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    • 4. 发明授权
    • Polymerization with living characteristics
    • 具有生活特性的聚合
    • US07666962B2
    • 2010-02-23
    • US11805949
    • 2007-05-25
    • Tam Phuong LeGraeme MoadEzio RizzardoSan Hoa Thang
    • Tam Phuong LeGraeme MoadEzio RizzardoSan Hoa Thang
    • C08F2/00
    • C08K5/38C07C327/36C07C329/00C07F9/4065C08F2/38C08F12/08C08F293/00C08F293/005C08L25/06
    • This invention concerns a free radical polymerization process, selected chain transfer agents employed in the process and polymers made thereby, in which the process comprises preparing polymer of general Formula (A) and Formula (B) comprising contacting: (i) a monomer selected from the group consisting of vinyl monomers (of structure CH2=CUV), maleic anhydride, N-alkylmaleimide, N-arylmaleimide, dialkyl fumarate and cyclopolymerizable monomers; (ii) a thiocarbonylthio compound selected from Formula (C) and Formula (D) having a chain transfer constant greater than about 0.1; and (iii) free radicals produced from a free radical source; the polymer of Formula (A) being made by contacting (i), (ii) C and (iii) and that of Formula (B) by contacting (i), (ii) D, and (iii); and (iv) controlling the polydispersity of the polymer being formed by varying the ratio of the number of molecules of (ii) to the number of molecules of (iii); wherein Q, R, U, V, Z, Z′, m, p and q am as defined in the text.
    • 本发明涉及自由基聚合方法,该方法中使用的选择的链转移剂和由此制备的聚合物,其中该方法包括制备通式(A)和式(B)的聚合物,其包括:(i)选自 由乙烯基单体(结构CH 2 = CUV),马来酸酐,N-烷基马来酰亚胺,N-芳基马来酰亚胺,富马酸二烷基酯和可环化聚合的单体组成的组; (ii)选自式(C)和式(D)的硫代羰基硫代化合物,其链转移常数大于约0.1; 和(iii)自由基产生的自由基; 式(A)的聚合物通过使(i),(ii)D和(iii)接触而使(i),(ii)C和(iii)与式(B) 和(iv)通过改变(ii)的分子数与(iii)的分子数之比来控制形成的聚合物的多分散性; 其中如文中所定义的Q,R,U,V,Z,Z',m,p和q am。