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51. 发明授权

US4446157A Prenyl methyl carbonate and organoleptic uses thereof 失效
公开(公告)号：US4446157A
公开(公告)日：1984-05-01
申请号：US528544
申请日：1983-09-01
申请人： Richard M Boden , Manfred H. Vock , Theodore J. Tyszkiewicz
发明人： Richard M Boden , Manfred H. Vock , Theodore J. Tyszkiewicz
IPC分类号： A23L27/20 , A23L1/226 , A23L1/235
CPC分类号： A23L27/2052 , A23L27/202
摘要： Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma augmenting, modifying, enhancing and imparting compositions and as foodstuffs, chewing gums, toothpastes and medicinal product aroma imparting materials of prenyl methyl carbonate defined according to the structure: ##STR1## Also described are uses of said prenyl methyl carbonate in conjunction with cyclic acetals of 2-methyl-2-pentenal defined according to the structures: ##STR2##

52. 发明授权

US4374054A Use in perfumery of carboalkoxy alkyl norbornanes 失效
标题翻译：用于香料中的烷氧基烷基降冰片烷烃
公开(公告)号：US4374054A
公开(公告)日：1983-02-15
申请号：US303163
申请日：1981-09-17
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A61K7/46
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Use in perfumery are compounds both separately and in admixture having the generic structure: ##STR1## wherein the dashed line is either a carbon-carbon single bond or a carbon-carbon double bond and each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.6 and R.sub.7 represents hydrogen or methyl with the proviso that one of R.sub.1, R.sub.2, R.sub.6 and R.sub.7 is methyl and each of the other of R.sub.1, Rhd 2, R.sub.6 and R.sub.7 is hydrogen and R.sub.3 and R.sub.4 are not both methyl; wherein R.sub.5 represents C.sub.1 -C.sub.4 alkyl are disclosed.
摘要翻译：在香料中使用的化合物分别是具有通用结构的化合物：其中虚线是碳 - 碳单键或碳 - 碳双键，R1，R2，R3，R4，R6和 R 7表示氢或甲基，条件是R 1，R 2，R 6和R 7中的一个为甲基，R 1，R 2d，R 6和R 7中的每一个为氢，且R 3和R 4不为甲基; 其中R5代表C1-C4烷基。

53. 发明授权

US4360032A Use of hydrogenated derivatives of 2,6,6-trimethyl-cyclohexene derivatives in augmenting or enhancing the aroma or taste of smoking tobacco and smoking tobacco articles 失效
标题翻译：使用2,6,6-三甲基 - 环己烯衍生物的氢化衍生物来增强或增强吸烟烟草和烟草制品的香气或味道
公开(公告)号：US4360032A
公开(公告)日：1982-11-23
申请号：US239052
申请日：1981-02-27
申请人： Robert W. Trenkle , Braja D. Mookherjee , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Robert W. Trenkle , Braja D. Mookherjee , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A24B15/34 , C07C45/62 , C07C49/303 , C07C49/543 , C11B9/00 , A24B3/12 , A24B15/30
CPC分类号： C11B9/0034 , A24B15/34 , C07C45/62 , C07C49/303 , C07C49/543
摘要： Described is the use of augmenting or enhancing the aroma or taste of smoking tobacco or smoking tobacco articles comprising the step of intimately admixing with smoking tobacco or a portion of a smoking tobacco article at least one substance selected from the group consisting of:(i) the compound having the structure: ##STR1## (ii) the compound having the structure: ##STR2## (iii) a mixture of compounds having the structures: ##STR3## (iv) a mixture of compounds having the structures: ##STR4##
摘要翻译：描述了增加或增强吸烟烟草或吸烟烟草制品的香味或味道的用途，其包括与吸烟烟草或吸烟烟草制品的一部分紧密混合的步骤至少一种选自以下的物质：（i）具有以下结构的化合物：（ii）具有以下结构的化合物：（iii）具有以下结构的化合物的混合物：（i）具有以下结构的化合物的混合物： + TR

