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    • 6. 发明授权
    • Initiating system for solid polyester granule manufacture
    • 固体聚酯颗粒制造的启动系统
    • US06533967B1
    • 2003-03-18
    • US09868910
    • 2001-08-23
    • Philip John Allan RitchieAlgirdas Kazimieras SerelisBruce Leary
    • Philip John Allan RitchieAlgirdas Kazimieras SerelisBruce Leary
    • C09K2100
    • C08F283/01C08F4/28
    • The invention relates to the use of a diacyl peroxide in combination with an aromatic amine of formula (I) where R1 is C1-C20 alkyl having at least one hydroxy substituent or —(CH′CHR′—O)nH where n is 1 to 10 and each R′ is independently selected from H and C1-C3 alkyl; R2 is C1-C20 alkyl optionally substituted with one or more hydroxy groups, or —(CHR′CHR′—O)nH where n=1 to 10; and each R is independently selected from H and C1-C3 alkyl; and Ar is an optionally substituted aryl group; as a redox initiating system in a process for the manufacture of polyester granules by suspension polymerisation. This invention also relates to a process for preparing solid polyester granules using such a redox initiating system.
    • 本发明涉及二酰基过氧化物与式(I)的芳族胺的组合的用途,其中R 1是具有至少一个羟基取代基的C 1 -C 20烷基或 - (CH'CHR'-O)n H,其中n为1至 10,每个R'独立地选自H和C 1 -C 3烷基; R2是任选被一个或多个羟基取代的C 1 -C 20烷基,或 - (CHR'CHR'-O)nH,其中n = 1-10; 并且每个R独立地选自H和C 1 -C 3烷基; 和Ar是任选取代的芳基; 作为通过悬浮聚合制造聚酯颗粒的方法中的氧化还原引发体系。 本发明还涉及使用这种氧化还原引发体系制备固体聚酯颗粒的方法。