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41. 发明授权

US5471836A Exhaust purification device of internal combustion engine 失效
标题翻译：内燃机排气净化装置
公开(公告)号：US5471836A
公开(公告)日：1995-12-05
申请号：US75518
申请日：1993-06-14
申请人： Shinichi Takeshima , Yasushi Araki , Shinya Hirota
发明人： Shinichi Takeshima , Yasushi Araki , Shinya Hirota
IPC分类号： B01D53/94 , F01N3/08 , F01N3/10 , F01N3/20 , F01N3/24 , F01N9/00 , F01N13/02 , F02B1/04 , F02D41/02 , F02D41/04 , F02D41/14 , F01N3/00
CPC分类号： F02D41/0275 , B01D53/9409 , B01D53/9481 , B01D53/9495 , F01N13/009 , F01N13/0097 , F01N3/0842 , F01N3/0871 , F01N2240/18 , F01N2250/12 , F01N2270/00 , F01N2560/025 , F01N2610/03 , F01N2610/146 , F01N2900/08 , F02B1/04 , Y02T10/166 , Y02T10/22
摘要： An NO.sub.x absorbent (19) is disposed in an exhaust passage of an internal combustion engine and an NO.sub.x oxidizing agent (18) is disposed in the exhaust passage upstream of the NO.sub.x absorbent (19). The NO.sub.x absorbent (19) absorbs the NO.sub.x when the air-fuel ratio of the exhaust gas flowing into the NO.sub.x absorbent (19) is lean and releases the absorbed NO.sub.x when the air-fuel ratio of the exhaust gas flowing into the NO.sub.x absorbent (19) becomes the stoichiometric air-fuel ratio or rich. When the lean air-fuel mixture is burned, if the temperature of the NO.sub.x absorbent (19) is low, the NO.sub.x oxidized by the NO.sub.x oxidizing agent (18) is absorbed by the NO.sub.x absorbent (19), while if the temperature of the NO.sub.x absorbent (19) is high, the NO.sub.x is oxidized by the NO.sub.x absorbent (19) and absorbed in the NO.sub.x absorbent (19).
摘要翻译： PCT No.PCT / JP92 / 01330 Sec。 371日期：1993年6月14日 102（e）日期1993年6月14日PCT提交1992年10月13日PCT公布。公开号WO93 / 08383 日本1997年4月29日，NO x吸收剂（19）设置在内燃机的排气通路中，NOx吸收剂（18）设置在NOx吸收剂（19）上游的排气通道内。当流入NOx吸收剂（19）的废气的空燃比是贫的时，NOx吸收剂（19）吸收NOx，并且当流入NOx吸收剂的废气的空燃比释放吸收的NOx 19）成为化学计量空燃比或浓。当稀薄的空气燃料混合物燃烧时，如果NOx吸收剂（19）的温度低，则由NOx氧化剂（18）氧化的NOx被NOx吸收剂（19）吸收，而如果NOx吸收剂 NOx吸收剂（19）高，NOx被NOx吸收剂（19）氧化并吸收在NOx吸收剂（19）中。