54. 发明授权

US4350823A Carbomethoxy methyl norbornanes 失效
标题翻译：甲氧基甲基降冰片烷
公开(公告)号：US4350823A
公开(公告)日：1982-09-21
申请号：US284107
申请日：1981-07-16
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , C07C69/753
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are compounds defined according to the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; and one of R.sub.1 and R.sub.2 is methyl and the other of R.sub.1 and R.sub.2 is hydrogen. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, chewing tobaccos, medicinal products, toothpastes, perfumes, perfumed articles (such as liquid or solid, anionic, cationic, nonionic or zwitterionic detergents), fabric softeners and dryer-added fabric softener articles.
摘要翻译：描述了根据通用结构定义的化合物：其中虚线表示碳 - 碳单键或碳 - 碳双键; R1和R2之一是甲基，R1和R2中的另一个是氢。此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香气或味道，包括食品，口香糖，咀嚼烟草，药用产品，牙膏，香料，加香制品（如液体或固体，阴离子，阳离子，非离子或两性离子洗涤剂），织物柔软剂和干燥剂添加的织物柔软剂制品。

55. 发明授权

US4347858A Use of carboalkoxy alkyl norbornanes for augmenting or enhancing the aroma or taste of a smoking tobacco composition or at least a portion of a smoking tobacco article 失效
标题翻译：用于增加或增强吸烟烟草组合物或吸烟烟草制品的至少一部分的香烟或味道的使用烷氧基烷基降冰片烷
公开(公告)号：US4347858A
公开(公告)日：1982-09-07
申请号：US303032
申请日：1981-09-17
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A24B3/10 , A24B15/30
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described is a process for augmenting or enhancing the aroma or taste of a smoking tobacco composition or at least a portion of a smoking tobacco article comprising the step of intimately admixing with a smoking tobacco composition or at least a portion of a smoking tobacco article, an aroma or taste augmenting or enhancing quantity of at least one compound defined according to the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; R.sub.1 ', R.sub.2 ', R.sub.3 ', R.sub.4 ', R.sub.6 ' and R.sub.7 ' are each selected from the group consisting of hydrogen and methyl and R.sub.5 ' is C.sub.1 -C.sub.4 alkyl with the provisos that;1. one of R.sub.1 ', R.sub.2 ', R.sub.6 ' and R.sub.7 ' is methyl and the other of R.sub.1 ', R.sub.2 ', R.sub.6 ' and R.sub.7 ' represents hydrogen;2. R.sub.3 ' and R.sub.4 ' are not both methyl;3. when the dashed line is a carbon-carbon double bond, R.sub.1 ', R.sub.3 ' and R.sub.4 ' are not all hydrogen when R.sub.2 ' is methyl.
摘要翻译：描述了用于增强或增强吸烟烟草组合物或吸烟烟草制品的至少一部分的香味或味道的方法，其包括与吸烟烟草组合物或吸烟烟草制品的至少一部分密切混合的步骤，根据通用结构定义的至少一种化合物的芳香或味道增加或增加量：其中虚线表示碳 - 碳单键或碳 - 碳双键; R 1'，R 2'，R 3'，R 4'，R 6'和R 7'各自选自氢和甲基，R 5'为C 1 -C 4烷基，条件是： R1'，R2'，R6'和R7'之一是甲基，R1'，R2'，R6'和R7'中的另一个表示氢; R3'和R4'都不是甲基; 3.当虚线为碳 - 碳双键时，当R2'为甲基时，R1'，R3'和R4'不全为氢。

