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41. 发明授权

US4769478A Preparation of (1,5) 6,6-dimethyl-4-hydroxy-3-oxabicyclo (3,1,0) hexan-2-one and its ethers 失效
标题翻译：（1,5）6,6-二甲基-4-羟基-3-氧杂双环（3,1,0）己-2-酮及其醚的制备
公开(公告)号：US4769478A
公开(公告)日：1988-09-06
申请号：US807857
申请日：1985-12-11
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07D307/33 , C07D307/60 , C07D307/93 , C07D307/77
CPC分类号： C07D307/60 , C07D307/93
摘要： An improved process for the preparation of compounds of the (1R,4R,5S) or (1S,4S,5R) configuration of the formula ##STR1## wherein Y is selected from the group consisting of hydrogen and the organic residue Z of a chiral alcohol of the formula ZOH is disclosed.
摘要翻译：用于制备式（1R，4R，5S）或（1S，4S，5R）构型的式I化合物的改进方法，其中Y选自氢和有机残基Z 披露了式ZOH的手性醇。

42. 发明授权

US4689342A Certain insecticidal cyclopropane carboxylic acid derivatives 失效
公开(公告)号：US4689342A
公开(公告)日：1987-08-25
申请号：US554092
申请日：1983-11-21
申请人： Jean Tessier , Jean-Pierre Demoute
发明人： Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C67/08 , A01N53/00 , A01N53/04 , A01N53/06 , A23K1/16 , A61K31/44 , A61K31/4402 , A61K31/4418 , A61K31/4427 , A61P17/00 , A61P33/00 , C07C67/00 , C07C69/74 , C07C69/747 , C07C253/00 , C07C255/39 , C07C313/00 , C07C317/44 , C07C323/55 , C07C325/00 , C07C327/22 , C07D207/00 , C07D207/32 , C07D207/325 , C07D207/327 , C07D213/30 , C07D213/57 , C07D213/75 , C07D213/79 , C07D307/45 , C07D401/04 , C07C69/743 , C07C121/46
CPC分类号： C07D207/325 , A01N53/00 , C07D207/327 , C07D213/75 , C07D213/79 , C07D401/04
摘要： Novel esters in all possible isomeric forms or a mixture thereof having the formula ##STR1## wherein Y is selected from the group consisting of hydrogen, halogen, --OAlK and ##STR2## AlK is alkyl of 1 to 6 carbon atoms, n is 0, 1 or 2, Z is selected from the group consisting of --O-- and --S--, R.sub.1 is selected from the group consisting of (a) optionally unsaturated alkyl of 1 to 8 carbon atoms and optionally unsaturated cycloalkyl or cycloalkylalkyl of 3 to 8 carbon atoms optionally substituted with at least one member of the group consisting of halogen, --OH, --SH, --OR', --SR', ##STR3## --SO.sub.2 AlK.sub.2, --SO.sub.3 AlK.sub.3, aryl optionally substtuted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3, --SCF.sub.3 and ##STR4## R' is alkyl of 1 to 8 carbon atoms, R" and R'" are individually selected from the group consisting of hydrogen and alkyl of 1 to 8 carbon atoms, AlK.sub.1, AlK.sub.2 and AlK.sub.3 are individually alkyl of 1 to 18 carbon atoms (b) aryl of 6 to 14 carbon atoms optionally substituted with at least one substituent selected from the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --OCF.sub.3, --CF.sub.3 and --SCF.sub.3 and (c) heterocycle optionally substituted with at least one member of the group consisting of --OH, alkoxy of 1 to 8 carbon atoms, alkyl of 1 to 8 carbon atoms, halogen, --CF.sub.3, --OCF.sub.3 and --SCF.sub.3, R.sub.2, R.sub.3 and R.sub.4 are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 8 carbon atoms, haloalkyl of 1 to 8 carbon atoms containing a plurality of halogens and alkoxy of 1 to 8 carbon atoms, W is selected from the group consisting of hydrogen and --CN, X is selected from the group consisting of carbon and nitrogen, Ar is selected from the group consisting of optionally substituted phenyl, pyridyl, thienyl, naphthyl, furyl and pyrrolyl and the ethylenic double bond may have Z or E geometry having parasitic activity, especially insecticidal, acaricidal and nematocidal activity.

