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41. 发明授权

US5527925A Functionalized photoinitiators, macromers thereof, and the use thereof 失效
标题翻译：官能化光引发剂，其大分子单体及其用途
公开(公告)号：US5527925A
公开(公告)日：1996-06-18
申请号：US265597
申请日：1994-06-24
申请人： Peter Chabrecek , Dieter Lohmann
发明人： Peter Chabrecek , Dieter Lohmann
IPC分类号： G02C7/04 , C07C49/76 , C07C49/82 , C07C271/20 , C07C271/24 , C07C271/28 , C07C271/32 , C07C271/38 , C07D317/26 , C07F7/10 , C08B31/00 , C08B33/00 , C08B37/00 , C08B37/08 , C08B37/16 , C08F2/48 , C08F2/50 , C08F8/30 , C08F16/36 , C08G18/00 , C08G18/08 , C08G18/71 , C08G77/04 , C08G77/38 , C08J3/28 , C08J7/12 , C08J7/18 , C08L101/02 , G02B1/04 , G03F7/031 , G03F7/075 , C07C249/00 , C07C251/00 , C07D317/32
CPC分类号： G03F7/075 , C07C271/20 , C07C271/24 , C07C271/28 , C07C271/38 , C08B37/0012 , C08B37/0072 , C08F2/50 , C08F8/30 , C08G77/38 , C08J7/12 , C08J7/18 , G02B1/043 , G03F7/031 , C07C2101/14 , Y10S522/904 , Y10S522/905 , Y10T428/31645 , Y10T428/31663 , Y10T428/31667 , Y10T428/31855 , Y10T428/31971
摘要： Compounds of formula I: ##STR1## are disclosed. The compounds are photoinitiators which can be functionalized by means of ethylenic groups or can be bonded to H-active substances, in order, for example, to modify surfaces by means of photopolymerizable substances. The compounds are especially useful in the manufacture of contact lenses.
摘要翻译：公开了式I化合物：。这些化合物是可以通过烯属基官能化或可以与H-活性物质结合的光引发剂，以便例如通过可光聚合物质来修饰表面。这些化合物在隐形眼镜的制造中特别有用。

42. 发明授权

US5281705A Method for making high bulk density crystalline 3-cyano-2-morpholino-5-(pyrid-4yl)-pyridine 失效
标题翻译：制备高密度结晶3-氰基-2-吗啉代-5-（吡啶-4-基） - 吡啶的方法
公开(公告)号：US5281705A
公开(公告)日：1994-01-25
申请号：US971297
申请日：1992-11-04
申请人： Volker Hagen , Gunter Reck , Brigitte Gentsch , Hans-Joachim Heidrich , Hans-Joachim Jansch , Ingrid Wielop , Dieter Lohmann
发明人： Volker Hagen , Gunter Reck , Brigitte Gentsch , Hans-Joachim Heidrich , Hans-Joachim Jansch , Ingrid Wielop , Dieter Lohmann
IPC分类号： A61K31/535 , A61K31/5377 , A61P9/04 , A61P9/08 , C07B63/00 , C07D213/85 , C07D413/14
CPC分类号： C07D213/85
摘要： A method for preparing high bulk density crystalline 3-cyano-2-morpholino-5-(pyrid-4-yl)-pyridine which comprises precipitating a high bulk density crystalline 3-cyano-2-morpholino-5-(pyrid-4-yl)-pyridine from a starting material that is(a) a solution in an inorganic or organic acid, and precipitating with a base, or(b) a solution in a chlorinated hydrocarbon, and precipitating with an aliphatic hydrocarbon, or(c) from an aliphatic ester of an aliphatic carboxylic acid and an aliphatic alcohol.The compact, crystalline 3-cyano-2-morpholino-5-(pyrid-4-yl)-pyridine, so obtained, has a bulk density of from about 220 to about 360 g/l and is most suitable for pharmaceutical preparations.
摘要翻译：一种制备高体积密度晶体3-氰基-2-吗啉代-5-（吡啶-4-基） - 吡啶的方法，其包括沉淀高体积密度的结晶3-氰基-2-吗啉代-5-（吡啶-4-基）（a）无机或有机酸溶液，并用碱沉淀的原料，或（b）氯代烃中的溶液，并用脂族烃沉淀，或（c）由脂肪族羧酸和脂肪族醇的脂肪族酯组成。如此获得的紧密结晶的3-氰基-2-吗啉代-5-（吡啶-4-基） - 吡啶的堆积密度为约220至约360g / l，最适用于药物制剂。

