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1. 发明授权

US4605712A Unsaturated polysiloxanes and polymers thereof 失效
标题翻译：不饱和聚硅氧烷及其聚合物
公开(公告)号：US4605712A
公开(公告)日：1986-08-12
申请号：US653416
申请日：1984-09-24
申请人： Karl F. Mueller , Dieter Lohmann , Robert A. Falk
发明人： Karl F. Mueller , Dieter Lohmann , Robert A. Falk
IPC分类号： C08F299/00 , C08F290/00 , C08F290/14 , C08F299/08 , C08G18/61 , C08G18/81 , C08G77/00 , C08G77/20 , C08G77/26 , C08G77/28 , C08G77/38 , C08G77/388 , C08G77/46 , C08G77/54 , C08L83/07 , C08L83/08 , C08L83/12 , G02B1/04 , G02C7/04 , C08F283/00
CPC分类号： G02B1/043 , C08F290/148 , C08F299/08 , C08G18/61 , C08G18/8108 , C08G18/8158 , C08G77/388 , C08G77/54
摘要： Polysiloxanes of uniform molecular weight (MW) distribution with 500-10,000 MW segments of polysiloxane and containing at least one vinyl group connected to said polysiloxane segments through intervening alkylene-urea or -urethane linkages are prepared from polysiloxane-polyols, -polyamines or -polythiols by reaction with an unsaturated compound containing an isocyanato moiety, for example 2-isocyanatoethyl methacrylate. The polysiloxanes containing the vinyl groups are useful as radiation- or thermally curable coatings for glass, textiles, plastics, wood, ceramics, metals, as films or bandages for medicinal purposes, or molded shapes, in form of contact lenses, catheters or implants, either by themselves or in combination with other vinyl monomers; and are particularly useful in preparing hard or soft contact lenses, including hydrogel contact lenses.
摘要翻译：由聚硅氧烷 - 多元醇，聚胺或聚硫醇制备具有500-10,000MW聚硅氧烷链段并含有至少一个通过插入的亚烷基 - 脲或 - 氨基键连接到所述聚硅氧烷链段上的乙烯基的分子量（MW）分布的聚硅氧烷通过与含有异氰酸酯基的不饱和化合物反应，例如甲基丙烯酸2-异氰酸根合乙酯。含有乙烯基的聚硅氧烷可用作玻璃，纺织品，塑料，木材，陶瓷，金属，作为药物用薄膜或绷带或隐形眼镜，导管或植入物形式的模制形状的辐射或热固化涂层，本身或与其它乙烯基单体组合; 并且特别可用于制备包括水凝胶隐形眼镜的硬或软性隐形眼镜。

2. 发明授权

US5459222A UV-absorbing polyurethanes and polyesters 失效
标题翻译：紫外线吸收聚氨酯和聚酯
公开(公告)号：US5459222A
公开(公告)日：1995-10-17
申请号：US73227
申请日：1993-06-04
申请人： Juliana Rodgers , Istvan Borsody , Athanasios Karydas , Robert A. Falk , Karl F. Mueller , Michele Kovaleski
发明人： Juliana Rodgers , Istvan Borsody , Athanasios Karydas , Robert A. Falk , Karl F. Mueller , Michele Kovaleski
IPC分类号： C07C225/16 , C07D249/20 , C08G18/32 , C08G18/38 , C08G18/50 , C08G18/65 , C08G63/685 , C09K3/00 , C08G18/28
CPC分类号： C07D249/20 , C07C225/16 , C08G18/329 , C08G18/3293 , C08G18/3851 , C08G63/6854 , Y10T428/31551 , Y10T428/31558 , Y10T428/31591
摘要： Polyurethanes and polyesters are described which are the reaction products of an aromatic, aliphatic or cycloaliphatic diisocyanate, or of a diacid or diacid derivative respectively, with a diol containing a pendent UV-absorbing moiety, optionally also with one or more other diols or diamines. These UV-absorbing polycondensates can be applied to the surfaces of substrates by exhaustion methods or by spraying and act to protect polymers and dyes from degradation by UV radiation. They are therefore useful, either alone or in combination with other coating materials, for the treatment of wood, paper, textiles, leather or other surfaces which are exposed to degrading radiation.
摘要翻译：描述了分别是芳族，脂族或脂环族二异氰酸酯，或二酸或二酸衍生物与含有侧链紫外线吸收部分的二醇，任选地还含有一种或多种其它二醇或二胺的反应产物的聚氨酯和聚酯。这些UV吸收性缩聚物可以通过耗尽方法或通过喷雾施加到基材的表面上，并且用于保护聚合物和染料免受UV辐射的降解。因此，它们单独使用或与其它涂料组合用于处理暴露于降解辐射的木材，纸张，纺织品，皮革或其他表面。