43. 发明授权

US4642372A Novel process for preparation of 1-furenyl-2,2-dimethyl-cyclopropane carboxylic acid derivatives 失效
标题翻译：制备1-呋喃基-2,2-二甲基 - 环丙烷羧酸衍生物的新方法
公开(公告)号：US4642372A
公开(公告)日：1987-02-10
申请号：US760313
申请日：1985-07-29
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C62/16 , A01N53/00 , C07C51/00 , C07C51/373 , C07C62/36 , C07C67/00 , C07C69/757 , C07C253/00 , C07C255/45 , C07C255/46 , C07C255/48 , C07C317/46
CPC分类号： C07C255/00 , A01N53/00 , C07C317/46 , C07C51/373
摘要： A process for the preparation of cyclopropane carboxylic acid derivatives of the formula ##STR1## wherein Z is selected from the group consisting of --CN, --COOH and --COOR.sub.1, R.sub.1 is alkyl of 1 to 6 carbon atoms and R.sub.2 and R.sub.3 are alkyl of 1 to 4 carbon atoms or taken together with the carbon atom to which they are attached form a carbon homocycle of 3 to 6 carbon atoms comprising reacting at low temperatures in a solvent in the presence of a strong base a compound of the formula ##STR2## wherein Z has the above definitions and R is alkyl of 1 to 6 carbon atoms or together form a polymethylene of 2 to 3 carbon atoms with a sulfone of the formula ##STR3## wherein R.sub.2 and R.sub.3 have the above definitions and Y is an aromatic group followed by aqueous treatment to obtain a compound of the formula ##STR4## wherein Y, R, R.sub.2, R.sub.3 and Z have the above definitions, reacting the latter at a low temperature in a solvent with a strong base while letting the temperature rise to obtain a compound of the formula ##STR5## wherein R, R.sub.2, R.sub.3 and Z have the above definitions of the cis/trans configuration richer in the trans isomer and either reacting the latter when Z is --CN or --COOR.sub.1 with a strong base in an aqueous media followed by acidification to obtain a compound of the formula ##STR6## wherein R, R.sub.2 and R.sub.3 have the above definitions having the same configuration as the compound of formula V or reacting the compound of formula V or Va with an acid agent in an aqueous media to obtain the corresponding compound of formula I with the same configuration as the compound of formula V or Va and optionally treating the latter with a weak base at room temperature to obtain the compound of formula I with a trans configuration which are valuable intermediates for the preparation of esters of cyclopropane carboxylic acid having elevated insecticidal activity.
摘要翻译：一种制备下式的环丙烷羧酸衍生物的方法，其中Z选自-CN，-COOH和-COOR 1，R 1是1至6个碳原子的烷基，R 2和R 3是烷基 1至4个碳原子或与它们所连接的碳原子一起形成3至6个碳原子的碳原子碳原子，包括在弱碱存在下在低温下在溶剂中使下式化合物 >其中Z具有上述定义，R是1至6个碳原子的烷基或一起形成2至3个碳原子的聚亚甲基与下式的砜其中R2和R3具有上述定义，Y是芳族基团，然后进行水处理，得到式IV的化合物，其中Y，R，R 2，R 3和Z具有上述定义，后者在低温下在溶剂中与强碱反应，同时使升温得到t的化合物其中R，R2，R3和Z具有上述反式异构体中更稠的顺式/反式构型的定义，并且当Z是-CN或-COOR1时在后者中与强碱在水性介质中反应然后酸化以得到下式的化合物其中R，R 2和R 3具有与式V化合物相同构型的上述定义，或使式V或Va的化合物与酸剂在水溶液培养基以获得与式V或Va化合物相同构型的相应的式I化合物，并任选地在室温下用弱碱处理后者，得到具有反式构型的式I化合物，其为具有提高的杀虫活性的环丙烷羧酸的酯的制备。