43. 发明授权

US4605712A Unsaturated polysiloxanes and polymers thereof 失效
标题翻译：不饱和聚硅氧烷及其聚合物
公开(公告)号：US4605712A
公开(公告)日：1986-08-12
申请号：US653416
申请日：1984-09-24
申请人： Karl F. Mueller , Dieter Lohmann , Robert A. Falk
发明人： Karl F. Mueller , Dieter Lohmann , Robert A. Falk
IPC分类号： C08F299/00 , C08F290/00 , C08F290/14 , C08F299/08 , C08G18/61 , C08G18/81 , C08G77/00 , C08G77/20 , C08G77/26 , C08G77/28 , C08G77/38 , C08G77/388 , C08G77/46 , C08G77/54 , C08L83/07 , C08L83/08 , C08L83/12 , G02B1/04 , G02C7/04 , C08F283/00
CPC分类号： G02B1/043 , C08F290/148 , C08F299/08 , C08G18/61 , C08G18/8108 , C08G18/8158 , C08G77/388 , C08G77/54
摘要： Polysiloxanes of uniform molecular weight (MW) distribution with 500-10,000 MW segments of polysiloxane and containing at least one vinyl group connected to said polysiloxane segments through intervening alkylene-urea or -urethane linkages are prepared from polysiloxane-polyols, -polyamines or -polythiols by reaction with an unsaturated compound containing an isocyanato moiety, for example 2-isocyanatoethyl methacrylate. The polysiloxanes containing the vinyl groups are useful as radiation- or thermally curable coatings for glass, textiles, plastics, wood, ceramics, metals, as films or bandages for medicinal purposes, or molded shapes, in form of contact lenses, catheters or implants, either by themselves or in combination with other vinyl monomers; and are particularly useful in preparing hard or soft contact lenses, including hydrogel contact lenses.
摘要翻译：由聚硅氧烷 - 多元醇，聚胺或聚硫醇制备具有500-10,000MW聚硅氧烷链段并含有至少一个通过插入的亚烷基 - 脲或 - 氨基键连接到所述聚硅氧烷链段上的乙烯基的分子量（MW）分布的聚硅氧烷通过与含有异氰酸酯基的不饱和化合物反应，例如甲基丙烯酸2-异氰酸根合乙酯。含有乙烯基的聚硅氧烷可用作玻璃，纺织品，塑料，木材，陶瓷，金属，作为药物用薄膜或绷带或隐形眼镜，导管或植入物形式的模制形状的辐射或热固化涂层，本身或与其它乙烯基单体组合; 并且特别可用于制备包括水凝胶隐形眼镜的硬或软性隐形眼镜。

