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1. 发明授权

US08729206B2 Solid particulate catalysts comprising bridged metallocenes 有权
标题翻译：包含桥连金属茂的固体颗粒催化剂
公开(公告)号：US08729206B2
公开(公告)日：2014-05-20
申请号：US13643865
申请日：2011-04-27
申请人： Luigi Resconi , Pascal Castro , Lauri Huhtanen , Norbert Hafner
发明人： Luigi Resconi , Pascal Castro , Lauri Huhtanen , Norbert Hafner
IPC分类号： C08F110/06 , C08F4/642 , C08F4/6592
CPC分类号： C08F4/76 , C08F4/6428 , C08F4/6592 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F4/65927 , C08F2500/12 , C08F2500/17 , C08F2500/03 , C08F2500/15
摘要： A polypropylene homopolymer with a melting point of less than 147° C., a percentage of 2.1 errors of at least 1% and a xylene soluble fraction of less than 0.5 wt %.
摘要翻译：熔点小于147℃的聚丙烯均聚物，至少1％的2.1误差百分比和小于0.5重量％的二甲苯可溶部分。

2. 发明申请

US20130018156A1 CATALYSTS 有权
标题翻译：催化剂
公开(公告)号：US20130018156A1
公开(公告)日：2013-01-17
申请号：US13518698
申请日：2010-12-21
申请人： Luigi Resconi , Pascal Castro , Lauri Huhtanen
发明人： Luigi Resconi , Pascal Castro , Lauri Huhtanen
IPC分类号： C08F4/6592 , C08F110/06
CPC分类号： C08F4/65927 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/06 , Y10S526/943 , C08F2500/12 , C08F2500/15
摘要： A solid particulate catalyst free from an external carrier comprising:(i) a complex of formula (I): whereinM is zirconium or hafnium;each X is a sigma ligand;L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR'2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl;each R1 independently is hydrogen or a linear or branched C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16 of the Periodic Table of the Elements;each R2 and R3 taken together form a 4-7 membered ring condensed to the benzene ring of the indenyl moiety, said ring optionally containing heteroatoms from groups 14-16, each atom forming said ring being optionally substituted with at least one R18 radical;each R18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16;each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16;each W is independently a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group;each R5 is the same of different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5; and(ii) a cocatalyst comprising an organometallic compound of a Group 13 metal, preferably aluminoxane.
摘要翻译：不含外部载体的固体颗粒催化剂，其包含：（i）式（I）的络合物：其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烷基，三（C 1 -C 20 - 烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1独立地是氢或任选地含有一个或多个元素周期表第14-16族的杂原子的直链或支链C 1 -C 20烃基; 每个R 2和R 3一起形成4-烯基部分的苯环稠合的4-7元环，所述环任选地含有14-16个杂原子，形成所述环的每个原子任选被至少一个R 18基团取代; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或任选地含有一个或多个属于第14-16族的杂原子的C 1-6烃基; 每个W独立地是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代; 每个R 5是不同的，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环，其被稠合至可任选地被一个或两个基团R 5取代的W; 和（ii）包含第13族金属的有机金属化合物，优选铝氧烷的助催化剂。

3. 发明申请

US20130289229A1 CATALYSTS 有权
标题翻译：催化剂
公开(公告)号：US20130289229A1
公开(公告)日：2013-10-31
申请号：US13806421
申请日：2011-06-29
申请人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
发明人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
IPC分类号： C08F110/06
CPC分类号： C08F4/65912 , C07F17/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F2500/03 , C08F2500/12
摘要： A complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; n is 0-3; each R18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group each R5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5.
摘要翻译：式（I）的络合物：其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1是在β-原子处与环戊二烯基环分支的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在β-原子处分支到环戊二烯基的C 3 -C 20烃基 β原子是Si原子的环; n为0-3; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R5基团取代，每个R 5相同或不同，并且是任选地含有一个或多个属于基团14的杂原子的C 1 -C 20烃基 -16; 并且任选地两个相邻的R5基团可以形成另外的单环或多环稠合至可任选被一个或两个基团R 5取代的W。