42. 发明授权

US5448887A Exhaust gas purification device for an engine 失效
标题翻译：发动机废气净化装置
公开(公告)号：US5448887A
公开(公告)日：1995-09-12
申请号：US251821
申请日：1994-05-31
申请人： Shinichi Takeshima
发明人： Shinichi Takeshima
IPC分类号： B01D53/94 , F01N3/08 , F01N3/18 , F01N3/20 , F01N3/22 , F01N3/24 , F01N9/00 , F01N13/02 , F02B1/04 , F02D21/08 , F02D41/00 , F02D41/02 , F02D41/04 , F02D41/14 , F02M25/07 , F02M25/06 , F02N3/00
CPC分类号： F02D41/0052 , B01D53/9481 , B01D53/9495 , F01N13/009 , F01N3/0842 , F01N3/0871 , F01N3/22 , F01N3/222 , F01N9/00 , F02D41/027 , F02D41/1474 , F02D41/1477 , F01N2250/12 , F01N3/20 , F02B1/04 , Y02T10/22 , Y02T10/47
摘要： An exhaust gas purification device of the present invention includes a three-way reducing and oxidizing catalyst disposed on an exhaust passage of an engine, and an NO.sub.x absorbent which absorbs NO.sub.x in the exhaust gas when the air-fuel ratio of the exhaust gas is lean and releases absorbed NO.sub.x when the air-fuel ratio of the exhaust gas is rich; the engine in the present invention is controlled in most of its operating region in such a manner that the operating air-fuel ratio of the engine oscillates between a rich air-fuel ratio and a lean air-fuel ratio about a center value of a stoichiometric air-fuel ratio; when the operating air-fuel ratio of the engine becomes lean, the ability of the three-way catalyst for reducing NO.sub.x in the exhaust gas becomes low, and a part of NO.sub.x in the exhaust gas passes through the three-way catalyst, and, since the air-fuel ratio of the exhaust gas is lean, this NO.sub.x is absorbed in the NO.sub.x absorbent located downstream of the three-way catalyst; when the operating air-fuel ratio of the engine becomes rich, the ability of the three-way catalyst for oxidizing HC and CO in the exhaust gas becomes low, and a part of HC and CO in the exhaust gas passes through the three-day catalyst; since the air-fuel ratio of the exhaust gas is rich, absorbed NO.sub.x is released from the NO.sub.x absorbent and this NO.sub.x is reduced as HC and CO passes through the three-way catalyst; therefore, the pollutants such as HC, CO, NO.sub.x are almost completely removed.
摘要翻译：本发明的废气净化装置包括设置在发动机的排气通路上的三通还原氧化催化剂和当废气的空燃比为稀的时吸收废气中的NOx的NOx吸收剂并且当排气的空燃比浓时释放吸收的NOx; 本发明的发动机在其大部分操作区域中被控制，使得发动机的运行空燃比在富空燃比和稀空燃比之间振荡，约为化学计量的中心值空燃比; 当发动机的工作空燃比变稀时，用于还原排气中的NOx的三元催化剂的能力变低，排气中的NOx的一部分通过三元催化剂，由于废气的空燃比是贫的，所以这种NOx被吸收在位于三元催化剂下游的NOx吸收剂中; 当发动机的运转空燃比变浓时，用于氧化废气中的HC和CO的三元催化剂的能力变低，排气中的HC和CO的一部分通过三天催化剂; 由于排气的空燃比丰富，吸收的NOx从NOx吸收剂中释放出来，并且随着HC和CO通过三元催化剂，NOx降低; 因此，HC，CO，NOx等污染物几乎完全被去除。

43. 发明授权

US5296196A Semiconductor hydrocarbon sensor 失效
标题翻译：半导体烃传感器
公开(公告)号：US5296196A
公开(公告)日：1994-03-22
申请号：US823720
申请日：1992-01-22
申请人： Shinichi Takeshima
发明人： Shinichi Takeshima
IPC分类号： B01D53/94 , B01D53/86 , G01N27/00 , G01N27/04 , G01N27/12 , G01N33/00
CPC分类号： G01N33/0047 , G01N27/12 , G01N33/0014 , Y10T436/21
摘要： A semiconductor-type hydrocarbon sensor includes an oxide semiconductor, an outer electrode formed on an outside surface of the oxide semiconductor, an inner electrode formed on an inside surface of the oxide semiconductor, and a zeolite layer constructed of zeolite carrying at least one metal selected from the group consisting of platinum and copper. Small molecular weight hydrocarbons enter pores of the zeolite layer and are oxidized so that the small molecular weight hydrocarbons cannot reach the oxide semiconductor. Large molecular weight hydrocarbons cannot enter the small pores of the zeolite layer and, instead, pass through grain boundaries of zeolite particles of the zeolite layer to reach the oxide semiconductor. As a result, the large molecular weight hydrocarbons are selectively detected by the semiconductor-type hydrocarbon sensor.
摘要翻译：半导体型烃传感器包括氧化物半导体，形成在氧化物半导体的外表面上的外电极，形成在氧化物半导体的内表面上的内电极和由载有至少一种金属的沸石构成的沸石层由铂和铜组成的组。小分子量碳氢化合物进入沸石层的气孔并被氧化，使得小分子量烃不能到达氧化物半导体。大分子量烃不能进入沸石层的小孔，而是通过沸石层沸石颗粒的晶界到达氧化物半导体。结果，通过半导体型烃传感器选择性地检测大分子量烃。