44. 发明授权

US4537897A 3-(1,2-Propadienyl)-cyclopropane-carboxylates 失效
标题翻译： 3-（1,2-丙二烯基） - 环丙烷羧酸酯
公开(公告)号：US4537897A
公开(公告)日：1985-08-27
申请号：US532825
申请日：1983-09-15
申请人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
发明人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
IPC分类号： C07C69/747 , A01N53/00 , A01N53/02 , A01N53/10 , C07C51/09 , C07C51/367 , C07C67/00 , C07C69/743 , C07C231/00 , C07C231/12 , C07C233/10 , C07C253/00 , C07C255/31 , C07C255/39 , C07C313/00 , C07C319/20 , C07C323/19 , C07C323/62 , C07C325/00 , C07C327/44 , C07D213/64 , C07D213/647 , C07D233/72 , C07D233/74 , C07D307/45 , C07D309/40 , C07D213/68
CPC分类号： C07D213/647 , A01N53/00 , C07C51/09 , C07C51/367 , C07D233/74 , C07D307/42
摘要： Novel 3-(1,2-propadienyl)-cyclopropane-carboxylates of the formula ##STR1## wherein R is alcohol used in pyrethrinoid synthesis, X and Y are both hydrogen or individually halogen or X is hydrogen or halogen and Y is alkyl of 1 to 18 carbon atoms or halogen or X is hydrogen or halogen or alkyl of 1 to 18 carbon atoms and Y is --COOR' or --CN or ##STR2## R' is alkyl of 1 to 18 carbon atoms, R.sub.2 and R.sub.3 are individually hydrogen or alkyl of 1 to 18 carbon atoms or R.sub.2 and R.sub.3 together with the nitrogen atom form a heterocycle having pesticidal properties.
摘要翻译：其中R是用于拟除虫菊酯合成的醇的新型3-（1,2-丙二烯基） - 环丙烷羧酸盐，X和Y都是氢或单独的卤素或X是氢或卤素，Y是 1至18个碳原子或卤素或X为氢或卤素或1至18个碳原子的烷基，Y为-COOR'或-CN或R 1为具有1至18个碳原子的烷基，R 2和R 3分别为氢或1至18个碳原子的烷基或R2和R3与氮原子一起形成具有杀虫性质的杂环。

45. 发明授权

US4500720A Tetrahydrofuran-2-ones 失效
标题翻译：四氢呋喃-2-酮
公开(公告)号：US4500720A
公开(公告)日：1985-02-19
申请号：US571995
申请日：1984-01-19
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/73 , A01N43/08 , C07C51/00 , C07C51/09 , C07C59/74 , C07C67/00 , C07D307/33 , C07D307/93 , C07F9/655 , C07D307/32
CPC分类号： C07D307/33 , C07C59/74 , C07D307/93
摘要： Novel 3-formyl-4-methyl-pent-3-ene-1-oic acid of the formula ##STR1## and a process for its preparation and intermediates and a process for the preparation of compounds of the formula ##STR2## wherein W is selected from the group consisting of hydrogen and R.sub.1 of an optionally chiral alcohol R.sub.1 OH, useful as an intermediate for the production of numerous ester having elevated insecticidal activity.
摘要翻译：具有下式的新颖的3-甲酰基-4-甲基 - 戊-3-烯-1-酸及其制备方法和中间体以及制备式（VI）的化合物的方法其中 W选自氢和任选的手性醇R 1 R的R 1，其可用作生产具有高杀虫活性的多种酯的中间体。

46. 发明授权

US4401601A Novel process for the preparation of tetra-substituted cyclopropane compounds 失效
标题翻译：制备四取代环丙烷化合物的新方法
公开(公告)号：US4401601A
公开(公告)日：1983-08-30
申请号：US246172
申请日：1981-03-23
申请人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre Demoute
IPC分类号： C07C69/74 , C07C51/00 , C07C61/04 , C07C61/125 , C07C67/00 , C07C253/00 , C07C255/46 , C07C313/00 , C07C315/04 , C07C317/44 , C07C121/46
CPC分类号： C07C317/44
摘要： A process for the preparation of tetrasubstituted cyclopropane compounds of the formula ##STR1## wherein Y is selected from the group consisting of --CN and --COOR, R is selected from the group consisting of hydrogen and alkyl of 1 to 6 carbon atoms and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are individually selected from alkyl of 1 to 4 carbon atoms or R.sub.1 and R.sub.2 or R.sub.3 and R.sub.4 together with the carbon atoms to which they are attached form a carbon homocycle of 3 to 6 carbon atoms with the 2 substituents not forming the ring being alkyl of 1 to 4 carbon atoms or R.sub.1 and R.sub.2 on the one hand and R.sub.3 and R.sub.4 on the other together with the carbon atom to which they are attached form a carbon homocycle of 3 to 6 carbon atoms which are useful intermediates for the preparation of insecticidal esters and novel intermediates.
摘要翻译：制备式IMA的四取代环丙烷化合物的方法，其中Y选自-CN和-COOR，R选自氢和1至6个碳原子的烷基，R 1 ，R 2，R 3和R 4分别选自1至4个碳原子的烷基或R 1和R 2或R 3和R 4与它们所连接的碳原子一起形成3至6个碳原子的碳均碳原子，而2个取代基不是形成环为1至4个碳原子的烷基或R 1和R 2，另一方面R 3和R 4与它们所连接的碳原子一起形成具有3至6个碳原子的碳原子，这是有用的中间体用于制备杀虫剂和新型中间体。