3. 发明授权

US4266080A Perfluoroalkylthioethyl ether derivatives 失效
标题翻译：全氟烷基硫代乙醚衍生物
公开(公告)号：US4266080A
公开(公告)日：1981-05-05
申请号：US874714
申请日：1978-02-02
申请人： Robert A. Falk , Karl F. Mueller
发明人： Robert A. Falk , Karl F. Mueller
IPC分类号： C09K3/18 , A01N25/30 , A01N31/02 , A01N37/12 , A01N37/44 , A61L2/18 , B01F17/16 , B01F17/18 , B01F17/42 , C02F1/40 , C07C67/00 , C07C313/00 , C07C323/12 , C09C3/08 , C09K3/00 , C09K3/32 , C11D1/00 , C11D1/62 , C07C149/18 , C07C149/36
CPC分类号： C11D1/004 , C07C323/00 , Y10S516/02
摘要： Perfluoroalkyl compounds containing ether groups have the formulaR.sub.f R.sub.1 SCH.sub.2 CH.sub.2 O T Zwherein R.sub.f is a perfluoroalkyl, R.sub.1 is alkylene or alkyleneoxy or aminoalkylene, T is alkylene, and Z is hydrogen; hydroxy; NR.sub.3 R.sub.4, where R.sub.3 and R.sub.4 each is alkyl or together with nitrogen form a heterocyclic ring; N.sup.+ R.sub.3 R.sub.4 (R.sub.5)X.sub.z.sup.-y, where R.sub.5 is hydrogen, oxide, alkyl, or substituted alkyl, X is an anion, and y is 1 or 2; z is 0 or 1 or is --OCH.sub.2 CH.sub.2 SR.sub.1 R.sub.f ; can be prepared directly by free-radical catalyzed addition of a perfluoroalkylthiol to a vinyl ether or subsequent reaction. These compounds are useful as surfactants and oil spill collecting agents.
摘要翻译：含有醚基的全氟烷基化合物具有式RfR1SCH2CH2O TZ，其中Rf是全氟烷基，R1是亚烷基或亚烷氧基或氨基亚烷基，T是亚烷基，Z是氢; 羟基; NR 3 R 4，其中R 3和R 4各自为烷基或与氮一起形成杂环; N + R3R4（R5）Xz-y，其中R5是氢，氧化物，烷基或取代的烷基，X是阴离子，y是1或2; z为0或1或为-OCH2CH2SR1Rf; 可直接通过自由基催化加成全氟烷基硫醇至乙烯基醚或随后的反应制备。这些化合物可用作表面活性剂和漏油收集剂。

4. 发明授权

US08320585B2 Radio with dual sided audio 有权
标题翻译：收音机带双面音频
公开(公告)号：US08320585B2
公开(公告)日：2012-11-27
申请号：US11672630
申请日：2007-02-08
申请人： Deborah A. Gruenhagen , Javier Alfaro , Karl F. Mueller , David M. Yeager
发明人： Deborah A. Gruenhagen , Javier Alfaro , Karl F. Mueller , David M. Yeager
IPC分类号： H03G5/00
CPC分类号： H04R1/225 , H04R2430/01
摘要： A dual-sided radio (100) for enhancing a user's experience is provided. The radio includes a primary transducer (110) on an audio-side of the radio that projects a primary sound, a secondary transducer (120) on a data-side of the radio that projects a mid-high frequency sound, a processor (160) that equalizes (200) audio to the primary transducer and the secondary transducer, and a communication module (130) that receives and transmits communication signals containing the audio. The secondary transducer supplements the primary sound with a mid-high frequency sound (404) to compensate for mid-high frequency loss of the primary sound due to diffraction (300).
摘要翻译：提供了用于增强用户体验的双面无线电（100）。无线电装置包括在无线电的音频侧投影主声音的主要换能器（110），投射中高频声音的无线电台的数据侧的次级换能器（120），处理器（160）），其将（200）音频与所述主换能器和所述次级换能器相等，以及通信模块（130），其接收并发送包含所述音频的通信信号。辅助传感器用中高频声音（124）补充主声，以补偿由于衍射（300）导致的主要声音的中高频率损失。

