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1. 发明授权

US5294728A Latent thiol mercaptan chain transfer agents and their use in the synthesis of polymers 失效
标题翻译：潜在的硫醇硫醇链转移剂及其在聚合物合成中的应用
公开(公告)号：US5294728A
公开(公告)日：1994-03-15
申请号：US787280
申请日：1991-11-04
申请人： William D. Emmons , Andrew W. Gross
发明人： William D. Emmons , Andrew W. Gross
IPC分类号： C08F2/00 , C08F2/38 , C08F293/00 , C07C67/02 , C08F8/00 , C08F12/30
CPC分类号： C08F2/38 , C08F293/00
摘要： This invention relates to latent thiol mercaptan chain transfer agents and their use in the synthesis of polymers. In addition, this invention relates to novel polymers and block copolymers formed using these latent thiol mercaptan chain transfer agents.
摘要翻译：本发明涉及潜在的硫醇硫醇链转移剂及其在聚合物合成中的应用。此外，本发明涉及使用这些潜在硫醇硫醇链转移剂形成的新型聚合物和嵌段共聚物。

2. 发明授权

US5436357A Polymer supported organotin catalyst 失效
标题翻译：聚合物负载的有机锡催化剂
公开(公告)号：US5436357A
公开(公告)日：1995-07-25
申请号：US254809
申请日：1994-06-06
申请人： Qian Jiang , Christine McDade , Andrew W. Gross
发明人： Qian Jiang , Christine McDade , Andrew W. Gross
IPC分类号： B01J31/06 , B01J31/12 , C07C67/02 , C07C67/03 , C07C69/33 , C07C69/54 , C07F7/22 , C08F8/00 , C08F30/04 , C08G63/78 , C08G63/82 , C08G63/85
CPC分类号： B01J31/122 , C07C67/03 , C07F7/2212 , B01J2231/49
摘要： A tetravalent organotin containing compound where the tin atom is attached via an alkyl group to a phenyl moiety with a polymerizable group thereon, is useful as a monomer. A polymer prepared from the monomer. A transesterification catalyst prepared from the polymer and a process for conducting a transesterification reaction using the transesterification catalyst.
摘要翻译：其中锡原子通过烷基连接到其上具有可聚合基团的苯基部分的含四价有机锡化合物可用作单体。由单体制备的聚合物。由聚合物制备的酯交换催化剂和使用酯交换催化剂进行酯交换反应的方法。

3. 发明授权

US5382640A Polymers containing latent thiol monomers 失效
标题翻译：含有潜在硫醇单体的聚合物
公开(公告)号：US5382640A
公开(公告)日：1995-01-17
申请号：US163646
申请日：1993-12-09
申请人： William D. Emmons , Andrew W. Gross
发明人： William D. Emmons , Andrew W. Gross
IPC分类号： C08F20/06 , C07C327/06 , C07C327/28 , C07C327/32 , C08F16/30 , C08F18/02 , C08F28/00 , C08F28/02 , C08F220/04 , C08F273/00 , C08L51/00 , C09D151/00 , C09J151/00 , C08F28/04 , C08F120/38
CPC分类号： C08F16/30 , C07C327/28 , C07C327/32 , C08F273/00
摘要： This invention relates to latent thiol monomers and their use in the synthesis of polymers. In addition, this invention relates to novel polymers and graft copolymers formed with these latent thiol monomers.
摘要翻译：本发明涉及潜在的硫醇单体及其在合成聚合物中的用途。此外，本发明涉及与这些潜在硫醇单体形成的新型聚合物和接枝共聚物。

4. 发明授权

US5331025A Coating compositions incorporating composite polymer particles 失效
标题翻译：包含复合聚合物颗粒的涂料组合物
公开(公告)号：US5331025A
公开(公告)日：1994-07-19
申请号：US971365
申请日：1992-11-04
申请人： Alvin C. Lavoie , Jen-Chi Chen , Chao-Jen Chung , Dennis P. Lorah , Peter R. Sperry , Andrew W. Gross
发明人： Alvin C. Lavoie , Jen-Chi Chen , Chao-Jen Chung , Dennis P. Lorah , Peter R. Sperry , Andrew W. Gross
IPC分类号： C09D151/06 , C09D7/12 , C09D151/00 , C09D201/00 , C08K5/01 , C08L63/02
CPC分类号： C09D7/1275 , C09D7/125
摘要： This invention relates to a non-aqueous coating composition and a method for reducing the drying time of a non-aqueous coating composition by incorporating composite polymer particles having a softer, insoluble first stage and a hard second stage without adversely affecting the viscosity and pot life of the liquid coating composition and without degrading the properties of the final dry coating, including color, flexibility, impact resistance, gasoline resistance, salt spray resistance and humidity resistance.
摘要翻译：本发明涉及非水性涂料组合物和通过掺入具有较软，不溶的第一阶段和硬的第二阶段的复合聚合物颗粒来减少非水性涂料组合物的干燥时间的方法，而不会不利地影响粘度和适用期的液体涂料组合物，并且不降低最终干涂层的性能，包括颜色，柔韧性，耐冲击性，耐汽油性，耐盐雾性和耐湿性。