47. 发明授权

US4357335A Substituted pyridine methyl esters of dimethyl cyclopropane carboxylic acids and their use as insecticides 失效
标题翻译：二甲基环丙烷羧酸的取代吡啶甲酯及其作为杀虫剂的用途
公开(公告)号：US4357335A
公开(公告)日：1982-11-02
申请号：US280547
申请日：1981-07-06
申请人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
IPC分类号： A01N53/04 , A01N53/00 , A01N53/08 , A61K31/44 , C07D213/64 , C07D213/643 , C07D213/647 , C07D213/70 , C07D405/12 , C07D409/12 , C07D213/55
CPC分类号： C07D213/643 , A01N53/00 , A61K31/44 , C07D213/647 , C07D213/70
摘要： Novel esters in all possible isomeric forms and mixtures thereof of the formula ##STR1## wherein A is selected from the group consisting of ##STR2## R is selected from the group consisting of hydrogen, --CN and --C.tbd.CH, Y is selected from the group consisting of oxygen and sulfur, Z is selected from the group consisting of alkyl and alkoxy of 1 to 4 carbon atoms, alkylthio and alkylsulfonyl of 1 to 4 carbon atoms, cycloalkyl of 3 to 4 carbon atoms, 3,4-methylenedioxy, chlorine, fluorine and bromine, n is an integer of 0, 1 or 2, Z.sub.1 and Z.sub.2 may both be methyl or Z.sub.1 is hydrogen and Z.sub.2 is ##STR3## R.sub.3 is selected from the group consisting of hydrogen and halogen, R.sub.1 and R.sub.2 are individually alkyl of 1 to 8 carbon atoms or taken together with the carbon they are attached to form cycloalkyl of 3 to 6 carbon atoms or ##STR4## X is selected from the group consisting of oxygen and sulfur, T is at least one member of the group consisting of halogen, alkyl of 1 to 8 carbon atoms, alkoxy of 1 to 8 carbon atoms optionally substituted with at least one halogen and --CF.sub.3 and m is an integer from 0, 1 or 2 having insecticidal activity as well as nematocidal and acaricidal activity.
摘要翻译：所有可能的异构体形式的新型酯及其下式的混合物，其中A选自由下列组成的组：R 1选自氢，-CN和-C 3位CH，Y选自 Z为选自由1至4个碳原子的烷基和烷氧基组成的组，1至4个碳原子的烷硫基和烷基磺酰基，3至4个碳原子的环烷基，3,4-亚甲二氧基，氯，氟和溴，n是0,1或2的整数，Z1和Z2都可以是甲基或Z1是氢，Z2是选自氢和卤素，R1和R2 具有1至8个碳原子的单独烷基或与它们所连接的碳一起形成3至6个碳原子的环烷基，或者X选自氧和硫，T是至少一个由卤素，1至8个碳原子的烷基，1至8个的烷氧基组成的组任选被至少一个卤素和-CF 3取代的碳原子，m是具有杀虫活性以及杀线虫和杀螨活性的0,1或2的整数。

48. 发明授权

US4328167A Process for the preparation of optically active cyano alcohols 失效
标题翻译：光学活性氰醇的制备方法
公开(公告)号：US4328167A
公开(公告)日：1982-05-04
申请号：US155753
申请日：1980-06-02
申请人： Jacques Martel , Jean Tessier , Jean-Pierre DeMoute
发明人： Jacques Martel , Jean Tessier , Jean-Pierre DeMoute
IPC分类号： C07B53/00 , C07B31/00 , C07C51/09 , C07C67/00 , C07C253/00 , C07C255/37 , C07C255/39 , C07C121/75
CPC分类号： C07C51/09
摘要： A novel process for the preparation of optically active alcohols of the formula ##STR1## wherein R.sub.1 and R.sub.2 are individually selected from the group consisting of hydrogen, saturated and unsaturated, optionally substituted aliphatic, cycloaliphatic, aromatic and heterocyclic, with the proviso that at least one of R.sub.1 and R.sub.2 is other than hydrogen, and R.sub.1 and R.sub.2 taken together with the carbon atom to which they are attached form a hydrocarbon ring comprising reacting an ester of an optically active alcohol of the formula ##STR2## wherein A is the organic radical of a chiral carboxylic acid of the formula ##STR3## with a boron halide and reacting the resulting mixture with water to obtain the optically active isomer of the alcohol of formula I with the same configuration of the alcohol moiety of the starting ester in high yields without by-products of known processes.
摘要翻译：一种制备下式的光学活性醇的新方法，其中R 1和R 2分别选自氢，饱和和不饱和的，任选取代的脂族，脂环族，芳族和杂环的，条件是在 R1和R2中的至少一个不是氢，R1和R2与它们所连接的碳原子一起形成烃环，包括使下式的光学活性醇的酯反应其中A是具有式“IMAGE”的手性羧酸的有机基团与卤化硼反应，并将所得混合物与水反应，得到具有相同构型的起始酯的醇部分的式I醇的旋光异构体，产量没有已知方法的副产物。