5. 发明授权

US5426158A Crosslinked siloxane-urethane polymer contact lens 失效
标题翻译：交联硅氧烷 - 聚氨酯聚合物隐形眼镜
公开(公告)号：US5426158A
公开(公告)日：1995-06-20
申请号：US227481
申请日：1994-04-14
申请人： Karl F. Mueller , Paul Harisiades
发明人： Karl F. Mueller , Paul Harisiades
IPC分类号： G02C7/04 , C08G18/61 , C08L75/04 , G02B1/04 , C08F283/04
CPC分类号： C08G18/61 , G02B1/043 , C08G2270/00 , Y10S525/903
摘要： A contact lens is described which is synthesized by reaction in a mold of a isocyanate capped poly(dialkylsiloxane) prepolymer with a poly(dialkylsiloxane) di- or polyalkanol. The clear polyurethane rubber contact lens is readily made completely wettable by a transfer-grafting process or post-treatment and has a high oxygen permeability.
摘要翻译：描述了通过在异氰酸酯封端的聚（二烷基硅氧烷）预聚物的模具中与聚（二烷基硅氧烷）二 - 或聚链烷醇反应合成的隐形眼镜。透明聚氨酯橡胶隐形眼镜易于通过转移接枝方法或后处理完全润湿，并且具有高的透氧性。

6. 发明授权

US5104954A Thermostropic biphilic hydrogels and hydroplastics 失效
标题翻译：恒温双相水凝胶和水塑料
公开(公告)号：US5104954A
公开(公告)日：1992-04-14
申请号：US620223
申请日：1990-11-29
申请人： Karl F. Mueller
发明人： Karl F. Mueller
IPC分类号： C08F220/18 , C08F220/54 , C09K9/02
CPC分类号： C08F220/54 , C08F220/18 , C09K9/02
摘要： Novel hydrogels and hydroplastics are described which exhibit temperature dependent, reversible phase separations and clear-opaque transitions between 1.degree. and 100.degree. C. These materials consist of linear or crosslinked random copolymers of N,N-dimethylacrylamide with alkyl- and alkoxyalkyl acrylates. The water solubility and water swelling of these polymers is extremely temperature dependent; they show sharply defined clear to opaque transitions in their water swollen state and as soluble polymers shown Lower Critical Solution Temperatures (LCST). They are useful in drug delivery systems, absorption and extraction processes and as qualitative thermometers, thermosensors and self-activating sunscreens, for example in greenhouses.
摘要翻译：描述了新的水凝胶和水塑料，其显示温度依赖性，可逆相分离和在1℃和100℃之间的透明不透明转变。这些材料由N，N-二甲基丙烯酰胺与丙烯酸烷基酯和烷氧基烷基酯的线性或交联的无规共聚物组成。这些聚合物的水溶性和水溶胀是非常温度的; 它们在其水溶胀状态下显示出清晰明确的不透明转变，并且可溶性聚合物显示出较低的临界溶液温度（LCST）。它们在药物递送系统，吸收和提取过程以及定性温度计，热敏机和自激活防晒剂中是有用的，例如在温室中。