5. 发明授权

US5290956A Latent thiol monomers 失效
标题翻译：潜在的硫醇单体
公开(公告)号：US5290956A
公开(公告)日：1994-03-01
申请号：US787272
申请日：1991-11-04
申请人： William D. Emmons , Andrew W. Gross
发明人： William D. Emmons , Andrew W. Gross
IPC分类号： C08F20/06 , C07C327/06 , C07C327/28 , C07C327/32 , C08F16/30 , C08F18/02 , C08F28/00 , C08F28/02 , C08F220/04 , C08F273/00 , C08L51/00 , C09D151/00 , C09J151/00 , C07D307/02 , C07C327/20
CPC分类号： C08F16/30 , C07C327/28 , C07C327/32 , C08F273/00
摘要： This invention relates to latent thiol monomers and their use in the synthesis of polymers. In addition, this invention relates to novel polymers and graft copolymers formed with these latent thiol monomers.
摘要翻译：本发明涉及潜在的硫醇单体及其在合成聚合物中的用途。此外，本发明涉及与这些潜在硫醇单体形成的新型聚合物和接枝共聚物。

6. 发明授权

US5498675A Block copolymers containing latent thiol mercaptan chain transfer agents and the method of making these block copolymers 失效
标题翻译：含有潜在硫醇硫醇链转移剂的嵌段共聚物和制备这些嵌段共聚物的方法
公开(公告)号：US5498675A
公开(公告)日：1996-03-12
申请号：US353011
申请日：1994-12-09
申请人： William D. Emmons , Andrew W. Gross
发明人： William D. Emmons , Andrew W. Gross
IPC分类号： C08F2/00 , C08F2/38 , C08F293/00 , C08F283/00
CPC分类号： C08F2/38 , C08F293/00
摘要： This invention relates to a block copolymer comprising: a) at least one first block of polymerized units of at least one first ethylenically unsaturated monomer and at least one latent thiol mercaptan chain transfer agent wherein the latent thiol mercaptan chain transfer agent has the general formula; ##STR1## wherein A is a polyvalent organic radical; x and y are positive integers such that x+y equals the valence of A; B is an organic acyl radical; and n and m are integers from 1 to 6; and b) at least one second block of polymerized units of at least one second ethylenically unsaturated monomer, wherein said at least one second block is attached to said at least one first block by reacting with terminal thiol functional groups contained on said at least one first block. In addition, this invention relates to the method of making this block copolymer.
摘要翻译：本发明涉及嵌段共聚物，其包含：a）至少一种至少一种第一烯键式不饱和单体和至少一种潜在硫醇硫醇链转移剂的聚合单元的第一嵌段，其中所述潜在的硫醇硫醇链转移剂具有通式; 其中A是多价有机基团; x和y是正整数，使得x + y等于A的化合价; B是有机酰基; n和m为1〜6的整数; 和b）至少一个第二嵌段的至少一种第二烯属不饱和单体的聚合单元，其中所述至少一个第二嵌段通过与所述至少一个第一嵌段上含有的末端硫醇官能团反应而连接到所述至少一个第一嵌段上块。此外，本发明涉及制备该嵌段共聚物的方法。

7. 发明授权

US5091573A Thiol-terminated hydroxyamides 失效
标题翻译：硫醇封端的羟基酰胺
公开(公告)号：US5091573A
公开(公告)日：1992-02-25
申请号：US581158
申请日：1990-08-27
申请人： Andrew W. Gross , William D. Emmons
发明人： Andrew W. Gross , William D. Emmons
IPC分类号： C07C323/60 , C08F2/38 , C08G63/688
CPC分类号： C08G63/6884 , C07C323/60 , C08F2/38
摘要： Novel thiol-terminated hydroxyamides, and processes for their preparation and use are provided. These hydroxyamide compounds may be prepared by the reaction of a mercapto-functional alkyl ester, such as methylmercaptopropionate, with a molar excess of an alcohol-substituted amine, such as a .beta.-hydroxyalkyl amine. The thiol-terminated hydroxyamides are useful as polymerization chain transfer agents, particularly when it is desirable to form polymers or oligomers containing functional hydroxyamide end groups. By chain terminating such polymers or oligomers with reactive hydroxyamide end groups the polymers or oligomers can be further reacted with acid-containing monomers or polymers to form block or graft copolymers.
摘要翻译：提供了新的硫醇封端的羟基酰胺，以及其制备和使用的方法。这些羟基酰胺化合物可以通过巯基官能的烷基酯如巯基丙酸甲酯与摩尔过量的醇取代的胺如β-羟烷基胺的反应来制备。硫醇封端的羟基酰胺可用作聚合链转移剂，特别是当需要形成含有官能羟基酰胺端基的聚合物或低聚物时。通过用反应性羟基酰胺端基链终止这种聚合物或低聚物，聚合物或低聚物可以进一步与含酸单体或聚合物反应以形成嵌段或接枝共聚物。

