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51. 发明授权

US4500720A Tetrahydrofuran-2-ones 失效
标题翻译：四氢呋喃-2-酮
公开(公告)号：US4500720A
公开(公告)日：1985-02-19
申请号：US571995
申请日：1984-01-19
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/73 , A01N43/08 , C07C51/00 , C07C51/09 , C07C59/74 , C07C67/00 , C07D307/33 , C07D307/93 , C07F9/655 , C07D307/32
CPC分类号： C07D307/33 , C07C59/74 , C07D307/93
摘要： Novel 3-formyl-4-methyl-pent-3-ene-1-oic acid of the formula ##STR1## and a process for its preparation and intermediates and a process for the preparation of compounds of the formula ##STR2## wherein W is selected from the group consisting of hydrogen and R.sub.1 of an optionally chiral alcohol R.sub.1 OH, useful as an intermediate for the production of numerous ester having elevated insecticidal activity.
摘要翻译：具有下式的新颖的3-甲酰基-4-甲基 - 戊-3-烯-1-酸及其制备方法和中间体以及制备式（VI）的化合物的方法其中 W选自氢和任选的手性醇R 1 R的R 1，其可用作生产具有高杀虫活性的多种酯的中间体。

52. 发明授权

US4401601A Novel process for the preparation of tetra-substituted cyclopropane compounds 失效
标题翻译：制备四取代环丙烷化合物的新方法
公开(公告)号：US4401601A
公开(公告)日：1983-08-30
申请号：US246172
申请日：1981-03-23
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/74 , C07C51/00 , C07C61/04 , C07C61/125 , C07C67/00 , C07C253/00 , C07C255/46 , C07C313/00 , C07C315/04 , C07C317/44 , C07C121/46
CPC分类号： C07C317/44
摘要： A process for the preparation of tetrasubstituted cyclopropane compounds of the formula ##STR1## wherein Y is selected from the group consisting of --CN and --COOR, R is selected from the group consisting of hydrogen and alkyl of 1 to 6 carbon atoms and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are individually selected from alkyl of 1 to 4 carbon atoms or R.sub.1 and R.sub.2 or R.sub.3 and R.sub.4 together with the carbon atoms to which they are attached form a carbon homocycle of 3 to 6 carbon atoms with the 2 substituents not forming the ring being alkyl of 1 to 4 carbon atoms or R.sub.1 and R.sub.2 on the one hand and R.sub.3 and R.sub.4 on the other together with the carbon atom to which they are attached form a carbon homocycle of 3 to 6 carbon atoms which are useful intermediates for the preparation of insecticidal esters and novel intermediates.
摘要翻译：制备式IMA的四取代环丙烷化合物的方法，其中Y选自-CN和-COOR，R选自氢和1至6个碳原子的烷基，R 1 ，R 2，R 3和R 4分别选自1至4个碳原子的烷基或R 1和R 2或R 3和R 4与它们所连接的碳原子一起形成3至6个碳原子的碳均碳原子，而2个取代基不是形成环为1至4个碳原子的烷基或R 1和R 2，另一方面R 3和R 4与它们所连接的碳原子一起形成具有3至6个碳原子的碳原子，这是有用的中间体用于制备杀虫剂和新型中间体。

53. 发明授权

US4357335A Substituted pyridine methyl esters of dimethyl cyclopropane carboxylic acids and their use as insecticides 失效
标题翻译：二甲基环丙烷羧酸的取代吡啶甲酯及其作为杀虫剂的用途
公开(公告)号：US4357335A
公开(公告)日：1982-11-02
申请号：US280547
申请日：1981-07-06
申请人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
IPC分类号： A01N53/04 , A01N53/00 , A01N53/08 , A61K31/44 , C07D213/64 , C07D213/643 , C07D213/647 , C07D213/70 , C07D405/12 , C07D409/12 , C07D213/55
CPC分类号： C07D213/643 , A01N53/00 , A61K31/44 , C07D213/647 , C07D213/70
摘要： Novel esters in all possible isomeric forms and mixtures thereof of the formula ##STR1## wherein A is selected from the group consisting of ##STR2## R is selected from the group consisting of hydrogen, --CN and --C.tbd.CH, Y is selected from the group consisting of oxygen and sulfur, Z is selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, alkylthio and alkylsulfonyl of 1 to 4 carbon atoms, cycloalkyl of 3 to 4 carbon atoms, 3,4-methylenedioxy, chlorine, fluorine and bromine, n is an integer of 0, 1 or 2, Z.sub.1 and Z.sub.2 may both be methyl or Z.sub.1 is hydrogen and Z.sub.2 is ##STR3## R.sub.3 is selected from the group consisting of hydrogen and halogen, R.sub.1 and R.sub.2 are individually alkyl of 1 to 8 carbon atoms or taken together with the carbon they are attached to form cycloalkyl of 3 to 6 carbon atoms or ##STR4## X is selected from the group consisting of oxygen and sulfur, T is at least one member of the group consisting of halogen, alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms optionally substituted with at least one halogen and --CF.sub.3 and m is an integer from 0, 1 or 2 having insecticidal activity as well as nematocidal and acaricidal activity.
摘要翻译：所有可能的异构体形式的新型酯及其下式的混合物，其中A选自由下列组成的组：R 1选自氢，-CN和-C 3位CH，Y选自 Z为选自由1至4个碳原子的烷基和烷氧基组成的组，1至4个碳原子的烷硫基和烷基磺酰基，3至4个碳原子的环烷基，3,4-亚甲二氧基，氯，氟和溴，n是0,1或2的整数，Z1和Z2都可以是甲基或Z1是氢，Z2是选自氢和卤素，R1和R2 具有1至8个碳原子的单独烷基或与它们所连接的碳一起形成3至6个碳原子的环烷基，或者X选自氧和硫，T是至少一个由卤素，1至8个碳原子的烷基，1至8个的烷氧基组成的组任选被至少一个卤素和-CF 3取代的碳原子，m是具有杀虫活性以及杀线虫和杀螨活性的0,1或2的整数。