4. 发明申请

US20130131291A1 SOLID PARTICULATE CATALYSTS COMPRISING BRIDGED METALLOCENES 有权
标题翻译：包含桥接金属的固体颗粒催化剂
公开(公告)号：US20130131291A1
公开(公告)日：2013-05-23
申请号：US13643865
申请日：2011-04-27
申请人： Luigi Resconi , Pascal Castro , Lauri Huhtanen , Norbert Hafner
发明人： Luigi Resconi , Pascal Castro , Lauri Huhtanen , Norbert Hafner
IPC分类号： C08F4/76
CPC分类号： C08F4/76 , C08F4/6428 , C08F4/6592 , C08F110/06 , Y10S526/943 , C08F4/65912 , C08F4/65927 , C08F2500/12 , C08F2500/17 , C08F2500/03 , C08F2500/15
摘要： A polypropylene homopolymer with a melting point of less than 147° C., a percentage of 2.1 errors of at least 1% and a xylene soluble fraction of less than 0.5 wt %.
摘要翻译：熔点小于147℃的聚丙烯均聚物，至少1％的2.1误差百分比和小于0.5重量％的二甲苯可溶部分。

5. 发明授权

US08933256B2 Catalysts 有权
标题翻译：催化剂
公开(公告)号：US08933256B2
公开(公告)日：2015-01-13
申请号：US13806421
申请日：2011-06-29
申请人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
发明人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
IPC分类号： C08F4/642 , C08F4/6592 , C08F10/00 , C07F17/00 , C08F4/659 , C08F110/06
CPC分类号： C08F4/65912 , C07F17/00 , C08F4/65927 , C08F110/06 , Y10S526/943 , C08F2500/03 , C08F2500/12
摘要： A complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; n is 0-3; each R18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group each R5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5.
摘要翻译：式（I）的络合物：其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20烷基芳基; 每个R 1是在原子团上分支到环戊二烯基的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在原子团分支的C 3 -C 20烃基其中原子是硅原子的环戊二烯基环; n为0-3; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R5基团取代，每个R 5相同或不同，并且是任选地含有一个或多个属于基团14的杂原子的C 1 -C 20烃基 -16; 并且任选地两个相邻的R5基团可以形成另外的单环或多环稠合至可任选被一个或两个基团R 5取代的W。

6. 发明授权

US09029284B2 Catalysts 有权
标题翻译：催化剂
公开(公告)号：US09029284B2
公开(公告)日：2015-05-12
申请号：US13518698
申请日：2010-12-21
申请人： Luigi Resconi , Pascal Castro , Lauri Huhtanen
发明人： Luigi Resconi , Pascal Castro , Lauri Huhtanen
IPC分类号： C08F4/642 , C08F4/6592 , C08F110/06 , C08F210/06 , C08F4/659 , C08F10/00
CPC分类号： C08F4/65927 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/06 , Y10S526/943 , C08F2500/12 , C08F2500/15
摘要： A solid particulate catalyst free from an external carrier comprising: (i) a complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR′2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-alkyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 independently is hydrogen or a linear or branched C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms from groups 14-16 of the Periodic Table of the Elements; each R2 and R3 taken together form a 4-7 membered ring condensed to the benzene ring of the indenyl moiety, said ring optionally containing heteroatoms from groups 14-16, each atom forming said ring being optionally substituted with at least one R18 radical; each R18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each W is independently a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group; each R5 is the same of different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5; and (ii) a cocatalyst comprising an organometallic compound of a Group 13 metal, preferably aluminoxane.
摘要翻译：不含外部载体的固体颗粒催化剂，其包含：（i）式（I）的络合物：其中M为锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR'2-，-R'2Ge-的二价桥，其中每个R' 独立地为氢原子，C 1 -C 20烷基，三（C 1 -C 20 - 烷基）甲硅烷基，C 6 -C 20 - 芳基，C 7 -C 20 - 芳基烷基或C 7 -C 20 - 烷基芳基; 每个R 1独立地是氢或任选地含有一个或多个元素周期表第14-16族的杂原子的直链或支链C 1 -C 20烃基; 每个R 2和R 3一起形成4-烯基部分的苯环稠合的4-7元环，所述环任选地含有14-16个杂原子，形成所述环的每个原子任选被至少一个R 18基团取代; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或任选地含有一个或多个属于第14-16族的杂原子的C 1-6烃基; 每个W独立地是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代; 每个R 5是不同的，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环，其被稠合至可任选地被一个或两个基团R 5取代的W; 和（ii）包含第13族金属的有机金属化合物，优选铝氧烷的助催化剂。

