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    • 53. 发明授权
    • Polymerization process and polymers produced thereby
    • 聚合方法和由此生产的聚合物
    • US4581429A
    • 1986-04-08
    • US629929
    • 1984-07-11
    • David H. SolomonEzio RizzardoPaul Cacioli
    • David H. SolomonEzio RizzardoPaul Cacioli
    • C08C19/22C08F4/00C08F4/32C08F291/00
    • C08F4/00C08C19/22C08F291/00
    • The present invention relates generally to improved processes for free radical polymerization, particularly to improved processes in which it is possible to control the growth steps of the polymerization to produce relatively short chain length homopolymers and copolymers, including block and graft copolymers, and further relates to new initiators which find particular application in the improved processes. Such initiators have the general structure of Formula I ##STR1## wherein X represents a group having at least one carbon atom and is such that the free radical X.sup.. is capable of polymerizing the unsaturated monomer by free radical polymerization, and the radical functionality resides on the or one of the carbon atoms,R.sup.1, R.sup.2, R.sup.5 and R.sup.6 represent the same or different straight chain or branched substituted or unsubstituted alkyl groups of a chain length sufficient to provide steric hindrance and weakening of the O--X bond, andR.sup.3 and R.sup.4 represent the same or different straight chain or branched substituted alkyl groups or R.sup.3 CNCR.sup.4 may be part of a cyclic structure which may have fused with it another saturated or aromatic ring, the cyclic structure or aromatic ring being optionally substituted.
    • 本发明一般涉及自由基聚合的改进方法,特别是改进方法,其中可以控制聚合的生长步骤以产生相对较短的链长均匀聚合物和共聚物,包括嵌段和接枝共聚物,还涉及 在改进过程中发现特定应用的新发起者。 这种引发剂具有通式I(I)的一般结构,其中X表示具有至少一个碳原子的基团,并且使得自由基X能够通过自由基聚合使不饱和单体聚合,并且基团 官能团位于碳原子或其中一个碳原子上,R1,R2,R5和R6表示相同或不同的直链或支链取代或未取代的烷基,其链长足以提供OX键的空间位阻和弱化,R3 并且R 4表示相同或不同的直链或支链取代的烷基或R 3 CNCR 4可以是可以与其另一个饱和或芳环稠合的环状结构的一部分,环状结构或芳环任选被取代。
    • 57. 发明授权
    • Polyurethane or polyurethane-urea elastomeric compositions
    • 聚氨酯或聚氨酯 - 脲弹性体组合物
    • US5393858A
    • 1995-02-28
    • US962799
    • 1993-02-23
    • Gordon F. MeijsEzio RizzardoArthur BrandwoodPathiraja GunatillakeKlaus H. Schindhelm
    • Gordon F. MeijsEzio RizzardoArthur BrandwoodPathiraja GunatillakeKlaus H. Schindhelm
    • A61L27/00A61L17/04A61L27/18A61L29/00A61L29/06A61L31/00C08G18/10C08G18/48C08G18/65C08G18/66C08G18/76C08G18/30
    • C08G18/765A61L17/04A61L27/18A61L29/06C08G18/10C08G18/4858
    • A polyurethane or polyurethane-urea elastomeric composition, characterized in that the composition is a reaction product of:(A) a soft segment macrodiol which is either:(i) a homopolymer represented by formula I,HO--[(CH.sub.2).sub.n O].sub.m --H Iwherein n represents an integer greater than 5 and less than 13, m is a number such that the number average molecular weight of the compound of formula I falls in the range from 218 to 5000 and optionally at least one hydrogen atom represented in formula I is substituted by a C.sub.1 to C.sub.3 alkyl group or a halogen atom;(ii) a copolymer containing at least 25% by mass of repeating units --(CH.sub.2).sub.n O-- wherein n is as defined in formula I above; or(iii) mixture of macrodiols comprising greater than 10% of a macrodiol as defined in formula I above;(B ) an aliphatic or aromatic diisocyanate known in the art of polyurethane manufacture; and(C) optionally a chain extender.A biomaterial and a medical device which are composed wholly or partly of the polyurethane or polyurethane-urea elastomeric composition are also described.
    • PCT No.PCT / AU91 / 00270 Sec。 371日期:1993年2月23日 102(e)1993年2月23日PCT PCT 1991年6月26日PCT公布。 出版物WO92 / 日本1992年1月9日。一种聚氨酯或聚氨酯 - 脲弹性体组合物,其特征在于所述组合物是以下物质的反应产物:(A)软段大分子二醇,其为:(i)由式I表示的均聚物,HO- [(CH 2)n O] m-HI其中n表示大于5且小于13的整数,m是使式I化合物的数均分子量在218至5000的范围内的数, 式I中表示的至少一个氢原子被C1至C3烷基或卤素原子取代; (ii)含有至少25质量%的重复单元 - (CH 2)n O-的共聚物,其中n如上述式I中所定义; 或(iii)包含大于10%上述式I定义的大分子二醇的大分子二醇的混合物; (B)聚氨酯制造领域已知的脂族或芳族二异氰酸酯; 和(C)任选的扩链剂。 还描述了全部或部分由聚氨酯或聚氨酯 - 脲弹性体组合物组成的生物材料和医疗装置。