56. 发明授权

US4327749A Alkyl esters of 1-alkanoyl cycloalkanols, process for preparing same and organoleptic uses thereof 失效
标题翻译： 1-烷酰基环烷醇的烷基酯，其制备方法及其感官用途
公开(公告)号：US4327749A
公开(公告)日：1982-05-04
申请号：US133828
申请日：1980-03-25
申请人： Ronald P. Schreck , Kenneth K. Light , John B. Hall , Frederick L. Schmitt , Manfred H. Vock , William L. Schreiber , Joaquin F. Vinals , Jacob Kiwala
发明人： Ronald P. Schreck , Kenneth K. Light , John B. Hall , Frederick L. Schmitt , Manfred H. Vock , William L. Schreiber , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A24B15/34 , A24B15/30
CPC分类号： A24B15/34
摘要： Described is a process for preparing several substituted or unsubstituted cycloalkyl acyl alkanoates defined according to the generic structure: ##STR1## wherein R.sub.1 and R.sub.2 taken together complete a cycloalkyl moiety or methyl, dimethyl or trimethyl substituted cycloalkyl moiety containing five or six carbon atoms in the ring and wherein R.sub.3 is C.sub.1 -C.sub.3 lower alkyl and R.sub.4 is methyl or hydrogen by reacting a compound having the generic structure: ##STR2## in an aqueous silver-ion containing solution having a weakly acidic pH at elevated temperatures. The compounds so produced are useful for their organoleptic properties in consumable materials, such as foodstuffs, foodstuff flavorants, chewing gums, chewing gum flavorants, toothpastes, toothpaste flavorants, medicinal products, medicinal product flavorants, chewing tobaccos, chewing tobacco flavorants, smoking tobaccos, smoking tobacco flavorants, perfume compositions, perfumed articles, such as cationic, anionic, nonionic and zwitterionic detergents, fabric softener compositions, drier-added fabric softener articles, textile sizing agents and optical brighteners for textiles as well as colognes.
摘要翻译：描述了根据通用结构定义的若干取代或未取代的环烷基酰基链烷酸酯的方法：其中R 1和R 2一起完成环烷基部分或含有5或6个碳原子的甲基，二甲基或三甲基取代的环烷基部分环，其中R 3是C 1 -C 3低级烷基，R 4是甲基或氢，通过使具有通式结构的化合物：在高温下具有弱酸性pH的含水银离子溶液中。如此生产的化合物可用于消费材料如食品，食品香料，口香糖，口香糖调味剂，牙膏，牙膏调味剂，药用产品，药用香料，咀嚼烟草，咀嚼烟草香料，烟草烟草，吸烟烟草调味剂，香料组合物，香料制品，例如阳离子，阴离子，非离子和两性离子洗涤剂，织物柔软剂组合物，干燥剂添加的织物柔软剂制品，纺织品上浆剂和用于纺织品的荧光增白剂以及古龙水。

57. 发明授权

US4321164A 2,4,6-Trimethylcyclohexanemethanol and derivatives, process for preparing same and organoleptic uses thereof 失效
标题翻译： 2,4,6-三甲基环己烷甲醇及其衍生物，其制备方法及其感官用途
公开(公告)号：US4321164A
公开(公告)日：1982-03-23
申请号：US195629
申请日：1980-10-09
申请人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
发明人： Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A24B15/34 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0034 , A24B15/34
摘要： Described are 2,4,6-Trimethylcyclohexanemethanol derivatives having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and R is hydrogen or acetyl. The 2,4,6-Trimethylcyclohexanemethanol and derivatives thereof are useful in perfumery and foodstuff, medicinal product and smoking tobacco flavors.
摘要翻译：描述了具有以下通用结构的2,4,6-三甲基环己烷甲醇衍生物：其中虚线表示碳 - 碳单键或碳 - 碳双键，R是氢或乙酰基。 2,4,6-三甲基环己烷甲醇及其衍生物可用于香料和食品，药用产品和吸烟香精。