7. 发明授权

US4954587A Dimethylacrylamide-copolymer hydrogels with high oxygen permeability 失效
标题翻译：具有高透氧性的二甲基丙烯酰胺共聚物水凝胶
公开(公告)号：US4954587A
公开(公告)日：1990-09-04
申请号：US356801
申请日：1989-05-23
申请人： Karl F. Mueller
发明人： Karl F. Mueller
IPC分类号： A61L26/00 , A61L27/16 , A61L27/52 , C08F220/22 , C08F220/54 , G02B1/04
CPC分类号： C08F220/54 , A61L26/0014 , A61L26/008 , A61L27/16 , A61L27/52 , C08F220/22 , G02B1/043
摘要： This invention describes polymers which are obtained by copolymerization of 15-85 wt % N,N-dimethylacrylamide with about 15-85% of a fluorinated monomer such as perfluoroalkyl-alkylene acrylate or methacrylate with from 3 to 25 fluorine atoms and optionally, 0-50 wt % other acrylates or methacrylates and 0-20 wt %, but not more than 5 mol % of a polyvinyl functional crosslinking agent. These polymers are machinable in the dry state and form clear hydrogels with about 25-75 wt % water content and which possess oxygen-permeabilities 3-7 times higher than conventional hydrogels of similar water content. In the absence of crosslinking, the novel polymers are plasticized by water, forming clear hydroplastics with 30-70 wt % water content. The crosslinked polymers are especially useful for fabricating contact lenses for extended wear by either cutting and polishing a xerogel button, or by spin casting or direct molding in bulk or in solution.
摘要翻译：本发明描述了通过使15-85重量％的N，N-二甲基丙烯酰胺与约15-85重量％的含氟单体如全氟烷基 - 亚烷基丙烯酸酯或甲基丙烯酸酯与3-25个氟原子和任选的0- 50重量％的其它丙烯酸酯或甲基丙烯酸酯和0-20重量％，但不超过5摩尔％的聚乙烯基官能交联剂。这些聚合物可在干燥状态下加工，并形成具有约25-75％（重量）水含量的透明水凝胶，并具有相似水含量的常规水凝胶的3-7倍的透氧性。在没有交联的情况下，新型聚合物被水塑化，形成具有30-70重量％含水量的透明水塑料。交联聚合物特别适用于通过切割和抛光干凝胶按钮来制造用于延长磨损的隐形眼镜，或通过旋转浇铸或大量或溶液中的直接模塑来制造。

8. 发明授权

US4171282A Fluorinated nonionic surfactants 失效
标题翻译：氟化非离子表面活性剂
公开(公告)号：US4171282A
公开(公告)日：1979-10-16
申请号：US858218
申请日：1977-12-07
申请人： Karl F. Mueller
发明人： Karl F. Mueller
IPC分类号： B01F17/38 , B23K35/36 , C08G63/688 , C08G65/332 , C08G65/334 , C08G65/338 , C08G77/382 , B01F17/36 , C07C69/40
CPC分类号： B23K35/3612 , C08G63/6884 , C08G65/332 , C08G65/3342 , C08G65/338 , C08G77/382
摘要： The perfluoroalkylthio-substituted half esters and amides of succinic acid having the formula ##STR1## wherein R.sub.f is a perfluoroalkyl, R.sup.1 alkylene optionally interrupted with oxygen, sulfur or nitrogen atom, X is oxygen or NH, y is zero or 1, Q is a polyether or polyester diradical moiety having a molecular weight of 300 to 5000 or a polysiloxane having 5 to 80 repeating units and A is hydrogen, hydroxyl, amino, alkoxy of 1 to 21 carbons, phenoxy, alkylphenoxy of 7 to 20 carbons, dialkylamino where each alkyl has 1 to 18 carbons or the group ##STR2## said compounds being prepared by first reacting maleic anhydride with a polyether, polyester, diamine or a polysiloxane derivative of an alcohol or a primary amine and then reacting the product with a perfluoroalkyl alkylene thiol. The novel compounds are useful as surfactants with specific applications as wetting agents in coatings, waxes, emulsions, paints and resins.
摘要翻译：具有式“IMAGE”的琥珀酸的全氟烷硫基取代的半酯和酰胺，其中Rf是全氟烷基，任选被氧，硫或氮原子间隔的R 1亚烷基，X是氧或NH，y是0或1，Q是分子量为300〜5000的聚醚或聚酯二元部分或具有5〜80个重复单元的聚硅氧烷，A为氢，羟基，氨基，1〜21个碳的烷氧基，苯氧基，7〜20个碳的烷基苯氧基，烷基具有1至18个碳或“IMAGE”组，所述化合物通过首先使马来酸酐与醇或伯胺的聚醚，聚酯，二胺或聚硅氧烷衍生物反应制备，然后使产物与全氟烷基亚烷基硫醇反应。新型化合物可用作具有特殊用途的表面活性剂，作为涂料，蜡，乳液，油漆和树脂中的润湿剂。