7. 发明授权

US08946363B2 Solid particulate catalysts comprising bridged metallocenes 有权
标题翻译：包含桥连金属茂的固体颗粒催化剂
公开(公告)号：US08946363B2
公开(公告)日：2015-02-03
申请号：US13643858
申请日：2011-04-27
申请人： Luigi Resconi , Pascal Castro , Lauri Huhtanen
发明人： Luigi Resconi , Pascal Castro , Lauri Huhtanen
IPC分类号： C08F4/642 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F4/659
CPC分类号： C08F4/65927 , C08F4/65912 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F2500/12 , C08F2500/15 , C08F2500/17
摘要： Solid, particulate catalysts comprising bridged bis indenyl π-ligands are disclosed, together with methods for the preparation and use thereof, for example, in olefin polymerization.
摘要翻译：公开了包含桥连双茚基和配体的固体颗粒催化剂，以及其制备和使用方法，例如在烯烃聚合中。

8. 发明申请

US20130116394A1 SOLID PARTICULATE CATALYSTS COMPRISING BRIDGED METALLOCENES 有权
标题翻译：包含桥接金属的固体颗粒催化剂
公开(公告)号：US20130116394A1
公开(公告)日：2013-05-09
申请号：US13643858
申请日：2011-04-27
申请人： Luigi Resconi , Pascal Castro , Lauri Huhtanen
发明人： Luigi Resconi , Pascal Castro , Lauri Huhtanen
IPC分类号： C08F4/6592
CPC分类号： C08F4/65927 , C08F4/65912 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F2500/12 , C08F2500/15 , C08F2500/17
摘要： Solid, particulate catalysts comprising bridged his indenyl n-ligands are disclosed, together with methods for the preparation and use thereat for example, in olefin polymerization.
摘要翻译：公开了包含桥连的茚基n配位体的固体颗粒催化剂，以及用于制备和在其中使用的方法，例如在烯烃聚合中。

9. 发明授权

US08865848B2 Process for olefin polymerisation using group 4 metallocene as catalysts 有权
标题翻译：使用4族茂金属作为催化剂的烯烃聚合方法
公开(公告)号：US08865848B2
公开(公告)日：2014-10-21
申请号：US13806386
申请日：2011-06-29
申请人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
发明人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
IPC分类号： C08F4/6592 , C08F4/642 , C08F210/06 , B01J31/22 , C08F210/16 , C08F4/659
CPC分类号： C08F4/6592 , C08F4/65912 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F2500/12 , C08F2500/03 , C08F4/65927
摘要： A process for the preparation of a random propylene copolymer comprising polymerizing propylene and at least one C2-10 alpha olefin (especially ethylene) in the presence of a catalyst; wherein said catalyst comprises: (i) a complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; n is 0-3; each R18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group; each R5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5; and (ii) a cocatalyst comprising an organometallic compound of a Group 13 metal.
摘要翻译：一种制备无规丙烯共聚物的方法，包括在催化剂存在下聚合丙烯和至少一种C 2-10α-烯烃（特别是乙烯）; 其中所述催化剂包括：（i）式（I）的络合物：其中M是锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR2-，-R'2Ge-的二价桥，其中每个R'独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20芳基，C 7 -C 20芳基烷基或C 7 -C 20烷基芳基; 每个R 1是在原子团上分支到环戊二烯基的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在原子团分支的C 3 -C 20烃基其中原子是硅原子的环戊二烯基环; n为0-3; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代; 每个R 5相同或不同，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环，其被稠合至可任选地被一个或两个基团R 5取代的W; 和（ii）包含第13族金属的有机金属化合物的助催化剂。