49. 发明授权

US4273727A (S) .alpha.-Cyano-3-phenoxy-benzyl alcohol 失效
标题翻译：（S）α-氰基-3-苯氧基 - 苄醇
公开(公告)号：US4273727A
公开(公告)日：1981-06-16
申请号：US973791
申请日：1978-12-28
申请人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
发明人： Jacques Martel , Jean Tessier , Andre Teche , Jean-Pierre Demoute
IPC分类号： A01N37/34 , A01N37/10 , A01N37/38 , A01N53/08 , A01P7/04 , C07B57/00 , C07C57/58 , C07C67/00 , C07C253/00 , C07C253/30 , C07C253/34 , C07C255/33 , C07C255/36 , C07C255/37 , C07C255/39 , C07C255/53 , C07D307/93 , C07C121/75
CPC分类号： C07D307/93 , A01N37/38 , C07C255/00 , C07C255/53 , C07C57/58
摘要： (S) .alpha.-cyano-3-phenoxy-benzyl alcohol having the formula ##STR1## and a novel process for its preparation and novel intermediates.
摘要翻译：（S）具有式“IMAGE”I的α-氰基-3-苯氧基 - 苄醇和其制备新颖的方法和新型中间体。

50. 发明授权

US4879302A Certain oximino-cyclopropane carboxylates having insecticidal activity 失效
标题翻译：某些具有杀虫活性的肟基 - 环丙烷羧酸盐
公开(公告)号：US4879302A
公开(公告)日：1989-11-07
申请号：US114534
申请日：1987-10-29
申请人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
发明人： Jean Tessier , Jean-Pierre Demoute , Joseph Cadiergue
IPC分类号： C07D209/49 , A01N53/00 , A01N53/02 , A23K1/16 , A61K31/35 , A61K31/351 , A61K31/40 , A61K31/403 , A61K31/4035 , A61K31/415 , A61K31/4166 , A61K31/44 , A61K31/4402 , A61K31/4418 , A61P33/10 , C07C67/00 , C07C239/00 , C07C251/36 , C07C251/38 , C07C251/40 , C07D213/64 , C07D213/647 , C07D213/68 , C07D213/70 , C07D233/72 , C07D307/42 , C07D309/38
CPC分类号： C07D213/647 , A01N53/00 , A23K20/00
摘要： All possible stereoisomeric forms and mixtures thereof of a compound of the formula ##STR1## wherein A is selected from the group consisting of hydrogen, optionally unsaturated alkyl and haloalkyl of 1 to 18 carbon atoms, optionally substituted with aryl or a heterocyclic and optionally interrupted by --O-- or --S--, optionally unsaturated cycloalkyl of 3 to 18 carbon atoms, aryl of 6 to 14 carbon atoms and heterocyclic, B is selected from the group consisting of hydrogen, alkyl of 1 to 18 carbon atoms optionally interrupted by --S-- or --O-- and optionally substituted with at least one member of the group consisting of halogen, --OH, alkoxy of 1 to 8 carbon atoms, --SH, thioalkoxy of 1 to 8 carbon atoms, --NO.sub.2 and --CN and R is selected from the group consisting of optionally unsaturated alkyl of 1 to 18 carbon atoms and residue of an alcohol used in the synthesis of pyrethrinoid esters having pesticidal activity.
摘要翻译：式I化合物的所有可能的立体异构形式及其混合物，其中A选自氢，任选不饱和的烷基和具有1至18个碳原子的卤代烷基，任选被芳基或杂环取代，并任选地中断 3至18个碳原子的任选不饱和环烷基，6至14个碳原子的芳基和杂环基，B选自氢，1至18个碳原子的烷基，任意地被 - 任选被至少一个卤素，-OH，1-8个碳原子的烷氧基，-SH，1至8个碳原子的硫代烷氧基，-NO 2和-CN和R 选自具有1至18个碳原子的任选不饱和的烷基和用于合成具有杀虫活性的拟除虫菊酯的醇的残基。

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