
标题翻译：制备乙烯共聚物的方法
公开(公告)号：US08742042B2
公开(公告)日：2014-06-03
申请号：US12226389
申请日：2007-04-06
申请人： Francesca Focante , Luigi Resconi
发明人： Francesca Focante , Luigi Resconi
IPC分类号： C08F4/642 , C08F4/6592 , C08F210/02 , C08F210/08
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65927 , C08F210/08 , C08F2500/17
摘要： A polymerization process comprising contacting under polymerization conditions ethylene and at least one alpha olefin of formula CH2=CHA wherein A is a C2-C20 alkyl radical to obtain a copolymer containing from 95% by mol to 50% by mol of ethylene derived units in the presence of a catalyst system obtainable by contacting: b) at least a metallocene compound of formula (I) b) alumoxane or a compound capable of forming an alkyl metallocene cation; and optionally c) an organo aluminum compound; wherein the groups R1-R4, L, M and W are described in the text.
摘要翻译：聚合方法，包括在聚合条件下使乙烯和至少一种式CH 2 = CHA的α-烯烃接触，其中A是C 2 -C 20烷基，以获得含有95摩尔％至50摩尔％的乙烯衍生单元的共聚物存在可通过以下方式获得的催化剂体系：b）至少一种式（I）的茂金属化合物b）铝氧烷或能够形成烷基金属茂阳离子的化合物; 和任选地c）有机铝化合物; 其中在文中描述了基团R1-R4，L，M和W。

57. 发明授权

US08097681B2 1-butene propylene copolymer compositions 有权
标题翻译： 1-丁烯丙烯共聚物组合物
公开(公告)号：US08097681B2
公开(公告)日：2012-01-17
申请号：US12310508
申请日：2007-08-22
申请人： Giampaolo Pellegatti , Daniele Bigiavi , Rita Martelli , Maria Silvia Tonti , Luigi Resconi , Simona Guidotti
发明人： Giampaolo Pellegatti , Daniele Bigiavi , Rita Martelli , Maria Silvia Tonti , Luigi Resconi , Simona Guidotti
IPC分类号： C08L23/20 , C08F210/08
CPC分类号： C08F210/08 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08L23/20 , C08L2205/02 , C08L2314/06 , Y10S526/943 , C08F2/001 , C08F4/65904 , C08L2666/06 , C08F210/06 , C08F2500/03 , C08F2500/20 , C08F2500/15 , C08F2500/17
摘要： A 1-butene/propylene copolymer composition having a content of propylene derived units from 1 to 4% by weight, wherein at least 50% of the crystalline polymer is present in the thermodynamically stable, trigonal Form I (detected by DSC analysis) after 100 hours of the first melting at room temperature comprising: b) from 5% by weight to 95% by weight of an atactic 1-butene propylene copolymer having the following features: i) distribution of molecular weight Mw/Mn equal to or lower than 4; ii) no enthalpy of fusion detectable at a differential scanning calorimeter (DSC); and iii) infrared crystallinity lower than 0.5%; b) from 5% by weight to 95% by weight of an isotactic 1-butene propylene copolymer having the following features: i) isotactic pentads (mmmm) measured by 13C-NMR, higher than 80%; ii) melting point (Tm(II)) higher than 70° C.; and iii) distribution of molecular weight Mw/Mn equal to or lower than 4.
摘要翻译：具有1至4重量％的丙烯衍生单元含量的1-丁烯/丙烯共聚物组合物，其中至少50％的结晶聚合物存在于热力学稳定的三角形式I（通过DSC分析检测）后100 包括：b）5重量％至95重量％的具有以下特征的无规立构1-丁烯丙烯共聚物：i）分子量Mw / Mn等于或低于4的分布 ; ii）在差示扫描量热计（DSC）处不可检测到融合焓; 和iii）红外结晶度低于0.5％; b）5重量％至95重量％的具有以下特征的全同立构1-丁烯丙烯共聚物：i）通过13 C-NMR测量的全同立构五单元组（mmmm）高于80％; ii）高于70℃的熔点（Tm（II））。和iii）等于或低于4的分子量Mw / Mn的分布。

58. 发明授权

US08003743B2 Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom 有权
标题翻译：金属茂化合物，其制备中使用的配体，由其制备1-丁烯聚合物和1-丁烯聚合物
公开(公告)号：US08003743B2
公开(公告)日：2011-08-23
申请号：US11632383
申请日：2005-05-31
申请人： Luigi Resconi , Friederike Morhard
发明人： Luigi Resconi , Friederike Morhard
IPC分类号： C08F10/00 , C08F10/08 , C08F110/00 , C08F110/08 , C08F210/00 , C08F210/08 , C08F210/16
CPC分类号： C07D495/04 , C07D333/78 , C07F7/08 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F10/08 , C08F110/08 , C08F210/08 , C08F2420/06 , C08F4/65927 , C08F2500/17 , C08F2500/15 , C08F2500/11 , C08F210/16 , C08F210/06 , C08F210/14
摘要： A process for preparing 1-butene polymers comprising polymerizing 1-butene and optionally ethylene, propylene or higher alpha-olefin, in the presence of a catalyst system obtainable by contacting:a) metallocene compound of formula (I): wherein: M is a transition metal; p is an integer from 0 to 3; X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent C1-C40 hydrocarbon radical; R1 is a C1-C40 hydrocarbon radical; T1, is a moiety of formula (IIa) or (IIb): wherein R2 and R3, are C1-C40 hydrocarbon radicals or they can form together a C3-C7-membered ring; R4 is C1-C40 hydrocarbon radicals; T2 and T3, are a moiety of formula (IIIa) or (IIIb): wherein R6 and R7, equal to or different from each other, are hydrogen atoms or C1-C40 hydrocarbon radicals; R5 is a hydrogen atom or a C1-C40 hydrocarbon radicals; with the proviso that if T1 is a moiety of formula (IIa) at least one between T2 and T3 is a moiety of formula (IIIb), and if T1 is a moiety of formula (IIb) at least one between T2 and T3 is a moiety of formula (IIIa); and b) at least an alumoxane or a compound able to form an alkylmetallocene cation.
摘要翻译：一种制备1-丁烯聚合物的方法，包括在可通过使下列物质接触的催化剂体系存在下聚合1-丁烯和任选的乙烯，丙烯或更高级的α-烯烃：a）式（I）的茂金属化合物：其中：M为过渡金属; p是0至3的整数; X相同或不同，是氢原子，卤素原子或烃基; L是二价C 1 -C 40烃基; R1是C1-C40烃基; T1，是式（IIa）或（IIb）的部分：其中R2和R3是C1-C40烃基，或者它们可以一起形成C 3 -C 7 - 元环; R4是C1-C40烃基; T2和T3是式（IIIa）或（IIIb）的部分：其中R6和R7彼此相同或不同，是氢原子或C1-C40烃基; R5是氢原子或C1-C40烃基; 条件是如果T1是式（IIa）的部分，则T2和T3之间的至少一个是式（IIIb）的部分，如果T1是式（IIb）的部分，则T2和T3之间的至少一个是式（IIIa）部分; 和b）至少一种铝氧烷或能够形成烷基茂金属阳离子的化合物。