58. 发明授权

US4319036A Carboalkoxy alkyl norbornanes and process for preparing same 失效
标题翻译：碳烷基烷基降冰片烷及其制备方法
公开(公告)号：US4319036A
公开(公告)日：1982-03-09
申请号：US133870
申请日：1980-03-25
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Frederick L. Schmitt , Edward J. Granda
IPC分类号： C07C69/753 , A23L27/20 , A24B3/12 , A24B15/34 , A61K8/33 , A61K8/36 , A61K8/37 , A61K8/42 , A61Q13/00 , C07C45/00 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C51/00 , C07C61/13 , C07C67/00 , C07C231/00 , C07C231/12 , C07C233/58 , C11B9/00 , C11D3/50 , C07C67/347
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are compounds having the generic structure: ##STR1## wherein the dashed line is either a carbon-carbon single bond or a carbon-carbon double bond and each of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents hydrogen or methyl with the proviso that one of R.sub.2 and R.sub.1 is methyl and the other of R.sub.1 or R.sub.2 is hydrogen and R.sub.3 and R.sub.4 are not both methyl; and wherein R.sub.5 represents C.sub.1 -C.sub.4 alkyl are disclosed. In addition organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, chewing tobaccos, medicinal products, toothpastes, perfumes, perfumed articles (such as liquid or solid anionic, cationic, nonionic or zwitterionic detergents) fabric softeners, dryer added fabric softener articles, and smoking tobaccos. Also disclosed is a process for preparing such compounds according to the reaction scheme: ##STR2## wherein R' represents C.sub.1 -C.sub.3 alkyl; m+n equals 3 with the proviso that m is one or two and n is one or two; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are defined as above.
摘要翻译：描述的是具有通用结构的化合物：其中虚线是碳 - 碳单键或碳 - 碳双键，R1，R2，R3和R4各自表示氢或甲基，条件是 R2和R1是甲基，R1或R2中的另一个是氢，R3和R4不都是甲基; 并且其中R5表示C1-C4烷基。此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香气或味道，包括食品，口香糖，咀嚼烟草，医药产品，牙膏，香料，香料制品（如液体或固体阴离子，阳离子，非离子或非离子的两性离子洗涤剂）织物柔软剂，干燥剂添加织物柔软剂制品和吸烟烟草。还公开了根据以下反应方案制备这些化合物的方法：其中R'表示C 1 -C 3烷基; m + n等于3，条件是m为1或2，n为1或2; 并且其中R1，R2，R3，R4和R5如上定义。

59. 发明授权

US4315951A Flavoring with indane alkanols and tricyclic isochromans 失效
标题翻译：用二环烷醇和三环异色素调味
公开(公告)号：US4315951A
公开(公告)日：1982-02-16
申请号：US212886
申请日：1980-12-04
申请人： Wilhelmus J. Wiegers , Mark A. Sprecker , Hugh Watkins , Manfred H. Vock , Frederick L. Schmitt
发明人： Wilhelmus J. Wiegers , Mark A. Sprecker , Hugh Watkins , Manfred H. Vock , Frederick L. Schmitt
IPC分类号： C07C2/42 , C07C29/36 , C07C33/34 , C07D311/94 , C11B9/00 , A23L1/226
CPC分类号： C11B9/008 , C07C2/42 , C07C29/36 , C07C33/34 , C07D311/94 , C07C2102/08 , C07C2521/16 , C07C2531/08
摘要： Processes and compositions are described for the use in foodstuff flavor and aroma and perfume and perfumed article aroma augmenting, modifying, altering and enhancing compositions and as foodstuff, chewing gum, toothpaste, medicinal product, perfume and perfumed article aroma imparting materials of certain indane alkanols and tricyclic isochromans defined according to the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2, R.sub.3 or R.sub.4 is C.sub.2 H.sub.5 and the remaining R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents methyl; wherein X is --CH.sub.2 -- or hydrogen and wherein the dashed line represents a carbon-carbon single bond or no bond with the proviso that when X is --CH.sub.2 --, then the dashed line is a carbon-carbon single bond and when X is hydrogen, the dashed line represents no bond.Addition of said indane alkanols or said tricyclic isochromans or mixtures thereof is indicated to produce:A. In food flavorings, a sweet, musky, patchouli-like, and ionone-like aroma and flavor characteristic; (useful for flavor augmentation or enhancement in pear, apricot and peach flavors);B. In perfumes and perfumed articles, a sweet, musky aroma with earthy, minty and sweet nuances.
摘要翻译：描述了用于食品香料和香料和香料和香料制品香气增强，改性，改变和增强组合物以及作为食品，口香糖，牙膏，药用产品，香料和香料制品中某些二烷基链烷醇的赋香材料的方法和组合物和根据通用结构定义的三环异染料：其中R 1，R 2，R 3或R 4中的一个为C 2 H 5，剩余的R 1，R 2，R 3和R 4表示甲基; 其中X是-CH 2 - 或氢，并且其中虚线表示碳 - 碳单键或没有键，条件是当X是-CH 2 - 时，虚线是碳 - 碳单键，当X是氢时，虚线表示没有键。表示添加所述二氢化茚烷醇或所述三环异色素或其混合物以产生：A.在食品调味品中，甜味，麝香，广藿香样和紫罗兰酮样芳香和风味特征; （用于梨，杏和桃味的增味或增强）; B.在香水和香水制品中，甜美，麝香的香气与土质，微小和甜美的细微差别。