44. 发明授权

US4934142A Exhaust emission control device for a diesel engine 失效
标题翻译：柴油机废气排放控制装置
公开(公告)号：US4934142A
公开(公告)日：1990-06-19
申请号：US281048
申请日：1988-12-07
申请人： Kotaro Hayashi , Tokuta Inoue , Sumio Ito , Kiyoshi Kobashi , Shinichi Takeshima
发明人： Kotaro Hayashi , Tokuta Inoue , Sumio Ito , Kiyoshi Kobashi , Shinichi Takeshima
IPC分类号： B01D46/00 , B01D46/42 , B01D53/38 , B01D53/81 , B01D53/86 , B01D53/94 , B01J29/06 , F01N3/02 , F01N3/027 , F01N3/031 , F01N3/033 , F01N3/08 , F01N3/20 , F01N3/28 , F02B3/06
CPC分类号： B01D53/9481 , B01D53/9472 , F01N3/027 , F01N3/031 , F01N3/033 , F01N3/0807 , F01N3/0835 , F01N3/0878 , F01N3/20 , F01N3/2882 , B01D2255/20761 , B01D2255/50 , B01D2257/90 , B01D2258/012 , F01N2240/18 , F01N2250/02 , F01N2250/12 , F01N2250/14 , F01N2330/06 , F01N2370/22 , F01N2370/24 , F01N2390/02 , F01N2410/04 , F01N2410/12 , F01N2510/12 , F01N2570/04 , F01N2570/08 , F02B3/06 , Y10S55/30
摘要： An exhaust emission gas control device having a first filter trapping particulates contained in an exhaust gas, and a second filter removing offensive odor components in the exhaust gas. The first filter is a honeycomb type having a cordierite substrate on which .tau.-alumina is coated. The second filter is provided downstream of the first filter, and is formed by an ion-exchange of copper on a synthetic zeolite rich in silica to form copper ions thereon.
摘要翻译：一种排气排放气体控制装置，其具有：第一过滤器，捕集废气中含有的微粒;以及第二过滤器，排除废气中的异味成分。第一过滤器是具有堇青石基底的蜂窝类型，其上涂覆有氧化钛。第二过滤器设置在第一过滤器的下游，并且通过在富含二氧化硅的合成沸石上离子交换铜而形成铜离子。

45. 发明授权

US09884770B2 Ammonia synthesis method 有权
公开(公告)号：US09884770B2
公开(公告)日：2018-02-06
申请号：US14905355
申请日：2013-08-08
申请人： Shinichi Takeshima
发明人： Shinichi Takeshima
IPC分类号： C01C1/04 , C01B3/02 , C01B3/04
CPC分类号： C01C1/04 , C01B3/025 , C01B3/042 , C01C1/0405 , Y02E60/364 , Y02P20/134 , Y02P20/52
摘要： According to the present invention there is provided an ammonia synthesis method using solar thermal energy, whereby it is possible to minimize the load of collecting solar thermal energy, and especially high-temperature solar thermal energy. The method of the present invention for synthesis of ammonia using solar thermal energy includes the following steps (a) to (c): (a) conducting ammonia synthesis reaction in which nitrogen and hydrogen are reacted to synthesize ammonia, (b) heating a heating medium by solar thermal energy and the reaction heat energy of the ammonia synthesis reaction, and (c) conducting at least part of the water splitting reaction in which water is split into hydrogen and oxygen, using the thermal energy of the heated heating medium, to obtain the hydrogen.