9. 发明申请

US20070297629A1 METHOD AND SYSTEM FOR EQUAL ACOUSTICS PORTING 有权
标题翻译：用于平等声学分析的方法和系统
公开(公告)号：US20070297629A1
公开(公告)日：2007-12-27
申请号：US11426780
申请日：2006-06-27
申请人： Shlomo Gelbart , Deborah A. Gruenhagen , Karl F. Mueller
发明人： Shlomo Gelbart , Deborah A. Gruenhagen , Karl F. Mueller
IPC分类号： H04R1/02 , H04R1/20
CPC分类号： H04R1/345 , H04R1/403 , H04R2499/11
摘要： A device (300) and method (600) for equal audio porting is provided. The device can include a first side with at least one first audio port (182) providing a data communication aspect, a second side with at least one second audio port (184) providing an audio communication aspect, and a transducer (110) positioned between the first side and the second side. The transducer projects sound out of the at least one first audio port and the at least one second audio port such that a quality of the sound through the at least one first audio port and the at least one second audio port are substantially the same.
摘要翻译：提供了用于相同音频端口的设备（300）和方法（600）。设备可以包括具有提供数据通信方面的至少一个第一音频端口（182）的第一侧，具有提供音频通信方面的至少一个第二音频端口（184）的第二侧和位于第一面和第二面。所述传感器从所述至少一个第一音频端口和所述至少一个第二音频端口发出声音，使得通过所述至少一个第一音频端口和所述至少一个第二音频端口的声音的质量基本相同。

10. 发明授权

US5525732A Poly-perfluoroalkyl-substituted alcohols and acids, and derivatives thereof 失效
公开(公告)号：US5525732A
公开(公告)日：1996-06-11
申请号：US455506
申请日：1995-05-31
申请人： Marlon Haniff , Robert Falk , Ted Deisenroth , Karl F. Mueller
发明人： Marlon Haniff , Robert Falk , Ted Deisenroth , Karl F. Mueller
IPC分类号： C07D211/06 , C07B61/00 , C07C43/12 , C07C43/17 , C07C43/178 , C07C43/23 , C07C217/08 , C07C217/28 , C07C229/12 , C07C229/16 , C07C229/24 , C07C271/20 , C07C305/10 , C07C305/14 , C07C323/12 , C07C323/14 , C07F9/09 , C07F9/6574 , C08G18/32 , C08G18/38 , C08G18/67 , C08G18/73 , C08G18/75 , C09K3/18 , C14C9/00 , D06M15/507 , D06M15/576 , D21H21/16 , C07C305/16
CPC分类号： C07C43/178 , C07C217/28 , C07C229/12 , C07C229/16 , C07C229/24 , C07C271/20 , C07C305/10 , C07C323/12 , C07F9/65742 , C08G18/3275 , C08G18/3812 , C08G18/6775 , C08G18/73 , C08G18/751 , C14C9/00 , D06M15/507 , D06M15/576 , D21H21/16
摘要： Di-, tri- and poly-perfluoroalkyl-substituted alcohols and acids and derivatives thereof are described which are prepared from perfluoroalkyl iodides and di-, tri- or polyallyl alcohols or acids. These compounds contain two or more perfluoroalkyl-iodoalkyl or perfluoroalkyl-alkenyl groups and one or two alcohol or acid groups or derivatized alcohol or acid functions. They can be reacted with isocyanates, epoxy compounds, anhydrides, acids or acid derivatives to prepare a great variety of oil- and water-repellent compositions which are useful for oil- and water-repellent treatment of textiles, glass, paper, leather and other substrates.

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