8. 发明授权

US5561205A Polymer supported organotin catalyst 失效
公开(公告)号：US5561205A
公开(公告)日：1996-10-01
申请号：US414844
申请日：1995-03-31
申请人： Oian Jiang , Christine McDade , Andrew W. Gross
发明人： Oian Jiang , Christine McDade , Andrew W. Gross
IPC分类号： B01J31/06 , B01J31/12 , C07C67/02 , C07C67/03 , C07C69/33 , C07C69/54 , C07F7/22 , C08F8/00 , C08F30/04 , C08G63/78 , C08G63/82 , C08G63/85 , C08F16/32 , C08F12/34
CPC分类号： B01J31/122 , C07C67/03 , C07F7/2212 , B01J2231/49
摘要： A tetravalent organotin containing compound where the tin atom is attached via an alkyl group to a phenyl moiety with a polymerizable group thereon, is useful as a monomer. A polymer prepared from the monomer. A transesterification catalyst prepared from the polymer and a process for conducting a transesterification reaction using the transesterification catalyst.

9. 发明授权

US5492965A Compositions containing block copolymers composed of latent thiol mercaptan chain transfer agents 失效
标题翻译：含有由潜在硫醇硫醇链转移剂组成的嵌段共聚物的组合物
公开(公告)号：US5492965A
公开(公告)日：1996-02-20
申请号：US471950
申请日：1995-06-06
申请人： William D. Emmons , Andrew W. Gross
发明人： William D. Emmons , Andrew W. Gross
IPC分类号： C08F2/00 , C08F2/38 , C08F293/00 , C08L31/00
CPC分类号： C08F2/38 , C08F293/00
摘要： This invention relates to a polymer composition of a block copolymer dispersed in water wherein the block copolymer is composed of: a) at least one first block of polymerized units of at least one first ethylenically unsaturated monomer and at least one latent thiol mercaptan chain transfer agent wherein the latent thiol mercaptan chain transfer agent has the general formula; ##STR1## wherein A is a polyvalent organic radical; x and y are positive integers such that x+y equals the valence of A; B is an organic acyl radical; and n and m are integers from 1 to 6; and b) at least one second block of polymerized units of at feast one second ethylenically unsaturated monomer, wherein said at least one second block is attached to said at least one first block by reacting with terminal thiol functional groups contained on said at least one first block.
摘要翻译：本发明涉及分散在水中的嵌段共聚物的聚合物组合物，其中嵌段共聚物由以下组成：a）至少一种至少一种第一烯属不饱和单体和至少一种潜在硫醇硫醇链转移剂的聚合单元的第一嵌段其中所述潜在硫醇硫醇链转移剂具有通式; 其中A是多价有机基团; x和y是正整数，使得x + y等于A的化合价; B是有机酰基; n和m为1〜6的整数; 和b）至少一个第二嵌段聚合单元，其中所述至少一个第二烯键式不饱和单体是通过与所述至少一个第一嵌段上含有的末端硫醇官能团反应而连接到所述至少一个第一嵌段上的至少一个第二嵌段块。

10. 发明授权

US5399642A Latent thiol mercaptan chain transfer agents and their use in the synthesis of polymers 失效
标题翻译：潜在的硫醇硫醇链转移剂及其在聚合物合成中的应用
公开(公告)号：US5399642A
公开(公告)日：1995-03-21
申请号：US166531
申请日：1993-12-13
申请人： William D. Emmons , Andrew W. Gross
发明人： William D. Emmons , Andrew W. Gross
IPC分类号： C08F2/00 , C08F2/38 , C08F293/00
CPC分类号： C08F2/38 , C08F293/00
摘要： This invention relates to latent thiol mercaptan chain transfer agents and their use in the synthesis of polymers. In addition, this invention relates to novel polymers and block copolymers formed using these latent thiol mercaptan chain transfer agents.
摘要翻译：本发明涉及潜在的硫醇硫醇链转移剂及其在聚合物合成中的应用。此外，本发明涉及使用这些潜在硫醇硫醇链转移剂形成的新型聚合物和嵌段共聚物。

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