46. 发明授权

US09381496B2 Nanoparticle carrying method 有权
标题翻译：纳米颗粒携带方法
公开(公告)号：US09381496B2
公开(公告)日：2016-07-05
申请号：US12673021
申请日：2009-03-18
申请人： Shinichi Takeshima , Toru Sasatani
发明人： Shinichi Takeshima , Toru Sasatani
IPC分类号： B01J23/10 , B01D53/94 , B01J35/00 , B01J23/745 , B01J37/02 , B01J37/03 , B01J21/04
CPC分类号： B01J23/10 , B01D53/9422 , B01D2255/2065 , B01D2255/20707 , B01D2255/20738 , B01D2255/2092 , B01D2255/91 , B01D2255/9202 , B01J21/04 , B01J23/745 , B01J35/0013 , B01J35/006 , B01J37/0207 , B01J37/0211 , B01J37/031
摘要： A nanoparticle carrying method making a carrier adsorb ammonium ions, making the nanoparticles adsorb an organic acid, and making the carrier and the nanoparticles contact each other in a basic solution to thereby cause the carrier to adsorb the nanoparticles. Nanoparticles can be carried in high dispersion irrespective of superhydrophilicity.
摘要翻译：使载体吸附铵离子的纳米颗粒携带方法，使得纳米颗粒吸附有机酸，并使载体和纳米颗粒在碱性溶液中相互接触，从而使载体吸附纳米颗粒。无论超亲水性如何，纳米颗粒都可以承载高分散体。

47. 发明申请

US20130280159A1 CATALYST FOR DECOMPOSITION OF SULFUR TRIOXIDE AND HYDROGEN PRODUCTION PROCESS 有权
标题翻译：用于分解三氧化硫和氢生产过程的催化剂
公开(公告)号：US20130280159A1
公开(公告)日：2013-10-24
申请号：US13997473
申请日：2011-12-27
申请人： Shinichi Takeshima , Masato Machida
发明人： Shinichi Takeshima , Masato Machida
IPC分类号： B01J23/847 , B01J23/26 , C01B3/06 , B01J23/22
CPC分类号： B01J23/8472 , B01J23/22 , B01J23/26 , B01J29/0333 , B01J29/0341 , B01J35/002 , B01J35/1061 , B01J35/109 , B01J37/0201 , B01J37/0205 , B01J37/0242 , C01B3/068 , Y02A50/2348 , Y02E60/36
摘要： To provide a sulfur trioxide decomposition catalyst, particularly, a sulfur trioxide decomposition catalyst capable of lowering the temperature required when producing hydrogen by an S—I cycle process.A sulfur trioxide decomposition catalyst comprising a composite oxide of vanadium and at least one metal selected from the group consisting of transition metal and rare earth elements is provided. Also, a sulfur dioxide production process comprising decomposing sulfur trioxide into sulfur dioxide and oxygen by using the sulfur trioxide decomposition catalyst above, is provided. Furthermore, a hydrogen production process, wherein the reaction of decomposing sulfur trioxide into sulfur dioxide and oxygen by an S—I cycle process is performed by the above-described sulfur dioxide production process, is provided.
摘要翻译：提供一种三氧化硫分解催化剂，特别是能够降低通过S-I循环过程产生氢气所需的温度的三氧化硫分解催化剂。提供了包含钒和选自过渡金属和稀土元素中的至少一种金属的复合氧化物的三氧化硫分解催化剂。此外，还提供了通过使用上述三氧化硫分解催化剂将三氧化硫分解成二氧化硫和氧气的二氧化硫生产方法。另外，通过上述二氧化硫的制造方法进行氢过程，其中通过S-I循环过程将三氧化硫分解成二氧化硫和氧的反应进行。

48. 发明授权

US08435486B2 Redox material for thermochemical water splitting, and method for producing hydrogen 有权
标题翻译：用于热化学水分解的氧化还原材料，以及生产氢的方法
公开(公告)号：US08435486B2
公开(公告)日：2013-05-07
申请号：US12785938
申请日：2010-05-24
申请人： Shinichi Takeshima
发明人： Shinichi Takeshima
IPC分类号： C01B3/08 , B01J21/00 , B01J23/00 , B01J23/10
CPC分类号： C01B3/042 , B01J21/08 , B01J23/002 , B01J23/34 , B01J23/83 , B01J23/8892 , B01J29/0333 , B01J29/0341 , B01J37/0203 , B01J2523/00 , Y02E60/364 , B01J2523/3706 , B01J2523/72 , B01J2523/3712 , B01J2523/842
摘要： An improved redox material able to be used for thermochemical water splitting, and a method for producing hydrogen using this redox material are provided. The redox material for thermochemical water splitting comprises a redox metal oxide selected from the group comprising perovskite-type composite metal oxides, fluorite-type composite metal oxides and combinations thereof, and a metal oxide carrier. The redox metal oxide is carried on the metal oxide carrier in a dispersed state. The method for producing hydrogen uses the oxidation and reduction of the redox material to decompose water into hydrogen and oxygen.
摘要翻译：提供能够用于热化学水分解的改进的氧化还原材料，以及使用该氧化还原材料制造氢的方法。用于热化学水分解的氧化还原材料包括选自钙钛矿型复合金属氧化物，萤石型复合金属氧化物及其组合的氧化还原金属氧化物和金属氧化物载体。氧化还原金属氧化物以分散状态载持在金属氧化物载体上。氢的制造方法使用氧化还原材料的氧化还原，将水分解成氢气和氧气。