44. 发明授权

US4424359A Vinyl-substituted 2,2'-bipyridine compounds 失效
标题翻译：乙烯基取代的2,2'-联吡啶化合物
公开(公告)号：US4424359A
公开(公告)日：1984-01-03
申请号：US287859
申请日：1981-07-27
申请人： Ju/ rgen Kaschig , Dieter Lohmann
发明人： Ju/ rgen Kaschig , Dieter Lohmann
IPC分类号： B01J31/22 , B01J31/00 , C07B61/00 , C07D213/18 , C07D213/22 , C07D213/26 , C07D213/30 , C07D213/89 , C07F9/58 , C07F15/00 , C08F26/00 , C08F26/06 , C07D401/04
CPC分类号： C07D213/22 , C07D213/26 , C07D213/30 , C07D213/89 , C07F9/582 , C08F26/06
摘要： Vinyl-substituted 2,2'-bipyridine compounds of the formula ##STR1## and complexes thereof with metals or metal compounds other than alkali metals or alkaline earth metals, or alkali metal compounds, or alkaline earth metal compounds are described, R.sub.1 and R.sub.2 being as defined in patent claim 1 and the vinyl group being bonded in the 4-position or 6-position. The 2,2'-bipyridine compounds (I) are suitable for the preparation of complex-forming or complexed, crosslinked or uncrosslinked polymers. Complexed polymers, obtainable from these, are used, for example, as catalysts, in particular for transvinylation reactions. Uncomplexed polymers, which can be prepared from compounds (I), are suitable as metal ion scavengers in various applications.
摘要翻译：描述了式（I）的乙烯基取代的2,2'-联吡啶化合物及其与碱金属或碱土金属以外的金属或金属化合物或其碱金属化合物或碱土金属化合物的络合物，R1 并且R 2如专利权利要求1中所定义，乙烯基键合在4-位或6-位。 2,2'-联吡啶化合物（I）适用于制备络合物形成或络合的交联或未交联的聚合物。可从这些获得的复合聚合物例如用作催化剂，特别是用于转乙烯化反应。可以由化合物（I）制备的未络合的聚合物在各种应用中适合作为金属离子清除剂。

45. 发明授权

US4417057A N-Substituted imides and bis-imides 失效
标题翻译： N-取代的酰亚胺和双酰亚胺
公开(公告)号：US4417057A
公开(公告)日：1983-11-22
申请号：US277555
申请日：1981-06-26
申请人： Dieter Lohmann , Martin Roth , Marcus Baumann
发明人： Dieter Lohmann , Martin Roth , Marcus Baumann
IPC分类号： C07D209/48 , C07D207/44 , C07D207/448 , C07D207/452 , C07D207/456 , C07D209/66 , C07D241/08 , C07D487/04 , C07D491/044 , C07D491/14 , C07D491/147 , C07F7/18 , C07D209/94
CPC分类号： C07D207/448 , C07D207/452 , C07D241/08 , C07D487/04 , C07D491/14 , C07F7/182
摘要： Compounds of the formulae I or II ##STR1## and processes for their preparation are described. In the above formulae, Z is a tetravalent aliphatic radical, which can be interrupted by hetero-atoms, or a substituted or unsubstituted tetravalent cycloaliphatic radical, which can contain hetero-atoms and/or can be fused to a benzene ring, A is --C(R.sup.4).dbd.C(R.sup.5)(R.sup.6) or --C.tbd.C--R.sup.5, especially --CH.dbd.CH.sub.2, R.sup.1 and R.sup.2 independenty of one another are H, methyl, phenyl, --CN or Cl, or together are trimethylene, tetramethylene, ##STR2## R.sup.3 is a direct bond, C.sub.1-8 alkylene, cyclohexylene, phenylene or --CH.sub.2 -phenylene with the --CH.sub.2 group bonded to the N atom, R.sup.4 and R.sup.6 independently of one another are H, methyl or ethyl and R.sup.5 is H or C.sub.1-9 alkyl. The compunds of the formula I and II are valuable intermediates for the preparation of silicon-modified adhesion promoters.
摘要翻译：描述式I或II化合物＆lt; IMAGE＆gt; + TR＆lt; IMAGE＆gt;及其制备方法。在上式中，Z是可以被杂原子间隔的四价脂肪族基团，或可以含有杂原子和/或可以与苯环稠合的取代或未取代的四价脂环族基团，A是 - C（R 4）= C（R 5）（R 6）或-C 3位C-R 5，特别是-CH = CH 2，R 1和R 2彼此独立地是H，甲基，苯基，-CN或Cl，四亚甲基，R 3是直接键，C 1-8亚烷基，亚环己基，亚苯基或-CH 2 - 亚苯基，其中-CH 2基团与N原子键合，R 4和R 6彼此独立地是H，甲基或乙基，R 5 是H或C 1-19烷基。式I和II的化合物是制备硅改性粘合促进剂的有价值的中间体。