59. 发明授权

US07964679B2 Process for the polymerization of alpha olefins 失效
标题翻译： α-烯烃聚合方法
公开(公告)号：US07964679B2
公开(公告)日：2011-06-21
申请号：US11919843
申请日：2006-04-12
申请人： Luigi Resconi , Simona Guidotti , Iolanda Santoriello
发明人： Luigi Resconi , Simona Guidotti , Iolanda Santoriello
IPC分类号： C08F4/6592 , C08F10/08 , C07F17/00
CPC分类号： C08F10/08 , C07F7/081 , C07F17/00 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F110/08 , C08F210/08 , Y10S526/943 , C08F4/65927 , C08F2/02 , C08F2500/17 , C08F210/16
摘要： A process for preparing 1-butene polymers, comprising polymerizing 1-butene or copolymerizing 1-butene with ethylene, propylene or an alpha-olefin of formula CH2═CHT wherein T is a C3-C10 alkyl group, in the presence of a catalyst system obtainable by contacting: A) a metallocene compound belonging to formula (I): wherein M is zirconium titanium or hafnium; X, equal to or different from each other, is a hydrogen atom, a halogen atom, a hydrocarbon radical, optionally containing heteroatoms; R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 are hydrogen atoms, or C1-C4O hydrocarbon radicals optionally containing heteroatoms; R1, R2 and R3, are linear or branched, C1-C20-alkyl radicals, optionally containing heteroatoms: B) a lumoxane or a compound capable of forming an alkyl metallocene cation; and optionally C) organo aluminum compound.
摘要翻译：一种制备1-丁烯聚合物的方法，包括在催化剂体系存在下使1-丁烯或1-丁烯与乙烯，丙烯或式CH 2 = CHT的α-烯烃聚合，其中T是C 3 -C 10烷基可通过以下方式获得：A）属于式（I）的茂金属化合物：其中M是锆钛或铪; X，彼此相同或不同，是氢原子，卤素原子，烃基，任选地含有杂原子; R 4，R 5，R 6，R 7，R 8，R 9，R 10，R 11，R 12和R 13是氢原子，或任选地含有杂原子的C 1 -C 40烃基; R 1，R 2和R 3是直链或支链的，任选地含有杂原子的C 1 -C 20烷基：B）能够形成烷基金属茂阳离子的环氧烷或化合物; 和任选的C）有机铝化合物。

60. 发明授权

US07943716B2 Process for polymerizing 1-hexene or higher alpha-olefins 失效
标题翻译：聚合1-己烯或更高级α-烯烃的方法
公开(公告)号：US07943716B2
公开(公告)日：2011-05-17
申请号：US10592563
申请日：2005-03-08
申请人： Luigi Resconi , Eleonora Ciaccia , Friederike Morhard , Giampaolo Pellegatti
发明人： Luigi Resconi , Eleonora Ciaccia , Friederike Morhard , Giampaolo Pellegatti
IPC分类号： C08F4/6592 , C08F4/642 , C08F210/06 , C08F210/08
CPC分类号： C08F210/14 , C08F4/65912 , Y10S526/943 , C08F4/65927 , C08F210/08 , C08F2500/17 , C08F2500/03 , C08F210/06
摘要： A process for preparing a polymer containing derived units of one or more alpha olefins of formula CH2═CHW wherein W is a C3-C10 hydrocarbon radical and optionally from 0 to 81% by mol of derived units of propylene or 1-butene, comprising contacting under polymerization conditions one or more alpha olefins of formula CH2═CHW and optionally propylene or 1-butene in the presence of a catalyst system obtainable by contacting: a) a metallocene compound of formula (I) wherein M, X, L, T1, T2, T3 and R1 are described in the text; and (b) an alumoxane or a compound capable of forming an alkyl metallocene cation.
摘要翻译：一种制备含有一种或多种式CH 2 = CHW的α-烯烃的衍生单元的聚合物的方法，其中W是C 3 -C 10烃基和任选地0至81摩尔％的丙烯或1-丁烯的衍生单元，包括接触在聚合条件下，一种或多种式CH 2 = CHW的α-烯烃和任选的丙烯或1-丁烯在催化剂体系存在下可通过以下方式获得：a）式（I）的茂金属化合物，其中M，X，L， T2，T3和R1在文中描述; 和（b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

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