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    • 41. 发明申请
    • READILY SUPPORTABLE METAL COMPLEXES
    • 易于支持的金属复合材料
    • WO1997015602A1
    • 1997-05-01
    • PCT/US1996014608
    • 1996-09-11
    • THE DOW CHEMICAL COMPANY
    • THE DOW CHEMICAL COMPANYSPENCER, LeeNICKIAS, Peter, N.
    • C08F10/00
    • C07F17/00C08F4/61908C08F4/6192C08F10/00
    • Metal complexes useful as olefin polymerization catalysts corresponding to formula (I), wherein L is a delocalized, pi -bonded group that is bound to M, containing up to 50 nonhydrogen atoms; M is a metal of Group 3, 4 or the Lanthanide series of the Periodic Table of the Elements; Z is a covalently bound, divalent substituent of up to 50 non-hydrogen atoms having the formula: -(ER2)m-, wherein E independently each occurrence is carbon, silicon or germanium, R independently each occurrence is selected from the group consisting of C1-20 hydrocarbyl, and C1-20 hydrocarbyloxy, with the proviso that in at least one occurrence R is C1-20 hydrocarbyloxy, and m is an integer from 1 to 3; Y is a divalent ligand group comprising nitrogen, phosphorus, oxygen or sulfur, said Y containing up to 20 nonhydrogen atoms; X' is a neutral Lewis base ligand having up to 20 non-hydrogen atoms; X'' independently each occurrence is a monovalent, anionic moiety selected from hydride, halo, hydrocarbyl, silyl, germyl, hydrocarbyloxy, amide, siloxy, halohydrocarbyl, halosilyl, silylhydrocarbyl, and aminohydrocarbyl having up to 20 non-hydrogen atoms, or two X'' groups together form a divalent hydrocarbadiyl group; n is a number from 0 to 3; and p is an integer from 0 to 2.
    • 可用作对应于式(I)的烯烃聚合催化剂的金属络合物,其中L是与M结合的离域的π键合基团,其含有至多50个非氢原子; M是元素周期表第3,4族金属或镧系元素; Z是具有下式的至多50个非氢原子的共价结合的二价取代基: - (ER 2)m - ,其中E独立地为碳,硅或锗,R各自独立地选自 C 1-20烃基和C 1-20烃氧基,条件是在至少一个出现中R是C 1-20烃基氧基,m是1至3的整数; Y是包含氮,磷,氧或硫的二价配体基团,所述Y含有至多20个非氢原子; X'是具有至多20个非氢原子的中性路易斯碱配体; X“独立地是选自氢化物,卤素,烃基,甲硅烷基,甲硅烷基,烃氧基,酰胺,甲硅烷氧基,卤代烃基,卤代甲硅烷基,甲硅烷基烃基和具有至多20个非氢原子的氨基烃基的一价阴离子部分,或两个X 一起形成二价烃基; n是从0到3的数字; p为0〜2的整数。
    • 47. 发明申请
    • METHOD TO PRODUCE A TRANSITION METAL CARBIDE FROM A PARTIALLY REDUCED TRANSITION METAL COMPOUND
    • 从部分还原过渡金属化合物生产过渡金属碳化物的方法
    • WO1997010176A1
    • 1997-03-20
    • PCT/US1996014521
    • 1996-09-10
    • THE DOW CHEMICAL COMPANY
    • THE DOW CHEMICAL COMPANYDUNMEAD, Steven, D.NILSEN, Kevin, J.LASHER, Gabrielle, R.REPMAN, Joseph, F.BARKER, Hobart, A.WEIMER, Alan, W.
    • C01B31/30
    • C01B32/949C01B32/914C01P2002/72C01P2004/62C01P2006/11C01P2006/12C01P2006/80
    • A transition metal carbide is formed from a precursor mixture comprising at least one of the group consisting of: a transition metal, a transition metal carbide and a transition metal oxide. The precursor mixture may contain the desired transition metal carbide (for example, WC), but if the desired transition metal carbide is present in the precursor mixture, there is necessarily a significant amount of another compound such as a transition metal oxide, undesired carbide (for example, W2C) or transition metal. The method involves forming an admixture by mixing the precursor mixture with a sufficient amount of carbon to carburize the precursor mixture to the transition metal carbide and reacting the admixture in an inert or reducing atmosphere at a temperature for a time sufficient to convert the admixture to the transition metal carbide, wherein the admixture is reacted in the presence of a means to enhance transfer of heat into the admixture, an inert or reducing gas flowing through at least a portion of the admixture or combination thereof.
    • 过渡金属碳化物由包含过渡金属,过渡金属碳化物和过渡金属氧化物中的至少一种的前体混合物形成。 前体混合物可以含有所需的过渡金属碳化物(例如WC),但是如果所需的过渡金属碳化物存在于前体混合物中,则必须有大量的其它化合物,例如过渡金属氧化物,不期望的碳化物 例如,W2C)或过渡金属。 该方法包括通过将前体混合物与足量的碳混合来形成混合物,以将前体混合物渗碳至过渡金属碳化物,并将该混合物在惰性或还原性气氛中,在足以将混合物转化为 过渡金属碳化物,其中所述混合物在增加热量进入所述混合物的手段的存在下反应,惰性或还原气体流过所述混合物的至少一部分或其组合。
    • 50. 发明申请
    • FORMULATIONS CONTAINING POLY-(NITRILE OXIDE) REAGENTS
    • 含有多(氧化镍)试剂的配方
    • WO1997003142A1
    • 1997-01-30
    • PCT/US1996011498
    • 1996-07-10
    • THE DOW CHEMICAL COMPANY
    • THE DOW CHEMICAL COMPANYLYSENKO, ZenonWESSLING, Ritchie, A.ROSE, Gene, D.
    • C09D179/04
    • C08G73/0655C07C291/06C07D261/04
    • Curable compositions contain: (a) at least one nitrile oxide monomer which contains on average more than one stable nitrile oxide group per molecule; and (b) at least one polyunsaturated monomer which: (1) has a weight average molecular weight of no more than 5000; and (2) contains on average more than one insaturated moiety which contains a sterically-unhindered carbon-carbon or carbon-nitrogen double bond or triple bond. The monomers are selected such that either the nitrile oxide monomers or the polyunsaturated monomers or both contain on average more than two reactive groups per molecule, and such that the equivalent ratio of nitrile oxide to unsaturated moieties is more than 0.5:1 and less than 2:1. The compositions can be used in coatings, composites, laminates and injection moldings.
    • 可固化组合物含有:(a)每分子平均含有多于一个稳定的氧化腈基团的至少一种氧化腈单体; 和(b)至少一种多不饱和单体:(1)重均分子量不大于5000; 和(2)平均包含多于一个不饱和部分,其含有空间上不受阻的碳 - 碳或碳 - 氮双键或三键。 选择单体使得氧化腈单体或多不饱和单体或两者每分子平均含有多于两个反应性基团,并且使得氧化腈与不饱和部分的当量比大于0.5:1且小于2 :1。 该组合物可用于涂料,复合材料,层压材料和注射成型品。