49. 发明授权

US08288310B2 Automobile exhaust gas purification catalyst and method of production of same 有权
标题翻译：汽车废气净化催化剂及其生产方法相同
公开(公告)号：US08288310B2
公开(公告)日：2012-10-16
申请号：US12513171
申请日：2007-11-01
申请人： Shinichi Takeshima , Akio Koyama
发明人： Shinichi Takeshima , Akio Koyama
IPC分类号： B01J23/00 , B01J21/00
CPC分类号： B01D53/945 , B01D2255/1025 , B01D2255/20715 , B01J21/066 , B01J23/464 , B01J35/006 , B01J35/1014 , B01J37/0207 , B01J37/0211 , B01J37/08 , Y02A50/2324 , Y02T10/22
摘要： An automobile exhaust gas purification catalyst comprised of a support mainly comprised of ZrO2 in which Rh is supported as a catalyst metal preventing sintering of the support, raising the supporting efficiency, and raising the low temperature activity and a method of production of the same are provided. An automobile exhaust gas purification catalyst comprised of a support mainly comprised of ZrO2, sintered under firing conditions where the as fired ZrO2 will substantially not be charged in a catalyst metal supporting treatment solution, in which Rh is supported as a catalyst metal in a particle state. The method of production includes a step of charging the support mainly comprised of ZrO2 fired under the above firing conditions by applying at least one treatment of an acid treatment and a base treatment and a step of dipping the charged state support in the catalyst supporting treatment solution including a colloid of Rh as the catalyst metal to make the Rh colloid be adsorbed on the support.
摘要翻译：本发明提供一种汽车排气净化催化剂，其特征在于，主要由作为催化剂金属负载的作为催化剂金属的ZrO 2的载体，能够防止烧结烧结，提高支持效率，提高低温活性的载体及其制造方法。一种汽车废气净化催化剂，由主要由ZrO 2组成的载体组成，在烧成条件下烧结ZrO 2基本上不会在催化剂金属负载处理溶液中充电，其中Rh作为催化剂金属以粒子状态负载。该制造方法包括以下步骤：在上述烧成条件下，通过进行至少一种酸处理和碱处理的处理，以及将带电状态的载体浸渍在催化剂负载处理液中的步骤，包括Rh的胶体作为催化剂金属，使Rh胶体吸附在载体上。

50. 发明申请

US20110082291A1 METHOD FOR GLYCOSYLATING AND SEPARATING PLANT FIBER MATERIAL 有权
标题翻译：用于糖化和分离植物纤维材料的方法
公开(公告)号：US20110082291A1
公开(公告)日：2011-04-07
申请号：US12995756
申请日：2009-06-02
申请人： Shinichi Takeshima , Takeshi Kikuchi
发明人： Shinichi Takeshima , Takeshi Kikuchi
IPC分类号： C07H1/08 , C07H1/00
CPC分类号： C13K1/02
摘要： The invention relates to a method for hydrolyzing a plant fiber material to produce and separate a saccharide including glucose. The method includes a hydrolysis process of using a cluster acid catalyst in a pseudo-molten state to hydrolyze cellulose contained in the plant fiber material, and produce glucose. The cluster acid catalyst is subjected to a clustering enhancing treatment by which clustering of the cluster acid catalyst in a crystalline state is enhanced.
摘要翻译：本发明涉及一种用于水解植物纤维材料以产生和分离包括葡萄糖的糖的方法。该方法包括使用假熔融状态的簇酸催化剂水解纤维素中所含的纤维素并产生葡萄糖的水解方法。聚簇酸催化剂进行聚簇增强处理，通过该聚集增强处理，晶体状态的聚集酸催化剂的聚集得到增强。

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