46. 发明授权

US4336353A Salts of 3-methyl-2-(2',4'-dimethyl-phenylimino)-4-thiazoline with polymers containing sulfonic acid groups 失效
标题翻译： 3-甲基-2-（2'，4'-二甲基 - 苯基亚氨基）-4-噻唑啉与含磺酸基的聚合物的盐
公开(公告)号：US4336353A
公开(公告)日：1982-06-22
申请号：US183560
申请日：1980-09-02
申请人： Christian d'Hondt , Dieter Lohmann , Ernst Neuenschwander
发明人： Christian d'Hondt , Dieter Lohmann , Ernst Neuenschwander
IPC分类号： A01N25/10 , A01N43/78 , C08F8/44 , C08G85/00 , C08F8/30
CPC分类号： A01N25/10 , A01N43/78 , C08F8/44 , C08G85/00 , Y10S424/08
摘要： Salts of 3-methyl-2-(2',4'-dimethyl-phenylimino)-4-thiazoline with polymers containing sulfonic acid groups, processes for producing them, and their use in combating pests.
摘要翻译： 3-甲基-2-（2'，4'-二甲基 - 苯基亚氨基）-4-噻唑啉与含有磺酸基的聚合物的盐，它们的制备方法及其在防治害虫中的用途。

47. 发明授权

US3950308A Crosslinked polymers containing siloxane groups 失效
标题翻译：交联聚硅氧烷聚合物
公开(公告)号：US3950308A
公开(公告)日：1976-04-13
申请号：US473022
申请日：1974-05-24
申请人： Gerd Greber , Roland Darms , Dieter Lohmann
发明人： Gerd Greber , Roland Darms , Dieter Lohmann
IPC分类号： C08G69/00 , B32B17/04 , C08G69/42 , C08G69/48 , C08G73/00 , C08G73/10 , C08G73/14 , C08G77/00 , C08G77/42 , C08J5/24 , C08L77/00 , C08L79/08 , C08G77/04
CPC分类号： C08G69/42 , C08G73/106
摘要： New crosslinked polyamides, polyimides and polyamide-imides, containing siloxane groups, are described, which are obtainable by heating silicon-modified polyamide, polyamide-acid and polyamide-amide-acid prepolymers in the presence of silanediols or siloxanediols to temperatures between 50.degree. and 350.degree.C. The crosslinked polymers, containing siloxane groups, according to the invention are distinguished by good mechanical, thermal and electrical properties.

48. 发明授权

US08071696B2 Amphiphilic block copolymers 有权
标题翻译：两亲嵌段共聚物
公开(公告)号：US08071696B2
公开(公告)日：2011-12-06
申请号：US13095954
申请日：2011-04-28
申请人： Thomas Hirt , Jacalyn Marie Schremmer , Troy Vernon Holland , Dieter Lohmann
发明人： Thomas Hirt , Jacalyn Marie Schremmer , Troy Vernon Holland , Dieter Lohmann
IPC分类号： C08G77/38
CPC分类号： C08G77/42
摘要： The invention relates to novel crosslinkable copolymers of formula wherein the variables are as defined in the claims. The copolymers of the invention are especially useful for the manufacture of biomedical moldings, for example ophthalmic moldings such as in particular contact lenses.
摘要翻译：本发明涉及新的可交联共聚物，其中变量如权利要求中所定义。本发明的共聚物特别可用于制造生物医学模制品，例如眼用模制品，例如隐形眼镜。