54. 发明授权

US4328167A Process for the preparation of optically active cyano alcohols 失效
标题翻译：光学活性氰醇的制备方法
公开(公告)号：US4328167A
公开(公告)日：1982-05-04
申请号：US155753
申请日：1980-06-02
申请人： Jacques Martel , Jean Tessier , Jean-Pierre DeMoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre DeMoute
IPC分类号： C07B53/00 , C07B31/00 , C07C51/09 , C07C67/00 , C07C253/00 , C07C255/37 , C07C255/39 , C07C121/75
CPC分类号： C07C51/09
摘要： A novel process for the preparation of optically active alcohols of the formula ##STR1## wherein R.sub.1 and R.sub.2 are individually selected from the group consisting of hydrogen, saturated and unsaturated, optionally substituted aliphatic, cycloaliphatic, aromatic and heterocyclic, with the proviso that at least one of R.sub.1 and R.sub.2 is other than hydrogen, and R.sub.1 and R.sub.2 taken together with the carbon atom to which they are attached form a hydrocarbon ring comprising reacting an ester of an optically active alcohol of the formula ##STR2## wherein A is the organic radical of a chiral carboxylic acid of the formula ##STR3## with a boron halide and reacting the resulting mixture with water to obtain the optically active isomer of the alcohol of formula I with the same configuration of the alcohol moiety of the starting ester in high yields without by-products of known processes.
摘要翻译：一种制备下式的光学活性醇的新方法，其中R 1和R 2分别选自氢，饱和和不饱和的，任选取代的脂族，脂环族，芳族和杂环的，条件是在 R1和R2中的至少一个不是氢，R1和R2与它们所连接的碳原子一起形成烃环，包括使下式的光学活性醇的酯反应其中A是具有式“IMAGE”的手性羧酸的有机基团与卤化硼反应，并将所得混合物与水反应，得到具有相同构型的起始酯的醇部分的式I醇的旋光异构体，产量没有已知方法的副产物。

55. 发明授权

US4315943A Cyclopropyl-carboxylates used as nematocides 失效
标题翻译：用作杀线虫剂的环丙基羧酸盐
公开(公告)号：US4315943A
公开(公告)日：1982-02-16
申请号：US132836
申请日：1980-03-24
申请人： Jacques Martel , Jean Tessier
发明人： Jacques Martel , Jean Tessier
IPC分类号： A61K31/275 , A01N53/00 , A01N53/08 , A01N53/14 , A01P7/04 , A61P33/00 , C07C67/00 , C07C253/00 , C07C253/30 , C07C255/39 , C07C255/53 , A01N37/34
CPC分类号： C07C255/00 , A01N53/00
摘要： Novel (R,S) and (S).alpha.-cyano-3-phenoxy-benzyl esters of cyclopropane carboxylic acids of the formula ##STR1## wherein n is an integer from 1,2 or 3 and the acid is (IR, trans) or IR, cis) which have excellent pesticidal activity and their preparation.
摘要翻译：式（I）的环丙烷羧酸的新型（R，S）和（S）α-氰基-3-苯氧基 - 苄基酯，其中n是1,2或3的整数，酸是（IR，）或IR，顺式），其具有优良的杀虫活性及其制备。