10. 发明申请

US20130217845A1 PROCESS FOR OLEFIN POLYMERISATION USING GROUP 4 METALLOCENE AS CATALYSTS 有权
标题翻译：使用第4组金属催化剂进行烯烃聚合的方法
公开(公告)号：US20130217845A1
公开(公告)日：2013-08-22
申请号：US13806386
申请日：2011-06-29
申请人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
发明人： Pascal Castro , Luigi Resconi , Lauri Huhtanen
IPC分类号： C08F210/16
CPC分类号： C08F4/6592 , C08F4/65912 , C08F210/06 , C08F210/16 , Y10S526/943 , C08F2500/12 , C08F2500/03 , C08F4/65927
摘要： A process for the preparation of a random propylene copolymer comprising polymerising propylene and at least one C2-10 alpha olefin (especially ethylene) in the presence of a catalyst; wherein said catalyst comprises: (i) a complex of formula (I): wherein M is zirconium or hafnium; each X is a sigma ligand; L is a divalent bridge selected from —R′2C—, —R′2C—CR′2—, —R′2Si—, —R′2Si—SiR2—, —R′2Ge—, wherein each R′ is independently a hydrogen atom, C1-C20-hydrocarbyl, tri(C1-C20-alkyl)silyl, C6-C20-aryl, C7-C20-arylalkyl or C7-C20-alkylaryl; each R1 is a C4-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring, optionally containing one or more heteroatoms belonging to groups 14-16, or is a C3-C20 hydrocarbyl radical branched at the β-atom to the cyclopentadienyl ring where the β-atom is an Si-atom; n is 0-3; each R18 is the same or different and may be a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; each R4 is a hydrogen atom or a C1-6-hydrocarbyl radical; each W is a 5 or 6 membered aryl or heteroaryl ring wherein each atom of said ring is optionally substituted with an R5 group; each R5 is the same or different and is a C1-C20 hydrocarbyl radical optionally containing one or more heteroatoms belonging to groups 14-16; and optionally two adjacent R5 groups taken together can form a further mono or multicyclic ring condensed to W optionally substituted by one or two groups R5; and (ii) a cocatalyst comprising an organometallic compound of a Group 13 metal.
摘要翻译：一种制备无规丙烯共聚物的方法，包括在催化剂存在下聚合丙烯和至少一种C 2-10α-烯烃（特别是乙烯）; 其中所述催化剂包括：（i）式（I）的络合物：其中M是锆或铪; 每个X是σ配体; L是选自-R'2C-，-R'2C-CR'2-，-R'2Si-，-R'2Si-SiR2-，-R'2Ge-的二价桥，其中每个R'独立地为氢原子，C 1 -C 20烃基，三（C 1 -C 20烷基）甲硅烷基，C 6 -C 20芳基，C 7 -C 20芳基烷基或C 7 -C 20烷基芳基; 每个R 1是在β-原子处与环戊二烯基环分支的C 4 -C 20烃基，任选地含有一个或多个属于第14-16族的杂原子，或者是在β-原子处分支到环戊二烯基的C 3 -C 20烃基 β原子是Si原子的环; n为0-3; 每个R 18相同或不同，并且可以是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 每个R 4是氢原子或C 1-6烃基; 每个W是5或6元芳基或杂芳基环，其中所述环的每个原子任选被R 5基团取代; 每个R 5相同或不同，并且是任选地含有一个或多个属于第14-16族的杂原子的C 1 -C 20烃基; 并且任选地两个相邻的R5基团可以形成另外的一个或多个环，其被稠合至可任选地被一个或两个基团R 5取代的W; 和（ii）包含第13族金属的有机金属化合物的助催化剂。

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