49. 发明申请

US20090046242A1 Extended Wear Ophthalmic Lens 审中-公开
标题翻译：延长佩戴眼科镜片
公开(公告)号：US20090046242A1
公开(公告)日：2009-02-19
申请号：US12252397
申请日：2008-10-16
申请人： Paul Clement Nicolson , Richard Carlton Baron , Peter Chabrecek , John Court , Angelika Domschke , Hans Jorge Griesser , Arthur Ho , Jens Hopken , Bronwyn Glenice Laycock , Qin Liu , Dieter Lohmann , Gordon Francis Meijs , Eric Papaspiliotopoulos , Judy Smith Riffle , Klaus Schindhelm , Deborah Sweeney , Wilson Leonard Terry, JR. , Jurgen Vogt , Lynn Cook Winterton
发明人： Paul Clement Nicolson , Richard Carlton Baron , Peter Chabrecek , John Court , Angelika Domschke , Hans Jorge Griesser , Arthur Ho , Jens Hopken , Bronwyn Glenice Laycock , Qin Liu , Dieter Lohmann , Gordon Francis Meijs , Eric Papaspiliotopoulos , Judy Smith Riffle , Klaus Schindhelm , Deborah Sweeney , Wilson Leonard Terry, JR. , Jurgen Vogt , Lynn Cook Winterton
IPC分类号： G02C7/04
CPC分类号： G02B1/043 , A61L27/26 , B29C39/42 , B29C71/00 , B29L2011/0041 , C08G18/10 , C08G18/4833 , C08G18/5015 , C08G18/61 , C08G18/672 , C08G18/8116 , C08G18/8175 , C08L43/04 , C08L75/04 , C08L51/085 , C08L2666/20 , C08L51/08 , C08L83/04 , C08L33/00 , C08G18/63 , C08G18/48
摘要： An ophthalmic lens suited for extended-wear periods of at least one day on the eye without a clinically significant amount of corneal swelling and without substantial wearer discomfort. In one embodiment, an opthalmic lens is a copolymerization product of at least one oxyperm, at least one ionoperm, and a crosslinker. In one embodiment, a lens has a tensile modulus of less than about 3.0 MPa, yet in another embodiment, the tensile modulus is between about 0.5 to about 1.5 MPa.
摘要翻译：一种适用于眼睛延长磨损期至少一天的眼科镜片，没有临床显着量的角膜肿胀，并且没有实质的佩戴者不适。在一个实施方案中，眼用透镜是至少一种氧精，至少一种离子交换剂和交联剂的共聚产物。在一个实施方案中，透镜的拉伸模量小于约3.0MPa，而在另一个实施方案中，拉伸模量为约0.5至约1.5MPa。

50. 发明授权

US06835410B2 Bottle-brush type coatings with entangled hydrophilic polymer 有权
标题翻译：带有缠结亲水性聚合物的瓶刷型涂料
公开(公告)号：US06835410B2
公开(公告)日：2004-12-28
申请号：US10142300
申请日：2002-05-09
申请人： Peter Chabrecek , Jörg Leukel , Dieter Lohmann
发明人： Peter Chabrecek , Jörg Leukel , Dieter Lohmann
IPC分类号： A61L2700
CPC分类号： A61L27/34
摘要： The invention relates to a process for coating a material surface comprising the steps of: (a) providing an inorganic or organic bulk material having covalently bound to its surface initiator moieties for radical polymerization; (b) graft polymerizing a hydrophilic ethylenically unsaturated macromonomer from the bulk material surface in the presence of a biocompatible hydrophilic polymer being devoid of polymerizable ethylenically unsaturated groups and thereby entrapping said hydrophilic polymer within the polymer matrix formed by the polymerization of the macromonomer. Composite materials obtainable according to the process of the invention have desirable characteristics regarding adherence to the substrate, durability, hydrophilicity, wettability, biocompatibility and permeability and are thus useful for the manufacture of biomedical articles such as ophthalmic devices.
摘要翻译：本发明涉及一种用于涂覆材料表面的方法，包括以下步骤：（a）提供与其表面引发剂部分共价结合的无机或有机本体材料用于自由基聚合;（b）将亲水烯属不饱和大分子单体从在生物相容性亲水性聚合物存在下，不存在可聚合的烯键式不饱和基团，从而将所述亲水性聚合物包埋在通过大分子单体聚合形成的聚合物基质中。根据本发明方法可获得的复合材料具有关于对基材的粘附性，耐久性，亲水性，润湿性，生物相容性和渗透性，因此可用于制造诸如眼科装置的生物医学制品。

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