56. 发明授权

US4273727A (S) .alpha.-Cyano-3-phenoxy-benzyl alcohol 失效
标题翻译：（S）α-氰基-3-苯氧基 - 苄醇
公开(公告)号：US4273727A
公开(公告)日：1981-06-16
申请号：US973791
申请日：1978-12-28
申请人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
IPC分类号： A01N37/34 , A01N37/10 , A01N37/38 , A01N53/08 , A01P7/04 , C07B57/00 , C07C57/58 , C07C67/00 , C07C253/00 , C07C253/30 , C07C253/34 , C07C255/33 , C07C255/36 , C07C255/37 , C07C255/39 , C07C255/53 , C07D307/93 , C07C121/75
CPC分类号： C07D307/93 , A01N37/38 , C07C255/00 , C07C255/53 , C07C57/58
摘要： (S) .alpha.-cyano-3-phenoxy-benzyl alcohol having the formula ##STR1## and a novel process for its preparation and novel intermediates.
摘要翻译：（S）具有式“IMAGE”I的α-氰基-3-苯氧基 - 苄醇和其制备新颖的方法和新型中间体。

57. 发明授权

US4111994A Preparation of optically active allethrolone 失效
标题翻译：光学活性依托罗酮的制备
公开(公告)号：US4111994A
公开(公告)日：1978-09-05
申请号：US820096
申请日：1977-07-29
申请人： Jacques Martel , Jean Tessier
发明人： Jacques Martel , Jean Tessier
IPC分类号： C07C49/743 , C07B31/00 , C07B55/00 , C07B57/00 , C07C45/00 , C07C45/42 , C07C45/67 , C07C49/707 , C07C67/00 , C07C309/73 , C07C45/24
CPC分类号： C07C309/00 , C07C45/673
摘要： A process for the preparation of optically active allethrolone of (S) or (R) configuration comprising reacting in at least one organic solvent a sulfonate of optically active allethrolone of (R) or (S) configuration of the formula ##STR1## wherein X is selected from the group consisting of alkyl of 1 to 3 carbon atoms and phenyl optionally substituted in the p-position with a member of the group consisting of methyl, chlorine, bromine and fluorine with a salt of an organic carboxylic acid selected from the group consisting of aliphatic carboxylic acids of 1 to 6 carbon atoms optionally substituted with one or more halogens and a monocyclic aromatic carboxylic acid to form the ester of the carboxylic acid and (S) or (R) allethrolone antipodal to that of the starting sulfonate of allethrolone and subjecting the latter to acid hydrolysis to form (S) or (R) allethrolone antipodal to the starting sulfonate which allethrolones form insecticidally active esters with cyclopropane carboxylic acids.
摘要翻译：一种用于制备（S）或（R）构型的光学活性缓释剂的方法，包括在至少一种有机溶剂中使式（I）的（R）或（S）构型的光学活性羟基丙酸酯的磺酸盐反应，其中X 选自由1-3个碳原子的烷基组成的组，和在p位上被选自甲基，氯，溴和氟的成员的任选取代的苯基与选自下组的有机羧酸的盐由任选被一个或多个卤素和单环芳族羧酸取代的具有1至6个碳原子的脂族羧酸组成，以形成羧酸和（S）或（R）依托罗酮对映体的酯，与抗坏血酸的起始磺酸酯并对其进行酸水解以形成（S）或（R）抗坏血酸对起始磺酸盐，其中环丙砜与环丙烷羧酸形成杀虫活性酯 cids。

58. 发明授权

US4053597A Hydroxy-phenylacetamido cephalosporin compositions and method of use 失效
标题翻译：羟基苯乙酮胺CEPHALOSPORIN组合物及其使用方法
公开(公告)号：US4053597A
公开(公告)日：1977-10-11
申请号：US635383
申请日：1975-11-25
申请人： Jacques Martel , Rene Heymes , Andre Lutz
发明人： Jacques Martel , Rene Heymes , Andre Lutz
IPC分类号： A61K31/545 , C07D501/22
CPC分类号： C07D501/22
摘要： Cephalosporan compounds of the formula ##STR1## in the form of racemic mixtures or optically active isomers or in the form of their cis or trans isomers or mixtures thereof wherein R is selected from the group consisting of phenyl substituted with at least one hydroxyl and sydnone optionally substituted with phenyl, R' is selected from the group consisting of hydrogen and R", R" is an ester group easily removable by acid hydrolysis or hydrogenolysis, R.sub.1 and R.sub.2 are alkyl of 1 to 3 carbon atoms, R.sub.3 is selected from the group consisting of hydrogen and alkyl of 1 to 3 carbon atoms, Y is selected from the group consisting of amino and Y', Y' is hydrogen and NHCOOZ, Z is straight or branched alkyl of 1 to 5 carbon atoms and their non-toxic, pharmaceutically acceptable addition salts with organic and inorganic acids and bases where appropriate with the proviso that when Y is amino, R' is hydrogen and when Y is amino or NHCOOZ, R is phenyl which have antibacterial activity and their preparation.

