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    • 53. 发明授权
    • Autoxidizable compositions containing low molecular weight polymers of
dicyclopentenyl methacrylate or dicyclopentenyloxyalkyl methacrylate
    • 含有甲基丙烯酸二环戊烯酯或甲基丙烯酸二环戊烯氧基烷基酯的低分子量聚合物的可自动氧化组合物
    • US4387190A
    • 1983-06-07
    • US289638
    • 1981-08-03
    • Wayne E. Feely
    • Wayne E. Feely
    • C08F32/00C08F20/10C08F20/12C08F20/26C08F20/28C08F242/00C08L33/00C08L33/02C08L33/04C08L33/06C08L67/00C08L67/08C08L91/00C09D133/04C09D133/06C09D133/10C09D157/00C09D167/08C09D191/00C09D3/66C09D3/81
    • C09D133/10C09D167/08C08L67/08
    • An improved autoxidizable coating and/or impregnating composition consisting essentially of:(1) from about 35% to about 80% by weight, based on the total weight of components (1), (2), and (3), of a film-forming component selected from the group consisting of drying oils, alkyd resins, and mixtures of drying oils and alkyd resins,(2) from about 10% to about 50% by weight, based on the total weight of components (1), (2), and (3), of a polymer of a molecular weight in the range of 1,000-50,000 (Mn) polymerized from a monomer system comprising:(a) from about 40% to 100% by weight of at least one monomer selected from the group consisting of dicyclopentenyl methacrylate and dicyclopentenyloxyalkyl methacrylate, and(b) from about 60% to 0% by weight of at least one compatible monomer,(3) from 0 to about 40% by weight, based on the total weight of components (1), (2), and (3), of a reactive, non-volatile diluent monomer, and(4) an effective amount of at least one polyvalent metal salt or complex that catalyzes the oxidative curing of components (1), (2), and (3), wherein the total of the percentages of components (1), (2), and (3) is 100.
    • 一种改进的可自动氧化的涂层和/或浸渍组合物,其基本上由以下组成:(1)基于组分(1),(2)和(3)的总重量的约35重量%至约80重量% 选自干油,醇酸树脂以及干性油和醇酸树脂的混合物的成分组分,(2)约10%至约50%重​​量,基于组分(1),( 2)和(3)分子量在1,000-50,000(Mn)范围内的聚合物的聚合物,该单体体系包含:(a)约40%至100%重量的至少一种所选择的单体 来自由二环戊烯基甲基丙烯酸酯和甲基丙烯酸二环戊烯氧基烷基酯组成的组,和(b)约60重量%至0重量%的至少一种相容单体,(3)0至约40重量%,基于组分 (1),(2)和(3)的反应性非挥发性稀释剂单体,和(4)有效量的至少一种多价金属盐 或催化组分(1),(2)和(3)的氧化固化的络合物,其中组分(1),(2)和(3)的百分比的合计为100。