60. 发明授权

US4308412A Indane alkanols and tricyclic isochromans and organoleptic uses thereof 失效
标题翻译：茚烷醇和三环异染料及其感官用途
公开(公告)号：US4308412A
公开(公告)日：1981-12-29
申请号：US212992
申请日：1980-12-04
申请人： Wilhelmus J. Wiegers , Mark A. Sprecker , Hugh Watkins , Manfred H. Vock , Frederick L. Schmitt
发明人： Wilhelmus J. Wiegers , Mark A. Sprecker , Hugh Watkins , Manfred H. Vock , Frederick L. Schmitt
IPC分类号： C07C2/42 , C07C29/36 , C07C33/34 , C07D311/94 , C11B9/00 , C07C3/00
CPC分类号： C11B9/008 , C07C2/42 , C07C29/36 , C07C33/34 , C07D311/94 , C07C2102/08 , C07C2521/16 , C07C2531/08
摘要： Processes and compositions are described for the use in foodstuff flavor and aroma and perfume and perfumed article aroma augmenting, modifying, altering and enhancing compositions and as foodstuff, chewing gum, toothpaste, medicinal product, perfume and perfumed article aroma imparting materials of certain indane alkanols and tricyclic isochromans defined according to the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2, R.sub.3 or R.sub.4 is C.sub.2 H.sub.5 and the remaining R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents methyl; wherein X is --CH.sub.2 -- or hydrogen and wherein the dashed line represents a carbon-carbon single bond or no bond with the proviso that when X is --CH.sub.2 --, then the dashed line is a carbon-carbon single bond and when X is hydrogen, the dashed line represents no bond.Addition of said indane alkanols or said tricyclic isochromans or mixtures thereof is indicated to produce:A. In food flavorings, a sweet, musky, patchouli-like, and ionone-like aroma and flavor characteristic; (useful for flavor augmentation or enhancement in pear, apricot and peach flavors);B. In perfumes and perfumed articles, a sweet, musky aroma with earthy, minty and sweet nuances.
摘要翻译：描述了用于食品香料和香料和香料和香料制品香气增强，改性，改变和增强组合物以及作为食品，口香糖，牙膏，药用产品，香料和香料制品中某些二烷基链烷醇的赋香材料的方法和组合物和根据通用结构定义的三环异染料：其中R 1，R 2，R 3或R 4中的一个为C 2 H 5，剩余的R 1，R 2，R 3和R 4表示甲基; 其中X是-CH 2 - 或氢，并且其中虚线表示碳 - 碳单键或没有键，条件是当X是-CH 2 - 时，虚线是碳 - 碳单键，当X是氢时，虚线表示没有键。表示添加所述二氢化茚烷醇或所述三环异色素或其混合物以产生：A.在食品调味品中，甜味，麝香，广藿香样和紫罗兰酮样芳香和风味特征; （用于梨，杏和桃味的增味或增强）; B.在香水和香水制品中，甜美，麝香的香气与土质，微小和甜美的细微差别。

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