59. 发明授权

US3962223A Substituted cephene-4-carboxylates and their method of preparation 失效
标题翻译：取代的CEPHENE-4-羧酸酯及其制备方法
公开(公告)号：US3962223A
公开(公告)日：1976-06-08
申请号：US320493
申请日：1973-01-02
申请人： Jacques Martel , Rene Heymes
发明人： Jacques Martel , Rene Heymes
IPC分类号： A61K31/545 , B01J23/44 , C07D209/48 , C07D303/48 , C07D501/08 , C07D501/18 , C07D501/20 , C07D501/22 , C07D501/24 , C07D501/06
CPC分类号： C07D209/48 , B01J23/44 , C07C255/00 , C07D303/48
摘要： Novel desacetoxycephalosporin derivatives of the formula ##EQU1## in racemic or optically active form or cis and trans forms and mixtures thereof wherein R is selected from the group consisting of aminophenyl and R', R' is selected from the group consisting of phenyl optionally substituted with at least one member of the group consisting of halogen and nitro and a 5 to 6 member heterocyclic group, Y is selected from the group consisting of amino, NHCOOR" where R" is alkyl of 1 to 5 carbon atoms, hydrogen and hydroxy, A is selected from the group consisting of alkyl of 2 to 5 carbon atoms and cycloalkyl of 3 to 7 carbon atoms optionally containing a heteroatom and R.sub.1 is selected from the group consisting of hydrogen, easily acid hydrolyzable group and easily hydrogenolysis removable group, with the proviso that when R is aminophenyl Y is other than amino and NHCOOR" and R.sub.1 is hydrogen and when Y is amino, R.sub.1 is hydrogen and the non-toxic pharmaceutically acceptable addition salts of with organic and inorganic bases and acids where appropriate which have antibacterial activity and a novel process for their preparation and novel intermediates therefor.

60. 发明授权

US4720556A 3-oxabicyclo-(3,1,0)-hexan-2-ones 失效
标题翻译： 3-氧杂双环 - （3,1,0） - 己烷-2-酮
公开(公告)号：US4720556A
公开(公告)日：1988-01-19
申请号：US930770
申请日：1986-11-14
申请人： Jacques Martel , Jean Tessier , Andre Teche
发明人： Jacques Martel , Jean Tessier , Andre Teche
IPC分类号： B01J31/02 , C07B31/00 , C07B57/00 , C07B61/00 , C07C27/00 , C07C29/10 , C07C29/88 , C07C37/86 , C07C41/18 , C07C43/295 , C07C45/57 , C07C51/487 , C07C62/02 , C07C62/04 , C07C67/00 , C07D307/33 , C07D307/88 , C07D307/93 , C07D315/00
CPC分类号： C07D307/33 , C07C29/10 , C07C41/26 , C07C43/295 , C07C45/57 , C07D307/93 , C07D315/00 , C07B2200/07 , C07C2101/14
摘要： Novel ethers of organic compounds containing chiral atoms of the formula ##STR1## wherein A is a hydrocarbonated chain of 1 to 10 groups, the said chain containing one or more heteroatoms, one or more unsaturations, the assembly of the groups constituting the chain may represent a mono- or polycyclic system, including a system of the spiro or endo type, the chain A can contain one or more chiral atoms or the lactone moiety can present a chirality due to the dissymetric spatial configuration of the whole of the molecule and Z is selected from the group consisting of primary, secondary or tertiary alcohol moiety containing at least an asymetric carbon atom, a phenol moiety substituted comprising at least one asymetric carbon atom and an substituted alcohol or phenol moiety with a chirality due to the dissymetric spatial configuration of the whole of the molecule, with the proviso Z is not (R) or (S) .alpha.-cyano-3-phenoxy-benzyl when A is ##STR2## which are useful for the resolution of compounds of the formulae ##STR3## wherein A and Z have the above definitions and X is selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms.
摘要翻译：含有式（I）的手性原子的有机化合物的新型醚，其中A是1至10个基团的烃化链，所述链含有一个或多个杂原子，一个或多个不饱和基团，构成链的基团的组合代表单环或多环系统，包括螺或内型的系统，链A可以含有一个或多个手性原子，或者内酯部分可以呈现手性，这是由于整个分子的不对称空间结构和Z 选自包含至少一个不对称碳原子的伯，仲或叔醇部分，被至少一个不对称碳原子取代的苯酚部分和具有手性的取代的醇或苯酚部分，这些部分具有由于不对称空间构型的手性整个分子，条件是Z不是（R）或（S）α-氰基-3-苯氧基 - 苄基，当A是，其可用于分辨c 其中A和Z具有上述定义并且X选自氢和1至4个碳原子的烷基的式的化合物。

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